RU2479592C2 - Битумно-полимерная композиция с термообратимой сшивкой - Google Patents
Битумно-полимерная композиция с термообратимой сшивкой Download PDFInfo
- Publication number
- RU2479592C2 RU2479592C2 RU2010101682/05A RU2010101682A RU2479592C2 RU 2479592 C2 RU2479592 C2 RU 2479592C2 RU 2010101682/05 A RU2010101682/05 A RU 2010101682/05A RU 2010101682 A RU2010101682 A RU 2010101682A RU 2479592 C2 RU2479592 C2 RU 2479592C2
- Authority
- RU
- Russia
- Prior art keywords
- polymer
- bitumen
- grafted
- composition according
- polymer composition
- Prior art date
Links
- 229920000642 polymer Polymers 0.000 title claims abstract description 190
- 239000000203 mixture Substances 0.000 title claims abstract description 109
- 239000010426 asphalt Substances 0.000 claims abstract description 68
- 150000001993 dienes Chemical class 0.000 claims abstract description 47
- 229920000578 graft copolymer Polymers 0.000 claims abstract description 46
- 239000000178 monomer Substances 0.000 claims abstract description 38
- 238000000034 method Methods 0.000 claims abstract description 20
- 125000003396 thiol group Chemical group [H]S* 0.000 claims abstract description 19
- 125000004432 carbon atom Chemical group C* 0.000 claims abstract description 9
- 229930195734 saturated hydrocarbon Natural products 0.000 claims abstract description 7
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims description 58
- 229920002554 vinyl polymer Polymers 0.000 claims description 21
- 238000004519 manufacturing process Methods 0.000 claims description 17
- 150000002430 hydrocarbons Chemical group 0.000 claims description 15
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 14
- 239000011384 asphalt concrete Substances 0.000 claims description 10
- 238000000576 coating method Methods 0.000 claims description 10
- 238000003756 stirring Methods 0.000 claims description 10
- 239000011230 binding agent Substances 0.000 claims description 9
- 238000011065 in-situ storage Methods 0.000 claims description 9
- 238000011066 ex-situ storage Methods 0.000 claims description 8
- 229930195733 hydrocarbon Natural products 0.000 claims description 8
- 239000004215 Carbon black (E152) Substances 0.000 claims description 6
- 239000000654 additive Substances 0.000 claims description 6
- 125000003118 aryl group Chemical group 0.000 claims description 6
- 238000007334 copolymerization reaction Methods 0.000 claims description 6
- 238000002156 mixing Methods 0.000 claims description 6
- 238000006243 chemical reaction Methods 0.000 claims description 5
- 239000000839 emulsion Substances 0.000 claims description 5
- 230000003993 interaction Effects 0.000 claims description 5
- 238000010276 construction Methods 0.000 abstract description 7
- 239000000126 substance Substances 0.000 abstract description 6
- 239000000463 material Substances 0.000 abstract description 3
- 230000000694 effects Effects 0.000 abstract description 2
- 125000001183 hydrocarbyl group Chemical group 0.000 abstract 1
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 28
- 238000004132 cross linking Methods 0.000 description 26
- 229910052717 sulfur Inorganic materials 0.000 description 15
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 11
- 150000001298 alcohols Chemical class 0.000 description 11
- 238000006116 polymerization reaction Methods 0.000 description 11
- 230000002441 reversible effect Effects 0.000 description 11
- 125000004434 sulfur atom Chemical group 0.000 description 9
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical group [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 8
- 150000008065 acid anhydrides Chemical class 0.000 description 8
- 229920001577 copolymer Polymers 0.000 description 8
- 125000004430 oxygen atom Chemical group O* 0.000 description 8
- 150000001408 amides Chemical class 0.000 description 7
- 150000001412 amines Chemical class 0.000 description 7
- 150000001735 carboxylic acids Chemical class 0.000 description 7
- 150000002148 esters Chemical class 0.000 description 7
- 239000011593 sulfur Substances 0.000 description 7
- 229920001897 terpolymer Polymers 0.000 description 7
- SDJHPPZKZZWAKF-UHFFFAOYSA-N 2,3-dimethylbuta-1,3-diene Chemical compound CC(=C)C(C)=C SDJHPPZKZZWAKF-UHFFFAOYSA-N 0.000 description 6
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 6
- 239000005977 Ethylene Substances 0.000 description 6
- 150000002924 oxiranes Chemical class 0.000 description 6
- 230000015572 biosynthetic process Effects 0.000 description 5
- 238000002425 crystallisation Methods 0.000 description 5
- 230000008025 crystallization Effects 0.000 description 5
- 239000010410 layer Substances 0.000 description 5
- 229910052698 phosphorus Inorganic materials 0.000 description 5
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical compound CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 description 4
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 4
- 125000003277 amino group Chemical group 0.000 description 4
- 229920006037 cross link polymer Polymers 0.000 description 4
- 238000004821 distillation Methods 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- 238000012545 processing Methods 0.000 description 4
- PMJHHCWVYXUKFD-SNAWJCMRSA-N (E)-1,3-pentadiene Chemical compound C\C=C\C=C PMJHHCWVYXUKFD-SNAWJCMRSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 239000005062 Polybutadiene Substances 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- YACLQRRMGMJLJV-UHFFFAOYSA-N chloroprene Chemical compound ClC(=C)C=C YACLQRRMGMJLJV-UHFFFAOYSA-N 0.000 description 3
- -1 divinyl ester Chemical class 0.000 description 3
- VOZRXNHHFUQHIL-UHFFFAOYSA-N glycidyl methacrylate Chemical compound CC(=C)C(=O)OCC1CO1 VOZRXNHHFUQHIL-UHFFFAOYSA-N 0.000 description 3
- 238000005470 impregnation Methods 0.000 description 3
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 3
- PMJHHCWVYXUKFD-UHFFFAOYSA-N piperylene Natural products CC=CC=C PMJHHCWVYXUKFD-UHFFFAOYSA-N 0.000 description 3
- 229920002857 polybutadiene Polymers 0.000 description 3
- 229920001195 polyisoprene Polymers 0.000 description 3
- AHAREKHAZNPPMI-AATRIKPKSA-N (3e)-hexa-1,3-diene Chemical compound CC\C=C\C=C AHAREKHAZNPPMI-AATRIKPKSA-N 0.000 description 2
- HLOUDBQOEJSUPI-UHFFFAOYSA-N 1-ethenyl-2,3-dimethylbenzene Chemical compound CC1=CC=CC(C=C)=C1C HLOUDBQOEJSUPI-UHFFFAOYSA-N 0.000 description 2
- NVZWEEGUWXZOKI-UHFFFAOYSA-N 1-ethenyl-2-methylbenzene Chemical compound CC1=CC=CC=C1C=C NVZWEEGUWXZOKI-UHFFFAOYSA-N 0.000 description 2
- WAEOXIOXMKNFLQ-UHFFFAOYSA-N 1-methyl-4-prop-2-enylbenzene Chemical group CC1=CC=C(CC=C)C=C1 WAEOXIOXMKNFLQ-UHFFFAOYSA-N 0.000 description 2
- QEDJMOONZLUIMC-UHFFFAOYSA-N 1-tert-butyl-4-ethenylbenzene Chemical compound CC(C)(C)C1=CC=C(C=C)C=C1 QEDJMOONZLUIMC-UHFFFAOYSA-N 0.000 description 2
- IGGDKDTUCAWDAN-UHFFFAOYSA-N 1-vinylnaphthalene Chemical compound C1=CC=C2C(C=C)=CC=CC2=C1 IGGDKDTUCAWDAN-UHFFFAOYSA-N 0.000 description 2
- OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- CTKINSOISVBQLD-UHFFFAOYSA-N Glycidol Chemical compound OCC1CO1 CTKINSOISVBQLD-UHFFFAOYSA-N 0.000 description 2
- 239000002174 Styrene-butadiene Substances 0.000 description 2
- 125000003158 alcohol group Chemical group 0.000 description 2
- 125000005250 alkyl acrylate group Chemical group 0.000 description 2
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 2
- 229920001400 block copolymer Polymers 0.000 description 2
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 description 2
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 2
- 229920005549 butyl rubber Polymers 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 229920000359 diblock copolymer Polymers 0.000 description 2
- HQQADJVZYDDRJT-UHFFFAOYSA-N ethene;prop-1-ene Chemical group C=C.CC=C HQQADJVZYDDRJT-UHFFFAOYSA-N 0.000 description 2
- 230000002427 irreversible effect Effects 0.000 description 2
- 230000035699 permeability Effects 0.000 description 2
- 229920001084 poly(chloroprene) Polymers 0.000 description 2
- 230000000379 polymerizing effect Effects 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- HJWLCRVIBGQPNF-UHFFFAOYSA-N prop-2-enylbenzene Chemical compound C=CCC1=CC=CC=C1 HJWLCRVIBGQPNF-UHFFFAOYSA-N 0.000 description 2
- 239000011115 styrene butadiene Substances 0.000 description 2
- 229920003048 styrene butadiene rubber Polymers 0.000 description 2
- NPLABXZRXCRBPI-UHFFFAOYSA-N 2-methylidene-1,3-dioxepine-4,7-dione Chemical compound C=C1OC(=O)C=CC(=O)O1 NPLABXZRXCRBPI-UHFFFAOYSA-N 0.000 description 1
- JLBJTVDPSNHSKJ-UHFFFAOYSA-N 4-Methylstyrene Chemical compound CC1=CC=C(C=C)C=C1 JLBJTVDPSNHSKJ-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 241000208202 Linaceae Species 0.000 description 1
- 235000004431 Linum usitatissimum Nutrition 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 1
- 229920002367 Polyisobutene Polymers 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- 125000002252 acyl group Chemical group 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- QYMGIIIPAFAFRX-UHFFFAOYSA-N butyl prop-2-enoate;ethene Chemical compound C=C.CCCCOC(=O)C=C QYMGIIIPAFAFRX-UHFFFAOYSA-N 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 239000010779 crude oil Substances 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 229920006245 ethylene-butyl acrylate Polymers 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 150000003948 formamides Chemical group 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- XIAJQOBRHVKGSP-UHFFFAOYSA-N hexa-1,2-diene Chemical compound CCCC=C=C XIAJQOBRHVKGSP-UHFFFAOYSA-N 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 229910052738 indium Inorganic materials 0.000 description 1
- 239000011810 insulating material Substances 0.000 description 1
- 238000010907 mechanical stirring Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000012299 nitrogen atmosphere Substances 0.000 description 1
- JFNLZVQOOSMTJK-KNVOCYPGSA-N norbornene Chemical compound C1[C@@H]2CC[C@H]1C=C2 JFNLZVQOOSMTJK-KNVOCYPGSA-N 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- RPQRDASANLAFCM-UHFFFAOYSA-N oxiran-2-ylmethyl prop-2-enoate Chemical compound C=CC(=O)OCC1CO1 RPQRDASANLAFCM-UHFFFAOYSA-N 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 239000002861 polymer material Substances 0.000 description 1
- 229920000193 polymethacrylate Polymers 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 150000003141 primary amines Chemical class 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000008439 repair process Effects 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 239000002344 surface layer Substances 0.000 description 1
- 238000009864 tensile test Methods 0.000 description 1
- 238000005292 vacuum distillation Methods 0.000 description 1
- 238000004073 vulcanization Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08C—TREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
- C08C19/00—Chemical modification of rubber
- C08C19/04—Oxidation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08C—TREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
- C08C19/00—Chemical modification of rubber
- C08C19/20—Incorporating sulfur atoms into the molecule
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08C—TREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
- C08C19/00—Chemical modification of rubber
- C08C19/22—Incorporating nitrogen atoms into the molecule
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/34—Introducing sulfur atoms or sulfur-containing groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/005—Processes for mixing polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L15/00—Compositions of rubber derivatives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L95/00—Compositions of bituminous materials, e.g. asphalt, tar, pitch
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D195/00—Coating compositions based on bituminous materials, e.g. asphalt, tar, pitch
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2800/00—Copolymer characterised by the proportions of the comonomers expressed
- C08F2800/20—Copolymer characterised by the proportions of the comonomers expressed as weight or mass percentages
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2395/00—Bituminous materials, e.g. asphalt, tar or pitch
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/04—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L53/02—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Civil Engineering (AREA)
- Structural Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Other Resins Obtained By Reactions Not Involving Carbon-To-Carbon Unsaturated Bonds (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR0705367A FR2919298B1 (fr) | 2007-07-24 | 2007-07-24 | Composition bitume/polymere a reticulation thermoreversible. |
| FR0705367 | 2007-07-24 | ||
| PCT/FR2008/001052 WO2009030840A2 (fr) | 2007-07-24 | 2008-07-17 | Composition bitume/polymere a reticulation thermoreversible |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| RU2010101682A RU2010101682A (ru) | 2011-08-27 |
| RU2479592C2 true RU2479592C2 (ru) | 2013-04-20 |
Family
ID=39154336
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RU2010101682/05A RU2479592C2 (ru) | 2007-07-24 | 2008-07-17 | Битумно-полимерная композиция с термообратимой сшивкой |
Country Status (17)
| Country | Link |
|---|---|
| US (1) | US8273809B2 (enExample) |
| EP (1) | EP2178924B1 (enExample) |
| JP (1) | JP2010534262A (enExample) |
| CN (1) | CN101790543B (enExample) |
| CA (1) | CA2694373C (enExample) |
| DK (1) | DK2178924T3 (enExample) |
| ES (1) | ES2388202T3 (enExample) |
| FR (1) | FR2919298B1 (enExample) |
| MA (1) | MA31537B1 (enExample) |
| MX (1) | MX2010000920A (enExample) |
| PL (1) | PL2178924T3 (enExample) |
| PT (1) | PT2178924E (enExample) |
| RU (1) | RU2479592C2 (enExample) |
| TN (1) | TN2010000039A1 (enExample) |
| UA (1) | UA103883C2 (enExample) |
| WO (1) | WO2009030840A2 (enExample) |
| ZA (1) | ZA201000329B (enExample) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2682614C1 (ru) * | 2013-11-14 | 2019-03-19 | Тотал Маркетинг Сервисез | Композиция битум/полимер, обладающая улучшенными низкотемпературными механическими свойствами |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2924121A1 (fr) * | 2007-11-27 | 2009-05-29 | Total France Sa | Composition bitumineuse elastique reticulee de maniere thermoreversible |
| US20120184650A1 (en) * | 2009-02-27 | 2012-07-19 | Arrmaz Products, Lp | Emulsion of a polymer modified asphalt |
| FR2943678B1 (fr) | 2009-03-25 | 2011-06-03 | Total Raffinage Marketing | Polymeres (meth)acryliques de bas poids moleculaire, exempts de composes soufres,metalliques et halogenes et de taux de monomeres residuels faible,leur procede de preparation et leurs utilisations |
| FR2962440B1 (fr) | 2010-07-12 | 2012-08-03 | Total Raffinage Marketing | Procede de preparation de polymeres greffes sans amorceur et sans solvant et compositions bitume/polymere comprenant lesdits polymeres greffes |
| FR2967414B1 (fr) * | 2010-11-12 | 2014-01-24 | Total Raffinage Marketing | Polymeres greffes reticules de maniere thermoreversible |
| FR2984329B1 (fr) * | 2011-12-20 | 2014-11-21 | Total Raffinage Marketing | Polymere greffe et composition bitume/polymere a reticulation thermoreversible contenant un tel polymere |
| JP5682594B2 (ja) * | 2012-05-24 | 2015-03-11 | 横浜ゴム株式会社 | 変性ジエン系ポリマー |
| FR2992653B1 (fr) | 2012-07-02 | 2015-06-19 | Total Raffinage Marketing | Compositions bitumineuses additivees aux proprietes thermoreversibles ameliorees |
| JP6425922B2 (ja) * | 2014-06-13 | 2018-11-21 | 株式会社ブリヂストン | ゴム組成物 |
| JP7110109B2 (ja) * | 2016-03-21 | 2022-08-01 | ビーエーエスエフ ソシエタス・ヨーロピア | 架橋ポリウレタン |
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| US5087652A (en) * | 1989-06-30 | 1992-02-11 | E. I. Du Pont De Nemours And Company | Asphalt blends with chloroprene polymers or copolymers thereof with dichlorobutadiene |
| WO1997014754A1 (fr) * | 1995-10-19 | 1997-04-24 | Elf Antar France | Procede de preparation de composition bitume/elastomere, leur application comme revetement routier |
| RU2103290C1 (ru) * | 1990-05-18 | 1998-01-27 | ЭУРОН С.п.А. | Способ получения битум-полимерных смесей, устойчивых в условиях текучести, используемых в дорожных работах |
| EP1350813A1 (en) * | 2002-04-01 | 2003-10-08 | Rohm And Haas Company | Polymer-modified asphalt |
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| JPS50139135A (enExample) | 1974-04-24 | 1975-11-06 | ||
| JPS5226765B2 (enExample) | 1974-08-09 | 1977-07-15 | ||
| US4045517A (en) | 1975-11-24 | 1977-08-30 | Rohm And Haas Company | Polyacrylic hot melt adhesives |
| FR2376188A1 (fr) | 1976-12-28 | 1978-07-28 | Elf Union | Procede de preparation de compositions de bitumes polymeres |
| FR2429241A1 (fr) | 1978-06-21 | 1980-01-18 | Elf Union | Procede de preparation de compositions bitumineuses mettant en oeuvre une solution mere contenant des polymeres et du soufre |
| JPS5614573A (en) | 1979-07-13 | 1981-02-12 | Kuraray Co Ltd | Preparing hot melt adhesive |
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| EP0072042B1 (en) * | 1981-06-29 | 1986-05-07 | Shell Internationale Researchmaatschappij B.V. | Preformed membrane comprising a bitumen/thermoplastic rubber layer |
| FR2558845B1 (fr) | 1984-01-31 | 1986-05-16 | Atochem | Compositions adhesives a reticulation thermoreversible, leur procede de fabrication et leurs applications |
| DE3412085A1 (de) | 1984-03-31 | 1985-10-17 | Agfa-Gevaert Ag, 5090 Leverkusen | Elektrostatographischer suspensionsentwickler |
| FR2703063A1 (fr) | 1993-03-26 | 1994-09-30 | Elf Antar France | Compositions bitume/polymère non gélifiables et stables au stockage à température élevée, leur procédé de préparation et leur application à la production de liants bitume/polymère pour revêtements. |
| FR2748487B1 (fr) | 1996-05-10 | 1998-07-10 | Elf Antar France | Compositions bitume/polymere a stabilite amelioree et leur application a la realisation de revetements |
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| FR2762322B1 (fr) * | 1997-04-21 | 1999-05-28 | Elf Antar France | Procede de preparation de compositions bitume/polymere, application des compositions obtenues a la production de liants bitume/polymere pour revetements et solution mere de polymere pour l'obtention desdites compositions |
| JP3598764B2 (ja) | 1997-10-08 | 2004-12-08 | 三菱化学株式会社 | オレフィン系樹脂組成物 |
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| JP4180051B2 (ja) | 2002-04-24 | 2008-11-12 | 旭化成ケミカルズ株式会社 | アスファルト組成物 |
| FR2849047B1 (fr) | 2002-12-20 | 2005-12-02 | Totalfinaelf France | Procede de preparation de compositions bitume/polymere a resistance aux solvants petroliers amelioree, compositions ainsi obtenues et leur utilisation comme liant bitumineux |
| FR2849048B1 (fr) | 2002-12-23 | 2005-11-04 | Totalfinaelf France | Procede de preparation de compositions bitume/polymere epoxyde reticule, composition ainsi obtenues et leur utilisation |
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-
2007
- 2007-07-24 FR FR0705367A patent/FR2919298B1/fr not_active Expired - Fee Related
-
2008
- 2008-07-17 US US12/670,382 patent/US8273809B2/en not_active Expired - Fee Related
- 2008-07-17 CA CA2694373A patent/CA2694373C/en not_active Expired - Fee Related
- 2008-07-17 PL PL08829045T patent/PL2178924T3/pl unknown
- 2008-07-17 ES ES08829045T patent/ES2388202T3/es active Active
- 2008-07-17 JP JP2010517440A patent/JP2010534262A/ja not_active Ceased
- 2008-07-17 RU RU2010101682/05A patent/RU2479592C2/ru not_active IP Right Cessation
- 2008-07-17 UA UAA201002035A patent/UA103883C2/uk unknown
- 2008-07-17 MX MX2010000920A patent/MX2010000920A/es active IP Right Grant
- 2008-07-17 EP EP08829045A patent/EP2178924B1/fr not_active Not-in-force
- 2008-07-17 WO PCT/FR2008/001052 patent/WO2009030840A2/fr not_active Ceased
- 2008-07-17 PT PT08829045T patent/PT2178924E/pt unknown
- 2008-07-17 DK DK08829045.7T patent/DK2178924T3/da active
- 2008-07-17 CN CN200880100413XA patent/CN101790543B/zh not_active Expired - Fee Related
-
2010
- 2010-01-18 ZA ZA2010/00329A patent/ZA201000329B/en unknown
- 2010-01-21 MA MA32541A patent/MA31537B1/fr unknown
- 2010-01-22 TN TNP2010000039A patent/TN2010000039A1/fr unknown
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5087652A (en) * | 1989-06-30 | 1992-02-11 | E. I. Du Pont De Nemours And Company | Asphalt blends with chloroprene polymers or copolymers thereof with dichlorobutadiene |
| RU2103290C1 (ru) * | 1990-05-18 | 1998-01-27 | ЭУРОН С.п.А. | Способ получения битум-полимерных смесей, устойчивых в условиях текучести, используемых в дорожных работах |
| WO1997014754A1 (fr) * | 1995-10-19 | 1997-04-24 | Elf Antar France | Procede de preparation de composition bitume/elastomere, leur application comme revetement routier |
| EP1350813A1 (en) * | 2002-04-01 | 2003-10-08 | Rohm And Haas Company | Polymer-modified asphalt |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2682614C1 (ru) * | 2013-11-14 | 2019-03-19 | Тотал Маркетинг Сервисез | Композиция битум/полимер, обладающая улучшенными низкотемпературными механическими свойствами |
| US10377900B2 (en) | 2013-11-14 | 2019-08-13 | Total Marketing Services | Bitumen/polymer composition having improved low-temperature mechanical properties |
Also Published As
| Publication number | Publication date |
|---|---|
| FR2919298B1 (fr) | 2012-06-08 |
| US20100197835A1 (en) | 2010-08-05 |
| US8273809B2 (en) | 2012-09-25 |
| CA2694373C (en) | 2014-06-10 |
| WO2009030840A2 (fr) | 2009-03-12 |
| PL2178924T3 (pl) | 2012-10-31 |
| CN101790543A (zh) | 2010-07-28 |
| RU2010101682A (ru) | 2011-08-27 |
| WO2009030840A3 (fr) | 2009-07-23 |
| MX2010000920A (es) | 2010-04-01 |
| EP2178924A2 (fr) | 2010-04-28 |
| CN101790543B (zh) | 2013-10-23 |
| JP2010534262A (ja) | 2010-11-04 |
| TN2010000039A1 (fr) | 2011-09-26 |
| UA103883C2 (uk) | 2013-12-10 |
| MA31537B1 (fr) | 2010-07-01 |
| PT2178924E (pt) | 2012-07-16 |
| EP2178924B1 (fr) | 2012-06-13 |
| DK2178924T3 (da) | 2012-07-16 |
| ES2388202T3 (es) | 2012-10-10 |
| FR2919298A1 (fr) | 2009-01-30 |
| ZA201000329B (en) | 2010-11-24 |
| CA2694373A1 (en) | 2009-03-12 |
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| MM4A | The patent is invalid due to non-payment of fees |
Effective date: 20200718 |