RU2450968C2 - ТЕХНОЛОГИЧЕСКИЙ РЕЖИМ ДЛЯ Pt-Re БИМЕТАЛЛИЧЕСКИХ КАТАЛИЗАТОРОВ КОНВЕРСИИ ВОДЯНОГО ГАЗА, КАТАЛИЗАТОРЫ - Google Patents
ТЕХНОЛОГИЧЕСКИЙ РЕЖИМ ДЛЯ Pt-Re БИМЕТАЛЛИЧЕСКИХ КАТАЛИЗАТОРОВ КОНВЕРСИИ ВОДЯНОГО ГАЗА, КАТАЛИЗАТОРЫ Download PDFInfo
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- RU2450968C2 RU2450968C2 RU2008128565/05A RU2008128565A RU2450968C2 RU 2450968 C2 RU2450968 C2 RU 2450968C2 RU 2008128565/05 A RU2008128565/05 A RU 2008128565/05A RU 2008128565 A RU2008128565 A RU 2008128565A RU 2450968 C2 RU2450968 C2 RU 2450968C2
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- gas
- catalyst
- water
- temperature
- space velocity
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- 235000012239 silicon dioxide Nutrition 0.000 description 1
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 description 1
- RDHFLXMETKTMPJ-UHFFFAOYSA-J silicon(4+);dicarbonate Chemical class [Si+4].[O-]C([O-])=O.[O-]C([O-])=O RDHFLXMETKTMPJ-UHFFFAOYSA-J 0.000 description 1
- 229910052851 sillimanite Inorganic materials 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052596 spinel Inorganic materials 0.000 description 1
- 239000011029 spinel Substances 0.000 description 1
- 229910052642 spodumene Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 238000000629 steam reforming Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- ZCUFMDLYAMJYST-UHFFFAOYSA-N thorium dioxide Chemical compound O=[Th]=O ZCUFMDLYAMJYST-UHFFFAOYSA-N 0.000 description 1
- 229910003452 thorium oxide Inorganic materials 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 238000000844 transformation Methods 0.000 description 1
- 229910003454 ytterbium oxide Inorganic materials 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052845 zircon Inorganic materials 0.000 description 1
Images
Classifications
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/06—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents
- C01B3/12—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents by reaction of water vapour with carbon monoxide
- C01B3/16—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents by reaction of water vapour with carbon monoxide using catalysts
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/06—Combination of fuel cells with means for production of reactants or for treatment of residues
- H01M8/0606—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants
- H01M8/0612—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants from carbon-containing material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/56—Platinum group metals
- B01J23/64—Platinum group metals with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/656—Manganese, technetium or rhenium
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- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/56—Platinum group metals
- B01J23/64—Platinum group metals with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/656—Manganese, technetium or rhenium
- B01J23/6567—Rhenium
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/024—Multiple impregnation or coating
- B01J37/0242—Coating followed by impregnation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/024—Multiple impregnation or coating
- B01J37/0248—Coatings comprising impregnated particles
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/56—Platinum group metals
- B01J23/64—Platinum group metals with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/652—Chromium, molybdenum or tungsten
- B01J23/6525—Molybdenum
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/02—Processes for making hydrogen or synthesis gas
- C01B2203/0283—Processes for making hydrogen or synthesis gas containing a CO-shift step, i.e. a water gas shift step
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/10—Catalysts for performing the hydrogen forming reactions
- C01B2203/1041—Composition of the catalyst
- C01B2203/1047—Group VIII metal catalysts
- C01B2203/1064—Platinum group metal catalysts
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/10—Catalysts for performing the hydrogen forming reactions
- C01B2203/1041—Composition of the catalyst
- C01B2203/1047—Group VIII metal catalysts
- C01B2203/1064—Platinum group metal catalysts
- C01B2203/107—Platinum catalysts
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M2008/1095—Fuel cells with polymeric electrolytes
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Sustainable Development (AREA)
- Inorganic Chemistry (AREA)
- General Health & Medical Sciences (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Combustion & Propulsion (AREA)
- Sustainable Energy (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Catalysts (AREA)
- Hydrogen, Water And Hydrids (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US11/303,369 | 2005-12-16 | ||
| US11/303,369 US7357911B2 (en) | 2005-12-16 | 2005-12-16 | Process conditions for Pt-Re bimetallic water gas shift catalysts |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| RU2008128565A RU2008128565A (ru) | 2010-01-27 |
| RU2450968C2 true RU2450968C2 (ru) | 2012-05-20 |
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| RU2008128565/05A RU2450968C2 (ru) | 2005-12-16 | 2006-12-04 | ТЕХНОЛОГИЧЕСКИЙ РЕЖИМ ДЛЯ Pt-Re БИМЕТАЛЛИЧЕСКИХ КАТАЛИЗАТОРОВ КОНВЕРСИИ ВОДЯНОГО ГАЗА, КАТАЛИЗАТОРЫ |
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| EP (1) | EP1963009B1 (enExample) |
| JP (1) | JP5702910B2 (enExample) |
| KR (1) | KR101365787B1 (enExample) |
| CN (1) | CN101330973B (enExample) |
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| RU (1) | RU2450968C2 (enExample) |
| WO (1) | WO2007075267A1 (enExample) |
| ZA (1) | ZA200806092B (enExample) |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7871961B2 (en) * | 2006-07-18 | 2011-01-18 | Sud-Chemie Inc. | Catalyst for production of hydrogen and synthesis gas |
| US8119558B2 (en) * | 2008-03-14 | 2012-02-21 | Süd-Chemie Inc. | Ultra high temperature shift catalyst with low methanation |
| US7811474B2 (en) * | 2008-12-04 | 2010-10-12 | Uop Llc | Simultaneous warm gas desulfurization and CO-shift for improved syngas cleanup |
| US8703636B2 (en) | 2009-02-27 | 2014-04-22 | Corning Incorporated | Method of manufacturing a catalyst body by post-impregnation |
| US8658554B2 (en) * | 2009-11-04 | 2014-02-25 | The United States Of America, As Represented By The Secretary Of The Navy | Catalytic support for use in carbon dioxide hydrogenation reactions |
| JP5737853B2 (ja) * | 2010-03-29 | 2015-06-17 | 千代田化工建設株式会社 | 貯蔵・輸送用水素の製造方法 |
| US20140255284A1 (en) * | 2013-03-08 | 2014-09-11 | Basf Corporation | Base Metal Catalyst And Method Of Using Same |
| WO2015120302A1 (en) * | 2014-02-07 | 2015-08-13 | Basf Corporation | Catalyst for pyrolysis of feedstock |
| US11616249B2 (en) | 2019-03-22 | 2023-03-28 | Bloom Energy Corporation | Solid oxide fuel cell system with hydrogen pumping cell with carbon monoxide tolerant anodes and integrated shift reactor |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| SU1482721A1 (ru) * | 1986-12-12 | 1989-05-30 | Предприятие П/Я Р-6603 | Катализатор дл конвенсии оксида углерода |
| EP1161991A1 (en) * | 1999-03-18 | 2001-12-12 | Matsushita Electric Works, Ltd. | Catalyst for water gas shift reaction, method for removing carbon monoxide in hydrogen gas and electric power-generating system of fuel cell |
| RU2281805C1 (ru) * | 2005-07-04 | 2006-08-20 | Институт Катализа Им. Г.К. Борескова Сибирского Отделения Российской Академии Наук | Катализатор и способ паровой конверсии монооксида углерода |
Family Cites Families (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2001003828A1 (en) * | 1999-07-08 | 2001-01-18 | Matsushita Electric Works, Ltd. | Water-gas-shift reaction catalyst, method for removing carbon monoxide in hydrogen gas and fuel cell power generation system |
| JP4096549B2 (ja) * | 2001-01-12 | 2008-06-04 | トヨタ自動車株式会社 | シフト触媒およびシフト触媒の製造方法 |
| WO2002059038A1 (en) * | 2001-01-26 | 2002-08-01 | Matsushita Electric Industrial Co., Ltd. | Hydrogen purification device and fuel cell power generation system |
| US6455182B1 (en) * | 2001-05-09 | 2002-09-24 | Utc Fuel Cells, Llc | Shift converter having an improved catalyst composition, and method for its use |
| JP2003144925A (ja) * | 2001-11-07 | 2003-05-20 | Sud-Chemie Catalysts Inc | 一酸化炭素シフト反応用触媒の製造方法 |
| JP4087621B2 (ja) * | 2002-03-05 | 2008-05-21 | エヌ・イーケムキャット株式会社 | 水素ガス中の一酸化炭素除去用触媒 |
| US20030186804A1 (en) | 2002-03-28 | 2003-10-02 | Sud-Chemie, Inc. | Catalyst for production of hydrogen |
| US6713032B2 (en) * | 2002-04-12 | 2004-03-30 | Matsushita Electric Works, Ltd. | Catalyst for removing carbon monoxide in hydrogen rich gas and production method therefor |
| JP2004000949A (ja) * | 2002-04-12 | 2004-01-08 | Matsushita Electric Works Ltd | 水性ガスシフト反応に基づいて水素リッチガス中のcoを除去するための触媒、同触媒を用いた処理装置、およびその方法 |
| US7682598B2 (en) * | 2002-12-20 | 2010-03-23 | Honda Giken Kogyo Kabushiki Kaisha | Alkali-containing catalyst formulations for low and medium temperature hydrogen generation |
| US6932848B2 (en) * | 2003-03-28 | 2005-08-23 | Utc Fuel Cells, Llc | High performance fuel processing system for fuel cell power plant |
| JP2005034778A (ja) * | 2003-07-16 | 2005-02-10 | Nissan Motor Co Ltd | モノリス触媒 |
| US20050119119A1 (en) * | 2003-12-02 | 2005-06-02 | Rogers David B. | Water gas shift catalyst on a lanthanum-doped anatase titanium dioxide support for fuel cells application |
| WO2007019361A1 (en) * | 2005-08-03 | 2007-02-15 | Genesis Fuel Tech, Inc. | Water-gas shift and reforming catalyst and method of reforming alcohol |
-
2005
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2006
- 2006-12-04 RU RU2008128565/05A patent/RU2450968C2/ru not_active IP Right Cessation
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- 2006-12-04 JP JP2008545636A patent/JP5702910B2/ja not_active Expired - Fee Related
- 2006-12-04 WO PCT/US2006/046229 patent/WO2007075267A1/en not_active Ceased
- 2006-12-04 BR BRPI0619904-6A patent/BRPI0619904B1/pt not_active IP Right Cessation
- 2006-12-04 ES ES06844780.4T patent/ES2467365T3/es active Active
- 2006-12-04 EP EP06844780.4A patent/EP1963009B1/en not_active Not-in-force
- 2006-12-04 KR KR1020087017150A patent/KR101365787B1/ko not_active Expired - Fee Related
- 2006-12-04 CN CN2006800470195A patent/CN101330973B/zh not_active Expired - Fee Related
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2008
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- 2008-07-14 ZA ZA200806092A patent/ZA200806092B/xx unknown
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| SU1482721A1 (ru) * | 1986-12-12 | 1989-05-30 | Предприятие П/Я Р-6603 | Катализатор дл конвенсии оксида углерода |
| EP1161991A1 (en) * | 1999-03-18 | 2001-12-12 | Matsushita Electric Works, Ltd. | Catalyst for water gas shift reaction, method for removing carbon monoxide in hydrogen gas and electric power-generating system of fuel cell |
| RU2281805C1 (ru) * | 2005-07-04 | 2006-08-20 | Институт Катализа Им. Г.К. Борескова Сибирского Отделения Российской Академии Наук | Катализатор и способ паровой конверсии монооксида углерода |
Also Published As
| Publication number | Publication date |
|---|---|
| CN101330973A (zh) | 2008-12-24 |
| CN101330973B (zh) | 2012-10-03 |
| ZA200806092B (en) | 2009-11-25 |
| WO2007075267A1 (en) | 2007-07-05 |
| ES2467365T3 (es) | 2014-06-12 |
| RU2008128565A (ru) | 2010-01-27 |
| JP5702910B2 (ja) | 2015-04-15 |
| KR101365787B1 (ko) | 2014-02-20 |
| US7357911B2 (en) | 2008-04-15 |
| US20070140953A1 (en) | 2007-06-21 |
| KR20080078895A (ko) | 2008-08-28 |
| EP1963009B1 (en) | 2014-04-16 |
| EP1963009A1 (en) | 2008-09-03 |
| CA2629078A1 (en) | 2007-07-05 |
| MX275108B (en) | 2010-04-13 |
| JP2009520660A (ja) | 2009-05-28 |
| BRPI0619904B1 (pt) | 2018-04-10 |
| BRPI0619904A2 (pt) | 2013-01-15 |
| CA2629078C (en) | 2016-03-22 |
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