RU2387637C2 - Способ получения изоцианатов - Google Patents
Способ получения изоцианатов Download PDFInfo
- Publication number
- RU2387637C2 RU2387637C2 RU2004130937/04A RU2004130937A RU2387637C2 RU 2387637 C2 RU2387637 C2 RU 2387637C2 RU 2004130937/04 A RU2004130937/04 A RU 2004130937/04A RU 2004130937 A RU2004130937 A RU 2004130937A RU 2387637 C2 RU2387637 C2 RU 2387637C2
- Authority
- RU
- Russia
- Prior art keywords
- central nozzle
- carbon atoms
- tubular reactor
- fed
- diamines
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims abstract description 29
- 239000012948 isocyanate Substances 0.000 title claims abstract description 7
- 150000002513 isocyanates Chemical class 0.000 title claims abstract description 7
- 230000015572 biosynthetic process Effects 0.000 title abstract description 3
- 238000003786 synthesis reaction Methods 0.000 title abstract 2
- 125000004432 carbon atom Chemical group C* 0.000 claims abstract description 18
- YGYAWVDWMABLBF-UHFFFAOYSA-N Phosgene Chemical compound ClC(Cl)=O YGYAWVDWMABLBF-UHFFFAOYSA-N 0.000 claims abstract description 15
- 150000001412 amines Chemical class 0.000 claims abstract description 9
- 239000000203 mixture Substances 0.000 claims abstract description 8
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 claims abstract description 6
- 125000003277 amino group Chemical group 0.000 claims abstract description 5
- 150000004985 diamines Chemical class 0.000 claims description 12
- NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 claims description 10
- -1 diamines toluylene diamine Chemical class 0.000 claims description 6
- RNLHGQLZWXBQNY-UHFFFAOYSA-N 3-(aminomethyl)-3,5,5-trimethylcyclohexan-1-amine Chemical compound CC1(C)CC(N)CC(C)(CN)C1 RNLHGQLZWXBQNY-UHFFFAOYSA-N 0.000 claims description 5
- 150000004984 aromatic diamines Chemical class 0.000 claims description 5
- SYSQUGFVNFXIIT-UHFFFAOYSA-N n-[4-(1,3-benzoxazol-2-yl)phenyl]-4-nitrobenzenesulfonamide Chemical class C1=CC([N+](=O)[O-])=CC=C1S(=O)(=O)NC1=CC=C(C=2OC3=CC=CC=C3N=2)C=C1 SYSQUGFVNFXIIT-UHFFFAOYSA-N 0.000 claims description 5
- RLYCRLGLCUXUPO-UHFFFAOYSA-N 2,6-diaminotoluene Chemical compound CC1=C(N)C=CC=C1N RLYCRLGLCUXUPO-UHFFFAOYSA-N 0.000 claims description 4
- FZZMTSNZRBFGGU-UHFFFAOYSA-N 2-chloro-7-fluoroquinazolin-4-amine Chemical compound FC1=CC=C2C(N)=NC(Cl)=NC2=C1 FZZMTSNZRBFGGU-UHFFFAOYSA-N 0.000 claims description 4
- DZIHTWJGPDVSGE-UHFFFAOYSA-N 4-[(4-aminocyclohexyl)methyl]cyclohexan-1-amine Chemical compound C1CC(N)CCC1CC1CCC(N)CC1 DZIHTWJGPDVSGE-UHFFFAOYSA-N 0.000 claims description 4
- CNPURSDMOWDNOQ-UHFFFAOYSA-N 4-methoxy-7h-pyrrolo[2,3-d]pyrimidin-2-amine Chemical compound COC1=NC(N)=NC2=C1C=CN2 CNPURSDMOWDNOQ-UHFFFAOYSA-N 0.000 claims description 4
- 125000001931 aliphatic group Chemical group 0.000 claims description 4
- 125000002029 aromatic hydrocarbon group Chemical group 0.000 claims description 4
- 125000005442 diisocyanate group Chemical group 0.000 claims description 4
- VOZKAJLKRJDJLL-UHFFFAOYSA-N 2,4-diaminotoluene Chemical compound CC1=CC=C(N)C=C1N VOZKAJLKRJDJLL-UHFFFAOYSA-N 0.000 claims 2
- 239000003153 chemical reaction reagent Substances 0.000 abstract description 4
- 230000000694 effects Effects 0.000 abstract description 2
- 150000004945 aromatic hydrocarbons Chemical group 0.000 abstract 2
- 239000007792 gaseous phase Substances 0.000 abstract 1
- 239000000126 substance Substances 0.000 abstract 1
- 239000007789 gas Substances 0.000 description 5
- 239000000443 aerosol Substances 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- 238000002474 experimental method Methods 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 239000011261 inert gas Substances 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- GEYOCULIXLDCMW-UHFFFAOYSA-N 1,2-phenylenediamine Chemical class NC1=CC=CC=C1N GEYOCULIXLDCMW-UHFFFAOYSA-N 0.000 description 1
- RHNNQENFSNOGAM-UHFFFAOYSA-N 1,8-diisocyanato-4-(isocyanatomethyl)octane Chemical compound O=C=NCCCCC(CN=C=O)CCCN=C=O RHNNQENFSNOGAM-UHFFFAOYSA-N 0.000 description 1
- MHQULXYNBKWNDF-UHFFFAOYSA-N 3,4-dimethylbenzene-1,2-diamine Chemical class CC1=CC=C(N)C(N)=C1C MHQULXYNBKWNDF-UHFFFAOYSA-N 0.000 description 1
- HMJBXEZHJUYJQY-UHFFFAOYSA-N 4-(aminomethyl)octane-1,8-diamine Chemical compound NCCCCC(CN)CCCN HMJBXEZHJUYJQY-UHFFFAOYSA-N 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 230000004323 axial length Effects 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- ZZTCPWRAHWXWCH-UHFFFAOYSA-N diphenylmethanediamine Chemical class C=1C=CC=CC=1C(N)(N)C1=CC=CC=C1 ZZTCPWRAHWXWCH-UHFFFAOYSA-N 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000012442 inert solvent Substances 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- NTNWKDHZTDQSST-UHFFFAOYSA-N naphthalene-1,2-diamine Chemical class C1=CC=CC2=C(N)C(N)=CC=C21 NTNWKDHZTDQSST-UHFFFAOYSA-N 0.000 description 1
- 229910052754 neon Inorganic materials 0.000 description 1
- GKAOGPIIYCISHV-UHFFFAOYSA-N neon atom Chemical compound [Ne] GKAOGPIIYCISHV-UHFFFAOYSA-N 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- DYFXGORUJGZJCA-UHFFFAOYSA-N phenylmethanediamine Chemical class NC(N)C1=CC=CC=C1 DYFXGORUJGZJCA-UHFFFAOYSA-N 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 238000004904 shortening Methods 0.000 description 1
- 229910052724 xenon Inorganic materials 0.000 description 1
- FHNFHKCVQCLJFQ-UHFFFAOYSA-N xenon atom Chemical compound [Xe] FHNFHKCVQCLJFQ-UHFFFAOYSA-N 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C263/00—Preparation of derivatives of isocyanic acid
- C07C263/10—Preparation of derivatives of isocyanic acid by reaction of amines with carbonyl halides, e.g. with phosgene
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE10349504.5 | 2003-10-23 | ||
| DE10349504A DE10349504A1 (de) | 2003-10-23 | 2003-10-23 | Verfahren zur Herstellung von Isocyanaten in der Gasphase |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| RU2004130937A RU2004130937A (ru) | 2006-04-10 |
| RU2387637C2 true RU2387637C2 (ru) | 2010-04-27 |
Family
ID=34384438
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RU2004130937/04A RU2387637C2 (ru) | 2003-10-23 | 2004-10-22 | Способ получения изоцианатов |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US7754915B2 (enExample) |
| EP (1) | EP1526129B1 (enExample) |
| JP (1) | JP4748966B2 (enExample) |
| KR (1) | KR101050909B1 (enExample) |
| CN (1) | CN100355726C (enExample) |
| AT (1) | ATE471927T1 (enExample) |
| CA (1) | CA2485396C (enExample) |
| DE (2) | DE10349504A1 (enExample) |
| ES (1) | ES2346308T3 (enExample) |
| MX (1) | MXPA04010369A (enExample) |
| PL (1) | PL1526129T3 (enExample) |
| RU (1) | RU2387637C2 (enExample) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2719392C1 (ru) * | 2016-05-25 | 2020-04-17 | Янмар Ко., Лтд. | Термоэлектрическое устройство генерирования мощности и термоэлектрическая система генерирования мощности |
Families Citing this family (46)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102005036870A1 (de) | 2005-08-02 | 2007-02-08 | Bayer Materialscience Ag | Verfahren zur Gasphasenphosgenierung |
| DE102005042392A1 (de) * | 2005-09-06 | 2007-03-08 | Basf Ag | Verfahren zur Herstellung von Isocyanaten |
| DE102005056650A1 (de) * | 2005-11-25 | 2007-05-31 | Behr Gmbh & Co. Kg | Koaxialrohr oder Rohr-in-Rohr-Anordnung, insbesondere für einen Wärmetauscher |
| WO2007145448A2 (en) * | 2006-06-12 | 2007-12-21 | Lg Electronics Inc. | Laundry dryer and method for controlling the same |
| CN101153015B (zh) * | 2006-09-28 | 2010-06-16 | 宁波万华聚氨酯有限公司 | 一种孔射流式反应器及利用该反应器制备异氰酸酯的方法 |
| DE102006058633A1 (de) | 2006-12-13 | 2008-06-19 | Bayer Materialscience Ag | Verfahren zur Herstellung von Isocyanaten in der Gasphase |
| DE102006058634A1 (de) | 2006-12-13 | 2008-06-19 | Bayer Materialscience Ag | Verfahren zur Herstellung von Isocyanaten in der Gasphase |
| WO2008077287A1 (en) * | 2006-12-27 | 2008-07-03 | Ningbo Wanhua Polyurethanes Co. Ltd. | An orifice jet-type injection reactor |
| CN101209405B (zh) | 2006-12-27 | 2013-08-28 | 宁波万华聚氨酯有限公司 | 一种孔射流式喷射反应器 |
| DE102007020444A1 (de) | 2007-04-27 | 2008-11-06 | Bayer Materialscience Ag | Verfahren zur Oxidation eines Chlorwasserstoffenthaltenden Gasgemisches |
| US8558026B2 (en) | 2007-08-30 | 2013-10-15 | Basf Se | Method for producing isocyanates |
| WO2009027234A1 (de) * | 2007-08-30 | 2009-03-05 | Basf Se | Verfahren zur herstellung von isocyanaten |
| DE102007056511A1 (de) | 2007-11-22 | 2009-05-28 | Bayer Materialscience Ag | Verfahren zur Herstellung aromatischer Diisocyanate in der Gasphase |
| CN102317254B (zh) | 2008-07-23 | 2014-11-19 | 巴斯夫欧洲公司 | 制备异氰酸酯的方法 |
| PL2323973T3 (pl) | 2008-08-07 | 2012-08-31 | Basf Se | Sposób wytwarzania aromatycznych izocyjanianów |
| DE102008061686A1 (de) | 2008-12-11 | 2010-06-17 | Bayer Materialscience Ag | Verfahren zur Herstellung von Isocyanaten in der Gasphase |
| DE102008063728A1 (de) | 2008-12-18 | 2010-06-24 | Bayer Materialscience Ag | Verfahren zur Herstellung von Isocyanaten in der Gasphase |
| DE102008063991A1 (de) | 2008-12-19 | 2010-06-24 | Bayer Materialscience Ag | Verfahren zur Herstellung von Isocyanaten in der Gasphase |
| DE102009032413A1 (de) | 2009-07-09 | 2011-01-13 | Bayer Materialscience Ag | Verfahren zur Herstellung von Isocyanaten |
| CN101670263B (zh) * | 2009-09-03 | 2012-11-21 | 天津大学 | 气相法制备甲苯二异氰酸酯的反应器及操作方法 |
| PL2507165T3 (pl) | 2009-12-01 | 2017-10-31 | Chemetics Inc | Sposób obróbki związków siarki |
| WO2012049158A1 (de) * | 2010-10-14 | 2012-04-19 | Basf Se | Verfahren zur herstellung von isocyanaten |
| US9321720B2 (en) | 2010-10-14 | 2016-04-26 | Basf Se | Process for preparing isocyanates |
| PL393216A1 (pl) | 2010-12-10 | 2012-06-18 | Zakłady Chemiczne Zachem Spółka Akcyjna | Sposób otrzymywania toluilenodiizocyjanianu (TDI) poprzez prowadzenia reakcji fosgenowania toluilenodiaminy (TDA) w fazie gazowej oraz urządzenie do otrzymywania toluilenodiizocyjanianu (TDI) poprzez prowadzenie reakcji fosgenowania toluilenodiaminy (TDA) w fazie gazowej |
| PL214498B1 (pl) | 2010-12-10 | 2013-08-30 | Inst Chemii Przemyslowej Im Prof Ignacego Moscickiego | Sposób wydzielania produktów reakcji fosgenowania toluilenodiaminy (TDA) w fazie gazowej przy wytwarzaniu toluilenodiizocyjanianu (TDI) |
| CN103958462B (zh) * | 2011-11-29 | 2016-10-19 | 巴斯夫欧洲公司 | 在气相中通过相应胺的光气化制备异氰酸酯的方法 |
| HUE031803T2 (en) | 2012-07-11 | 2017-08-28 | Covestro Deutschland Ag | Process for processing distillation residues from the production of isocyanate |
| US9932299B2 (en) | 2013-02-08 | 2018-04-03 | Covestro Deutschland Ag | Process for separating an isocyanate prepared by phosgenation of a primary amine in the gas phase from the gaseous crude product of the phosgenation |
| EP2829533A1 (de) | 2013-07-26 | 2015-01-28 | Bayer MaterialScience AG | Verfahren zur herstellung von isocyanaten |
| CN103638893B (zh) * | 2013-12-14 | 2015-04-01 | 甘肃银光聚银化工有限公司 | 一种节流子反应器及利用其制备异氰酸酯的方法 |
| JP6621759B2 (ja) | 2014-03-27 | 2019-12-18 | コベストロ、ドイチュラント、アクチエンゲゼルシャフトCovestro Deutschland Ag | 気相ホスゲン化プラントの運転方法 |
| WO2015144681A1 (de) | 2014-03-27 | 2015-10-01 | Bayer Material Science Ag | Verfahren zum betreiben einer gasphasenphosgenierungsanlage |
| US10294198B2 (en) | 2014-04-11 | 2019-05-21 | Covestro Deutschland Ag | Method for producing xylylene diisocyanates in the gaseous phase |
| WO2016042124A1 (de) | 2014-09-19 | 2016-03-24 | Covestro Deutschland Ag | Verfahren zur herstellung von isocyanaten in der gasphase |
| WO2016198404A1 (de) | 2015-06-12 | 2016-12-15 | Covestro Deutschland Ag | Verfahren zur herstellung von diisocyanaten in der gasphase |
| WO2017055311A1 (de) | 2015-09-30 | 2017-04-06 | Covestro Deutschland Ag | Verfahren zur herstellung von isocyanaten |
| EP3558940B1 (de) | 2016-12-21 | 2021-01-20 | Covestro Intellectual Property GmbH & Co. KG | Verfahren zur herstellung eines isocyanats |
| HUE060475T2 (hu) | 2017-06-08 | 2023-03-28 | Covestro Intellectual Property Gmbh & Co Kg | Eljárás izocianátok elõállítására |
| EP3634947B1 (de) | 2017-06-08 | 2022-09-07 | Covestro Intellectual Property GmbH & Co. KG | Verfahren zur herstellung von isocyanaten in der gasphase |
| CN107597028B (zh) * | 2017-09-21 | 2020-05-08 | 万华化学(宁波)有限公司 | 一种制备异氰酸酯的反应器及方法 |
| CN211770461U (zh) * | 2019-09-11 | 2020-10-27 | Arc阿罗马珀尔公司 | 脉冲电场室 |
| HUE068310T2 (hu) | 2019-09-17 | 2024-12-28 | Covestro Deutschland Ag | Eljárás izocianátok elõállítására |
| CN111205178B (zh) * | 2020-02-21 | 2022-04-19 | 万华化学集团股份有限公司 | 一种氧化反应装置及其在醛类化合物氧化反应中的应用 |
| CN111518129B (zh) * | 2020-05-22 | 2021-05-21 | 江西宏柏新材料股份有限公司 | 一种连续法合成含硫硅烷的生产系统及生产工艺 |
| CN113024416A (zh) * | 2021-04-26 | 2021-06-25 | 上海交通大学 | 一种由有机胺光气化制备异氰酸酯的反应系统 |
| EP4378576A1 (en) * | 2022-11-29 | 2024-06-05 | Basf Se | Apparatus and process for preparing isocyanates |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0289840A1 (de) * | 1987-04-30 | 1988-11-09 | Bayer Ag | Verfahren zur Herstellung von (cyclo) aliphatischen Diisocyanaten |
| US5449818A (en) * | 1992-05-22 | 1995-09-12 | Bayer Aktiengesellschaft | Process for the preparation of aromatic diisocyanates |
| US5516935A (en) * | 1994-04-11 | 1996-05-14 | Bayer Aktiengesellschaft | Process for the production of diisocyanates |
| RU2201799C2 (ru) * | 2000-09-29 | 2003-04-10 | Институт проблем химической физики РАН | Трубчатый реактор |
| EP1362847A2 (de) * | 2002-05-17 | 2003-11-19 | Bayer Aktiengesellschaft | Verfahren zur Herstellung von Isocyanaten in der Gasphase |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1238669A (enExample) | 1968-03-12 | 1971-07-07 | ||
| US4289732A (en) * | 1978-12-13 | 1981-09-15 | The Upjohn Company | Apparatus for intimately admixing two chemically reactive liquid components |
| CA1137076A (en) * | 1978-12-13 | 1982-12-07 | John R. Bauer | Fluid spray mixer - reactor system |
| DE3121036A1 (de) * | 1981-05-27 | 1982-12-16 | Bayer Ag, 5090 Leverkusen | Verfahren zur kontinuierlicehn herstellung von organischen mono- oder polyisocyanaten |
| FR2697017B1 (fr) * | 1992-10-16 | 1995-01-06 | Rhone Poulenc Chimie | Procédé de préparation de composés du type isocyanates aromatiques en phase gazeuse. |
| DE19523385A1 (de) * | 1995-06-23 | 1997-01-09 | Bayer Ag | Verfahren zur Herstellung von Triisocyanaten |
| DE10129233A1 (de) * | 2001-06-19 | 2003-01-02 | Basf Ag | Verfahren zur Herstellung von Isocyanaten |
| DE10133729A1 (de) * | 2001-07-11 | 2003-01-23 | Bayer Ag | Verfahren zur Herstellung von (cyclo)aliphatischen Diisocyanaten |
| DE10161384A1 (de) * | 2001-12-14 | 2003-06-18 | Bayer Ag | Verbessertes Verfahren für die Herstellung von (/Poly)-isocyanaten in der Gasphase |
| DE10307141A1 (de) * | 2003-02-20 | 2004-09-02 | Bayer Ag | Verfahren zur Herstellung von (Poly)isocyanaten in der Gasphase |
-
2003
- 2003-10-23 DE DE10349504A patent/DE10349504A1/de not_active Withdrawn
-
2004
- 2004-10-13 AT AT04024364T patent/ATE471927T1/de not_active IP Right Cessation
- 2004-10-13 DE DE502004011303T patent/DE502004011303D1/de not_active Expired - Lifetime
- 2004-10-13 PL PL04024364T patent/PL1526129T3/pl unknown
- 2004-10-13 EP EP04024364A patent/EP1526129B1/de not_active Expired - Lifetime
- 2004-10-13 ES ES04024364T patent/ES2346308T3/es not_active Expired - Lifetime
- 2004-10-20 CA CA2485396A patent/CA2485396C/en not_active Expired - Fee Related
- 2004-10-20 US US10/969,704 patent/US7754915B2/en not_active Expired - Fee Related
- 2004-10-20 MX MXPA04010369A patent/MXPA04010369A/es active IP Right Grant
- 2004-10-22 JP JP2004308048A patent/JP4748966B2/ja not_active Expired - Fee Related
- 2004-10-22 CN CNB2004100870383A patent/CN100355726C/zh not_active Expired - Fee Related
- 2004-10-22 RU RU2004130937/04A patent/RU2387637C2/ru not_active IP Right Cessation
- 2004-10-22 KR KR1020040084693A patent/KR101050909B1/ko not_active Expired - Fee Related
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0289840A1 (de) * | 1987-04-30 | 1988-11-09 | Bayer Ag | Verfahren zur Herstellung von (cyclo) aliphatischen Diisocyanaten |
| US4847408A (en) * | 1987-04-30 | 1989-07-11 | Bayer Aktiengesellschaft | Process for the preparation of (cyclo)aliphatic diisocyanates |
| US5449818A (en) * | 1992-05-22 | 1995-09-12 | Bayer Aktiengesellschaft | Process for the preparation of aromatic diisocyanates |
| US5516935A (en) * | 1994-04-11 | 1996-05-14 | Bayer Aktiengesellschaft | Process for the production of diisocyanates |
| RU2201799C2 (ru) * | 2000-09-29 | 2003-04-10 | Институт проблем химической физики РАН | Трубчатый реактор |
| EP1362847A2 (de) * | 2002-05-17 | 2003-11-19 | Bayer Aktiengesellschaft | Verfahren zur Herstellung von Isocyanaten in der Gasphase |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2719392C1 (ru) * | 2016-05-25 | 2020-04-17 | Янмар Ко., Лтд. | Термоэлектрическое устройство генерирования мощности и термоэлектрическая система генерирования мощности |
Also Published As
| Publication number | Publication date |
|---|---|
| ATE471927T1 (de) | 2010-07-15 |
| DE10349504A1 (de) | 2005-05-25 |
| PL1526129T3 (pl) | 2010-11-30 |
| US20050113601A1 (en) | 2005-05-26 |
| CN100355726C (zh) | 2007-12-19 |
| CA2485396C (en) | 2012-05-08 |
| JP2005126437A (ja) | 2005-05-19 |
| KR20050039633A (ko) | 2005-04-29 |
| HK1080450A1 (zh) | 2006-04-28 |
| CN1636972A (zh) | 2005-07-13 |
| RU2004130937A (ru) | 2006-04-10 |
| US7754915B2 (en) | 2010-07-13 |
| DE502004011303D1 (de) | 2010-08-05 |
| CA2485396A1 (en) | 2005-04-23 |
| KR101050909B1 (ko) | 2011-07-20 |
| ES2346308T3 (es) | 2010-10-14 |
| EP1526129A1 (de) | 2005-04-27 |
| JP4748966B2 (ja) | 2011-08-17 |
| MXPA04010369A (es) | 2005-07-05 |
| EP1526129B1 (de) | 2010-06-23 |
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