RU2375511C2 - Водные растворы оптических отбеливателей - Google Patents
Водные растворы оптических отбеливателей Download PDFInfo
- Publication number
- RU2375511C2 RU2375511C2 RU2007141414A RU2007141414A RU2375511C2 RU 2375511 C2 RU2375511 C2 RU 2375511C2 RU 2007141414 A RU2007141414 A RU 2007141414A RU 2007141414 A RU2007141414 A RU 2007141414A RU 2375511 C2 RU2375511 C2 RU 2375511C2
- Authority
- RU
- Russia
- Prior art keywords
- optical brightener
- paper
- polyvinyl alcohol
- solution
- parts
- Prior art date
Links
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- 239000004471 Glycine Substances 0.000 description 1
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Classifications
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- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
- D21H19/62—Macromolecular organic compounds or oligomers thereof obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
- D21H19/46—Non-macromolecular organic compounds
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/41—Organic pigments; Organic dyes
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- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
- D21H21/30—Luminescent or fluorescent substances, e.g. for optical bleaching
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3467—Heterocyclic compounds having nitrogen in the ring having more than two nitrogen atoms in the ring
- C08K5/3477—Six-membered rings
- C08K5/3492—Triazines
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31971—Of carbohydrate
- Y10T428/31993—Of paper
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Paper (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Paints Or Removers (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP20050007691 EP1712677A1 (en) | 2005-04-08 | 2005-04-08 | Aqueous solutions of optical brighteners |
| EP05007691.8 | 2005-04-08 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| RU2007141414A RU2007141414A (ru) | 2009-05-20 |
| RU2375511C2 true RU2375511C2 (ru) | 2009-12-10 |
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Families Citing this family (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1712677A1 (en) * | 2005-04-08 | 2006-10-18 | Clariant International Ltd. | Aqueous solutions of optical brighteners |
| US8758886B2 (en) | 2005-10-14 | 2014-06-24 | International Paper Company | Recording sheet with improved image dry time |
| EP1881108A1 (en) * | 2006-07-18 | 2008-01-23 | CIBA SPECIALTY CHEMICALS HOLDING INC. Patent Departement | Fluorescent Whitening Compositions |
| KR20090058502A (ko) * | 2006-08-08 | 2009-06-09 | 클라리언트 파이넌스 (비브이아이)리미티드 | 광증백제 수용액 |
| PT2274478E (pt) | 2008-03-31 | 2012-10-02 | Int Paper Co | Folha de registo com qualidade de impressão melhorada a baixos niveis de aditivos |
| PT2370632E (pt) * | 2008-11-27 | 2015-02-09 | Clariant Int Ltd | Composições de branqueamento ótico aperfeiçoadas, para a impressão de alta qualidade por jato de tinta |
| EP2192230B2 (en) * | 2008-11-27 | 2020-01-01 | Clariant Finance (BVI) Limited | Optical brightening compositions for high quality inkjet printing |
| EP2192231A1 (en) * | 2008-11-27 | 2010-06-02 | Clariant International Ltd. | Improved optical brightening compositions for high quality inkjet printing |
| US20100129553A1 (en) * | 2008-11-27 | 2010-05-27 | International Paper Company | Optical Brightening Compositions For High Quality Inkjet Printing |
| US20110281042A1 (en) * | 2009-02-02 | 2011-11-17 | Akzo Nobel Chemicals International B.V. | Surface additives for whiteness improvements to reverse whiteness loss due to calcium chloride |
| ES2394545T3 (es) * | 2009-09-17 | 2013-02-01 | Blankophor Gmbh & Co. Kg | Agente blanqueador fluorescente de tipo disulfo |
| US8574690B2 (en) | 2009-12-17 | 2013-11-05 | International Paper Company | Printable substrates with improved dry time and acceptable print density by using monovalent salts |
| US8652593B2 (en) | 2009-12-17 | 2014-02-18 | International Paper Company | Printable substrates with improved brightness from OBAs in presence of multivalent metal salts |
| US8608908B2 (en) | 2010-04-02 | 2013-12-17 | International Paper Company | Method and system using low fatty acid starches in paper sizing composition to inhibit deposition of multivalent fatty acid salts |
| US8440053B2 (en) | 2010-04-02 | 2013-05-14 | International Paper Company | Method and system using surfactants in paper sizing composition to inhibit deposition of multivalent fatty acid salts |
| US8586156B2 (en) | 2010-05-04 | 2013-11-19 | International Paper Company | Coated printable substrates resistant to acidic highlighters and printing solutions |
| CA2806213C (en) | 2010-07-23 | 2016-06-21 | International Paper Company | Coated printable substrates providing higher print quality and resolution at lower ink usage |
| US8697203B2 (en) | 2010-11-16 | 2014-04-15 | International Paper Company | Paper sizing composition with salt of calcium (II) and organic acid, products made thereby, method of using, and method of making |
| CN104312202A (zh) * | 2014-09-29 | 2015-01-28 | 浙江亿得化工有限公司 | 低碱或无碱型活性深红染料及其制备方法 |
| CN106087546A (zh) * | 2016-06-23 | 2016-11-09 | 河南鑫昌新材料科技股份有限公司 | 一种薄膜涂层及其制备方法 |
| CN106190108A (zh) * | 2016-07-05 | 2016-12-07 | 太仓市东明化工有限公司 | 一种高稳定性荧光增白剂 |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| SU391209A1 (ru) * | 1971-03-12 | 1973-07-25 | Всесоюзный научно исследовательский институт Министерства финансов СССР | Люминесцентный состав покровной смеси для мелованной бумаги |
| SU520057A3 (ru) * | 1967-08-03 | 1976-06-30 | И.Р. Гейги Аг, (Фирма) | Способ отбеливани бумаги |
| SU1714013A1 (ru) * | 1990-05-22 | 1992-02-23 | Центральный научно-исследовательский институт бумаги | Способ поверхностей обработки бумаги |
| WO1996000221A1 (en) * | 1994-06-23 | 1996-01-04 | Clariant Finance (Bvi) Limited | Optical brightening agents |
| WO1998042685A1 (en) * | 1997-03-25 | 1998-10-01 | Ciba Specialty Chemicals Holding Inc. | Fluorescent whitening agents |
| RU2222654C2 (ru) * | 1998-10-22 | 2004-01-27 | Циба Спешиалти Кемикалз Холдинг Инк. | Способ предупреждения пожелтения целлюлозы и бумаги с использованием гидроксиламинов и других добавок и композиция с повышенной устойчивостью к пожелтению |
| RU2245952C2 (ru) * | 1999-04-29 | 2005-02-10 | Геркулес Инкорпорейтед | Композиция для мелования бумаги с усовершенствованными носителями для оптических отбеливателей |
Family Cites Families (37)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CH603879B5 (enExample) * | 1975-02-28 | 1978-08-31 | Ciba Geigy Ag | |
| JPS62106965A (ja) | 1985-11-05 | 1987-05-18 | Shin Nisso Kako Co Ltd | 螢光増白剤 |
| DE3622820A1 (de) * | 1986-07-08 | 1988-01-21 | Wacker Chemie Gmbh | Cobinder fuer streichmassen |
| DE3643215A1 (de) | 1986-12-18 | 1988-06-30 | Bayer Ag | Weisstoenerhaltige papierstreichmassen |
| DE3839865C2 (de) * | 1988-11-25 | 1994-07-07 | Wacker Chemie Gmbh | Verfahren zur Herstellung kaltwasserlöslicher auf Pigmente aufgezogener Polyvinylalkohole |
| DE4403480A1 (de) * | 1994-02-04 | 1995-08-10 | Basf Ag | Bindemittelmischungen für Papierstreichmassen |
| GB9813248D0 (en) | 1998-06-22 | 1998-08-19 | Clariant Int Ltd | Improvements in or relating to organic compounds |
| FR2785629B1 (fr) * | 1998-11-10 | 2000-12-22 | Coatex Sa | Composition polymerique retenteur d'eau et activateur d'azurants optiques, sauces de couchage pour papier, et feuilles de papier couche ainsi obtenues |
| ATE318954T1 (de) * | 1999-08-13 | 2006-03-15 | Ciba Sc Holding Ag | Formulierungen fluoreszierender optischer aufheller |
| CN1373758A (zh) * | 1999-09-10 | 2002-10-09 | 西巴特殊化学品控股有限公司 | 用作荧光增白剂的三嗪基氨基1,2－二苯乙烯衍生物 |
| DE19960862A1 (de) * | 1999-12-17 | 2001-06-28 | Basf Ag | Papierstreichmassen mit erhöhter Wasserretention |
| DE19960863A1 (de) * | 1999-12-17 | 2001-06-28 | Basf Ag | Mit Polyvinylalkohol stabilisierte Polymerisate zur Verstärkung der optimalen Aufhellung von Beschichtungsmassen |
| GB9930177D0 (en) * | 1999-12-22 | 2000-02-09 | Clariant Int Ltd | Improvements in or relating to organic compounds |
| GB9930247D0 (en) * | 1999-12-22 | 2000-02-09 | Clariant Int Ltd | Improvements in or relating to organic compounds |
| GB0021404D0 (en) * | 2000-09-01 | 2000-10-18 | Clariant Int Ltd | Improvement in or to organic compounds |
| GB0100610D0 (en) * | 2001-01-10 | 2001-02-21 | Clariant Int Ltd | Improvements in or relating to organic compounds |
| DE10138631A1 (de) * | 2001-08-13 | 2003-02-27 | Basf Ag | Verfahren zur Herstellung von beschichtetem Papier mit hoher Weiße |
| DE10149313A1 (de) * | 2001-10-05 | 2003-04-17 | Bayer Ag | Verwendung wässriger Aufhellerpräparationen zum Aufhellen von natürlichen und synthetischen Materialien |
| GB0125177D0 (en) * | 2001-10-19 | 2001-12-12 | Clariant Int Ltd | Improvements in or relating to organic compounds |
| GB0127903D0 (en) * | 2001-11-21 | 2002-01-16 | Clariant Int Ltd | Improvements relating to organic compounds |
| DE10217677A1 (de) * | 2002-04-19 | 2003-11-06 | Bayer Ag | Verwendung von Aufhellern zur Herstellung von Streichmassen |
| US7270771B2 (en) * | 2002-07-05 | 2007-09-18 | Ciba Specialty Chemicals Corporation | Triazinylaminostilbene disulphonic acid mixtures |
| DE10232665C1 (de) * | 2002-07-18 | 2003-10-02 | Wacker Polymer Systems Gmbh | Silan-modifizierte Polyvinylalkohol-Mischungen, Verfahren zu deren Herstellung, sowie deren Verwendung |
| US6818709B1 (en) * | 2003-07-11 | 2004-11-16 | Celanese International Corporation | Production of vinyl alcohol copolymers |
| WO2005056658A1 (en) | 2003-12-09 | 2005-06-23 | Celanese International Corporation | Optical brightener and method of preparing it |
| US20050124755A1 (en) * | 2003-12-09 | 2005-06-09 | Mitchell Craig E. | Polyvinyl alcohol and optical brightener concentrate |
| EP1571149A1 (en) * | 2004-03-05 | 2005-09-07 | Clariant International Ltd. | Optical brightener solutions |
| EP1612209A1 (en) * | 2004-06-28 | 2006-01-04 | Clariant International Ltd. | Improvements relating to optical brightening agents |
| EP1712677A1 (en) | 2005-04-08 | 2006-10-18 | Clariant International Ltd. | Aqueous solutions of optical brighteners |
| CN101547968A (zh) * | 2006-08-08 | 2009-09-30 | 克莱里安特财务(Bvi)有限公司 | 荧光增白剂的水溶液 |
| KR20090058502A (ko) * | 2006-08-08 | 2009-06-09 | 클라리언트 파이넌스 (비브이아이)리미티드 | 광증백제 수용액 |
| US8894815B2 (en) * | 2007-12-12 | 2014-11-25 | Clariant Finance (Bvi) Limited | Storage stable solutions of optical brighteners |
| PT2260146E (pt) * | 2008-03-26 | 2015-02-09 | Clariant Finance Bvi Ltd | Composições de branqueamento ótico melhoradas |
| US20100129553A1 (en) * | 2008-11-27 | 2010-05-27 | International Paper Company | Optical Brightening Compositions For High Quality Inkjet Printing |
| PT2370632E (pt) * | 2008-11-27 | 2015-02-09 | Clariant Int Ltd | Composições de branqueamento ótico aperfeiçoadas, para a impressão de alta qualidade por jato de tinta |
| AU2010327087A1 (en) * | 2009-12-02 | 2012-05-17 | Clariant Finance (Bvi) Limited | Concentrated storage-stable aqueous optical brightening solutions |
| CN102971463B (zh) * | 2010-07-01 | 2015-08-26 | 科莱恩金融(Bvi)有限公司 | 在涂料应用中用于增白和遮蔽的水性组合物 |
-
2005
- 2005-04-08 EP EP20050007691 patent/EP1712677A1/en not_active Withdrawn
-
2006
- 2006-04-05 BR BRPI0609733-2A patent/BRPI0609733B1/pt not_active IP Right Cessation
- 2006-04-05 US US11/918,188 patent/US8859679B2/en active Active
- 2006-04-05 EP EP20060743245 patent/EP1869252B1/en not_active Expired - Lifetime
- 2006-04-05 DE DE200660015789 patent/DE602006015789D1/de not_active Expired - Lifetime
- 2006-04-05 AT AT06743245T patent/ATE475746T1/de active
- 2006-04-05 RU RU2007141414A patent/RU2375511C2/ru not_active IP Right Cessation
- 2006-04-05 CA CA2600299A patent/CA2600299C/en not_active Expired - Lifetime
- 2006-04-05 ES ES06743245T patent/ES2347074T3/es not_active Expired - Lifetime
- 2006-04-05 JP JP2008504758A patent/JP4728391B2/ja not_active Expired - Lifetime
- 2006-04-05 AU AU2006233879A patent/AU2006233879B2/en not_active Ceased
- 2006-04-05 CN CN2006800113893A patent/CN101155962B/zh not_active Expired - Fee Related
- 2006-04-05 KR KR1020077022804A patent/KR101329924B1/ko not_active Expired - Fee Related
- 2006-04-05 WO PCT/EP2006/061329 patent/WO2006108785A2/en not_active Ceased
- 2006-04-05 PT PT06743245T patent/PT1869252E/pt unknown
- 2006-04-06 AR ARP060101356 patent/AR056305A1/es not_active Application Discontinuation
- 2006-04-06 TW TW095112145A patent/TWI490393B/zh not_active IP Right Cessation
-
2007
- 2007-09-05 ZA ZA200707652A patent/ZA200707652B/xx unknown
- 2007-10-04 NO NO20075021A patent/NO20075021L/no not_active Application Discontinuation
- 2007-10-07 IL IL186384A patent/IL186384A/en not_active IP Right Cessation
-
2014
- 2014-08-19 US US14/462,622 patent/US20140374042A1/en not_active Abandoned
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| SU520057A3 (ru) * | 1967-08-03 | 1976-06-30 | И.Р. Гейги Аг, (Фирма) | Способ отбеливани бумаги |
| SU391209A1 (ru) * | 1971-03-12 | 1973-07-25 | Всесоюзный научно исследовательский институт Министерства финансов СССР | Люминесцентный состав покровной смеси для мелованной бумаги |
| SU1714013A1 (ru) * | 1990-05-22 | 1992-02-23 | Центральный научно-исследовательский институт бумаги | Способ поверхностей обработки бумаги |
| WO1996000221A1 (en) * | 1994-06-23 | 1996-01-04 | Clariant Finance (Bvi) Limited | Optical brightening agents |
| WO1998042685A1 (en) * | 1997-03-25 | 1998-10-01 | Ciba Specialty Chemicals Holding Inc. | Fluorescent whitening agents |
| RU2222654C2 (ru) * | 1998-10-22 | 2004-01-27 | Циба Спешиалти Кемикалз Холдинг Инк. | Способ предупреждения пожелтения целлюлозы и бумаги с использованием гидроксиламинов и других добавок и композиция с повышенной устойчивостью к пожелтению |
| RU2245952C2 (ru) * | 1999-04-29 | 2005-02-10 | Геркулес Инкорпорейтед | Композиция для мелования бумаги с усовершенствованными носителями для оптических отбеливателей |
Also Published As
| Publication number | Publication date |
|---|---|
| KR101329924B1 (ko) | 2013-11-14 |
| TW200710309A (en) | 2007-03-16 |
| TWI490393B (zh) | 2015-07-01 |
| RU2007141414A (ru) | 2009-05-20 |
| ES2347074T3 (es) | 2010-10-25 |
| CN101155962B (zh) | 2012-09-05 |
| AU2006233879A1 (en) | 2006-10-19 |
| US20140374042A1 (en) | 2014-12-25 |
| WO2006108785A3 (en) | 2007-05-10 |
| AR056305A1 (es) | 2007-10-03 |
| WO2006108785A2 (en) | 2006-10-19 |
| ATE475746T1 (de) | 2010-08-15 |
| DE602006015789D1 (de) | 2010-09-09 |
| CA2600299C (en) | 2015-06-02 |
| HK1121789A1 (en) | 2009-04-30 |
| ZA200707652B (en) | 2009-10-28 |
| JP2008534762A (ja) | 2008-08-28 |
| EP1869252B1 (en) | 2010-07-28 |
| US20090081475A1 (en) | 2009-03-26 |
| US8859679B2 (en) | 2014-10-14 |
| NO20075021L (no) | 2008-01-08 |
| CA2600299A1 (en) | 2006-10-19 |
| EP1712677A1 (en) | 2006-10-18 |
| CN101155962A (zh) | 2008-04-02 |
| IL186384A0 (en) | 2008-01-20 |
| IL186384A (en) | 2011-12-29 |
| EP1869252A2 (en) | 2007-12-26 |
| PT1869252E (pt) | 2010-09-07 |
| BRPI0609733A2 (pt) | 2010-04-27 |
| JP4728391B2 (ja) | 2011-07-20 |
| BRPI0609733B1 (pt) | 2018-06-19 |
| AU2006233879B2 (en) | 2011-04-28 |
| KR20080004482A (ko) | 2008-01-09 |
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