RU2338590C2 - Каталитическая композиция для гидрокрекинга и способ превращения углеводородного сырья в низкокипящие материалы - Google Patents

Каталитическая композиция для гидрокрекинга и способ превращения углеводородного сырья в низкокипящие материалы Download PDF

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RU2338590C2
RU2338590C2 RU2005120000/04A RU2005120000A RU2338590C2 RU 2338590 C2 RU2338590 C2 RU 2338590C2 RU 2005120000/04 A RU2005120000/04 A RU 2005120000/04A RU 2005120000 A RU2005120000 A RU 2005120000A RU 2338590 C2 RU2338590 C2 RU 2338590C2
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Russia
Prior art keywords
zeolite
catalyst
range
surface area
unit cell
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RU2005120000/04A
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English (en)
Russian (ru)
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RU2005120000A (ru
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Эдвард Джулиус КРЕЙТОН (NL)
Эдвард Джулиус КРЕЙТОН
Корнелис ОУВЕХЕНД (NL)
Корнелис ОУВЕХЕНД
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Шелл Интернэшнл Рисерч Маатсхаппий Б.В.
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • B01J29/084—Y-type faujasite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • B01J29/10—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y containing iron group metals, noble metals or copper
    • B01J29/14—Iron group metals or copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/80—Mixtures of different zeolites
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G47/00—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
    • C10G47/02—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used
    • C10G47/10—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used with catalysts deposited on a carrier
    • C10G47/12—Inorganic carriers
    • C10G47/16—Crystalline alumino-silicate carriers
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G47/00—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
    • C10G47/02—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used
    • C10G47/10—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used with catalysts deposited on a carrier
    • C10G47/12—Inorganic carriers
    • C10G47/16—Crystalline alumino-silicate carriers
    • C10G47/20—Crystalline alumino-silicate carriers the catalyst containing other metals or compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/16—After treatment, characterised by the effect to be obtained to increase the Si/Al ratio; Dealumination
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/20—After treatment, characterised by the effect to be obtained to introduce other elements in the catalyst composition comprising the molecular sieve, but not specially in or on the molecular sieve itself
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/22—After treatment, characterised by the effect to be obtained to destroy the molecular sieve structure or part thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/36—Steaming
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/37—Acid treatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/40—Special temperature treatment, i.e. other than just for template removal
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/42—Addition of matrix or binder particles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B01J2235/15—X-ray diffraction
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • B01J29/10—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y containing iron group metals, noble metals or copper
    • B01J29/12—Noble metals
    • B01J29/126—Y-type faujasite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • B01J29/10—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y containing iron group metals, noble metals or copper
    • B01J29/14—Iron group metals or copper
    • B01J29/146—Y-type faujasite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • B01J29/16—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y containing arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J29/166—Y-type faujasite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/7007—Zeolite Beta
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/70—Catalysts, in general, characterised by their form or physical properties characterised by their crystalline properties, e.g. semi-crystalline
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/70—Catalysts, in general, characterised by their form or physical properties characterised by their crystalline properties, e.g. semi-crystalline
    • B01J35/77—Compounds characterised by their crystallite size
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S423/00—Chemistry of inorganic compounds
    • Y10S423/21—Faujasite, e.g. X, Y, CZS-3, ECR-4, Z-14HS, VHP-R

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  • Chemical & Material Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
RU2005120000/04A 2002-11-27 2003-11-25 Каталитическая композиция для гидрокрекинга и способ превращения углеводородного сырья в низкокипящие материалы RU2338590C2 (ru)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US42962002P 2002-11-27 2002-11-27
US60/429,620 2002-11-27

Publications (2)

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RU2005120000A RU2005120000A (ru) 2006-01-20
RU2338590C2 true RU2338590C2 (ru) 2008-11-20

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Country Status (12)

Country Link
US (1) US7192900B2 (https=)
EP (1) EP1565263B1 (https=)
JP (1) JP4813797B2 (https=)
KR (1) KR101062641B1 (https=)
CN (1) CN1717277B (https=)
AU (1) AU2003298324A1 (https=)
BR (1) BR0316682A (https=)
CA (1) CA2507351A1 (https=)
RU (1) RU2338590C2 (https=)
UA (1) UA86193C2 (https=)
WO (1) WO2004047988A1 (https=)
ZA (1) ZA200503826B (https=)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2540071C2 (ru) * 2009-04-29 2015-01-27 Шелл Интернэшнл Рисерч Маатсхаппий Б.В. Катализатор гидрокрекинга
RU2548362C2 (ru) * 2009-06-25 2015-04-20 Чайна Петролеум & Кемикал Корпорейшн Катализатор каталитического крекинга и способ повышения селективности катализатора(варианты)
RU2552645C2 (ru) * 2009-12-03 2015-06-10 Шелл Интернэшнл Рисерч Маатсхаппий Б.В. Способ приготовления фожазитного цеолита
RU2622382C2 (ru) * 2011-12-23 2017-06-15 Шелл Интернэшнл Рисерч Маатсхаппий Б.В. Способ получения композиций катализатора гидрокрекинга
RU2640804C2 (ru) * 2012-09-17 2018-01-18 Шелл Интернэшнл Рисерч Маатсхаппий Б.В. Способ получения катализатора гидрокрекинга
RU2786516C1 (ru) * 2022-04-08 2022-12-21 Акционерное общество "Газпромнефть - Омский НПЗ" (АО "Газпромнефть - ОНПЗ") Способ гидрокрекинга углеводородного сырья

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US7169291B1 (en) * 2003-12-31 2007-01-30 Uop Llc Selective hydrocracking process using beta zeolite
RU2366505C2 (ru) * 2004-03-03 2009-09-10 Шелл Интернэшнл Рисерч Маатсхаппий Б.В. Носитель катализатора и каталитическая композиция, способы их получения и применения
US7611689B2 (en) * 2004-09-24 2009-11-03 Shell Oil Company Faujasite zeolite, its preparation and use in hydrocracking
US7585405B2 (en) * 2005-11-04 2009-09-08 Uop Llc Hydrocracking catalyst containing beta and Y zeolites, and process for its use to make jet fuel or distillate
US7510645B2 (en) * 2005-11-04 2009-03-31 Uop Llc Hydrocracking catalyst containing beta and Y zeolites, and process for its use to produce naphtha
EP2000203A4 (en) * 2006-03-30 2012-07-25 Nippon Oil Corp HYDROCRACK CATALYST AND MANUFACTURING METHOD FOR A FUEL SUBSTRATE
WO2007114012A1 (ja) * 2006-03-31 2007-10-11 Nippon Oil Corporation 水素化分解触媒および燃料基材の製造方法
US20080011647A1 (en) * 2006-07-17 2008-01-17 Li Wang Hydrocracking Catalyst Containing Beta and Y Zeolites, and Process for its use to make Distillate
US20080011648A1 (en) * 2006-07-17 2008-01-17 Li Wang Hydrocracking Catalyst Containing Beta and Y Zeolites, and Process for its use to make Distillate
US20080011649A1 (en) * 2006-07-17 2008-01-17 Li Wang Hydrocracking Catalyst Containing Beta and Y Zeolites, and Process for its use to make Distillate
TW201029929A (en) * 2008-12-18 2010-08-16 Grace W R & Co Novel ultra stable zeolite Y and method for manufacturing the same
RU2487756C1 (ru) 2009-04-29 2013-07-20 ПиКью КОРПОРЕЙШН Цеолит y
CN102802792A (zh) * 2009-06-22 2012-11-28 日挥株式会社 低级烯烃制造用催化剂及使用其制造低级烯烃的方法
US8637419B2 (en) * 2009-12-06 2014-01-28 Chevron U.S.A. Inc. Method for making a hydroprocessing catalyst
FR2970259B1 (fr) 2011-01-07 2014-07-18 IFP Energies Nouvelles Procede d'hydrocraquage utilisant un catalyseur zeolithique contenant deux fonctions hydrogenantes distinctes.
KR101162612B1 (ko) * 2011-11-30 2012-07-04 이엔에프씨 주식회사 폐원료로부터의 오일 생성 시스템 및 그 촉매
KR101413993B1 (ko) * 2012-06-27 2014-08-07 주식회사 오일시티 바이오매스로부터의 오일 생성 시스템 및 그 촉매
FR3021748B1 (fr) * 2014-06-03 2016-09-02 Ifp Energies Now Procede pour l'evaluation d'au moins une caracteristique petroliere d'un echantillon de roche
EP3204473B1 (en) 2014-10-07 2020-05-06 Shell International Research Maatschappij B.V. A hydrocracking process integrated with solvent deasphalting to reduce heavy polycyclic aromatic buildup in heavy oil hydrocracker recycle stream
RU2695381C2 (ru) 2014-10-22 2019-07-23 Шелл Интернэшнл Рисерч Маатсхаппий Б.В. Способ гидрокрекинга, объединенный с вакуумной перегонкой и сольвентной деасфальтизацией для уменьшения накопления тяжелых полициклических ароматических соединений
WO2017144438A1 (en) * 2016-02-25 2017-08-31 Sabic Global Technologies B.V. Process for combined hydrodesulfurization and hydrocracking of heavy hydrocarbons
EP3423548B1 (en) 2016-03-01 2020-11-25 SABIC Global Technologies B.V. Process for producing monoaromatic hydrocarbons from a hydrocarbon feed comprising polyaromatics
US20180105761A1 (en) 2016-10-14 2018-04-19 Exxonmobil Research And Engineering Company Lubricant basestock production with enhanced aromatic saturation
US20190309231A1 (en) 2018-04-06 2019-10-10 Exxonmobil Research And Engineering Company Catalysts and methods for distillate end point reduction
CN112166172B (zh) 2018-05-25 2022-10-25 国际壳牌研究有限公司 由轻质烃原料制备中间馏出物的加氢裂化方法
US12018218B2 (en) 2018-05-25 2024-06-25 Shell Usa, Inc. Hydrocracking process for making middle distillate from a light hydrocarbon feedstock
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