RU2250873C2 - Способ каталитического предварительного реформинга углеводородного сырья, содержащего высшие углеводороды - Google Patents

Способ каталитического предварительного реформинга углеводородного сырья, содержащего высшие углеводороды Download PDF

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RU2250873C2
RU2250873C2 RU2000121898/04A RU2000121898A RU2250873C2 RU 2250873 C2 RU2250873 C2 RU 2250873C2 RU 2000121898/04 A RU2000121898/04 A RU 2000121898/04A RU 2000121898 A RU2000121898 A RU 2000121898A RU 2250873 C2 RU2250873 C2 RU 2250873C2
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catalyst
catalytic
raw materials
reforming
temperature
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RU2000121898/04A
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RU2000121898A (ru
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Мартин ЭСТБЕРГ (DK)
Мартин ЭСТБЕРГ
Йенс-Хенрик Бак ХАНСЕН (DK)
Йенс-Хенрик Бак ХАНСЕН
НИЛЬСЕН Поль Эрик ХЕЙЛЮНД (DK)
НИЛЬСЕН Поль Эрик ХЕЙЛЮНД
Ким ААСБЕРГ-ПЕТЕРСЕН (DK)
Ким Аасберг-Петерсен
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Хальдор Топсеэ А/С
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    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen; Reversible storage of hydrogen
    • C01B3/02—Production of hydrogen; Production of gaseous mixtures containing hydrogen
    • C01B3/32—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air
    • C01B3/34—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air by reaction of hydrocarbons with gasifying agents
    • C01B3/38—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air by reaction of hydrocarbons with gasifying agents using catalysts
    • C01B3/40—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air by reaction of hydrocarbons with gasifying agents using catalysts characterised by the catalyst
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen; Reversible storage of hydrogen
    • C01B3/02—Production of hydrogen; Production of gaseous mixtures containing hydrogen
    • C01B3/32—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air
    • C01B3/34—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air by reaction of hydrocarbons with gasifying agents
    • C01B3/38—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air by reaction of hydrocarbons with gasifying agents using catalysts
    • C—CHEMISTRY; METALLURGY
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    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen; Reversible storage of hydrogen
    • C01B3/02—Production of hydrogen; Production of gaseous mixtures containing hydrogen
    • C01B3/32—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air
    • C01B3/34—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air by reaction of hydrocarbons with gasifying agents
    • C01B3/38—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air by reaction of hydrocarbons with gasifying agents using catalysts
    • C01B3/382—Processes with two or more reaction steps, of which at least one is catalytic, e.g. steam reforming and partial oxidation
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
    • C01B2203/0227—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
    • C01B2203/0233—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being a steam reforming step
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
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    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
    • C01B2203/0227—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
    • C01B2203/0244—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being an autothermal reforming step, e.g. secondary reforming processes
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/025—Processes for making hydrogen or synthesis gas containing a partial oxidation step
    • C01B2203/0261—Processes for making hydrogen or synthesis gas containing a partial oxidation step containing a catalytic partial oxidation step [CPO]
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
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    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0283—Processes for making hydrogen or synthesis gas containing a CO-shift step, i.e. a water gas shift step
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/08—Methods of heating or cooling
    • C01B2203/0805—Methods of heating the process for making hydrogen or synthesis gas
    • C01B2203/0838—Methods of heating the process for making hydrogen or synthesis gas by heat exchange with exothermic reactions, other than by combustion of fuel
    • C01B2203/0844—Methods of heating the process for making hydrogen or synthesis gas by heat exchange with exothermic reactions, other than by combustion of fuel the non-combustive exothermic reaction being another reforming reaction as defined in groups C01B2203/02 - C01B2203/0294
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    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/08—Methods of heating or cooling
    • C01B2203/0805—Methods of heating the process for making hydrogen or synthesis gas
    • C01B2203/085—Methods of heating the process for making hydrogen or synthesis gas by electric heating
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    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/08—Methods of heating or cooling
    • C01B2203/0805—Methods of heating the process for making hydrogen or synthesis gas
    • C01B2203/0866—Methods of heating the process for making hydrogen or synthesis gas by combination of different heating methods
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    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1005—Arrangement or shape of catalyst
    • C01B2203/1011—Packed bed of catalytic structures, e.g. particles, packing elements
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C01B2203/1047—Group VIII metal catalysts
    • C01B2203/1064—Platinum group metal catalysts
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C01B2203/1082—Composition of support materials
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12—Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1205—Composition of the feed
    • C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
    • C01B2203/1235—Hydrocarbons
    • C01B2203/1247—Higher hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
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    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/14—Details of the flowsheet
    • C01B2203/142—At least two reforming, decomposition or partial oxidation steps in series
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/80—Aspect of integrated processes for the production of hydrogen or synthesis gas not covered by groups C01B2203/02 - C01B2203/1695
    • C01B2203/82—Several process steps of C01B2203/02 - C01B2203/08 integrated into a single apparatus
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Inorganic Chemistry (AREA)
  • Hydrogen, Water And Hydrids (AREA)
  • Catalysts (AREA)
RU2000121898/04A 1999-08-19 2000-08-18 Способ каталитического предварительного реформинга углеводородного сырья, содержащего высшие углеводороды RU2250873C2 (ru)

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Application Number Priority Date Filing Date Title
DKPA199901137 1999-08-19
DKPA199901137 1999-08-19

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RU2000121898A RU2000121898A (ru) 2002-07-10
RU2250873C2 true RU2250873C2 (ru) 2005-04-27

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RU2000121898/04A RU2250873C2 (ru) 1999-08-19 2000-08-18 Способ каталитического предварительного реформинга углеводородного сырья, содержащего высшие углеводороды

Country Status (9)

Country Link
US (1) US6335474B1 (https=)
EP (1) EP1077198A3 (https=)
JP (1) JP2001080907A (https=)
CN (1) CN1165597C (https=)
AU (1) AU769128B2 (https=)
CA (1) CA2316043A1 (https=)
NO (1) NO329966B1 (https=)
RU (1) RU2250873C2 (https=)
ZA (1) ZA200004258B (https=)

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US6914029B2 (en) * 2001-11-02 2005-07-05 California Institute Of Technology Polyoxometallate catalysts and catalytic processes
US6981994B2 (en) * 2001-12-17 2006-01-03 Praxair Technology, Inc. Production enhancement for a reactor
JP2004079262A (ja) * 2002-08-13 2004-03-11 Mitsubishi Heavy Ind Ltd 水素供給システム及び移動式水素製造装置
US6977067B2 (en) * 2003-02-12 2005-12-20 Engelhard Corporation Selective removal of olefins from hydrocarbon feed streams
US7427388B2 (en) 2004-03-19 2008-09-23 Air Products And Chemicals, Inc. Process for improving prereforming and reforming of natural gas containing higher hydrocarbons along with methane
TWI398406B (zh) * 2005-09-21 2013-06-11 Nippon Oil Corp Automatic starting method of thermal reformer
JP5224651B2 (ja) 2006-03-31 2013-07-03 Ｊｘ日鉱日石エネルギー株式会社 固体酸化物形燃料電池
JP4933818B2 (ja) 2006-04-07 2012-05-16 Ｊｘ日鉱日石エネルギー株式会社 固体酸化物形燃料電池システムの運転方法
US7365102B1 (en) 2007-02-26 2008-04-29 Delphi Technologies, Inc. Process for pre-reforming hydrocarbon fuels
WO2008147860A1 (en) 2007-05-22 2008-12-04 Praxair Technology, Inc. Dual mode reactor smr integration
US8808654B2 (en) 2009-09-29 2014-08-19 Praxair Technology, Inc. Process for sulfur removal from refinery off gas
EP2703340B1 (en) 2011-04-26 2017-07-19 Panasonic Intellectual Property Management Co., Ltd. Hydrogen generation apparatus and fuel cell system
JP5230849B2 (ja) 2011-04-26 2013-07-10 パナソニック株式会社 水素生成装置、燃料電池システム、及びその運転方法
CN104190427A (zh) * 2014-09-26 2014-12-10 中国科学院上海高等研究院 多相镍基催化剂及其制备方法与应用
US11826745B2 (en) 2021-04-22 2023-11-28 Petróleo Brasileiro S.A.—Petrobras Method of maintaining the activity of pre-reform catalysts

Citations (4)

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GB2274284A (en) * 1992-12-23 1994-07-20 Snam Progetti Catalytic process for producing synthesis gas
RU2058813C1 (ru) * 1990-01-26 1996-04-27 Снампрогетти С.П.А. Катализатор для получения синтез-газа и способ получения синтез-газа
EP0855366A1 (en) * 1997-01-22 1998-07-29 Haldor Topsoe A/S Synthesis gas production by steam reforming using catalyzed hardware
WO1999035082A1 (en) * 1998-01-12 1999-07-15 Regents Of The University Of Minnesota Control of hydrogen and carbon monoxide produced in partial oxidation process

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JPS5274591A (en) * 1975-12-17 1977-06-22 Nippon Soken Catalysts for reforming hydrocarbon fuels
US4844837A (en) * 1982-09-30 1989-07-04 Engelhard Corporation Catalytic partial oxidation process
JPS63248444A (ja) * 1987-04-03 1988-10-14 Tokyo Gas Co Ltd 炭化水素の水蒸気改質および／または部分酸化用触媒
JPH0733242B2 (ja) * 1988-12-15 1995-04-12 川崎重工業株式会社 燃料電池用燃料改質方法
JP4226684B2 (ja) * 1997-04-11 2009-02-18 千代田化工建設株式会社 部分酸化法による合成ガスの製造方法
DE69825576T2 (de) * 1997-04-11 2005-08-11 Chiyoda Corp., Yokohama Katalysator für die herstellung von synthesegas und verfahren zur herstellung von kohlenmonoxid
GB9806199D0 (en) * 1998-03-24 1998-05-20 Johnson Matthey Plc Catalytic generation of hydrogen

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2058813C1 (ru) * 1990-01-26 1996-04-27 Снампрогетти С.П.А. Катализатор для получения синтез-газа и способ получения синтез-газа
GB2274284A (en) * 1992-12-23 1994-07-20 Snam Progetti Catalytic process for producing synthesis gas
EP0855366A1 (en) * 1997-01-22 1998-07-29 Haldor Topsoe A/S Synthesis gas production by steam reforming using catalyzed hardware
WO1999035082A1 (en) * 1998-01-12 1999-07-15 Regents Of The University Of Minnesota Control of hydrogen and carbon monoxide produced in partial oxidation process

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CN1285390A (zh) 2001-02-28
US6335474B1 (en) 2002-01-01
CN1165597C (zh) 2004-09-08
EP1077198A3 (en) 2001-03-07
NO329966B1 (no) 2011-01-31
JP2001080907A (ja) 2001-03-27
AU5349000A (en) 2001-02-22
AU769128B2 (en) 2004-01-15
NO20004138L (no) 2001-02-20
NO20004138D0 (no) 2000-08-18
EP1077198A2 (en) 2001-02-21
CA2316043A1 (en) 2001-02-19
ZA200004258B (en) 2001-11-22

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