RU2207190C2 - Гибридные органо-неорганические гели для экстракции химических элементов, таких как лантаниды и актиниды, и способы получения этих гелей - Google Patents
Гибридные органо-неорганические гели для экстракции химических элементов, таких как лантаниды и актиниды, и способы получения этих гелей Download PDFInfo
- Publication number
- RU2207190C2 RU2207190C2 RU2000113194/04A RU2000113194A RU2207190C2 RU 2207190 C2 RU2207190 C2 RU 2207190C2 RU 2000113194/04 A RU2000113194/04 A RU 2000113194/04A RU 2000113194 A RU2000113194 A RU 2000113194A RU 2207190 C2 RU2207190 C2 RU 2207190C2
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- RU
- Russia
- Prior art keywords
- gel
- organic
- functional group
- group
- graphic part
- Prior art date
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- 238000000034 method Methods 0.000 title claims abstract 17
- 229910052768 actinide Inorganic materials 0.000 title claims abstract 3
- 150000001255 actinides Chemical class 0.000 title claims abstract 3
- 150000002602 lanthanoids Chemical class 0.000 title claims abstract 3
- 239000000499 gel Substances 0.000 title claims 11
- 238000000605 extraction Methods 0.000 title claims 3
- 229910052747 lanthanoid Inorganic materials 0.000 title claims 2
- 229910052500 inorganic mineral Inorganic materials 0.000 title 1
- 239000011707 mineral Substances 0.000 title 1
- 229910052710 silicon Inorganic materials 0.000 claims abstract 11
- 229910052751 metal Inorganic materials 0.000 claims abstract 7
- 239000002184 metal Substances 0.000 claims abstract 7
- 150000002500 ions Chemical class 0.000 claims abstract 6
- 230000000536 complexating effect Effects 0.000 claims abstract 5
- 239000007864 aqueous solution Substances 0.000 claims abstract 3
- 230000000694 effects Effects 0.000 claims abstract 2
- 125000000524 functional group Chemical group 0.000 claims 7
- 150000004703 alkoxides Chemical class 0.000 claims 6
- 125000000217 alkyl group Chemical group 0.000 claims 4
- 125000000962 organic group Chemical group 0.000 claims 4
- 238000006116 polymerization reaction Methods 0.000 claims 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims 2
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 claims 2
- 239000010703 silicon Substances 0.000 claims 2
- -1 silicon alkoxide Chemical class 0.000 claims 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 2
- DDFHBQSCUXNBSA-UHFFFAOYSA-N 5-(5-carboxythiophen-2-yl)thiophene-2-carboxylic acid Chemical compound S1C(C(=O)O)=CC=C1C1=CC=C(C(O)=O)S1 DDFHBQSCUXNBSA-UHFFFAOYSA-N 0.000 claims 1
- ROFVEXUMMXZLPA-UHFFFAOYSA-N Bipyridyl Chemical group N1=CC=CC=C1C1=CC=CC=N1 ROFVEXUMMXZLPA-UHFFFAOYSA-N 0.000 claims 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims 1
- BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 claims 1
- 150000001408 amides Chemical class 0.000 claims 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims 1
- 239000012528 membrane Substances 0.000 claims 1
- SBOJXQVPLKSXOG-UHFFFAOYSA-N o-amino-hydroxylamine Chemical compound NON SBOJXQVPLKSXOG-UHFFFAOYSA-N 0.000 claims 1
- 238000006068 polycondensation reaction Methods 0.000 claims 1
- 239000000843 powder Substances 0.000 claims 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 claims 1
- 239000000741 silica gel Substances 0.000 claims 1
- 229910002027 silica gel Inorganic materials 0.000 claims 1
- 238000003980 solgel method Methods 0.000 claims 1
- 125000001424 substituent group Chemical group 0.000 claims 1
- 238000005406 washing Methods 0.000 claims 1
- 238000011084 recovery Methods 0.000 abstract 1
- 239000000126 substance Substances 0.000 abstract 1
- 0 CCCCNC(CC(N)=C)=* Chemical compound CCCCNC(CC(N)=C)=* 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J45/00—Ion-exchange in which a complex or a chelate is formed; Use of material as complex or chelate forming ion-exchangers; Treatment of material for improving the complex or chelate forming ion-exchange properties
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Silicon Polymers (AREA)
- Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR9713565 | 1997-10-29 | ||
| FR9713565A FR2770153B1 (fr) | 1997-10-29 | 1997-10-29 | Gels hybrides inorganiques-organiques pour l'extraction d'especes chimiques telles que les lanthanides et les actinides, et leur preparation |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| RU2000113194A RU2000113194A (ru) | 2002-05-10 |
| RU2207190C2 true RU2207190C2 (ru) | 2003-06-27 |
Family
ID=9512784
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RU2000113194/04A RU2207190C2 (ru) | 1997-10-29 | 1998-10-28 | Гибридные органо-неорганические гели для экстракции химических элементов, таких как лантаниды и актиниды, и способы получения этих гелей |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US6667016B1 (enExample) |
| JP (1) | JP2001520932A (enExample) |
| KR (1) | KR100531108B1 (enExample) |
| FR (1) | FR2770153B1 (enExample) |
| GB (1) | GB2349347B (enExample) |
| RU (1) | RU2207190C2 (enExample) |
| WO (1) | WO1999021654A1 (enExample) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4540935B2 (ja) * | 2003-01-31 | 2010-09-08 | 日本曹達株式会社 | シラン誘導体及び有機薄膜形成体 |
| FR2866341B1 (fr) * | 2004-02-12 | 2006-04-28 | Commissariat Energie Atomique | Gel hybride organique-inorganique imprime comprenant un complexant organique mettant en jeu des interactions pi - pi et/ou pi-nu |
| US7534510B2 (en) | 2004-09-03 | 2009-05-19 | The Gillette Company | Fuel compositions |
| US7674864B2 (en) * | 2005-12-23 | 2010-03-09 | Boston Scientific Scimed, Inc. | Polymeric hybrid precursors, polymeric hybrid precursor composite matrices, medical devices, and methods |
| US8455088B2 (en) | 2005-12-23 | 2013-06-04 | Boston Scientific Scimed, Inc. | Spun nanofiber, medical devices, and methods |
| FR2933703B1 (fr) | 2008-07-11 | 2012-08-17 | Commissariat Energie Atomique | Detecteurs nanoporeux de composes aromatiques monocycliques et autres polluants |
| FR3013059B1 (fr) | 2013-11-08 | 2016-01-01 | Commissariat Energie Atomique | Utilisation d'un materiau hybride organique-inorganique pour extraire l'uranium(vi) d'une solution aqueuse d'acide sulfurique, issue notamment de la lixiviation sulfurique d'un minerai uranifere |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| SU213875A1 (enExample) * | Ф. Миронов, Г. Д. Хатунцев , В. Д. Шелуд ков | |||
| US4203952A (en) * | 1974-05-28 | 1980-05-20 | The British Petroleum Company Limited | Process for the removal of heavy metals and transition metals other than platinum from solution |
| US4278803A (en) * | 1980-01-07 | 1981-07-14 | Polaroid Corporation | Preparation of 2-Methylene-1,3-propanediamide |
| SU906998A1 (ru) * | 1980-04-08 | 1982-02-23 | Предприятие П/Я Г-4302 | Способ получени элементоорганических карбодиимидов |
| RU2052271C1 (ru) * | 1990-03-06 | 1996-01-20 | Хенкель Рисерч Корпорейшн | Экстракционная система для выделения из группы: золото, серебро, медь и цинк |
| RU2058317C1 (ru) * | 1994-07-18 | 1996-04-20 | Иркутский институт органической химии СО РАН | Способ получения n,n′ -бис[3-триалкил(алкокси)силилпропил]-тиомочевины |
| RU2074187C1 (ru) * | 1994-09-30 | 1997-02-27 | Иркутский институт органической химии СО РАН | Способ получения n,n'-бис(3-триалкилсилилпропил)- или n,n'-бис(3-триалкоксисилилпропил)тиокарбамидов |
Family Cites Families (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB956276A (en) * | 1960-07-06 | 1964-04-22 | Wolfen Filmfab Veb | Process for the manufacture of thermostable organo silicon anion exchangers |
| DE2357184A1 (de) * | 1973-11-16 | 1975-05-22 | Merck Patent Gmbh | Verfahren zur herstellung von organisch modifizierten siliciumdioxiden |
| US4448694A (en) * | 1981-09-04 | 1984-05-15 | Dow Corning Corporation | Metal extraction from solution and immobilized chelating agents used therefor |
| DE3616133A1 (de) * | 1985-09-25 | 1987-11-19 | Merck Patent Gmbh | Kugelfoermige sio(pfeil abwaerts)2(pfeil abwaerts)-partikel |
| DE3751856T3 (de) * | 1986-10-03 | 2001-04-19 | Ppg Industries Ohio, Inc. | Organisch-anorganisches Hybridpolymer |
| US4746572A (en) * | 1986-11-28 | 1988-05-24 | E. I. Dupont De Nemours And Company | Structures surface modified with bidentate silanes |
| US4943375A (en) * | 1987-09-04 | 1990-07-24 | Brigham Young University | The process of separating a selected ion from a plurality of other ions in a multiple ion solution by contacting the solution with a macrocyclic ligand bonded to silica which selectively complexes with the desired ion |
| US5039419A (en) * | 1988-07-13 | 1991-08-13 | Brigham Young University | Sulfur-containing hydrocarbon compounds and process of using same in recovering and concentrating desired ions from solutions thereof |
| US5071819A (en) * | 1988-08-26 | 1991-12-10 | Ibc Advanced Technologies | Sulfur and nitrogen-containing hydrocarbons and process of using same in recovering and concentrating desired ions from solutions thereof |
| US5084430A (en) * | 1988-08-26 | 1992-01-28 | Brigham Young University | Sulfur and nitrogen containing hydrocarbons and process of using same in separating desired ions from solutions thereof |
| US5078978A (en) * | 1989-11-06 | 1992-01-07 | Brigham Young University | Pyridine-containing alkoxysilanes bonded to inorganic supports and processes of using the same for removing and concentrating desired ions from solutions |
| JP2795379B2 (ja) * | 1989-11-29 | 1998-09-10 | 科学技術振興事業団 | 金属配位性有機珪素ポリマーの製造方法 |
| DE4309660A1 (de) * | 1993-03-25 | 1994-09-29 | Studiengesellschaft Kohle Mbh | Selektive anorganische Katalysatoren in Form von molekularen Abdrücken in Hohlräumen |
| JP3170529B2 (ja) | 1993-03-25 | 2001-05-28 | 大日本印刷株式会社 | トナー容器 |
| DE4319909C2 (de) * | 1993-06-16 | 1996-11-07 | Solvay Deutschland | Palladium, Platin, Nickel, Kobalt und/oder Kupfer umfassender Aerogel-Trägerkatalysator, Verfahren zu seiner Herstellung und Verwendung eines Palladium-Aerogel-Trägerkatalysators |
| US5668079A (en) * | 1994-09-27 | 1997-09-16 | Syracuse University | Chemically active ceramic compositions with an hydroxyquinoline moiety |
| FR2725552B1 (fr) * | 1994-10-05 | 1996-10-31 | Commissariat Energie Atomique | Procede de decontamination partielle alpha d'un effluent aqueux |
| US5637135A (en) * | 1995-06-26 | 1997-06-10 | Capillary Technology Corporation | Chromatographic stationary phases and adsorbents from hybrid organic-inorganic sol-gels |
-
1997
- 1997-10-29 FR FR9713565A patent/FR2770153B1/fr not_active Expired - Lifetime
-
1998
- 1998-10-28 JP JP2000517801A patent/JP2001520932A/ja active Pending
- 1998-10-28 US US09/530,133 patent/US6667016B1/en not_active Expired - Fee Related
- 1998-10-28 KR KR10-2000-7004656A patent/KR100531108B1/ko not_active Expired - Fee Related
- 1998-10-28 GB GB0009736A patent/GB2349347B/en not_active Expired - Fee Related
- 1998-10-28 WO PCT/FR1998/002309 patent/WO1999021654A1/fr not_active Ceased
- 1998-10-28 RU RU2000113194/04A patent/RU2207190C2/ru not_active IP Right Cessation
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| SU213875A1 (enExample) * | Ф. Миронов, Г. Д. Хатунцев , В. Д. Шелуд ков | |||
| US4203952A (en) * | 1974-05-28 | 1980-05-20 | The British Petroleum Company Limited | Process for the removal of heavy metals and transition metals other than platinum from solution |
| US4278803A (en) * | 1980-01-07 | 1981-07-14 | Polaroid Corporation | Preparation of 2-Methylene-1,3-propanediamide |
| SU906998A1 (ru) * | 1980-04-08 | 1982-02-23 | Предприятие П/Я Г-4302 | Способ получени элементоорганических карбодиимидов |
| RU2052271C1 (ru) * | 1990-03-06 | 1996-01-20 | Хенкель Рисерч Корпорейшн | Экстракционная система для выделения из группы: золото, серебро, медь и цинк |
| RU2058317C1 (ru) * | 1994-07-18 | 1996-04-20 | Иркутский институт органической химии СО РАН | Способ получения n,n′ -бис[3-триалкил(алкокси)силилпропил]-тиомочевины |
| RU2074187C1 (ru) * | 1994-09-30 | 1997-02-27 | Иркутский институт органической химии СО РАН | Способ получения n,n'-бис(3-триалкилсилилпропил)- или n,n'-бис(3-триалкоксисилилпропил)тиокарбамидов |
Also Published As
| Publication number | Publication date |
|---|---|
| FR2770153A1 (fr) | 1999-04-30 |
| GB2349347B (en) | 2001-11-14 |
| GB0009736D0 (en) | 2000-06-07 |
| US6667016B1 (en) | 2003-12-23 |
| FR2770153B1 (fr) | 1999-11-19 |
| JP2001520932A (ja) | 2001-11-06 |
| WO1999021654A1 (fr) | 1999-05-06 |
| GB2349347A (en) | 2000-11-01 |
| KR100531108B1 (ko) | 2005-11-24 |
| KR20010031605A (ko) | 2001-04-16 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MM4A | The patent is invalid due to non-payment of fees |
Effective date: 20171029 |