JP2001520932A - ランタニドとアクチニドのような化学種を抽出するための無機−有機ハイブリッドゲル並びにその調製法 - Google Patents
ランタニドとアクチニドのような化学種を抽出するための無機−有機ハイブリッドゲル並びにその調製法Info
- Publication number
- JP2001520932A JP2001520932A JP2000517801A JP2000517801A JP2001520932A JP 2001520932 A JP2001520932 A JP 2001520932A JP 2000517801 A JP2000517801 A JP 2000517801A JP 2000517801 A JP2000517801 A JP 2000517801A JP 2001520932 A JP2001520932 A JP 2001520932A
- Authority
- JP
- Japan
- Prior art keywords
- gel
- organic
- group
- complex
- inorganic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 229910052768 actinide Inorganic materials 0.000 title claims abstract description 15
- 150000001255 actinides Chemical class 0.000 title claims abstract description 15
- 239000000499 gel Substances 0.000 title abstract description 118
- 229910052747 lanthanoid Inorganic materials 0.000 title abstract description 7
- 150000002602 lanthanoids Chemical class 0.000 title abstract description 7
- 238000002360 preparation method Methods 0.000 title description 30
- 238000000034 method Methods 0.000 claims abstract description 62
- 229910052710 silicon Inorganic materials 0.000 claims abstract description 59
- 229910052719 titanium Inorganic materials 0.000 claims abstract description 24
- 229910052726 zirconium Inorganic materials 0.000 claims abstract description 24
- 150000004703 alkoxides Chemical class 0.000 claims abstract description 22
- 229910052751 metal Inorganic materials 0.000 claims abstract description 22
- 239000002184 metal Substances 0.000 claims abstract description 22
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 13
- AVXURJPOCDRRFD-UHFFFAOYSA-N Hydroxylamine Chemical compound ON AVXURJPOCDRRFD-UHFFFAOYSA-N 0.000 claims abstract description 5
- SBOJXQVPLKSXOG-UHFFFAOYSA-N o-amino-hydroxylamine Chemical compound NON SBOJXQVPLKSXOG-UHFFFAOYSA-N 0.000 claims abstract description 5
- 238000003980 solgel method Methods 0.000 claims abstract 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 58
- 229910052757 nitrogen Inorganic materials 0.000 claims description 48
- 229910052760 oxygen Inorganic materials 0.000 claims description 26
- 239000007864 aqueous solution Substances 0.000 claims description 24
- 238000000605 extraction Methods 0.000 claims description 23
- 125000000962 organic group Chemical group 0.000 claims description 23
- 239000000843 powder Substances 0.000 claims description 19
- 150000002500 ions Chemical class 0.000 claims description 16
- 239000000243 solution Substances 0.000 claims description 15
- 125000000217 alkyl group Chemical group 0.000 claims description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 12
- 239000010703 silicon Substances 0.000 claims description 11
- -1 silicon alkoxides Chemical class 0.000 claims description 8
- 229910021644 lanthanide ion Inorganic materials 0.000 claims description 5
- 230000000694 effects Effects 0.000 claims description 4
- 238000006068 polycondensation reaction Methods 0.000 claims description 3
- DDFHBQSCUXNBSA-UHFFFAOYSA-N 5-(5-carboxythiophen-2-yl)thiophene-2-carboxylic acid Chemical compound S1C(C(=O)O)=CC=C1C1=CC=C(C(O)=O)S1 DDFHBQSCUXNBSA-UHFFFAOYSA-N 0.000 claims description 2
- BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 claims description 2
- 238000006116 polymerization reaction Methods 0.000 claims 4
- 238000005406 washing Methods 0.000 claims 1
- 239000013626 chemical specie Substances 0.000 abstract description 5
- 230000000536 complexating effect Effects 0.000 abstract description 5
- 150000002739 metals Chemical class 0.000 abstract 1
- 238000005481 NMR spectroscopy Methods 0.000 description 58
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 37
- 229910052739 hydrogen Inorganic materials 0.000 description 37
- 238000005384 cross polarization magic-angle spinning Methods 0.000 description 33
- 229910017855 NH 4 F Inorganic materials 0.000 description 26
- LIVNPJMFVYWSIS-UHFFFAOYSA-N silicon monoxide Inorganic materials [Si-]#[O+] LIVNPJMFVYWSIS-UHFFFAOYSA-N 0.000 description 26
- 229910002027 silica gel Inorganic materials 0.000 description 25
- 239000000741 silica gel Substances 0.000 description 25
- 229910018557 Si O Inorganic materials 0.000 description 24
- 230000000704 physical effect Effects 0.000 description 24
- 229910052799 carbon Inorganic materials 0.000 description 23
- 239000003153 chemical reaction reagent Substances 0.000 description 21
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 18
- 229910052695 Americium Inorganic materials 0.000 description 17
- 238000009833 condensation Methods 0.000 description 16
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 15
- LXQXZNRPTYVCNG-UHFFFAOYSA-N americium atom Chemical compound [Am] LXQXZNRPTYVCNG-UHFFFAOYSA-N 0.000 description 15
- 230000015572 biosynthetic process Effects 0.000 description 14
- 241000894007 species Species 0.000 description 14
- 230000005494 condensation Effects 0.000 description 13
- 238000004458 analytical method Methods 0.000 description 12
- 125000003118 aryl group Chemical group 0.000 description 12
- 229910052778 Plutonium Inorganic materials 0.000 description 11
- 238000003786 synthesis reaction Methods 0.000 description 11
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 10
- 239000007788 liquid Substances 0.000 description 10
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 9
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 9
- 238000004821 distillation Methods 0.000 description 9
- 238000000921 elemental analysis Methods 0.000 description 9
- 239000000463 material Substances 0.000 description 9
- 229910017604 nitric acid Inorganic materials 0.000 description 9
- OYEHPCDNVJXUIW-UHFFFAOYSA-N plutonium atom Chemical compound [Pu] OYEHPCDNVJXUIW-UHFFFAOYSA-N 0.000 description 9
- 238000005259 measurement Methods 0.000 description 8
- 239000011148 porous material Substances 0.000 description 8
- 238000012545 processing Methods 0.000 description 8
- 239000010936 titanium Substances 0.000 description 8
- 125000004429 atom Chemical group 0.000 description 7
- 239000003054 catalyst Substances 0.000 description 7
- 150000001875 compounds Chemical class 0.000 description 6
- 239000000284 extract Substances 0.000 description 6
- 239000000047 product Substances 0.000 description 6
- 239000000377 silicon dioxide Substances 0.000 description 6
- 238000003756 stirring Methods 0.000 description 6
- 239000000758 substrate Substances 0.000 description 6
- 229910052779 Neodymium Inorganic materials 0.000 description 5
- 229910018540 Si C Inorganic materials 0.000 description 5
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 5
- 238000001879 gelation Methods 0.000 description 5
- 238000010907 mechanical stirring Methods 0.000 description 5
- 239000012429 reaction media Substances 0.000 description 5
- 229910010271 silicon carbide Inorganic materials 0.000 description 5
- 239000002904 solvent Substances 0.000 description 5
- 238000011282 treatment Methods 0.000 description 5
- KMLVDTJUQJXRRH-UHFFFAOYSA-N triethoxy(2-pyridin-2-ylethyl)silane Chemical compound CCO[Si](OCC)(OCC)CCC1=CC=CC=N1 KMLVDTJUQJXRRH-UHFFFAOYSA-N 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- 238000009826 distribution Methods 0.000 description 4
- 238000003760 magnetic stirring Methods 0.000 description 4
- JWESKZMVTRCFAC-UHFFFAOYSA-N n'-(3-triethoxysilylpropyl)propanediamide Chemical compound CCO[Si](OCC)(OCC)CCCNC(=O)CC(N)=O JWESKZMVTRCFAC-UHFFFAOYSA-N 0.000 description 4
- DTRFVBYMIUKDEO-UHFFFAOYSA-N n,n'-bis(3-triethoxysilylpropyl)propanediamide Chemical compound CCO[Si](OCC)(OCC)CCCNC(=O)CC(=O)NCCC[Si](OCC)(OCC)OCC DTRFVBYMIUKDEO-UHFFFAOYSA-N 0.000 description 4
- RTHWPWJSSJEQNU-UHFFFAOYSA-N n,n,n',n'-tetraethylpropanediamide Chemical compound CCN(CC)C(=O)CC(=O)N(CC)CC RTHWPWJSSJEQNU-UHFFFAOYSA-N 0.000 description 4
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 description 3
- 125000004432 carbon atom Chemical group C* 0.000 description 3
- 238000012937 correction Methods 0.000 description 3
- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 description 3
- 230000007062 hydrolysis Effects 0.000 description 3
- 238000006460 hydrolysis reaction Methods 0.000 description 3
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 3
- 239000012535 impurity Substances 0.000 description 3
- 238000002329 infrared spectrum Methods 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000012528 membrane Substances 0.000 description 3
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 description 3
- PHVXTQIROLEEDB-UHFFFAOYSA-N n-[2-(2-chlorophenyl)ethyl]-4-[[3-(2-methylphenyl)piperidin-1-yl]methyl]-n-pyrrolidin-3-ylbenzamide Chemical compound CC1=CC=CC=C1C1CN(CC=2C=CC(=CC=2)C(=O)N(CCC=2C(=CC=CC=2)Cl)C2CNCC2)CCC1 PHVXTQIROLEEDB-UHFFFAOYSA-N 0.000 description 3
- QEFYFXOXNSNQGX-UHFFFAOYSA-N neodymium atom Chemical compound [Nd] QEFYFXOXNSNQGX-UHFFFAOYSA-N 0.000 description 3
- 238000005192 partition Methods 0.000 description 3
- 239000007790 solid phase Substances 0.000 description 3
- WYTZZXDRDKSJID-UHFFFAOYSA-N (3-aminopropyl)triethoxysilane Chemical compound CCO[Si](OCC)(OCC)CCCN WYTZZXDRDKSJID-UHFFFAOYSA-N 0.000 description 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- 229910013627 M-Si Inorganic materials 0.000 description 2
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 2
- MZRVEZGGRBJDDB-UHFFFAOYSA-N N-Butyllithium Chemical compound [Li]CCCC MZRVEZGGRBJDDB-UHFFFAOYSA-N 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- 125000003545 alkoxy group Chemical group 0.000 description 2
- 150000001768 cations Chemical class 0.000 description 2
- 238000010828 elution Methods 0.000 description 2
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 2
- 229910001385 heavy metal Inorganic materials 0.000 description 2
- 238000005470 impregnation Methods 0.000 description 2
- CGJMROBVSBIBKP-UHFFFAOYSA-M malonamate Chemical compound NC(=O)CC([O-])=O CGJMROBVSBIBKP-UHFFFAOYSA-M 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 229910052697 platinum Inorganic materials 0.000 description 2
- SXYFKXOFMCIXQW-UHFFFAOYSA-N propanedioyl dichloride Chemical compound ClC(=O)CC(Cl)=O SXYFKXOFMCIXQW-UHFFFAOYSA-N 0.000 description 2
- 238000000746 purification Methods 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N tetrahydrofuran Substances C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
- 150000003573 thiols Chemical class 0.000 description 2
- 229910052723 transition metal Inorganic materials 0.000 description 2
- 150000003624 transition metals Chemical class 0.000 description 2
- MMZPUXVBQAQQDQ-UHFFFAOYSA-N triethoxy(2-pyridin-4-ylethyl)silane Chemical compound CCO[Si](OCC)(OCC)CCC1=CC=NC=C1 MMZPUXVBQAQQDQ-UHFFFAOYSA-N 0.000 description 2
- VUDZSIYXZUYWSC-DBRKOABJSA-N (4r)-1-[(2r,4r,5r)-3,3-difluoro-4-hydroxy-5-(hydroxymethyl)oxolan-2-yl]-4-hydroxy-1,3-diazinan-2-one Chemical compound FC1(F)[C@H](O)[C@@H](CO)O[C@H]1N1C(=O)N[C@H](O)CC1 VUDZSIYXZUYWSC-DBRKOABJSA-N 0.000 description 1
- IGVKWAAPMVVTFX-BUHFOSPRSA-N (e)-octadec-5-en-7,9-diynoic acid Chemical compound CCCCCCCCC#CC#C\C=C\CCCC(O)=O IGVKWAAPMVVTFX-BUHFOSPRSA-N 0.000 description 1
- USFZMSVCRYTOJT-UHFFFAOYSA-N Ammonium acetate Chemical compound N.CC(O)=O USFZMSVCRYTOJT-UHFFFAOYSA-N 0.000 description 1
- 239000005695 Ammonium acetate Substances 0.000 description 1
- 229910052693 Europium Inorganic materials 0.000 description 1
- 240000001973 Ficus microcarpa Species 0.000 description 1
- 229910004298 SiO 2 Inorganic materials 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- BHELZAPQIKSEDF-UHFFFAOYSA-N allyl bromide Chemical compound BrCC=C BHELZAPQIKSEDF-UHFFFAOYSA-N 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 229940043376 ammonium acetate Drugs 0.000 description 1
- 235000019257 ammonium acetate Nutrition 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 238000005119 centrifugation Methods 0.000 description 1
- PBAYDYUZOSNJGU-UHFFFAOYSA-N chelidonic acid Natural products OC(=O)C1=CC(=O)C=C(C(O)=O)O1 PBAYDYUZOSNJGU-UHFFFAOYSA-N 0.000 description 1
- 239000007810 chemical reaction solvent Substances 0.000 description 1
- 238000004587 chromatography analysis Methods 0.000 description 1
- 229940126214 compound 3 Drugs 0.000 description 1
- 229940125898 compound 5 Drugs 0.000 description 1
- 239000000356 contaminant Substances 0.000 description 1
- 239000013256 coordination polymer Substances 0.000 description 1
- HPNMFZURTQLUMO-UHFFFAOYSA-N diethylamine Chemical compound CCNCC HPNMFZURTQLUMO-UHFFFAOYSA-N 0.000 description 1
- 239000003480 eluent Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- CWAFVXWRGIEBPL-UHFFFAOYSA-N ethoxysilane Chemical compound CCO[SiH3] CWAFVXWRGIEBPL-UHFFFAOYSA-N 0.000 description 1
- OGPBJKLSAFTDLK-UHFFFAOYSA-N europium atom Chemical compound [Eu] OGPBJKLSAFTDLK-UHFFFAOYSA-N 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 125000005843 halogen group Chemical group 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 125000000623 heterocyclic group Chemical group 0.000 description 1
- 229910003480 inorganic solid Inorganic materials 0.000 description 1
- 239000013067 intermediate product Substances 0.000 description 1
- 238000005342 ion exchange Methods 0.000 description 1
- 229910052943 magnesium sulfate Inorganic materials 0.000 description 1
- 235000019341 magnesium sulphate Nutrition 0.000 description 1
- 238000004949 mass spectrometry Methods 0.000 description 1
- 238000001819 mass spectrum Methods 0.000 description 1
- 239000013335 mesoporous material Substances 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- GBYFDEWNIZWJMR-UHFFFAOYSA-N n,n,n',n'-tetraethyl-2-prop-1-enylpropanediamide Chemical compound CCN(CC)C(=O)C(C=CC)C(=O)N(CC)CC GBYFDEWNIZWJMR-UHFFFAOYSA-N 0.000 description 1
- SGZRFMMIONYDQU-UHFFFAOYSA-N n,n-bis(2-methylpropyl)-2-[octyl(phenyl)phosphoryl]acetamide Chemical compound CCCCCCCCP(=O)(CC(=O)N(CC(C)C)CC(C)C)C1=CC=CC=C1 SGZRFMMIONYDQU-UHFFFAOYSA-N 0.000 description 1
- 150000002823 nitrates Chemical class 0.000 description 1
- 239000012011 nucleophilic catalyst Substances 0.000 description 1
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 150000003377 silicon compounds Chemical class 0.000 description 1
- 238000000935 solvent evaporation Methods 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- WHRNULOCNSKMGB-UHFFFAOYSA-N tetrahydrofuran thf Chemical compound C1CCOC1.C1CCOC1 WHRNULOCNSKMGB-UHFFFAOYSA-N 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 238000013519 translation Methods 0.000 description 1
- QQQSFSZALRVCSZ-UHFFFAOYSA-N triethoxysilane Chemical compound CCO[SiH](OCC)OCC QQQSFSZALRVCSZ-UHFFFAOYSA-N 0.000 description 1
- 238000007738 vacuum evaporation Methods 0.000 description 1
- 229910001928 zirconium oxide Inorganic materials 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J45/00—Ion-exchange in which a complex or a chelate is formed; Use of material as complex or chelate forming ion-exchangers; Treatment of material for improving the complex or chelate forming ion-exchange properties
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Silicon Polymers (AREA)
- Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR97/13565 | 1997-10-29 | ||
| FR9713565A FR2770153B1 (fr) | 1997-10-29 | 1997-10-29 | Gels hybrides inorganiques-organiques pour l'extraction d'especes chimiques telles que les lanthanides et les actinides, et leur preparation |
| PCT/FR1998/002309 WO1999021654A1 (fr) | 1997-10-29 | 1998-10-28 | Gels hybrides inorganiques-organiques pour l'extraction d'especes chimiques telles que les lanthanides et les actinides, et leur preparation |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2001520932A true JP2001520932A (ja) | 2001-11-06 |
| JP2001520932A5 JP2001520932A5 (enExample) | 2008-11-13 |
Family
ID=9512784
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2000517801A Pending JP2001520932A (ja) | 1997-10-29 | 1998-10-28 | ランタニドとアクチニドのような化学種を抽出するための無機−有機ハイブリッドゲル並びにその調製法 |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US6667016B1 (enExample) |
| JP (1) | JP2001520932A (enExample) |
| KR (1) | KR100531108B1 (enExample) |
| FR (1) | FR2770153B1 (enExample) |
| GB (1) | GB2349347B (enExample) |
| RU (1) | RU2207190C2 (enExample) |
| WO (1) | WO1999021654A1 (enExample) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2004231590A (ja) * | 2003-01-31 | 2004-08-19 | Nippon Soda Co Ltd | シラン誘導体及び有機薄膜形成体 |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2866341B1 (fr) * | 2004-02-12 | 2006-04-28 | Commissariat Energie Atomique | Gel hybride organique-inorganique imprime comprenant un complexant organique mettant en jeu des interactions pi - pi et/ou pi-nu |
| US7534510B2 (en) | 2004-09-03 | 2009-05-19 | The Gillette Company | Fuel compositions |
| US7674864B2 (en) * | 2005-12-23 | 2010-03-09 | Boston Scientific Scimed, Inc. | Polymeric hybrid precursors, polymeric hybrid precursor composite matrices, medical devices, and methods |
| US8455088B2 (en) | 2005-12-23 | 2013-06-04 | Boston Scientific Scimed, Inc. | Spun nanofiber, medical devices, and methods |
| FR2933703B1 (fr) | 2008-07-11 | 2012-08-17 | Commissariat Energie Atomique | Detecteurs nanoporeux de composes aromatiques monocycliques et autres polluants |
| FR3013059B1 (fr) | 2013-11-08 | 2016-01-01 | Commissariat Energie Atomique | Utilisation d'un materiau hybride organique-inorganique pour extraire l'uranium(vi) d'une solution aqueuse d'acide sulfurique, issue notamment de la lixiviation sulfurique d'un minerai uranifere |
Family Cites Families (24)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB956276A (en) * | 1960-07-06 | 1964-04-22 | Wolfen Filmfab Veb | Process for the manufacture of thermostable organo silicon anion exchangers |
| DE2357184A1 (de) * | 1973-11-16 | 1975-05-22 | Merck Patent Gmbh | Verfahren zur herstellung von organisch modifizierten siliciumdioxiden |
| US4203952A (en) * | 1974-05-28 | 1980-05-20 | The British Petroleum Company Limited | Process for the removal of heavy metals and transition metals other than platinum from solution |
| US4278803A (en) * | 1980-01-07 | 1981-07-14 | Polaroid Corporation | Preparation of 2-Methylene-1,3-propanediamide |
| SU906998A1 (ru) * | 1980-04-08 | 1982-02-23 | Предприятие П/Я Г-4302 | Способ получени элементоорганических карбодиимидов |
| US4448694A (en) * | 1981-09-04 | 1984-05-15 | Dow Corning Corporation | Metal extraction from solution and immobilized chelating agents used therefor |
| DE3616133A1 (de) * | 1985-09-25 | 1987-11-19 | Merck Patent Gmbh | Kugelfoermige sio(pfeil abwaerts)2(pfeil abwaerts)-partikel |
| DE3751856T3 (de) * | 1986-10-03 | 2001-04-19 | Ppg Industries Ohio, Inc. | Organisch-anorganisches Hybridpolymer |
| US4746572A (en) * | 1986-11-28 | 1988-05-24 | E. I. Dupont De Nemours And Company | Structures surface modified with bidentate silanes |
| US4943375A (en) * | 1987-09-04 | 1990-07-24 | Brigham Young University | The process of separating a selected ion from a plurality of other ions in a multiple ion solution by contacting the solution with a macrocyclic ligand bonded to silica which selectively complexes with the desired ion |
| US5039419A (en) * | 1988-07-13 | 1991-08-13 | Brigham Young University | Sulfur-containing hydrocarbon compounds and process of using same in recovering and concentrating desired ions from solutions thereof |
| US5071819A (en) * | 1988-08-26 | 1991-12-10 | Ibc Advanced Technologies | Sulfur and nitrogen-containing hydrocarbons and process of using same in recovering and concentrating desired ions from solutions thereof |
| US5084430A (en) * | 1988-08-26 | 1992-01-28 | Brigham Young University | Sulfur and nitrogen containing hydrocarbons and process of using same in separating desired ions from solutions thereof |
| US5078978A (en) * | 1989-11-06 | 1992-01-07 | Brigham Young University | Pyridine-containing alkoxysilanes bonded to inorganic supports and processes of using the same for removing and concentrating desired ions from solutions |
| JP2795379B2 (ja) * | 1989-11-29 | 1998-09-10 | 科学技術振興事業団 | 金属配位性有機珪素ポリマーの製造方法 |
| US5158603A (en) * | 1990-03-06 | 1992-10-27 | Henkel Research Corporation | Process of extracting anions with quaternary amines |
| DE4309660A1 (de) * | 1993-03-25 | 1994-09-29 | Studiengesellschaft Kohle Mbh | Selektive anorganische Katalysatoren in Form von molekularen Abdrücken in Hohlräumen |
| JP3170529B2 (ja) | 1993-03-25 | 2001-05-28 | 大日本印刷株式会社 | トナー容器 |
| DE4319909C2 (de) * | 1993-06-16 | 1996-11-07 | Solvay Deutschland | Palladium, Platin, Nickel, Kobalt und/oder Kupfer umfassender Aerogel-Trägerkatalysator, Verfahren zu seiner Herstellung und Verwendung eines Palladium-Aerogel-Trägerkatalysators |
| RU2058317C1 (ru) * | 1994-07-18 | 1996-04-20 | Иркутский институт органической химии СО РАН | Способ получения n,n′ -бис[3-триалкил(алкокси)силилпропил]-тиомочевины |
| US5668079A (en) * | 1994-09-27 | 1997-09-16 | Syracuse University | Chemically active ceramic compositions with an hydroxyquinoline moiety |
| RU2074187C1 (ru) * | 1994-09-30 | 1997-02-27 | Иркутский институт органической химии СО РАН | Способ получения n,n'-бис(3-триалкилсилилпропил)- или n,n'-бис(3-триалкоксисилилпропил)тиокарбамидов |
| FR2725552B1 (fr) * | 1994-10-05 | 1996-10-31 | Commissariat Energie Atomique | Procede de decontamination partielle alpha d'un effluent aqueux |
| US5637135A (en) * | 1995-06-26 | 1997-06-10 | Capillary Technology Corporation | Chromatographic stationary phases and adsorbents from hybrid organic-inorganic sol-gels |
-
1997
- 1997-10-29 FR FR9713565A patent/FR2770153B1/fr not_active Expired - Lifetime
-
1998
- 1998-10-28 JP JP2000517801A patent/JP2001520932A/ja active Pending
- 1998-10-28 US US09/530,133 patent/US6667016B1/en not_active Expired - Fee Related
- 1998-10-28 KR KR10-2000-7004656A patent/KR100531108B1/ko not_active Expired - Fee Related
- 1998-10-28 GB GB0009736A patent/GB2349347B/en not_active Expired - Fee Related
- 1998-10-28 WO PCT/FR1998/002309 patent/WO1999021654A1/fr not_active Ceased
- 1998-10-28 RU RU2000113194/04A patent/RU2207190C2/ru not_active IP Right Cessation
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2004231590A (ja) * | 2003-01-31 | 2004-08-19 | Nippon Soda Co Ltd | シラン誘導体及び有機薄膜形成体 |
Also Published As
| Publication number | Publication date |
|---|---|
| FR2770153A1 (fr) | 1999-04-30 |
| GB2349347B (en) | 2001-11-14 |
| GB0009736D0 (en) | 2000-06-07 |
| US6667016B1 (en) | 2003-12-23 |
| FR2770153B1 (fr) | 1999-11-19 |
| WO1999021654A1 (fr) | 1999-05-06 |
| RU2207190C2 (ru) | 2003-06-27 |
| GB2349347A (en) | 2000-11-01 |
| KR100531108B1 (ko) | 2005-11-24 |
| KR20010031605A (ko) | 2001-04-16 |
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