RU2018122223A - Высокомодульные олефиновые соединения для буферных трубок оптоволоконного кабеля - Google Patents
Высокомодульные олефиновые соединения для буферных трубок оптоволоконного кабеля Download PDFInfo
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- RU2018122223A RU2018122223A RU2018122223A RU2018122223A RU2018122223A RU 2018122223 A RU2018122223 A RU 2018122223A RU 2018122223 A RU2018122223 A RU 2018122223A RU 2018122223 A RU2018122223 A RU 2018122223A RU 2018122223 A RU2018122223 A RU 2018122223A
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- 150000001875 compounds Chemical class 0.000 title 1
- 239000013307 optical fiber Substances 0.000 title 1
- 239000000203 mixture Substances 0.000 claims 12
- 229920001903 high density polyethylene Polymers 0.000 claims 11
- 239000004700 high-density polyethylene Substances 0.000 claims 11
- 239000004743 Polypropylene Substances 0.000 claims 10
- 229920001155 polypropylene Polymers 0.000 claims 10
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims 6
- 238000000034 method Methods 0.000 claims 5
- 239000002667 nucleating agent Substances 0.000 claims 5
- -1 polypropylene Polymers 0.000 claims 5
- 239000000945 filler Substances 0.000 claims 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims 3
- 229910000019 calcium carbonate Inorganic materials 0.000 claims 3
- 238000013329 compounding Methods 0.000 claims 3
- 239000004005 microsphere Substances 0.000 claims 3
- 239000000454 talc Substances 0.000 claims 3
- 229910052623 talc Inorganic materials 0.000 claims 3
- 150000001336 alkenes Chemical class 0.000 claims 2
- 230000002902 bimodal effect Effects 0.000 claims 2
- XXHCQZDUJDEPSX-KNCHESJLSA-L calcium;(1s,2r)-cyclohexane-1,2-dicarboxylate Chemical compound [Ca+2].[O-]C(=O)[C@H]1CCCC[C@H]1C([O-])=O XXHCQZDUJDEPSX-KNCHESJLSA-L 0.000 claims 2
- 239000002131 composite material Substances 0.000 claims 2
- 229920001577 copolymer Polymers 0.000 claims 2
- 239000011521 glass Substances 0.000 claims 2
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims 2
- 239000000463 material Substances 0.000 claims 2
- 239000000155 melt Substances 0.000 claims 2
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims 2
- 229920000642 polymer Polymers 0.000 claims 2
- YKTSYUJCYHOUJP-UHFFFAOYSA-N [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] Chemical compound [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] YKTSYUJCYHOUJP-UHFFFAOYSA-N 0.000 claims 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims 1
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 claims 1
- 239000010428 baryte Substances 0.000 claims 1
- 229910052601 baryte Inorganic materials 0.000 claims 1
- 239000000919 ceramic Substances 0.000 claims 1
- 239000004927 clay Substances 0.000 claims 1
- 229910052570 clay Inorganic materials 0.000 claims 1
- 239000010459 dolomite Substances 0.000 claims 1
- 229910000514 dolomite Inorganic materials 0.000 claims 1
- 239000010433 feldspar Substances 0.000 claims 1
- 235000013312 flour Nutrition 0.000 claims 1
- 239000008187 granular material Substances 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 claims 1
- 239000010445 mica Substances 0.000 claims 1
- 229910052618 mica group Inorganic materials 0.000 claims 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims 1
- 239000004576 sand Substances 0.000 claims 1
- 239000000377 silicon dioxide Substances 0.000 claims 1
- 235000012239 silicon dioxide Nutrition 0.000 claims 1
- 229920001169 thermoplastic Polymers 0.000 claims 1
- 239000004416 thermosoftening plastic Substances 0.000 claims 1
- 239000010456 wollastonite Substances 0.000 claims 1
- 229910052882 wollastonite Inorganic materials 0.000 claims 1
- 239000002023 wood Substances 0.000 claims 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/06—Polyethene
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/03—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
- B29C48/09—Articles with cross-sections having partially or fully enclosed cavities, e.g. pipes or channels
- B29C48/10—Articles with cross-sections having partially or fully enclosed cavities, e.g. pipes or channels flexible, e.g. blown foils
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/01—Use of inorganic substances as compounding ingredients characterized by their specific function
- C08K3/013—Fillers, pigments or reinforcing additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
- C08K5/0083—Nucleating agents promoting the crystallisation of the polymer matrix
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/12—Polypropene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/06—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to homopolymers or copolymers of aliphatic hydrocarbons containing only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
- H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
- H01B3/30—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
- H01B3/44—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins
- H01B3/441—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins from alkenes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/18—Applications used for pipes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/08—Polymer mixtures characterised by other features containing additives to improve the compatibility between two polymers
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B6/00—Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings
- G02B6/44—Mechanical structures for providing tensile strength and external protection for fibres, e.g. optical transmission cables
- G02B6/4401—Optical cables
- G02B6/4429—Means specially adapted for strengthening or protecting the cables
- G02B6/44384—Means specially adapted for strengthening or protecting the cables the means comprising water blocking or hydrophobic materials
Claims (29)
1. Композиция, содержащая, в массовых процентах (мас. %) в расчете на массу композиции:
(A) 22-49% полипропилена (ПП),
(B) 50-65% полиэтилена высокой плотности (ПЭВП),
(C) 7-12% средства для обеспечения совместимости, содержащее следующие компоненты, содержание которых выражено в мас. % в расчете на массу средства для обеспечения совместимости:
(1) 30-90% олефинового блок-композита, содержащего сополимер этилена-пропилена (ЭП), изотактический полипропилен (иПП) и диблок-полимер ЭП-иПП, и
(2) 10-70% ПЭВП, привитого малеиновым ангидридом (MAH-g-ПЭВП),
(D) 0,05-5,0% нуклеирующего агента.
2. Композиция по п. 1, отличающаяся тем, что ПЭВП представляет собой бимодальный ПЭВП (b-ПЭВП).
3. Композиция по п. 1, отличающаяся тем, что ПП представляет собой полипропилен с высокой степенью кристалличности с показателем текучести расплава (ПТР) менее или ровно (≤) 12 г/10 мин. (230 °C/2,16 кг).
4. Композиция по п. 1, отличающаяся тем, что нуклеирующий агент представляет собой по меньшей мере один из NA-11, HPN-20E, талька и карбоната кальция.
5. Композиция по п. 1, дополнительно содержащая наполнитель.
6. Композиция по п. 5, отличающаяся тем, что наполнитель присутствует в количестве от более 0 до 60 мас. % в расчете на общую массу композиции.
7. Композиция по п. 6, отличающаяся тем, что наполнитель представляет собой по меньшей мере один из следующих материалов: песок, тальк, доломит, карбонат кальция, глина, диоксид кремния, слюда, волластонит, полевой шпат, силикат алюминия, оксид алюминия, гидратированный оксид алюминия, стеклянные гранулы, стеклянная микросфера, керамическая микросфера, термопластичная микросфера, барит, древесная мука и комбинации двух или более указанных материалов.
8. Композиция по п. 1 без наполнителя, в которой нуклеирующий агент присутствует в количестве менее 1 мас. % в расчете на общую массу композиции.
9. Способ изготовления трубки, включающий стадии:
(I) компаундирования:
(A) 22-49% полипропилена (ПП),
(B) 50-65% полиэтилена высокой плотности (ПЭВП),
(C) 7-12% средства для обеспечения совместимости, содержащего следующие компоненты, содержание которых выражено в мас. % в расчете на массу средства для обеспечения совместимости:
(1) 30-90% олефинового блок-композита, содержащего сополимер этилена-пропилена (ЭП), изотактический полипропилен (иПП) и диблок-полимер ЭП-иПП, и
(2) 10-70% ПЭВП, привитого малеиновым ангидридом (MAH-g-ПЭВП),
(D) 0,05-5,0% нуклеирующего агента; и
(II) экструзии смеси (a) в форму трубки.
10. Способ по п. 9, отличающийся тем, что компаундирование представляет собой компаундирование в расплаве.
11. Трубка, изготовленная способом по п. 9.
12. Кабель, содержащий трубку по п. 11.
13. Способ по п. 9, отличающийся тем, что ПЭВП является бимодальным.
14. Способ по п. 9, отличающийся тем, что ПП представляет собой ПП с высокой степенью кристалличности с ПТР (≤) 12 г/10 мин. (230 °С/2,16 кг).
15. Способ по п. 9, отличающийся тем, что нуклеирующий агент представляет собой по меньшей мере один из NA-11, HPN-20E, талька и карбоната кальция.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201562265735P | 2015-12-10 | 2015-12-10 | |
| US62/265,735 | 2015-12-10 | ||
| PCT/US2016/065109 WO2017100175A1 (en) | 2015-12-10 | 2016-12-06 | High modulus olefin compounds for fiber optic cable buffer tubes |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| RU2018122223A true RU2018122223A (ru) | 2019-12-19 |
| RU2018122223A3 RU2018122223A3 (ru) | 2020-03-04 |
| RU2739982C2 RU2739982C2 (ru) | 2020-12-30 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RU2018122223A RU2739982C2 (ru) | 2015-12-10 | 2016-12-06 | Высокомодульные олефиновые соединения для буферных трубок оптоволоконного кабеля |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US11034823B2 (ru) |
| EP (1) | EP3387065B1 (ru) |
| JP (1) | JP6906517B2 (ru) |
| KR (1) | KR102606076B1 (ru) |
| CN (1) | CN108291064B (ru) |
| BR (1) | BR112018010314B1 (ru) |
| CA (1) | CA3007770C (ru) |
| MX (1) | MX2018006358A (ru) |
| RU (1) | RU2739982C2 (ru) |
| WO (1) | WO2017100175A1 (ru) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2717347C1 (ru) * | 2016-03-25 | 2020-03-23 | Дау Глоубл Текнолоджиз Ллк | Буферные трубки для оптоволоконных кабелей |
| EP3645623B1 (en) * | 2017-06-29 | 2021-05-19 | Dow Global Technologies LLC | Plastic living hinges with block composite polymer |
| WO2019000360A1 (en) | 2017-06-30 | 2019-01-03 | Dow Global Technologies Llc | FILLING COMPOSITION FOR FIBER OPTIC CABLES |
| KR102545899B1 (ko) | 2017-09-06 | 2023-06-22 | 롬 앤드 하스 캄파니 | 광섬유 케이블 구성요소를 위한 중합체성 조성물 |
| TWI762739B (zh) * | 2017-11-13 | 2022-05-01 | 美商比瑞全球股份有限公司 | 包括具有改善成分間黏著的多成分纖維的非織布及其形成方法 |
| WO2021032378A1 (en) * | 2019-08-18 | 2021-02-25 | Sabic Global Technologies B.V. | Use of a composition for the manufacture of a foamed article |
| CA3161845A1 (en) | 2019-12-18 | 2021-06-24 | Krischan JELTSCH | Halogen free flame retardant polymeric compositions |
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| US8785554B2 (en) | 2010-06-21 | 2014-07-22 | Dow Global Technologies Llc | Crystalline block composites as compatibilizers |
| BR112012032683B1 (pt) * | 2010-06-21 | 2020-12-29 | Dow Global Technologies Llc | composição |
| KR102010107B1 (ko) * | 2011-12-14 | 2019-10-21 | 다우 글로벌 테크놀로지스 엘엘씨 | 상용화제로서 작용화된 블록 복합체 및 결정질 블록 복합체 조성물 |
| SG10201700173TA (en) * | 2011-12-14 | 2017-03-30 | Dow Global Technologies Llc | Functionalized block composite and crystalline block composite compositions |
| KR102157916B1 (ko) * | 2012-12-21 | 2020-09-18 | 다우 글로벌 테크놀로지스 엘엘씨 | 광섬유 케이블 내의 개선된 과잉 섬유 길이를 갖는 hdpe-기재 완충관 |
| BR112016012925B1 (pt) | 2013-12-18 | 2021-08-10 | Dow Global Technologies Llc | Composição polimérica, componente de proteção de cabo ótico extrusado e cabo de fibra ótica |
-
2016
- 2016-12-06 WO PCT/US2016/065109 patent/WO2017100175A1/en active Application Filing
- 2016-12-06 CN CN201680069877.3A patent/CN108291064B/zh active Active
- 2016-12-06 BR BR112018010314-4A patent/BR112018010314B1/pt active IP Right Grant
- 2016-12-06 KR KR1020187017310A patent/KR102606076B1/ko active IP Right Grant
- 2016-12-06 CA CA3007770A patent/CA3007770C/en active Active
- 2016-12-06 EP EP16816128.9A patent/EP3387065B1/en active Active
- 2016-12-06 JP JP2018526230A patent/JP6906517B2/ja active Active
- 2016-12-06 RU RU2018122223A patent/RU2739982C2/ru active
- 2016-12-06 MX MX2018006358A patent/MX2018006358A/es unknown
- 2016-12-06 US US15/781,587 patent/US11034823B2/en active Active
Also Published As
| Publication number | Publication date |
|---|---|
| BR112018010314A2 (pt) | 2018-12-04 |
| RU2739982C2 (ru) | 2020-12-30 |
| CN108291064A (zh) | 2018-07-17 |
| BR112018010314B1 (pt) | 2022-01-25 |
| JP6906517B2 (ja) | 2021-07-21 |
| CA3007770A1 (en) | 2017-06-15 |
| CN108291064B (zh) | 2021-05-25 |
| RU2018122223A3 (ru) | 2020-03-04 |
| WO2017100175A1 (en) | 2017-06-15 |
| US20200263006A1 (en) | 2020-08-20 |
| CA3007770C (en) | 2024-01-02 |
| JP2019501246A (ja) | 2019-01-17 |
| KR20180092994A (ko) | 2018-08-20 |
| EP3387065A1 (en) | 2018-10-17 |
| EP3387065B1 (en) | 2021-07-14 |
| KR102606076B1 (ko) | 2023-11-27 |
| US11034823B2 (en) | 2021-06-15 |
| MX2018006358A (es) | 2018-09-05 |
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