RU2016152223A - Способ активации катализаторов гидрообработки - Google Patents

Способ активации катализаторов гидрообработки Download PDF

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RU2016152223A
RU2016152223A RU2016152223A RU2016152223A RU2016152223A RU 2016152223 A RU2016152223 A RU 2016152223A RU 2016152223 A RU2016152223 A RU 2016152223A RU 2016152223 A RU2016152223 A RU 2016152223A RU 2016152223 A RU2016152223 A RU 2016152223A
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range
nitrogen compound
nitrogen
gmol
catalyst
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RU2016152223A
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RU2719483C2 (ru
RU2016152223A3 (ru
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Франсис Юмбло
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Аркема Франс
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    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/888—Tungsten
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    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/24—Nitrogen compounds
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    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
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    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
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    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
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    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
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    • C10G45/60—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins characterised by the catalyst used
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G47/00—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
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    • B01J38/64—Liquid treating or treating in liquid phase, e.g. dissolved or suspended using alkaline material; using salts
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    • C10G2300/70—Catalyst aspects
    • C10G2300/703—Activation

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Claims (27)

1. Применение в способе активации in situ катализатора гидрообработки, по меньшей мере, одного соединения азота, имеющего, по меньшей мере, две, более предпочтительно, по меньшей мере, три, а еще более предпочтительно, по меньшей мере, четыре следующих далее характеристики:
a) содержание азота по массе в пределах от 15 до 35% масс, предпочтительно, в пределах от 20 до 35%, более предпочтительно, в пределах от 20 до 30%, и более преимущественно, в пределах от 20 до 25%, по отношению к общей массе соединения азота;
b) количество атомов азота в пределах от 2 до 20, предпочтительно, в пределах от 2 до 15, более предпочтительно, в пределах от 2 до 10, еще более предпочтительно, в пределах от 2 до 5, на молекулу, преимущественно, два атома азота на молекулу;
c) температуру кипения в пределах от 140°C до 300°C, предпочтительно, в пределах от 140°C до 250°C, более предпочтительно, в пределах от 140°C до 200°C, еще более предпочтительно, в пределах от 140°C до 175°C; и
d) указанное соединение азота находится в жидкой форме при комнатной температуре и при атмосферном давлении.
2. Применение по п.1, в котором соединение азота имеет, в дополнение к этому, молекулярную массу в пределах от 80 г⋅моль-1 до 300 г⋅моль-1, предпочтительно, в пределах от 100 г⋅моль-1 до 250 г⋅моль-1, еще более предпочтительно, в пределах от 100 г⋅моль-1 до 200 г⋅моль-1, преимущественно, в пределах от 120 г⋅моль-1 до 150 г⋅моль-1; определяемую далее как характеристика e).
3. Применение по любому из предыдущих пунктов, в котором соединение азота имеет характеристику f) такую, что указанное соединение азота не содержит ароматической или циклической группы.
4. Применение по любому из предыдущих пунктов, в котором указанное, по меньшей мере, одно соединение азота обязательно имеет характеристику b).
5. Применение по любому из пп.1-4, в котором соединение азота выбирают из N,N'-диэтил-1,3-пропандиамина (DEAPA), тетраметил-1,3-пропандиамина (TMPDA), N-метил-1,3-пропандиамина, N,N'-дибутил-1,3-пропандиамина, N-(3-диметиламинопропил)пропан-1,3-диамина (DMAPAPA), N-(3-аминопропил)-1,3-пропандиамина, N,N'-1,2-этандиил-бис-1,3-пропандиамина, N-(аминопропил)диэтаноламина (APDEA) и их смесей.
6. Применение соединения азота или соединения, как определено в любом из предыдущих пунктов, для контроля активности, по меньшей мере, одного катализатора гидрообработки.
7. Применение соединения азота или соединения, как определено в любом из пп.1-4, для пассивации кислотных активных центров катализатора гидрообработки.
8. Применение по любому из предыдущих пунктов, в способе активации in situ, по меньшей мере, одного соединения азота, имеющего, по меньшей мере, две, более предпочтительно, по меньшей мере, три, а еще более предпочтительно, по меньшей мере, четыре следующих характеристики:
a) содержание азота по массе в пределах от 15 до 35% масс, предпочтительно, в пределах от 20 до 35%, более предпочтительно, в пределах от 20 до 30%, и более преимущественно, в пределах от 20 до 25%, по отношению к общей массе соединения азота;
b) количество атомов азота в пределах от 2 до 20, предпочтительно, в пределах от 2 до 15, более предпочтительно, в пределах от 2 до 10, еще более предпочтительно, в пределах от 2 до 5, на молекулу, преимущественно, два атома азота на молекулу;
c) температуру кипения в пределах от 140°C до 300°C, предпочтительно, в пределах от 140°C до 250°C, более предпочтительно, в пределах от 140°C до 200°C, еще более предпочтительно, в пределах от 140°C до 175°C; и
d) указанное соединение азота находится в жидкой форме при комнатной температуре и при атмосферном давлении.
9. Применение по п.8, в котором указанное, по меньшей мере, одно соединение азота обязательно имеет характеристику b).
10. Способ активации in situ, по меньшей мере, одного катализатора гидрообработки, включающий, по меньшей мере:
1) стадию сульфидирования указанного катализатора гидрообработки в присутствии сульфидирующего агента и
2) стадию пассивации указанного катализатора гидрообработки в присутствии, по меньшей мере, одного соединения азота, как определено по любому из пп.1-4.
11. Способ по п.10, в котором стадию сульфидирования и стадию пассивации осуществляют одновременно.
12. Способ по п.10 или 11, в котором соединение азота инжектируется в жидкой фазе или в газовой фазе, предпочтительно, в жидкой фазе.
13. Способ по любому из пп.10-12, в котором соединение азота инжектируется при содержании в пределах от 0,01 до 20% масс, предпочтительно, от 0,01 до 10% масс, более предпочтительно, от 0,01 до 5% масс, по отношению к общей массе катализатора гидрообработки.
14. Способ по любому из пп.10-13, в котором на стадии сульфидирования, сульфидирующий агент выбирается из сернистого водорода, дисульфида углерода, диметилдисульфида (DMDS), диметилсульфида, меркаптанов, тиофенов и их производных, алкилполисульфидов, диалкилполисульфидов и всех сульфидных соединений, способных к сульфидированию оксидов металлов катализаторов гидрообработки, а предпочтительно, сульфидирующий агент представляет собой DMDS.
15. Способ активации in situ по любому из пп.10-14, по меньшей мере, одного катализатора гидрокрекинга, включающий, по меньшей мере:
1) стадию сульфидирования указанного катализатора гидрокрекинга в присутствии сульфидирующего агента; и
2) стадию пассивации указанного катализатора гидрокрекинга в присутствии, по меньшей мере, одного соединения азота, как определено по любому из пп.1-5.
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