RU2016122205A - Материал покрытия - Google Patents

Материал покрытия Download PDF

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RU2016122205A
RU2016122205A RU2016122205A RU2016122205A RU2016122205A RU 2016122205 A RU2016122205 A RU 2016122205A RU 2016122205 A RU2016122205 A RU 2016122205A RU 2016122205 A RU2016122205 A RU 2016122205A RU 2016122205 A RU2016122205 A RU 2016122205A
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coating material
paragraphs
coating
containing particles
material according
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Мартин КАТРАЙН
Майкл О'САЛЛИВАН
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Планзее ЗЕ
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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C27/00Alloys based on rhenium or a refractory metal not mentioned in groups C22C14/00 or C22C16/00
    • C22C27/06Alloys based on chromium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F1/00Metallic powder; Treatment of metallic powder, e.g. to facilitate working or to improve properties
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F1/00Metallic powder; Treatment of metallic powder, e.g. to facilitate working or to improve properties
    • B22F1/05Metallic powder characterised by the size or surface area of the particles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F1/00Metallic powder; Treatment of metallic powder, e.g. to facilitate working or to improve properties
    • B22F1/14Treatment of metallic powder
    • B22F1/148Agglomerating
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
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    • B22F9/00Making metallic powder or suspensions thereof
    • B22F9/16Making metallic powder or suspensions thereof using chemical processes
    • B22F9/18Making metallic powder or suspensions thereof using chemical processes with reduction of metal compounds
    • B22F9/20Making metallic powder or suspensions thereof using chemical processes with reduction of metal compounds starting from solid metal compounds
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    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C19/00Alloys based on nickel or cobalt
    • C22C19/03Alloys based on nickel or cobalt based on nickel
    • C22C19/05Alloys based on nickel or cobalt based on nickel with chromium
    • C22C19/058Alloys based on nickel or cobalt based on nickel with chromium without Mo and W
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    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/06Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the coating material
    • C23C14/14Metallic material, boron or silicon
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C24/00Coating starting from inorganic powder
    • C23C24/02Coating starting from inorganic powder by application of pressure only
    • C23C24/04Impact or kinetic deposition of particles
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    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C24/00Coating starting from inorganic powder
    • C23C24/08Coating starting from inorganic powder by application of heat or pressure and heat
    • C23C24/082Coating starting from inorganic powder by application of heat or pressure and heat without intermediate formation of a liquid in the layer
    • C23C24/085Coating with metallic material, i.e. metals or metal alloys, optionally comprising hard particles, e.g. oxides, carbides or nitrides
    • C23C24/087Coating with metal alloys or metal elements only
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C4/00Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
    • C23C4/04Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge characterised by the coating material
    • C23C4/06Metallic material
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    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C4/00Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
    • C23C4/04Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge characterised by the coating material
    • C23C4/06Metallic material
    • C23C4/073Metallic material containing MCrAl or MCrAlY alloys, where M is nickel, cobalt or iron, with or without non-metal elements
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C4/00Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
    • C23C4/04Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge characterised by the coating material
    • C23C4/06Metallic material
    • C23C4/08Metallic material containing only metal elements
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    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C4/00Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
    • C23C4/04Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge characterised by the coating material
    • C23C4/10Oxides, borides, carbides, nitrides or silicides; Mixtures thereof
    • C23C4/11Oxides
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    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C4/00Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
    • C23C4/12Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge characterised by the method of spraying
    • C23C4/129Flame spraying
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F2301/00Metallic composition of the powder or its coating
    • B22F2301/20Refractory metals
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F2998/00Supplementary information concerning processes or compositions relating to powder metallurgy
    • B22F2998/10Processes characterised by the sequence of their steps

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
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  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Plasma & Fusion (AREA)
  • Physics & Mathematics (AREA)
  • General Chemical & Material Sciences (AREA)
  • Coating By Spraying Or Casting (AREA)
  • Powder Metallurgy (AREA)
  • Other Surface Treatments For Metallic Materials (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)
  • Paints Or Removers (AREA)
  • Manufacture Of Metal Powder And Suspensions Thereof (AREA)
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Claims (32)

1. Материал покрытия, содержащий богатые Cr области, имеющие содержание Cr>95 мас.%, которые образуют Cr-содержащие частицы, отличающийся тем, что по меньшей мере часть Cr-содержащих частиц присутствует в форме агрегатов или агломератов.
2. Материал покрытия, содержащий богатые Cr области, имеющие содержание Cr>95 мас.%, которые образуют Cr-содержащие частицы, отличающийся тем, что по меньшей мере часть Cr-содержащих частиц имеет поры.
3. Материал покрытия, содержащий богатые Cr области, имеющие содержание Cr>95 мас.%, которые образуют Cr-содержащие частицы, отличающийся тем, что богатые Cr области имеют среднюю нанотвердость HIT 0,005/5/1/5 ≤ 4 ГПа.
4. Материал покрытия, содержащий богатые Cr области, имеющие содержание Cr>95 мас.%, которые образуют Cr-содержащие частицы, отличающийся тем, что Cr-содержащие частицы имеют среднюю площадь поверхности, измеренную по методу БЭТ, >0,05 м2/г.
5. Материал покрытия по пп. 1 и 2 или 4, отличающийся тем, что богатые Cr области имеют среднюю нанотвердость HIT 0,005/5/1/5 ≤ 4 ГПа.
6. Материал покрытия по пп. 1 и 3 или 4, отличающийся тем, что по меньшей мере часть Cr-содержащих частиц имеет поры.
7. Материал покрытия по пп. 2 и 3 или 4, отличающийся тем, что по меньшей мере часть Cr-содержащих частиц присутствует в форме агрегатов или агломератов.
8. Материал покрытия по пп. 1 и 2 или 3, отличающийся тем, что Cr-содержащие частицы имеют среднюю площадь поверхности, измеренную по методу БЭТ, >0,05 м2/г.
9. Материал покрытия по любому из пп. 1-4, отличающийся тем, что он присутствует в порошковой или гранулированной форме.
10. Материал покрытия по любому из пп. 1-4, отличающийся тем, что по меньшей мере часть Cr-содержащих частиц имеет среднюю пористость, определенную посредством количественного анализа изображений, составляющую >10 об. %.
11. Материал покрытия по любому из пп. 1-4, отличающийся тем, что на поверхность Cr-содержащих частиц, по меньшей мере в областях, нанесен материал, который имеет более низкий предел текучести, чем Cr.
12. Материал покрытия по любому из пп. 1-4, отличающийся тем, что Cr-содержащие частицы имеют средний размер частиц/размер гранул d50, измеренный посредством лазерной дифрактометрии, составляющий 5 мкм < d50 < 150 мкм.
13. Материал покрытия по любому из пп. 1-4, отличающийся тем, что материал покрытия содержит по меньшей мере один компонент из группы, состоящей из твердого материала и смазочного материала.
14. Материал покрытия по любому из пп. 1-4, отличающийся тем, что материал покрытия содержит по меньшей мере один дополнительный металл или является составляющим компонентом смеси порошков.
15. Материал покрытия по п. 14, отличающийся тем, что смесь порошков имеет состав сплава MCrAlY.
16. Материал покрытия по любому из пп. 1-4, отличающийся тем, что содержание Cr составляет >50 мас.%.
17. Способ получения покрытия с использованием материала покрытия по любому из пп. 1-16.
18. Способ по п. 17, отличающийся тем, что получение материала покрытия включает восстановление по меньшей мере одного соединения из группы, состоящей из оксида Cr и гидроксида Cr, возможно с добавленным источником твердого углерода, при по меньшей мере временном воздействии водорода и углеводорода.
19. Способ по п. 17, отличающийся тем, что покрытие получают путем способа термического напыления.
20. Способ по любому из пп. 17-19, отличающийся тем, что покрытие получают путем холодного газодинамического напыления.
21. Способ по п. 20, отличающийся тем, что он включает по меньшей мере следующие стадии:
- поставка технологического газа, имеющего давление от 1 до 10 МПа (от 10 до 100 бар) и температуру от комнатной температуры до 1400°C,
- ускорение технологического газа в сужающемся - расширяющемся сопле,
- введение материала покрытия в технологический газ выше по потоку или ниже по потоку от сужающегося - расширяющегося сопла,
- образование плотно присоединенного покрытия после соударения материала покрытия с подложкой.
22. Способ по п. 21, отличающийся тем, что технологический газ является азотом или богатым азотом газом.
23. Способ по любому из пп. 17-19, отличающийся тем, что покрытие получают путем высокоскоростного газопламенного напыления.
24. Покрытие, имеющее содержание Cr>50 мас.%, среднюю толщину >20 мкм и микроструктуру, которая содержит по меньшей мере частично деформированные Cr-содержащие зерна.
25. Покрытие по п. 24, отличающееся тем, что деформированные Cr-содержащие зерна являются холоднодеформированными.
26. Покрытие по п. 24, отличающееся тем, что по меньшей мере часть зерен вытянута в направлении, параллельном поверхности слоя.
27. Покрытие по п. 26, отличающееся тем, что зерна имеют среднее аспектное отношение >1,3.
28. Покрытие по любому из пп. 24-27, отличающееся тем, что деформированные Cr-содержащие зерна имеют среднюю нанотвердость HIT 0,005/5/1/5 > 4 ГПа.
RU2016122205A 2013-12-20 2014-12-17 Материал покрытия RU2674050C1 (ru)

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ATGM458/2013 2013-12-20
AT4582013 2013-12-20
PCT/AT2014/000226 WO2015089534A2 (de) 2013-12-20 2014-12-17 Beschichtungsstoff

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EP (1) EP3083108B1 (ru)
JP (1) JP6694817B2 (ru)
KR (1) KR20160099567A (ru)
CN (1) CN106133191B (ru)
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US11781223B2 (en) 2021-06-16 2023-10-10 The Boeing Company Repair coating and method for repairing a damaged portion of a steel member

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EP3083108A2 (de) 2016-10-26
CN106133191B (zh) 2020-07-07
CN106133191A (zh) 2016-11-16
WO2015089534A2 (de) 2015-06-25
WO2015089534A3 (de) 2015-08-13
JP6694817B2 (ja) 2020-05-20
US10837088B2 (en) 2020-11-17
RU2674050C1 (ru) 2018-12-04
US20170002444A1 (en) 2017-01-05
KR20160099567A (ko) 2016-08-22
JP2017508870A (ja) 2017-03-30

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