RU2015143885A - 4-амино-6-(гетероциклил)пиколинаты и 6-амино-2-(гетероциклил)пиримидин-4-карбоксилаты и их применение в качестве гербицидов - Google Patents
4-амино-6-(гетероциклил)пиколинаты и 6-амино-2-(гетероциклил)пиримидин-4-карбоксилаты и их применение в качестве гербицидов Download PDFInfo
- Publication number
- RU2015143885A RU2015143885A RU2015143885A RU2015143885A RU2015143885A RU 2015143885 A RU2015143885 A RU 2015143885A RU 2015143885 A RU2015143885 A RU 2015143885A RU 2015143885 A RU2015143885 A RU 2015143885A RU 2015143885 A RU2015143885 A RU 2015143885A
- Authority
- RU
- Russia
- Prior art keywords
- alkyl
- hydrogen
- alkoxy
- halogen
- haloalkyl
- Prior art date
Links
- 125000000623 heterocyclic group Chemical group 0.000 title 2
- 239000004009 herbicide Substances 0.000 title 1
- SIOXPEMLGUPBBT-UHFFFAOYSA-N picolinic acid Chemical class OC(=O)C1=CC=CC=N1 SIOXPEMLGUPBBT-UHFFFAOYSA-N 0.000 title 1
- YPOXGDJGKBXRFP-UHFFFAOYSA-N pyrimidine-4-carboxylic acid Chemical class OC(=O)C1=CC=NC=N1 YPOXGDJGKBXRFP-UHFFFAOYSA-N 0.000 title 1
- 229910052739 hydrogen Inorganic materials 0.000 claims 38
- 239000001257 hydrogen Substances 0.000 claims 38
- 150000002431 hydrogen Chemical group 0.000 claims 28
- 150000001875 compounds Chemical class 0.000 claims 22
- 229910052736 halogen Inorganic materials 0.000 claims 21
- 150000002367 halogens Chemical group 0.000 claims 21
- -1 C 1 -C 3 alkoxy Chemical group 0.000 claims 13
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 10
- 125000004455 (C1-C3) alkylthio group Chemical group 0.000 claims 8
- 125000006677 (C1-C3) haloalkoxy group Chemical group 0.000 claims 8
- 125000000217 alkyl group Chemical group 0.000 claims 8
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims 8
- 239000000460 chlorine Substances 0.000 claims 6
- 125000002485 formyl group Chemical group [H]C(*)=O 0.000 claims 6
- 229910052801 chlorine Inorganic materials 0.000 claims 5
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims 5
- 125000004765 (C1-C4) haloalkyl group Chemical group 0.000 claims 4
- 125000000171 (C1-C6) haloalkyl group Chemical group 0.000 claims 4
- 125000006656 (C2-C4) alkenyl group Chemical group 0.000 claims 4
- 125000003342 alkenyl group Chemical group 0.000 claims 4
- 125000003545 alkoxy group Chemical group 0.000 claims 4
- 125000000304 alkynyl group Chemical group 0.000 claims 4
- 229910052731 fluorine Inorganic materials 0.000 claims 4
- 125000001188 haloalkyl group Chemical group 0.000 claims 4
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims 4
- 229920006395 saturated elastomer Polymers 0.000 claims 4
- SNOOUWRIMMFWNE-UHFFFAOYSA-M sodium;6-[(3,4,5-trimethoxybenzoyl)amino]hexanoate Chemical compound [Na+].COC1=CC(C(=O)NCCCCCC([O-])=O)=CC(OC)=C1OC SNOOUWRIMMFWNE-UHFFFAOYSA-M 0.000 claims 4
- 125000001424 substituent group Chemical group 0.000 claims 3
- 125000004454 (C1-C6) alkoxycarbonyl group Chemical group 0.000 claims 2
- 125000004739 (C1-C6) alkylsulfonyl group Chemical group 0.000 claims 2
- 125000006650 (C2-C4) alkynyl group Chemical group 0.000 claims 2
- 125000005913 (C3-C6) cycloalkyl group Chemical group 0.000 claims 2
- 125000006017 1-propenyl group Chemical group 0.000 claims 2
- 150000001204 N-oxides Chemical class 0.000 claims 2
- 125000003282 alkyl amino group Chemical group 0.000 claims 2
- 125000004448 alkyl carbonyl group Chemical group 0.000 claims 2
- 125000004414 alkyl thio group Chemical group 0.000 claims 2
- 125000003710 aryl alkyl group Chemical group 0.000 claims 2
- 125000004093 cyano group Chemical group *C#N 0.000 claims 2
- 125000001559 cyclopropyl group Chemical group [H]C1([H])C([H])([H])C1([H])* 0.000 claims 2
- 125000000262 haloalkenyl group Chemical group 0.000 claims 2
- 125000004438 haloalkoxy group Chemical group 0.000 claims 2
- 125000004992 haloalkylamino group Chemical group 0.000 claims 2
- 125000004692 haloalkylcarbonyl group Chemical group 0.000 claims 2
- 125000004995 haloalkylthio group Chemical group 0.000 claims 2
- 230000002363 herbicidal effect Effects 0.000 claims 2
- 125000004433 nitrogen atom Chemical group N* 0.000 claims 2
- 150000003839 salts Chemical class 0.000 claims 2
- 125000004890 (C1-C6) alkylamino group Chemical group 0.000 claims 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims 1
- 239000002671 adjuvant Substances 0.000 claims 1
- 230000009286 beneficial effect Effects 0.000 claims 1
- 125000001153 fluoro group Chemical group F* 0.000 claims 1
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 claims 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims 1
- 229920002554 vinyl polymer Polymers 0.000 claims 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D405/00—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom
- C07D405/02—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom containing two hetero rings
- C07D405/10—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom containing two hetero rings linked by a carbon chain containing aromatic rings
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/08—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing solids as carriers or diluents
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
- A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/54—1,3-Diazines; Hydrogenated 1,3-diazines
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
- C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
- C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D213/06—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom containing only hydrogen and carbon atoms in addition to the ring nitrogen atom
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
- C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
- C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D213/78—Carbon atoms having three bonds to hetero atoms, with at the most one bond to halogen, e.g. ester or nitrile radicals
- C07D213/79—Acids; Esters
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D239/00—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings
- C07D239/02—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings
- C07D239/24—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D401/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom
- C07D401/02—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings
- C07D401/04—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings directly linked by a ring-member-to-ring-member bond
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N41/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom
- A01N41/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom containing a sulfur-to-oxygen double bond
- A01N41/10—Sulfones; Sulfoxides
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/80—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/90—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D403/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, not provided for by group C07D401/00
- C07D403/02—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, not provided for by group C07D401/00 containing two hetero rings
- C07D403/04—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, not provided for by group C07D401/00 containing two hetero rings directly linked by a ring-member-to-ring-member bond
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D405/00—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom
- C07D405/02—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom containing two hetero rings
- C07D405/04—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom containing two hetero rings directly linked by a ring-member-to-ring-member bond
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D409/00—Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms
- C07D409/02—Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms containing two hetero rings
- C07D409/04—Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms containing two hetero rings directly linked by a ring-member-to-ring-member bond
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D411/00—Heterocyclic compounds containing two or more hetero rings, at least one ring having oxygen and sulfur atoms as the only ring hetero atoms
- C07D411/02—Heterocyclic compounds containing two or more hetero rings, at least one ring having oxygen and sulfur atoms as the only ring hetero atoms containing two hetero rings
- C07D411/04—Heterocyclic compounds containing two or more hetero rings, at least one ring having oxygen and sulfur atoms as the only ring hetero atoms containing two hetero rings directly linked by a ring-member-to-ring-member bond
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Dentistry (AREA)
- Plant Pathology (AREA)
- Engineering & Computer Science (AREA)
- Pest Control & Pesticides (AREA)
- Agronomy & Crop Science (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Toxicology (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Plural Heterocyclic Compounds (AREA)
- Pyridine Compounds (AREA)
Claims (76)
1. Соединение формулы (I)
где
X означает N или CY, где Y представляет собой водород, галоген, C1-C3 алкил, C1-C3 галогеналкил, C1-C3 алкокси, C1-C3 галогеналкокси, C1-C3 алкокси, C1-C3 алкилтио или C1-C3 галогеналкилтио;
R1 представляет собой OR1' или NR1"R1"', где R1' представляет собой водород, C1-C8 алкил или C7-C10 арилалкил, и R1" и R1"', независимо представляют собой водород, C1-C12 алкил, C3-C12 алкенил или C3-C12 алкинил;
R2 означает галоген, C1-C4 алкил, C1-C4 галогеналкил, C2-C4 алкенил, C2-C4 галогеналкенил, C2-C4 алкинил, C1-C4 алкокси, C1-C4 галогеналкокси, C1-C4 алкилтио, C1-C4 галогеналкилтио, амино, C1-C4 алкиламино, C2-C4 галогеналкиламино, формил, C1-C3 алкилкарбонил, C1-C3 галогеналкилкарбонил, циано или группу формулы -CR17=CR18-SiR19R20R21, где R17 означает водород, F или Cl; R18 означает водород, F, Cl, C1-C4 алкил или C1-C4 галогеналкил, и R19, R20 и R21 независимо представляют собой C1-C10 алкил, C3-C6 циклоалкил, фенил, замещенный фенил, C1-C10 алкокси или OH;
R3 и R4 независимо представляют собой водород, C1-C6 алкил, C1-C6 галогеналкил, C3-C6 алкенил, C3-C6 галогеналкил, C3-C6 алкинил, формил, C1-C3 алкилкарбонил, C1-C3 галогеналкилкарбонил, C1-C6 алкоксикарбонил, C1-C6 алкилкарбамил, C1-C6 алкилсульфонил, C1-C6 триалкилсилил, C1-C6 диалкилфосфонил, или R3 и R4 совместно с атомом N образуют 5- или 6-членный насыщенный или ненасыщенный цикл, или же R3 и R4 совместно представляют собой =СR3'(R4'), где R3' и R4' независимо представляют собой водород, C1-C6 алкил, C3-C6 алкенил, C3-C6 алкинил, C1-C6 алкокси или C1-C6 алкиламино, или R3' и R4' совместно с =C представляют собой 5- или 6-членный насыщенный цикл;
A представляет собой одну из групп Ar1-Ar28:
R5 представляет собой водород, галоген, C1-C4 алкил, C1-C4 галогеналкил, C1-C3 алкокси, C1-C3 галогеналкокси, C1-C3 алкилтио, C1-C3 галогеналкилтио, амино, C1-C4 алкиламино или C2-C4 галогеналкиламино;
R6 представляет собой водород, галоген, C1-C4 алкил, C1-C4 галогеналкил, C1-C3 алкокси, C1-C3 галогеналкокси, C1-C3 алкилтио, C1-C3 галогеналкилтио, амино, C1-C4 алкиламино или C2-C4 галогеналкиламино;
R6' означает водород или галоген;
R6" представляет собой водород, галоген, C1-C4 алкил, C1-C4 галогеналкил, циклопропил, галогенциклопропил, C2-C4 алкенил, C2-C4 галогеналкенил, C2-C4 алкинил, C1-C3 алкокси, C1-C3 галогеналкокси, C1-C3 алкилтио, C1-C3 галогеналкилтио, амино, C1-C4 алкиламино, C2-C4 галогеналкиламино, CN или NO2;
R7 и R7' независимо представляют собой водород, галоген, C1-C4 алкил, C1-C4 галогеналкил или C1-C3 алкокси;
R8 и R8' независимо представляют собой водород, галоген, C1-C4 алкил, C1-C4 галогеналкил или C1-C3 алкокси;
R9, R9', R9" и R9"' независимо представляют собой водород, галоген, C1-C4 алкил, C1-C4 галогеналкил или C1-C3 алкокси;
R10 представляет собой водород, C1-C6 алкил, C1-C6 галогеналкил, C3-C6 алкенил, C3-C6 галогеналкил, C3-C6 алкинил, формил, C1-C3 алкилкарбонил, C1-C3 галогеналкилкарбонил или C1-C6 триалкилсилил;
коэффициент m, если он присутствует в формуле, означает 0, 1 или 2; и
коэффициент n, если он присутствует в формуле, означает 0, 1 или 2;
или N-оксид или приемлемая для сельскохозяйственного применения соль указанного соединения; при условии, что A не является
2. Соединение по п.1, где
X означает N или CY, где Y представляет собой водород, галоген, C1-C3 алкил, C1-C3 галогеналкил, C1-C3 алкокси, C1-C3 галогеналкокси, C1-C3 алкокси, C1-C3 алкилтио или C1-C3 галогеналкилтио;
R1 представляет собой OR1' или NR1"R1"', где R1' представляет собой водород, C1-C8 алкил или C7-C10 арилалкил, и R1" и R1"' независимо представляют собой водород, C1-C12 алкил, C3-C12 алкенил или C3-C12 алкинил;
R2 означает галоген, C1-C4 алкил, C1-C4 галогеналкил, C2-C4 алкенил, C2-C4 галогеналкенил, C2-C4 алкинил, C1-C4 алкокси, C1-C4 галогеналкокси, C1-C4 алкилтио, C1-C4 галогеналкилтио, амино, C1-C4 алкиламино, C2-C4 галогеналкиламино, формил, C1-C3 алкилкарбонил, C1-C3 галогеналкилкарбонил, циано или группу формулы -CR17=CR18-SiR19R20R21, где R17 означает водород, F или Cl; R18 означает водород, F, Cl, C1-C4 алкил или C1-C4 галогеналкил, и R19, R20 и R21 независимо представляют собой C1-C10 алкил, C3-C6 циклоалкил, фенил, замещенный фенил, C1-C10 алкокси или OH;
R3 и R4 независимо представляют собой водород, C1-C6 алкил, C1-C6 галогеналкил, C3-C6 алкенил, C3-C6 галогеналкил, C3-C6 алкинил, формил, C1-C3 алкилкарбонил, C1-C3 галогеналкилкарбонил, C1-C6 алкоксикарбонил, C1-C6 алкилкарбамил, C1-C6 алкилсульфонил, C1-C6 триалкилсилил, C1-C6 диалкилфосфонил, или R3 и R4 совместно с атомом N образуют 5- или 6-членный насыщенный цикл, или же R3 и R4 совместно представляют собой =СR3'(R4'), где R3' и R4' независимо представляют собой водород, C1-C6 алкил, C3-C6 алкенил, C3-C6 алкинил, C1-C6 алкокси или C1-C6 алкиламино, или R3' и R4' совместно с =C представляют собой 5- или 6-членный насыщенный цикл;
A представляет собой одну из групп Ar1, Ar2, Ar3, Ar4, Ar5, Ar6, Ar7, Ar8, Ar9, Ar10, Ar11, Ar12, Ar13, Ar14, Ar15, Ar16, Ar17, Ar18, Ar19, Ar20, Ar21, Ar22, Ar23 или Ar24;
R5 представляет собой водород, галоген, C1-C4 алкил, C1-C4 галогеналкил, C1-C3 алкокси, C1-C3 галогеналкокси, C1-C3 алкилтио, C1-C3 галогеналкилтио, амино, C1-C4 алкиламино или C2-C4 галогеналкиламино;
R6 представляет собой водород, галоген, C1-C4 алкил, C1-C4 галогеналкил, C1-C3 алкокси, C1-C3 галогеналкокси, C1-C3 алкилтио, C1-C3 галогеналкилтио, амино, C1-C4 алкиламино или C2-C4 галогеналкиламино;
R6' означает водород или галоген;
R6" представляет собой водород, галоген, C1-C4 алкил, C1-C4 галогеналкил, циклопропил, галогенциклопропил, C2-C4 алкенил, C2-C4 галогеналкенил, C2-C4 алкинил, C1-C3 алкокси, C1-C3 галогеналкокси, C1-C3 алкилтио, C1-C3 галогеналкилтио, амино, C1-C4 алкиламино, C2-C4 галогеналкиламино, CN или NO2;
R7 и R7' независимо представляют собой водород, галоген, C1-C4 алкил, C1-C4 галогеналкил или C1-C3 алкокси;
R8 и R8' независимо представляют собой водород, галоген, C1-C4 алкил, C1-C4 галогеналкил или C1-C3 алкокси;
R9, R9', R9" и R9"' независимо представляют собой водород, галоген, C1-C4 алкил, C1-C4 галогеналкил или C1-C3 алкокси;
R10 представляет собой водород, C1-C6 алкил, C1-C6 галогеналкил, C3-C6 алкенил, C3-C6 галогеналкил, C3-C6 алкинил, формил, C1-C3 алкилкарбонил, C1-C3 галогеналкилкарбонил или C1-C6 триалкилсилил;
коэффициент m, если он присутствует в формуле, означает 0, 1 или 2; и
коэффициент n, если он присутствует в формуле, означает 0, 1 или 2;
или N-оксид или приемлемая для сельскохозяйственного применения соль указанного соединения; при условии, что A не является
3. Соединение по п.2, где Ar представляет собой Ar1, Ar2, Ar3, Ar4, Ar5, Ar6, Ar7, Ar8, Ar15, Ar16, Ar17 или Ar18.
4. Соединение по п.1, где коэффициент m в случае его присутствия в формуле, означает 0 или 1, и где коэффициент n, в случае его присутствия в формуле, означает 0 или 1.
5. Соединение по любому из пп.1-4, где R1 означает OR1'.
6. Соединение по любому из пп.1-4, где R2 означает галоген, C2-C4 алкенил, C2-C4 галогеналкенил или C1-C4 алкокси.
7. Соединение по п.6, где R2 означает Cl, метокси, винил или 1-пропенил.
8. Соединение по любому из пп.1-4, где оба заместителя R3 и R4 представляют собой атомы водорода.
9. Соединение по любому из пп.1-4, где X означает N, CH или CF.
10. Соединение по любому из пп.1-4, где R5 представляет собой водород или галоген.
11. Соединение по п.10, где R5 представляет собой водород или F.
12. Соединение по любому из пп.1-4, где R6 представляет собой водород или F.
13. Соединение по любому из пп.1-4, где R6' представляет собой водород.
14. Соединение по любому из пп.1-4, где
R2 означает галоген, C2-C4 алкенил или C1-C4 алкокси;
оба заместителя R3 и R4 являются атомами водорода; и
X означает N, CH или CF;
Ar представляет собой Ar1, Ar3, Ar7, Ar9, Ar10, Ar13, Ar15, Ar16, Ar19, Ar21 или Ar22;
R5 означает водород или F;
R6 означает водород или F;
R6' означает водород;
R7, R7', R8, R8', R9, R9', R9" и R9"', если эти заместители имеются у соответствующей группы Ar, независимо представляют собой водород или фтор.
15. Соединение по п. 14, где
R2 означает хлор;
R3 и R4 являются атомами водорода; и
X означает N, CH или CF.
16. Соединение по п. 14, где
R2 означает метокси;
R3 и R4 являются атомами водорода; и
X означает N, CH или CF.
17. Соединение по п. 14, где
R2 означает винил или 1-пропенил;
R3 и R4 являются атомами водорода; и
X означает N, CH или CF.
18. Гербицидная композиция, включающая соединение по любому из пп.1-17 и приемлемый для сельскохозяйственного применения адъювант или носитель.
19. Композиция по п.18, дополнительно включающая по крайней мере одно дополнительное гербицидное соединение.
20. Композиция по п.18 или 19, дополнительно включающая средство, предохраняющее полезные растения.
21. Способ борьбы с нежелательной растительностью, включающий нанесение гербицидно-эффективного количества соединения по любому из пп.1-17 или композиции по любому из пп.18-20.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US201361790391P | 2013-03-15 | 2013-03-15 | |
US61/790,391 | 2013-03-15 | ||
PCT/US2014/024749 WO2014151008A1 (en) | 2013-03-15 | 2014-03-12 | 4-amino-6-(heterocyclic)picolinates and 6-amino-2-(heterocyclic)pyrimidine-4-carboxylates and their use as herbicides |
Related Child Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
RU2018133163A Division RU2782064C2 (ru) | 2013-03-15 | 2014-03-12 | 4-амино-6-(гетероциклил)пиколинаты и 6-амино-2-(гетероциклил)пиримидин-4-карбоксилаты и их применение в качестве гербицидов |
Publications (2)
Publication Number | Publication Date |
---|---|
RU2015143885A true RU2015143885A (ru) | 2017-04-27 |
RU2672584C2 RU2672584C2 (ru) | 2018-11-16 |
Family
ID=51529783
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
RU2015143885A RU2672584C2 (ru) | 2013-03-15 | 2014-03-12 | 4-амино-6-(гетероциклил)пиколинаты и 6-амино-2-(гетероциклил)пиримидин-4-карбоксилаты и их применение в качестве гербицидов |
Country Status (22)
Country | Link |
---|---|
US (1) | US9149038B2 (ru) |
EP (2) | EP2970185B1 (ru) |
JP (2) | JP6543241B2 (ru) |
KR (2) | KR102305436B1 (ru) |
CN (3) | CN110583663A (ru) |
AR (2) | AR095508A1 (ru) |
AU (4) | AU2014235455B2 (ru) |
BR (1) | BR102014006224B8 (ru) |
CA (1) | CA2905103C (ru) |
CL (1) | CL2015002737A1 (ru) |
CR (1) | CR20150561A (ru) |
ES (1) | ES2959637T3 (ru) |
IL (2) | IL241602B (ru) |
MX (1) | MX2015012947A (ru) |
MY (1) | MY184855A (ru) |
PH (2) | PH12015502147A1 (ru) |
PT (1) | PT2970185T (ru) |
RU (1) | RU2672584C2 (ru) |
UA (2) | UA119536C2 (ru) |
UY (1) | UY35433A (ru) |
WO (1) | WO2014151008A1 (ru) |
ZA (1) | ZA201507019B (ru) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
RU2791978C2 (ru) * | 2018-12-27 | 2023-03-15 | Циндао Кингагрут Кемикал Компаунд Ко., Лтд. | R-пиридилоксикарбоновая кислота и соль, сложноэфирное производное, способ получения, гербицидная композиция и их применение |
Families Citing this family (22)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP6437452B2 (ja) | 2013-01-14 | 2018-12-12 | インサイト・ホールディングス・コーポレイションIncyte Holdings Corporation | Pimキナーゼ阻害剤として有用な二環式芳香族カルボキサミド化合物 |
NZ710079A (en) | 2013-01-15 | 2020-01-31 | Incyte Holdings Corp | Thiazolecarboxamides and pyridinecarboxamide compounds useful as pim kinase inhibitors |
US9637505B2 (en) | 2013-03-15 | 2017-05-02 | Dow Agrosciences Llc | 4-amino-6-(heterocyclic)picolinates and 6-amino-2-(heterocyclic)pyrimidine-4-carboxylates and their use as herbicides |
AR097431A1 (es) | 2013-08-23 | 2016-03-16 | Incyte Corp | Compuestos de carboxamida de furo y tienopiridina útiles como inhibidores de quinasas pim |
US9580418B2 (en) | 2014-07-14 | 2017-02-28 | Incyte Corporation | Bicyclic aromatic carboxamide compounds useful as Pim kinase inhibitors |
US9822124B2 (en) | 2014-07-14 | 2017-11-21 | Incyte Corporation | Bicyclic heteroaromatic carboxamide compounds useful as Pim kinase inhibitors |
TWI689252B (zh) | 2014-09-15 | 2020-04-01 | 美商陶氏農業科學公司 | 源自於施用吡啶羧酸除草劑與乙醯乳酸合成酶(als)抑制劑的協同性雜草控制 |
TWI689251B (zh) | 2014-09-15 | 2020-04-01 | 美商陶氏農業科學公司 | 源自於施用吡啶羧酸除草劑與合成生長素除草劑及/或生長素轉運抑制劑的協同性雜草控制 |
AR101858A1 (es) | 2014-09-15 | 2017-01-18 | Dow Agrosciences Llc | Composiciones herbicidas protegidas que comprenden un herbicida de ácido piridincarboxílico |
TWI685302B (zh) | 2014-09-15 | 2020-02-21 | 美商陶氏農業科學公司 | 包含吡啶羧酸除草劑之安全的除草組成物 |
WO2016044276A1 (en) | 2014-09-15 | 2016-03-24 | Dow Agrosciences Llc | Synergistic weed control from applications of pyridine carboxylic acid herbicides and photosystem ii inhibitors |
WO2016196244A1 (en) | 2015-05-29 | 2016-12-08 | Incyte Corporation | Pyridineamine compounds useful as pim kinase inhibitors |
TWI734699B (zh) | 2015-09-09 | 2021-08-01 | 美商英塞特公司 | Pim激酶抑制劑之鹽 |
US9920032B2 (en) | 2015-10-02 | 2018-03-20 | Incyte Corporation | Heterocyclic compounds useful as pim kinase inhibitors |
JP7113762B2 (ja) | 2016-05-19 | 2022-08-05 | コルテバ アグリサイエンス エルエルシー | 直接的な鈴木カップリングによる6-アリール-4-アミノピコリネートおよび2-アリール-6-アミノピリミジン-4-カルボキシレートの合成 |
CA3026903C (en) * | 2016-06-09 | 2024-05-28 | Pramana Pharmaceuticals Inc. | Compounds containing benzo[d][1,3]oxathiole, benzo[d][1,3]oxathiole 3-oxide or benzo[d][1,3]oxathiole 3,3-dioxide and methods/uses thereof as agonists of g protein-coupled receptor 119 |
KR102014320B1 (ko) | 2016-06-27 | 2019-08-26 | (주)목우연구소 | 이속사졸린 고리를 포함하는 피리딘계 화합물 및 제초제로서의 이의 용도 |
US11358956B2 (en) | 2017-11-30 | 2022-06-14 | Pramana Pharmaceuticals Inc. | Compounds containing polysubstituted benzo[d][1,3]oxathiole, benzo[d][1,3]oxathiole 3-oxide or benzo[d][1,3]oxathiole 3,3-dioxide and methods/uses thereof as agonists of G protein-coupled receptor 119 |
AR113922A1 (es) | 2017-12-08 | 2020-07-01 | Incyte Corp | Terapia de combinación de dosis baja para el tratamiento de neoplasias mieloproliferativas |
SG11202011025RA (en) * | 2018-05-11 | 2020-12-30 | Dow Agrosciences Llc | 4-amino-6-(1,3-benzodioxole)picolinates and their use as herbicides |
BR112021005140A8 (pt) | 2018-09-19 | 2021-06-29 | Corteva Agriscience Llc | preparação de análogos de halogênio de picloram |
CN116120272A (zh) * | 2022-12-31 | 2023-05-16 | 淮北师范大学 | 一种合成咯菌腈中间体2,2-二氟-1,3-苯并二噁茂-4-甲醛的方法 |
Family Cites Families (35)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DK1498413T3 (da) | 2000-01-14 | 2011-12-05 | Dow Agrosciences Llc | 4-aminopicolinater og deres anvendelse som herbicider |
AR037228A1 (es) * | 2001-07-30 | 2004-11-03 | Dow Agrosciences Llc | Compuestos del acido 6-(aril o heteroaril)-4-aminopicolinico, composicion herbicida que los comprende y metodo para controlar vegetacion no deseada |
TWI355894B (en) * | 2003-12-19 | 2012-01-11 | Du Pont | Herbicidal pyrimidines |
WO2006062979A1 (en) | 2004-12-06 | 2006-06-15 | E.I. Dupont De Nemours And Company | Herbicidal 6-cyclopropyl-substitute 4-aminopicolinic acid derivatives |
CA2607934C (en) * | 2005-05-06 | 2013-10-01 | E. I. Du Pont De Nemours And Company | Method for preparation of optionally 2-substituted 1,6-dihydro-6-oxo-4-pyrimidinecarboxylic acids |
GB0512844D0 (en) | 2005-06-23 | 2005-08-03 | Novartis Ag | Organic compounds |
JP5068985B2 (ja) | 2005-12-16 | 2012-11-07 | 石原産業株式会社 | カルボン酸アミド誘導体を含有する殺菌性組成物 |
KR101350071B1 (ko) | 2006-01-13 | 2014-01-14 | 다우 아그로사이언시즈 엘엘씨 | 6-(다-치환 아릴)-4-아미노피콜리네이트 및 그의제초제로서의 용도 |
TWI396505B (zh) * | 2006-01-13 | 2013-05-21 | Dow Agrosciences Llc | 2-(聚-經取代芳基)-6-胺-5-鹵-4-嘧啶羧酸及其作為除草劑之用途 |
TWI389895B (zh) | 2006-08-21 | 2013-03-21 | Infinity Discovery Inc | 抑制bcl蛋白質與結合夥伴間之交互作用的化合物及方法 |
US20080234262A1 (en) | 2007-03-21 | 2008-09-25 | Wyeth | Pyrazolopyrimidine analogs and their use as mtor kinase and pi3 kinase inhibitors |
EP2311815B1 (en) | 2007-08-13 | 2012-12-19 | Dow AgroSciences LLC | 2-(2-Fluoro-substituted phenyl)-6-amino-5-chloro-4-pyrimidinecarboxylates and their use as herbicides |
AR068145A1 (es) * | 2007-08-30 | 2009-11-04 | Dow Agrosciences Llc | 2- (fenil sustituido )-6-amino-5-alcoxi, tiolcoxi y aminoalquil-4- pirimidina carboxilatos, sus usos como herbicidas y composicion herbicida |
EP2332914B1 (en) | 2007-10-02 | 2013-03-13 | Dow AgroSciences LLC | Substituted 4-amino-picolinic acids and their use as herbicides |
GB0725218D0 (en) | 2007-12-24 | 2008-02-06 | Syngenta Ltd | Chemical compounds |
US8598202B2 (en) | 2008-02-19 | 2013-12-03 | Janssen Pharmaceutica Nv | Aryl-hydroxyethylamino-pyrimidines and triazines as modulators of fatty acid amide hydrolase |
GB0808664D0 (en) * | 2008-05-13 | 2008-06-18 | Syngenta Ltd | Chemical compounds |
US8536210B2 (en) | 2008-09-11 | 2013-09-17 | Semmelweis Egyetem | Compounds for inhibiting semicarbazide-sensitive amine oxidase (SSAO)/vascular adhesion protein-1 (VAP-1) and uses thereof for treatment and prevention of diseases |
EP2191719A1 (de) | 2008-11-29 | 2010-06-02 | Bayer CropScience AG | Herbizid-Safener-Kombination |
WO2010068863A2 (en) | 2008-12-12 | 2010-06-17 | Cystic Fibrosis Foundation Therapeutics, Inc. | Pyrimidine compounds and methods of making and using same |
GB0902474D0 (en) * | 2009-02-13 | 2009-04-01 | Syngenta Ltd | Chemical compounds |
WO2010099279A1 (en) * | 2009-02-27 | 2010-09-02 | Dow Agrosciences Llc | N-alkoxyamides of 6-(substituted phenyl)-4-aminopicolinates and 2-(substituted phenyl)-6-amino-4-pyrimidinecarboxylates and their use as selective herbicides for crops |
GB0907625D0 (en) * | 2009-05-01 | 2009-06-10 | Syngenta Ltd | Method of controlling undesired vegetation |
WO2011053705A1 (en) | 2009-10-30 | 2011-05-05 | Janssen Pharmaceutica Nv | Pyrimidine compounds as delta opioid receptor modulators |
US20120288492A1 (en) * | 2009-12-28 | 2012-11-15 | Dcb-Usa Llc | NOVEL PYRIMIDINE COMPOUNDS AS mTOR AND PI3K INHIBITORS |
CN102812006B (zh) | 2010-01-18 | 2016-01-20 | Mmv疟疾药物投资公司 | 新型抗疟疾试剂 |
AU2011248877B9 (en) | 2010-04-27 | 2015-11-05 | Calcimedica Inc. | Compounds that modulate intracellular calcium |
CN102241621A (zh) | 2010-05-11 | 2011-11-16 | 江苏恒瑞医药股份有限公司 | 5,5-双取代-2-亚氨基吡咯烷类衍生物、其制备方法及其在医药上的应用 |
CA2815272A1 (en) * | 2010-10-22 | 2012-04-26 | Bayer Intellectual Property Gmbh | Novel substituted picolinic acids, salts and acid derivatives thereof, and use thereof as herbicides |
KR20140037804A (ko) * | 2010-12-16 | 2014-03-27 | 바이엘 인텔렉쳐 프로퍼티 게엠베하 | 6-(2-아미노페닐)피콜리네이트 및 제초제로서의 그의 용도 |
TWI592401B (zh) | 2011-01-25 | 2017-07-21 | 陶氏農業科學公司 | 用於製備4-胺基-3-氯-5-氟-6-(經取代的)吡啶甲酸酯的方法(一) |
CA2825392C (en) * | 2011-01-25 | 2016-10-25 | Dow Agrosciences Llc | 6-amino-2-substituted-5-vinylsilylpyrimidine-4-carboxylic acids and esters and 4-amino-6-substituted-3-vinylsilylpyridine-2-carboxylic acids and esters as herbicides |
WO2012149528A1 (en) | 2011-04-29 | 2012-11-01 | Exelixis, Inc. | Inhibitors of inducible form of 6-phosphofructose-2-kinase |
UA113412C2 (xx) * | 2011-06-30 | 2017-01-25 | 3-алкокси, тіоалкіл і аміно-4-аміно-6-(заміщені) піколінати та їхнє застосування як гербіцидів | |
US9179676B2 (en) | 2011-07-27 | 2015-11-10 | Bayer Intellectual Property Gmbh | Substituted picolinic acids and pyrimidine-4-carboxylic acids, method for the production thereof and use thereof as herbicides and plant growth regulators |
-
2014
- 2014-03-12 MX MX2015012947A patent/MX2015012947A/es unknown
- 2014-03-12 CN CN201910784316.7A patent/CN110583663A/zh active Pending
- 2014-03-12 UA UAA201510097A patent/UA119536C2/uk unknown
- 2014-03-12 KR KR1020157029724A patent/KR102305436B1/ko active IP Right Grant
- 2014-03-12 WO PCT/US2014/024749 patent/WO2014151008A1/en active Application Filing
- 2014-03-12 US US14/205,883 patent/US9149038B2/en active Active
- 2014-03-12 ES ES14769792T patent/ES2959637T3/es active Active
- 2014-03-12 MY MYPI2015703135A patent/MY184855A/en unknown
- 2014-03-12 JP JP2016501628A patent/JP6543241B2/ja active Active
- 2014-03-12 PT PT147697924T patent/PT2970185T/pt unknown
- 2014-03-12 AU AU2014235455A patent/AU2014235455B2/en active Active
- 2014-03-12 EP EP14769792.4A patent/EP2970185B1/en active Active
- 2014-03-12 EP EP19211468.4A patent/EP3640249A1/en not_active Withdrawn
- 2014-03-12 KR KR1020217029746A patent/KR20210125575A/ko active Application Filing
- 2014-03-12 RU RU2015143885A patent/RU2672584C2/ru active
- 2014-03-12 CN CN201480027999.7A patent/CN105209452A/zh active Pending
- 2014-03-12 CA CA2905103A patent/CA2905103C/en active Active
- 2014-03-12 CN CN201810902468.8A patent/CN109134440A/zh active Pending
- 2014-03-12 UA UAA201808752A patent/UA126851C2/uk unknown
- 2014-03-14 UY UY0001035433A patent/UY35433A/es active IP Right Grant
- 2014-03-14 AR ARP140101113A patent/AR095508A1/es active IP Right Grant
- 2014-03-17 BR BR102014006224A patent/BR102014006224B8/pt active IP Right Grant
-
2015
- 2015-09-15 PH PH12015502147A patent/PH12015502147A1/en unknown
- 2015-09-15 CL CL2015002737A patent/CL2015002737A1/es unknown
- 2015-09-16 IL IL241602A patent/IL241602B/en unknown
- 2015-09-21 ZA ZA2015/07019A patent/ZA201507019B/en unknown
- 2015-10-15 CR CR20150561A patent/CR20150561A/es unknown
-
2018
- 2018-06-07 PH PH12018501214A patent/PH12018501214A1/en unknown
- 2018-08-23 AU AU2018220080A patent/AU2018220080A1/en not_active Abandoned
-
2019
- 2019-03-27 JP JP2019060979A patent/JP6836617B2/ja active Active
- 2019-05-15 IL IL266664A patent/IL266664A/en unknown
-
2020
- 2020-02-21 AU AU2020201263A patent/AU2020201263B2/en active Active
-
2021
- 2021-10-26 AU AU2021257919A patent/AU2021257919A1/en not_active Abandoned
- 2021-10-26 AR ARP210102973A patent/AR123926A2/es unknown
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
RU2791978C2 (ru) * | 2018-12-27 | 2023-03-15 | Циндао Кингагрут Кемикал Компаунд Ко., Лтд. | R-пиридилоксикарбоновая кислота и соль, сложноэфирное производное, способ получения, гербицидная композиция и их применение |
Also Published As
Similar Documents
Publication | Publication Date | Title |
---|---|---|
RU2015143885A (ru) | 4-амино-6-(гетероциклил)пиколинаты и 6-амино-2-(гетероциклил)пиримидин-4-карбоксилаты и их применение в качестве гербицидов | |
HRP20230184T1 (hr) | 4-amino-6-(heterociklički)pikolinati i 6-amino-2-(heterociklički)pirimidin-4-karboksilati i njihova upotreba kao herbicidi | |
AR118275A2 (es) | 4-amino-6-(heterocíclico)picolinatos y 6-amino-2-(heterocíclico)pirimidin-4-carboxilatos y su uso como herbicidas | |
RU2018114460A (ru) | 4-амино-6-(4-замещенные-фенил)-пиколинаты и 6-амино-2-(4-замещенные-фенил)-пиримидин-4-карбоксилаты и их применение в качестве гербицидов | |
AR105322A1 (es) | Heterociclos nitrogenados como pesticidas | |
RU2016144197A (ru) | Фунгицидные производные n'-[2-метил-6[2-алкоксиэтокси]-3-пиридил]-n-алкилформамидина для применения в сельском хозяйстве | |
AR087535A1 (es) | Compuestos fungicidas de 1-{2-[2-halo-4-(4-halogen-fenoxi)-fenil]-2-etoxi-etil}-1h-[1,2,4]triazol sustituidos | |
AR087536A1 (es) | Compuestos fungicidas de 1-{2-[2-halo-4-(4-halogen-fenoxi)-fenil]-2-alquiniloxi-etil}-1h-[1,2,4]triazol sustituidos | |
AR087949A1 (es) | Compuestos fungicidas de 1-{2-[halo-4-(4-halogeno-fenoxi)-fenil]-2-alcoxi-3-metil-butil}-1h-[1,2,4]triazol sustituidos, un metodo para su preparacion y su empleo en composiciones agroquimicas para combatir hongos fitopatogenicos | |
AR087537A1 (es) | Compuestos fungicidas de 1-{2-[2-halo-4-(4-halogen-fenoxi)-fenil]-2-alcoxi-2-ciclil-etil}-1h-[1,2,4]triazol sustituidos | |
AR086819A1 (es) | 3-alcoxi, tioalquil y amino-4-amino-6-picolinatos (sustituidos) y su uso como herbicidas | |
AR103965A1 (es) | Derivados de pirimidiniloxi piridina sustituida como herbicidas | |
AR110724A1 (es) | Derivados heterocíclicos como pesticidas | |
AR101132A1 (es) | Derivados de pirazina agonistas del gpr40 para el tratamiento de la diabetes tipo ii | |
MX2016005319A (es) | Composiciones pesticidas y metodos relacionados. | |
RU2018136239A (ru) | Гербициды | |
AR106873A1 (es) | Compuestos de piridina como fungicidas | |
AR089889A1 (es) | Compuestos fungicidas de pirimidina | |
AR097252A1 (es) | Derivado de pirazolilpirazol sustituido y el uso del mismo como herbicida | |
AR095518A1 (es) | 4-amino-6-(heterocíclico)picolinatos y 6-amino-2-(heterocíclico)pirimidin-4-carboxilatos y su uso como herbicidas | |
AR101489A1 (es) | Compuestos reguladores del crecimiento vegetal | |
AR097245A1 (es) | Derivado de pirazolilpirazol sustituido y su empleo como herbicida | |
RS54248B1 (en) | NEW UNITS AS LISTS OF HISTAMINE H3 RECEPTORS | |
AR111252A1 (es) | Compuestos de isoxazol carboxamida y usos de los mismos | |
UA112623C2 (uk) | Розгалужені олігоарилсилани та спосіб їх отримання |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PD4A | Correction of name of patent owner |