RU2018114460A - 4-амино-6-(4-замещенные-фенил)-пиколинаты и 6-амино-2-(4-замещенные-фенил)-пиримидин-4-карбоксилаты и их применение в качестве гербицидов - Google Patents
4-амино-6-(4-замещенные-фенил)-пиколинаты и 6-амино-2-(4-замещенные-фенил)-пиримидин-4-карбоксилаты и их применение в качестве гербицидов Download PDFInfo
- Publication number
- RU2018114460A RU2018114460A RU2018114460A RU2018114460A RU2018114460A RU 2018114460 A RU2018114460 A RU 2018114460A RU 2018114460 A RU2018114460 A RU 2018114460A RU 2018114460 A RU2018114460 A RU 2018114460A RU 2018114460 A RU2018114460 A RU 2018114460A
- Authority
- RU
- Russia
- Prior art keywords
- compound according
- alkyl
- hydrogen
- phenyl
- amino
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
- C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
- C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D213/06—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom containing only hydrogen and carbon atoms in addition to the ring nitrogen atom
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N31/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic oxygen or sulfur compounds
- A01N31/04—Oxygen or sulfur attached to an aliphatic side-chain of a carbocyclic ring system
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
- A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/54—1,3-Diazines; Hydrogenated 1,3-diazines
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
- C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
- C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D213/78—Carbon atoms having three bonds to hetero atoms, with at the most one bond to halogen, e.g. ester or nitrile radicals
- C07D213/79—Acids; Esters
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D239/00—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings
- C07D239/02—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings
- C07D239/24—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members
- C07D239/28—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, directly attached to ring carbon atoms
- C07D239/32—One oxygen, sulfur or nitrogen atom
- C07D239/42—One nitrogen atom
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D239/00—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings
- C07D239/02—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings
- C07D239/24—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members
- C07D239/28—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, directly attached to ring carbon atoms
- C07D239/46—Two or more oxygen, sulphur or nitrogen atoms
- C07D239/47—One nitrogen atom and one oxygen or sulfur atom, e.g. cytosine
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
- C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
- C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D213/72—Nitrogen atoms
- C07D213/73—Unsubstituted amino or imino radicals
Landscapes
- Organic Chemistry (AREA)
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Plant Pathology (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Agronomy & Crop Science (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Plural Heterocyclic Compounds (AREA)
- Pyridine Compounds (AREA)
Claims (25)
1. Соединение формулы (I)
в которой X означает N или CY; где Y означает водород, галоген, C1-C3-алкил, C1-C3-галогеналкил, C1-C3-алкоксигруппу, C1-C3-галогеналкоксигруппу, C1-C3-алкилтиогруппу или C1-C3-галогеналкилтиогруппу;
R1 означает OR1′, в которой R1′ означает H, C1-C8-алкил или C7-C10-арилалкил;
R2 означает галоген, C1-C4-алкил, C1-C4-галогеналкил, C2-C4-алкенил, C1-C4-алкоксигруппу или C1-C4-галогеналкоксигруппу;
R3 и R4 все независимо означают водород, C1-C6-алкил, C1-C6-галогеналкил, C3-C6-алкенил, C3-C6-галогеналкенил, C3-C6-алкинил, гидроксигруппу, C1-C6-алкоксигруппу, C1-C6-галогеналкоксигруппу, формил, (C1-C3-алкил)карбонил, (C1-C3-галогеналкил)карбонил, (C1-C6-алкокси)карбонил, (C1-C6-алкил)карбамил, C1-C6-алкилсульфонил, три(C1-C6-алкил)силил, ди(C1-C6-алкил)фосфонил, или R3 и R4 вместе с атомом азота, к которому они присоединены, образуют 5- или 6-членное насыщенное кольцо, или R3 и R4, взятые вместе, означают =CR3′R4′, где R3′ и R4′ все независимо означают водород, C1-C6-алкил, C3-C6-алкенил, C3-C6-алкинил, C1-C6-алкоксигруппу или C1-C6-алкиламиногруппу или R3′ и R4′ вместе с атомом углерода, к которому они присоединены, образуют 5- или 6-членное насыщенное кольцо;
Ar означает:
где
X1 означает H, F, Cl, Br, I, этинил, галогенэтинил, CF2H, OCF2H, OCF3, CN, CONH2, CO2H, CO2СН3 или NO2;
или его N-оксид, или сельскохозяйственно-приемлемая соль.
2. Соединение по п.1, в котором R2 означает Cl.
3. Соединение по п.1, в котором R2 означает C1-C4-алкоксигруппу.
4. Соединение по п.1, в котором R2 означает OСН3 или OСН2СН3.
5. Соединение по любому из пп.1-4, в котором X означает N, CH, CF, CCl или CCH3.
6. Соединение по любому из пп.1-4, в котором X означает CF.
7. Соединение по любому из пп.1-4, в котором X означает N.
8. Соединение по любому из пп.1-7, в котором X1 означает I, этинил или CN.
9. Соединение по любому из пп.1-7, в котором X1 означает I.
10. Соединение по любому из пп.1-7, в котором X1 означает этинил.
11. Соединение по любому из пп.1-7, в котором X1 означает CN.
12. Соединение по любому из пп.1-11, в котором R3 и R4 каждый означают водород.
13. Соединение по п.1, в котором X означает CF, R1 означает OН, R2 означает Cl, R3 и R4 каждый означают водород, и X1 означает I.
14. Соединение по п.1, в котором X означает CF, R1 означает OСН3, R2 означает Cl, R3 и R4 каждый означают водород, и X1 означает CN.
15. Соединение по п.1, в котором X означает CF, R1 означает OН, R2 означает Cl, R3 и R4 каждый означают водород, и X1 означает этинил.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US13/840,233 | 2013-03-15 | ||
US13/840,233 US9113629B2 (en) | 2013-03-15 | 2013-03-15 | 4-amino-6-(4-substituted-phenyl)-picolinates and 6-amino-2-(4-substituted-phenyl)-pyrimidine-4-carboxylates and their use as herbicides |
Related Parent Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
RU2015143829A Division RU2652132C2 (ru) | 2013-03-15 | 2014-03-12 | 4-амино-6-(4-замещенные-фенил)-пиколинаты и 6-амино-2-(4-замещенные-фенил)-пиримидин-4-карбоксилаты и их применение в качестве гербицидов |
Publications (3)
Publication Number | Publication Date |
---|---|
RU2018114460A true RU2018114460A (ru) | 2019-03-04 |
RU2018114460A3 RU2018114460A3 (ru) | 2021-09-01 |
RU2771326C2 RU2771326C2 (ru) | 2022-04-29 |
Family
ID=51529778
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
RU2018114460A RU2771326C2 (ru) | 2013-03-15 | 2014-03-12 | 4-амино-6-(4-замещенные-фенил)-пиколинаты и 6-амино-2-(4-замещенные-фенил)-пиримидин-4-карбоксилаты и их применение в качестве гербицидов |
RU2015143829A RU2652132C2 (ru) | 2013-03-15 | 2014-03-12 | 4-амино-6-(4-замещенные-фенил)-пиколинаты и 6-амино-2-(4-замещенные-фенил)-пиримидин-4-карбоксилаты и их применение в качестве гербицидов |
Family Applications After (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
RU2015143829A RU2652132C2 (ru) | 2013-03-15 | 2014-03-12 | 4-амино-6-(4-замещенные-фенил)-пиколинаты и 6-амино-2-(4-замещенные-фенил)-пиримидин-4-карбоксилаты и их применение в качестве гербицидов |
Country Status (29)
Country | Link |
---|---|
US (1) | US9113629B2 (ru) |
EP (2) | EP3440938B1 (ru) |
JP (4) | JP6527502B2 (ru) |
KR (2) | KR102414529B1 (ru) |
CN (2) | CN108689924B (ru) |
AP (1) | AP2015008772A0 (ru) |
AR (2) | AR095449A1 (ru) |
AU (3) | AU2014235571C1 (ru) |
BR (2) | BR122019021766B8 (ru) |
CA (2) | CA2902347C (ru) |
CL (1) | CL2015002665A1 (ru) |
CR (1) | CR20150521A (ru) |
DK (1) | DK2967069T3 (ru) |
ES (2) | ES2959334T3 (ru) |
HR (1) | HRP20182056T1 (ru) |
HU (1) | HUE063201T2 (ru) |
IL (1) | IL240854A (ru) |
LT (1) | LT2967069T (ru) |
MX (1) | MX367303B (ru) |
PH (1) | PH12015502146B1 (ru) |
PL (2) | PL2967069T3 (ru) |
PT (1) | PT2967069T (ru) |
RS (1) | RS58151B1 (ru) |
RU (2) | RU2771326C2 (ru) |
SI (1) | SI2967069T1 (ru) |
UA (2) | UA118189C2 (ru) |
UY (1) | UY35477A (ru) |
WO (1) | WO2014150850A1 (ru) |
ZA (1) | ZA201507330B (ru) |
Families Citing this family (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
PL2967057T3 (pl) * | 2013-03-15 | 2019-05-31 | Dow Agrosciences Llc | Nowe karboksylany 4-aminopirydyny i 6-aminopirymidyny jako herbicydy |
EP3193607A4 (en) | 2014-09-15 | 2018-05-02 | Dow AgroSciences LLC | Synergistic weed control from applications of pyridine carboxylic acid herbicides and photosystem ii inhibitors |
TWI689251B (zh) | 2014-09-15 | 2020-04-01 | 美商陶氏農業科學公司 | 源自於施用吡啶羧酸除草劑與合成生長素除草劑及/或生長素轉運抑制劑的協同性雜草控制 |
TWI689252B (zh) | 2014-09-15 | 2020-04-01 | 美商陶氏農業科學公司 | 源自於施用吡啶羧酸除草劑與乙醯乳酸合成酶(als)抑制劑的協同性雜草控制 |
KR20190007048A (ko) * | 2016-05-19 | 2019-01-21 | 다우 아그로사이언시즈 엘엘씨 | 직접 스즈키 커플링에 의한 6-아릴-4-아미노피콜리네이트 및 2-아릴-6-아미노피리미딘-4-카르복실레이트의 합성 |
CA3028949C (en) | 2016-06-27 | 2020-10-27 | Korea Research Institute Of Chemical Technology | Pyridine-based compound including isoxazoline ring and use thereof as herbicide |
CN109400526B (zh) * | 2018-12-27 | 2020-10-16 | 青岛清原化合物有限公司 | 吡啶氧基硫酯衍生物及其制备方法、除草组合物和应用 |
WO2020253696A1 (zh) * | 2019-06-20 | 2020-12-24 | 青岛清原化合物有限公司 | 取代的吡啶甲酸吡啶亚甲基酯衍生物及其制备方法、除草组合物和应用 |
CN113603637B (zh) * | 2021-08-27 | 2023-05-30 | 浙江埃森化学有限公司 | 氟氯吡啶酯的制备方法 |
CN113548982B (zh) * | 2021-09-03 | 2022-05-06 | 上海三牧化工技术有限公司 | 一种4-氰基-2-氟苄醇的制备方法 |
Family Cites Families (32)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
RO109848B1 (ro) * | 1991-12-18 | 1995-06-30 | Kumiai Chemical Industry Co | Derivati de acid picolinic, procedee pentru prepararea acestora si compozitii erbicide |
ES2073951T3 (es) * | 1992-07-03 | 1995-08-16 | Synthelabo | Derivados de 2-amino-n-(((4-(aminocarbonil)pirimidin-2-il)amino)alquil)pirimidina-4-carboxamida, su preparacion y su aplicacion en terapeutica. |
ES2279817T3 (es) | 2000-01-14 | 2007-09-01 | Dow Agrosciences Llc | 4-aminopicolinatos y su uso como herbicidas. |
DE10111649A1 (de) * | 2001-03-12 | 2002-09-19 | Bayer Ag | Substituierte Fluoralkoxyphenylsulfonylharnstoffe |
AR037228A1 (es) * | 2001-07-30 | 2004-11-03 | Dow Agrosciences Llc | Compuestos del acido 6-(aril o heteroaril)-4-aminopicolinico, composicion herbicida que los comprende y metodo para controlar vegetacion no deseada |
UA84724C2 (ru) * | 2003-12-19 | 2008-11-25 | Э. И. Дю Пон Де Немур Энд Компани | Производные пиримидина, гербицидные смеси и композиции на их основе, способ контроля роста нежелательной растительности |
TWI355894B (en) | 2003-12-19 | 2012-01-11 | Du Pont | Herbicidal pyrimidines |
WO2006062979A1 (en) | 2004-12-06 | 2006-06-15 | E.I. Dupont De Nemours And Company | Herbicidal 6-cyclopropyl-substitute 4-aminopicolinic acid derivatives |
CA2607934C (en) * | 2005-05-06 | 2013-10-01 | E. I. Du Pont De Nemours And Company | Method for preparation of optionally 2-substituted 1,6-dihydro-6-oxo-4-pyrimidinecarboxylic acids |
AU2007204887B2 (en) | 2006-01-13 | 2011-06-23 | Corteva Agriscience Llc | 2-(poly-substituted aryl)-6-amino-5-halo-4-pyrimidinecarboxylic acids and their use as herbicides |
BR122015016965B8 (pt) * | 2006-01-13 | 2022-06-28 | Dow Agrosciences Llc | 6-(aril polissubstituído)-4-aminopicolinatos, composição herbicida, e método para controle de vegetação indesejável |
AU2007212702A1 (en) | 2006-02-02 | 2007-08-16 | E. I. Du Pont De Nemours And Company | Method for improving harvestability of crops |
PL2311815T3 (pl) | 2007-08-13 | 2013-05-31 | Dow Agrosciences Llc | 2-(2-fluoro-podstawiony fenyl)-6-amino-5-chloro-4-pirymidyno-karboksylany i ich zastosowanie jako herbicydów |
BRPI0816075A2 (pt) * | 2007-08-30 | 2015-02-24 | Dow Agrosciences Llc | 2-(fenil substituído)-6-amino-5-alcóxi, tioalcóxi e aminoalquil-4-pirimidinacarboxilatos e seus usos como herbicidas |
DE102007042754A1 (de) * | 2007-09-07 | 2009-03-12 | Bayer Healthcare Ag | Substituierte 6-Phenylnikotinsäuren und ihre Verwendung |
EP2327694B1 (en) | 2007-10-02 | 2013-07-24 | Dow AgroSciences LLC | Substituted 4-amino-picolinic acids and their use as herbicides |
CN103333157A (zh) * | 2008-09-02 | 2013-10-02 | 诺瓦提斯公司 | 作为激酶抑制剂的吡啶甲酰胺衍生物 |
EP2191719A1 (de) * | 2008-11-29 | 2010-06-02 | Bayer CropScience AG | Herbizid-Safener-Kombination |
EP2191716A1 (de) * | 2008-11-29 | 2010-06-02 | Bayer CropScience AG | Herbizid-Safener-Kombination |
EP2191720A1 (de) * | 2008-11-29 | 2010-06-02 | Bayer CropScience AG | Herbizid-Safener-Kombination |
GB0902474D0 (en) | 2009-02-13 | 2009-04-01 | Syngenta Ltd | Chemical compounds |
CA2750539A1 (en) * | 2009-02-27 | 2010-09-02 | Dow Agrosciences Llc | N-alkoxyamides of 6-(substituted phenyl)-4-aminopicolinates and 2-(substituted phenyl)-6-amino-4-pyrimidinecarboxylates and their use as selective herbicides for crops |
GB0907625D0 (en) * | 2009-05-01 | 2009-06-10 | Syngenta Ltd | Method of controlling undesired vegetation |
AR079417A1 (es) | 2009-10-29 | 2012-01-25 | Dow Agrosciences Llc | Proteccion del dano causado por el herbicida 6-amino-2-(fenil sustituido)-5-sustituido-4-pirimidincarboxilato en cultivo de cereales |
CA2804445A1 (en) * | 2010-07-15 | 2012-01-19 | Dow Agrosciences Llc | Solid herbicide compositions with built-in adjuvant |
AU2011317665A1 (en) | 2010-10-22 | 2013-05-02 | Bayer Intellectual Property Gmbh | Novel substituted picolinic acids, salts and acid derivatives thereof, and use thereof as herbicides |
AU2011344342A1 (en) | 2010-12-16 | 2013-07-04 | Bayer Intellectual Property Gmbh | 6-(2-aminophenyl)picolinates and their use as herbicides |
US8835409B2 (en) | 2011-01-25 | 2014-09-16 | Dow Agrosciences, Llc. | 3-alkenyl-6-halo-4-aminopicolinates and their use as herbicides |
TWI592401B (zh) | 2011-01-25 | 2017-07-21 | 陶氏農業科學公司 | 用於製備4-胺基-3-氯-5-氟-6-(經取代的)吡啶甲酸酯的方法(一) |
BR112013018859A2 (pt) * | 2011-01-25 | 2016-07-12 | Dow Agrosciences Llc | "ácidos e ésteres 6-amino-2-substituídos-5-vinilsililpirimidina-4-carboxílicos e ácidos e ésteres 4-amino-6-substituídos-3-vinilsililpiridina-picolínicos como herbicidas" |
TWI596088B (zh) | 2011-01-25 | 2017-08-21 | 陶氏農業科學公司 | 4-胺基-6-(經取代的苯基)吡啶甲酸酯及6-胺基-2-(經取代的苯基)-4-嘧啶羧酸酯之芳烷酯以及其等作為除草劑之用途 |
JP6147252B2 (ja) * | 2011-06-30 | 2017-06-14 | ダウ アグロサイエンシィズ エルエルシー | 3−アルコキシ、チオアルキルおよびアミノ−4−アミノ−6−(置換)ピコリネート、ならびに除草剤としてのそれらの使用 |
-
2013
- 2013-03-15 US US13/840,233 patent/US9113629B2/en active Active
-
2014
- 2014-03-12 PL PL14769101T patent/PL2967069T3/pl unknown
- 2014-03-12 KR KR1020217020172A patent/KR102414529B1/ko active IP Right Grant
- 2014-03-12 CA CA2902347A patent/CA2902347C/en active Active
- 2014-03-12 PT PT14769101T patent/PT2967069T/pt unknown
- 2014-03-12 CN CN201810419595.2A patent/CN108689924B/zh active Active
- 2014-03-12 UA UAA201509839A patent/UA118189C2/uk unknown
- 2014-03-12 CA CA3124191A patent/CA3124191A1/en active Pending
- 2014-03-12 ES ES18195928T patent/ES2959334T3/es active Active
- 2014-03-12 CN CN201480025045.2A patent/CN105163588B/zh active Active
- 2014-03-12 WO PCT/US2014/024388 patent/WO2014150850A1/en active Application Filing
- 2014-03-12 RS RS20181536A patent/RS58151B1/sr unknown
- 2014-03-12 ES ES14769101T patent/ES2706504T3/es active Active
- 2014-03-12 RU RU2018114460A patent/RU2771326C2/ru active
- 2014-03-12 PL PL18195928.9T patent/PL3440938T3/pl unknown
- 2014-03-12 RU RU2015143829A patent/RU2652132C2/ru active
- 2014-03-12 UA UAA201807765A patent/UA125174C2/uk unknown
- 2014-03-12 AU AU2014235571A patent/AU2014235571C1/en active Active
- 2014-03-12 EP EP18195928.9A patent/EP3440938B1/en active Active
- 2014-03-12 KR KR1020157028565A patent/KR102272777B1/ko active IP Right Grant
- 2014-03-12 LT LTEP14769101.8T patent/LT2967069T/lt unknown
- 2014-03-12 EP EP14769101.8A patent/EP2967069B1/en active Active
- 2014-03-12 DK DK14769101.8T patent/DK2967069T3/en active
- 2014-03-12 AP AP2015008772A patent/AP2015008772A0/xx unknown
- 2014-03-12 SI SI201431000T patent/SI2967069T1/sl unknown
- 2014-03-12 JP JP2016501520A patent/JP6527502B2/ja active Active
- 2014-03-12 MX MX2015013242A patent/MX367303B/es active IP Right Grant
- 2014-03-12 HU HUE18195928A patent/HUE063201T2/hu unknown
- 2014-03-14 AR ARP140100999A patent/AR095449A1/es active IP Right Grant
- 2014-03-17 BR BR122019021766A patent/BR122019021766B8/pt active IP Right Grant
- 2014-03-17 UY UY0001035477A patent/UY35477A/es not_active Application Discontinuation
- 2014-03-17 BR BR102014006229A patent/BR102014006229B8/pt active IP Right Grant
-
2015
- 2015-08-26 IL IL240854A patent/IL240854A/en active IP Right Grant
- 2015-09-14 CL CL2015002665A patent/CL2015002665A1/es unknown
- 2015-09-15 PH PH12015502146A patent/PH12015502146B1/en unknown
- 2015-10-02 ZA ZA2015/07330A patent/ZA201507330B/en unknown
- 2015-10-08 CR CR20150521A patent/CR20150521A/es unknown
-
2018
- 2018-03-07 AU AU2018201665A patent/AU2018201665A1/en not_active Abandoned
- 2018-04-12 JP JP2018076745A patent/JP2018127480A/ja active Pending
- 2018-12-06 HR HRP20182056TT patent/HRP20182056T1/hr unknown
-
2019
- 2019-09-13 AU AU2019229409A patent/AU2019229409B2/en active Active
-
2020
- 2020-01-30 AR ARP200100245A patent/AR117923A2/es active IP Right Grant
- 2020-02-13 JP JP2020022143A patent/JP2020097614A/ja active Pending
-
2022
- 2022-03-29 JP JP2022052676A patent/JP2022088515A/ja active Pending
Also Published As
Similar Documents
Publication | Publication Date | Title |
---|---|---|
RU2018114460A (ru) | 4-амино-6-(4-замещенные-фенил)-пиколинаты и 6-амино-2-(4-замещенные-фенил)-пиримидин-4-карбоксилаты и их применение в качестве гербицидов | |
JP2015535277A5 (ru) | ||
NZ631738A (en) | (hetero) arylacetamide derivatives as antiretroviral agents | |
NZ631762A (en) | 5-membered heteroaryls and their use as antiviral agents | |
NZ712174A (en) | 4-amino-6-(heterocyclic)picolinates and 6-amino-2-(heterocyclic) pyrimidine-4-carboxylates and their use as herbicides | |
CY1118721T1 (el) | Παραγωγα 2,3 διϋδρο-1η-ινδεν-1-υλ-2,7-διαζασπειρο[3.6]εννεανιου και η χρηση αυτων ως ανταγωνιστες ή αντιστροφοι αγωνιστες του υποδοχεα γκρελινης | |
IN2014DN10806A (ru) | ||
EA201390884A1 (ru) | Азабензимидазолы в качестве противовирусных средств в отношении респираторного синцитиального вируса | |
NZ727792A (en) | Therapeutic compounds | |
EA201501142A1 (ru) | Гетероциклические соединения в качестве средств для борьбы с вредителями | |
NZ728537A (en) | Amide compounds for the treatment of hiv | |
NZ719634A (en) | Pesticidal compositions and related methods | |
JP2016514139A5 (ru) | ||
AR105322A1 (es) | Heterociclos nitrogenados como pesticidas | |
NZ748260A (en) | Substituted pyrimidine bmi-1 inhibitors | |
MX339033B (es) | Derivados de acido antranilico. | |
EA201590992A1 (ru) | ЗАМЕЩЕННЫЕ ПИРИМИДИНОВЫЕ ОБРАТНЫЕ ИНГИБИТОРЫ Bmi-1 | |
JP2014501766A5 (ru) | ||
CO6551673A2 (es) | Derivados de heteroarilpiperidina y heteroarilpiperazina | |
NZ719749A (en) | Pesticidal compositions and related methods | |
RU2021109549A (ru) | ИНГИБИТОРЫ α-АМИНО-β-КАРБОКСИМУКОНАТ ε-СЕМИАЛЬДЕГИД-ДЕКАРБОКСИЛАЗЫ | |
JP2016514138A5 (ru) | ||
EA201590021A1 (ru) | Новые замещенные производные 1,3-дигидро-2h-бензимидазол-2-она, замещенные гетероциклами, в качестве противовирусных средств против респираторного синцитиального вируса | |
EA201391265A1 (ru) | Амиды индолкарбоновых и бензимидазолкарбоновых кислот в качестве инсектицидов и акарицидов | |
NZ719759A (en) | Pesticidal compositions and related methods |