RU2014149845A - Улучшенный способ алканолиза, способ выделения катализатора из смеси продуктов и устройство для них - Google Patents
Улучшенный способ алканолиза, способ выделения катализатора из смеси продуктов и устройство для них Download PDFInfo
- Publication number
- RU2014149845A RU2014149845A RU2014149845A RU2014149845A RU2014149845A RU 2014149845 A RU2014149845 A RU 2014149845A RU 2014149845 A RU2014149845 A RU 2014149845A RU 2014149845 A RU2014149845 A RU 2014149845A RU 2014149845 A RU2014149845 A RU 2014149845A
- Authority
- RU
- Russia
- Prior art keywords
- ion exchange
- reactor
- exchange resin
- column
- polyether polyol
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims abstract 16
- 239000003054 catalyst Substances 0.000 title claims abstract 12
- 239000000203 mixture Substances 0.000 title claims 6
- NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 claims abstract 18
- 239000004721 Polyphenylene oxide Substances 0.000 claims abstract 18
- 239000003456 ion exchange resin Substances 0.000 claims abstract 18
- 229920003303 ion-exchange polymer Polymers 0.000 claims abstract 18
- 229920000570 polyether Polymers 0.000 claims abstract 18
- 229920005862 polyol Polymers 0.000 claims abstract 14
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims abstract 12
- 150000003077 polyols Chemical class 0.000 claims abstract 11
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims abstract 9
- 239000003513 alkali Substances 0.000 claims abstract 9
- 150000005690 diesters Chemical class 0.000 claims abstract 8
- 239000011347 resin Substances 0.000 claims abstract 6
- 229920005989 resin Polymers 0.000 claims abstract 6
- 150000001342 alkaline earth metals Chemical class 0.000 claims abstract 5
- 239000002245 particle Substances 0.000 claims abstract 5
- 229910001413 alkali metal ion Inorganic materials 0.000 claims abstract 3
- 229910001420 alkaline earth metal ion Inorganic materials 0.000 claims abstract 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 claims abstract 2
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 claims abstract 2
- KXKVLQRXCPHEJC-UHFFFAOYSA-N acetic acid trimethyl ester Natural products COC(C)=O KXKVLQRXCPHEJC-UHFFFAOYSA-N 0.000 claims abstract 2
- 239000006227 byproduct Substances 0.000 claims abstract 2
- 229920000728 polyester Polymers 0.000 claims abstract 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims 6
- -1 polyol diester Chemical class 0.000 claims 6
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims 4
- WQDUMFSSJAZKTM-UHFFFAOYSA-N Sodium methoxide Chemical group [Na+].[O-]C WQDUMFSSJAZKTM-UHFFFAOYSA-N 0.000 claims 4
- 229910052751 metal Inorganic materials 0.000 claims 3
- 239000002184 metal Substances 0.000 claims 3
- 238000004821 distillation Methods 0.000 claims 2
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims 2
- 229920000642 polymer Polymers 0.000 claims 2
- 229910052783 alkali metal Inorganic materials 0.000 claims 1
- 150000002148 esters Chemical class 0.000 claims 1
- 239000011521 glass Substances 0.000 claims 1
- 239000000178 monomer Substances 0.000 claims 1
- 229920000909 polytetrahydrofuran Polymers 0.000 claims 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/34—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from hydroxy compounds or their metallic derivatives
- C08G65/48—Polymers modified by chemical after-treatment
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/24—Stationary reactors without moving elements inside
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
- C08G65/30—Post-polymerisation treatment, e.g. recovery, purification, drying
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
- C08G65/32—Polymers modified by chemical after-treatment
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
- C08G65/32—Polymers modified by chemical after-treatment
- C08G65/329—Polymers modified by chemical after-treatment with organic compounds
- C08G65/331—Polymers modified by chemical after-treatment with organic compounds containing oxygen
- C08G65/3311—Polymers modified by chemical after-treatment with organic compounds containing oxygen containing a hydroxy group
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/24—Stationary reactors without moving elements inside
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Polyethers (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201261663015P | 2012-06-22 | 2012-06-22 | |
| US61/663,015 | 2012-06-22 | ||
| PCT/US2013/045412 WO2013191987A1 (en) | 2012-06-22 | 2013-06-12 | Improved alkanolysis process and method for separating catalyst from product mixture and apparatus therefor |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| RU2014149845A true RU2014149845A (ru) | 2016-08-10 |
Family
ID=49769229
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RU2014149845A RU2014149845A (ru) | 2012-06-22 | 2013-06-12 | Улучшенный способ алканолиза, способ выделения катализатора из смеси продуктов и устройство для них |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US20150158976A1 (enExample) |
| EP (1) | EP2864392A4 (enExample) |
| KR (1) | KR20150024840A (enExample) |
| CN (2) | CN204138580U (enExample) |
| BR (1) | BR112014029525A2 (enExample) |
| IN (1) | IN2015MN00017A (enExample) |
| RU (1) | RU2014149845A (enExample) |
| WO (1) | WO2013191987A1 (enExample) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105131274B (zh) * | 2015-08-20 | 2017-11-10 | 西安蓝晓科技新材料股份有限公司 | 一种用于聚四氢呋喃生产中除钠离子的方法 |
| EP3392288A1 (en) | 2017-04-21 | 2018-10-24 | Sulzer Chemtech AG | A process to prepare a cyclic oligomer and a cyclic oligomer obtainable thereby and a process to polymerize it |
| US12515212B2 (en) | 2022-10-12 | 2026-01-06 | Covestro Llc | Processes for purifying polyether polyols using ion exchange resins |
Family Cites Families (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4584414A (en) * | 1984-12-21 | 1986-04-22 | E. I. Du Pont De Nemours And Company | Process for preparing improved poly(tetramethylene ether) glycol by alcoholysis |
| US4985551A (en) * | 1988-12-29 | 1991-01-15 | Basf Corporation | Process for purification of catalysts from polyols using ion exchange resins |
| US5254227A (en) | 1989-06-16 | 1993-10-19 | Olin Corporation | Process for removing catalyst impurities from polyols |
| WO1990015659A1 (en) * | 1989-06-16 | 1990-12-27 | Olin Corporation | Process for removing ionizable impurities from non-aqueous fluids |
| US5852218A (en) * | 1995-12-14 | 1998-12-22 | E. I. Du Pont De Nemours And Company | Alkanolysis of polyether polyol esters by reactive distillation |
| DE19758296A1 (de) | 1997-12-31 | 1999-07-01 | Basf Ag | Herstellung von Polytetrahydrofuran mit endständigen Hydroxylgruppen unter Verwendung von Ionenaustauschern |
| JPH11279275A (ja) * | 1998-03-27 | 1999-10-12 | Mitsubishi Chemical Corp | ポリテトラメチレンエーテルグリコールの製造方法 |
| JP3837966B2 (ja) * | 1999-06-22 | 2006-10-25 | 三菱化学株式会社 | ポリテトラメチレンエーテルグリコールの製造方法 |
| JP2001011173A (ja) * | 1999-06-30 | 2001-01-16 | Mitsubishi Chemicals Corp | ポリテトラメチレンエーテルグリコールの製造方法 |
| DE10032266A1 (de) | 2000-07-03 | 2002-01-17 | Basf Ag | Verbessertes Verfahren zur einstufigen Herstellung von Polytetrahydrofuran und Tetrahydrofuran-Copolymeren |
| DE10112116A1 (de) * | 2001-03-14 | 2002-09-19 | Basf Ag | Verfahren zur Herstellung von Polyetherolen mit definiertem CPR-Wert |
| DE10140949A1 (de) | 2001-08-21 | 2003-03-06 | Basf Ag | Verfahren zur Herstellung einer alkoholischen Lösung von Polytetrahydrofuran mit endständigen OH-Gruppen |
| CN101080433B (zh) * | 2005-03-17 | 2012-06-27 | 三菱化学株式会社 | 聚醚多元醇化合物的制造方法 |
| BRPI0822694B1 (pt) * | 2008-05-15 | 2018-11-27 | Asahi Kasei Chemicals Corp | processo para produzir um isocianato |
| US20140378712A1 (en) * | 2012-01-26 | 2014-12-25 | Invista North America S.A.R.L. | Alkanolysis process |
-
2013
- 2013-06-12 EP EP13806916.6A patent/EP2864392A4/en not_active Withdrawn
- 2013-06-12 WO PCT/US2013/045412 patent/WO2013191987A1/en not_active Ceased
- 2013-06-12 BR BR112014029525A patent/BR112014029525A2/pt not_active IP Right Cessation
- 2013-06-12 US US14/407,296 patent/US20150158976A1/en not_active Abandoned
- 2013-06-12 IN IN17MUN2015 patent/IN2015MN00017A/en unknown
- 2013-06-12 KR KR1020147035429A patent/KR20150024840A/ko not_active Withdrawn
- 2013-06-12 RU RU2014149845A patent/RU2014149845A/ru not_active Application Discontinuation
- 2013-06-24 CN CN201320364301.3U patent/CN204138580U/zh not_active Expired - Lifetime
- 2013-06-24 CN CN201310252804.6A patent/CN103509177B/zh active Active
Also Published As
| Publication number | Publication date |
|---|---|
| CN103509177A (zh) | 2014-01-15 |
| EP2864392A1 (en) | 2015-04-29 |
| IN2015MN00017A (enExample) | 2015-10-16 |
| EP2864392A4 (en) | 2015-12-23 |
| BR112014029525A2 (pt) | 2017-06-27 |
| KR20150024840A (ko) | 2015-03-09 |
| WO2013191987A1 (en) | 2013-12-27 |
| CN103509177B (zh) | 2017-04-12 |
| US20150158976A1 (en) | 2015-06-11 |
| CN204138580U (zh) | 2015-02-04 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| KR102121906B1 (ko) | (퍼)플루오로폴리에테르 알코올의 알콕실화 공정 | |
| CN109107207B (zh) | 一种带有外循环系统的反应精馏装置及其应用 | |
| CN101918347A (zh) | 丙二醇单烷基醚的制备 | |
| KR20260046442A (ko) | 메틸 3-메톡시프로피오네이트 및 3-메톡시-n,n-디메틸프로피온아미드의 제조 방법 | |
| CN108484896A (zh) | 一种低voc高活性高分子量聚醚多元醇的制备方法 | |
| JPS5914018B2 (ja) | メタクリル酸エステルの製造方法 | |
| RU2162862C2 (ru) | Способ получения простых полиэфирполиолов с двумя концевыми гидроксильными группами | |
| CN203159515U (zh) | 改进的醇解装置 | |
| CN100519497C (zh) | 从二氯丙醇盐酸水溶液中萃取分离二氯丙醇的方法 | |
| CN106892798A (zh) | 制备二氯丙醇的方法 | |
| CN103509177B (zh) | 改进的醇解方法和用于从产物混合物分离催化剂的方法及其装置 | |
| CN103509176A (zh) | 用于聚四亚甲基醚二醇分子量分布窄化的受控的部分解聚方法 | |
| EP2137176A1 (en) | Process for preparing an 1,2-alkylene carbonate | |
| CN103588622A (zh) | 连续水解反应合成2-甲基烯丙醇的方法 | |
| WO2021049459A1 (ja) | 抽出対象物の抽出方法および液液抽出塔 | |
| CN108017598B (zh) | 环氧丁烷组合物及其制备方法 | |
| CN214636274U (zh) | 一种用于生产hfpo三聚体的微孔管道反应器 | |
| CN214654566U (zh) | 一种连续生产hfpo三聚体的反应设备 | |
| KR20130115102A (ko) | 다중하이드록실화된 지방족 탄화수소의 염화수소첨가 방법 | |
| CN110734372B (zh) | 一种合成烯丙基脂肪醇聚氧乙烯醚羧酸（apea-9）的方法 | |
| KR20220163415A (ko) | 마이크로 반응기를 통해 옥세탄 화합물을 합성하는 방법 | |
| JP3852543B2 (ja) | ポリテトラメチレンエーテルグリコールの製造方法 | |
| JP5561157B2 (ja) | （メタ）アクリレート混合物の製造方法 | |
| EP3199515B1 (en) | Method for producing 3-chloro-2-hydroxypropyl (meth)acrylate and method for producing glycidyl (meth)acrylate | |
| CN110642704B (zh) | 一种合成烯丙基脂肪醇聚氧乙烯醚羧酸（apea-4）的方法 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FA92 | Acknowledgement of application withdrawn (lack of supplementary materials submitted) |
Effective date: 20170901 |