RU2008147212A - Катализатор фишера-тропша, включающий оксид кобальта и цинка - Google Patents

Катализатор фишера-тропша, включающий оксид кобальта и цинка Download PDF

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RU2008147212A
RU2008147212A RU2008147212/04A RU2008147212A RU2008147212A RU 2008147212 A RU2008147212 A RU 2008147212A RU 2008147212/04 A RU2008147212/04 A RU 2008147212/04A RU 2008147212 A RU2008147212 A RU 2008147212A RU 2008147212 A RU2008147212 A RU 2008147212A
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Тьяллинг РЕККЕР (NL)
Тьяллинг РЕККЕР
Корнелис БАИЙЕНС (NL)
Корнелис БАИЙЕНС
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Басф Каталистс Ллк (Us)
Басф Каталистс Ллк
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  • General Chemical & Material Sciences (AREA)
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  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

1. Катализатор, подходящий для катализирования реакции Фишера-Тропша, включающий металлический кобальт, нанесенный на оксид цинка и имеющий следующее распределение размера частиц по объему: ! <10% имеет размер частиц ниже 1 мкм, ! 70-99% имеет размер частиц между 1 и 5 мкм, и ! <20% имеет размер частиц выше 5 мкм. ! 2. Катализатор по п.1, имеющий следующее распределение размера частиц по объему: ! <10% имеет размер частиц ниже 1 мкм, ! 75-95% имеет размер частиц между 1 и 5 мкм, и ! <15% имеет размер частиц выше 5 мкм. ! 3. Катализатор по п.1 или 2, в котором средняя объемная величина частиц составляет менее чем 25 мкм, предпочтительно от 1,5 до 15 мкм. ! 4. Катализатор по п.1 или 2, в котором объем пор главным образом образован порами, имеющими диаметр в диапазоне 5-100 нм. ! 5. Катализатор по п.1 или 2, в котором объем пор составляет менее чем 0,5 мл/г, предпочтительно менее чем 0,45 мл/г. ! 6. Катализатор по п.1 или 2, в котором удельная поверхность составляет менее чем 120 м2/г, предпочтительно находится в диапазоне 5-100 м2/г. ! 7. Катализатор по п.1 или п.2, в котором атомное соотношение цинка к кобальту находится в диапазоне 75 : 0,1, предпочтительно 40 : 0,1. ! 8. Катализатор по п.1 или 2, в котором присутствует один или несколько промоторов, таких как рутений, гафний, платина, цирконий, палладий, рений, церий, лантан или их комбинация, обычно при атомном соотношении кобальта к промотору вплоть до 10:1. ! 9. Катализатор по п.1 или 2, дополнительно включающий по меньшей мере один элемент соединений из группы IIIa, предпочтительно в концентрации 0,1-60, более предпочтительно 0,1-10 мас.% вес катализатора. ! 10. Применение катализатора по любому из пп.1-9 в способе Фишера-Тропша или гидрогенизации функ�

Claims (11)

1. Катализатор, подходящий для катализирования реакции Фишера-Тропша, включающий металлический кобальт, нанесенный на оксид цинка и имеющий следующее распределение размера частиц по объему:
<10% имеет размер частиц ниже 1 мкм,
70-99% имеет размер частиц между 1 и 5 мкм, и
<20% имеет размер частиц выше 5 мкм.
2. Катализатор по п.1, имеющий следующее распределение размера частиц по объему:
<10% имеет размер частиц ниже 1 мкм,
75-95% имеет размер частиц между 1 и 5 мкм, и
<15% имеет размер частиц выше 5 мкм.
3. Катализатор по п.1 или 2, в котором средняя объемная величина частиц составляет менее чем 25 мкм, предпочтительно от 1,5 до 15 мкм.
4. Катализатор по п.1 или 2, в котором объем пор главным образом образован порами, имеющими диаметр в диапазоне 5-100 нм.
5. Катализатор по п.1 или 2, в котором объем пор составляет менее чем 0,5 мл/г, предпочтительно менее чем 0,45 мл/г.
6. Катализатор по п.1 или 2, в котором удельная поверхность составляет менее чем 120 м2/г, предпочтительно находится в диапазоне 5-100 м2/г.
7. Катализатор по п.1 или п.2, в котором атомное соотношение цинка к кобальту находится в диапазоне 75 : 0,1, предпочтительно 40 : 0,1.
8. Катализатор по п.1 или 2, в котором присутствует один или несколько промоторов, таких как рутений, гафний, платина, цирконий, палладий, рений, церий, лантан или их комбинация, обычно при атомном соотношении кобальта к промотору вплоть до 10:1.
9. Катализатор по п.1 или 2, дополнительно включающий по меньшей мере один элемент соединений из группы IIIa, предпочтительно в концентрации 0,1-60, более предпочтительно 0,1-10 мас.% вес катализатора.
10. Применение катализатора по любому из пп.1-9 в способе Фишера-Тропша или гидрогенизации функциональных групп.
11. Способ Фишера-Тропша, который характеризуется тем, что применяют катализатор по пп.1-9.
RU2008147212/04A 2006-05-01 2007-04-30 Катализатор фишера-тропша, включающий оксид кобальта и цинка RU2451549C2 (ru)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EPEP060759727 2006-05-01
EP06075972A EP1852182A1 (en) 2006-05-01 2006-05-01 Fischer-Tropsch Catalyst comprising cobalt and zinc oxide
PCT/US2007/067769 WO2007130908A2 (en) 2006-05-01 2007-04-30 Fischer-tropsch catalyst comprising cobalt and zinc oxide

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RU2008147212A true RU2008147212A (ru) 2010-06-10
RU2451549C2 RU2451549C2 (ru) 2012-05-27

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US (2) US8778832B2 (ru)
EP (2) EP1852182A1 (ru)
JP (2) JP2010505599A (ru)
CN (1) CN101631611A (ru)
AR (1) AR060734A1 (ru)
AU (1) AU2007248198B2 (ru)
BR (1) BRPI0709751A2 (ru)
CA (1) CA2650840C (ru)
MY (1) MY158711A (ru)
NO (1) NO20084574L (ru)
RU (1) RU2451549C2 (ru)
WO (1) WO2007130908A2 (ru)
ZA (1) ZA200810092B (ru)

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EP1852182A1 (en) * 2006-05-01 2007-11-07 Engelhard Corporation Fischer-Tropsch Catalyst comprising cobalt and zinc oxide
EP2008714A1 (en) * 2007-06-19 2008-12-31 BASF Catalysts LLC Process for the preparation of a cobalt-zinc oxide Fischer-Tropsch catalyst
EP2090363A1 (en) * 2008-02-05 2009-08-19 Basf Se Fischer-Tropsch catalyst containing cobalt on Zinc oxide support doped with either Alumina or Zirconia
ATE551318T1 (de) 2008-05-13 2012-04-15 Basf Se Verfahren zur herstellung von n,n-substituierten- 1,3-propandiaminen
DE102008025307A1 (de) * 2008-05-27 2009-12-03 Süd-Chemie AG Kobalt-Fischer-Tropsch-Katalysator
WO2010052181A2 (de) 2008-11-05 2010-05-14 Basf Se Verfahren zur herstellung von n,n-substituierten-3-aminopropan-1-olen
CN102266780B (zh) * 2011-05-30 2012-12-26 陕西师范大学 酸活化蒙脱土载钴催化剂及其制备方法和应用
CN102266779B (zh) * 2011-05-30 2012-12-26 陕西师范大学 离子交换蒙脱土载钴催化剂及其制备方法和应用
RU2538088C1 (ru) * 2013-10-14 2015-01-10 Федеральное государственное автономное образовательное учреждение высшего образования "Новосибирский национальный исследовательский государственный университет" (Новосибирский государственный университет, НГУ) Способ приготовления катализатора превращения синтез-газа в углеводороды и катализатор
US12042785B1 (en) 2023-09-13 2024-07-23 Dimensional Energy, Inc. Fischer-Tropsch catalysts

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RU2451549C2 (ru) 2012-05-27
CA2650840C (en) 2013-04-02
US8778832B2 (en) 2014-07-15
US20090197981A1 (en) 2009-08-06
CA2650840A1 (en) 2007-11-15
CN101631611A (zh) 2010-01-20
WO2007130908A2 (en) 2007-11-15
JP5795393B2 (ja) 2015-10-14
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AU2007248198B2 (en) 2011-11-03
AU2007248198A1 (en) 2007-11-15
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