RU2008103094A - METHOD FOR PRODUCING 1-ALCOXY (CYCLOALCOXY) -1,2-DIHYDRO [60] FULLERENES - Google Patents

METHOD FOR PRODUCING 1-ALCOXY (CYCLOALCOXY) -1,2-DIHYDRO [60] FULLERENES Download PDF

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RU2008103094A
RU2008103094A RU2008103094/04A RU2008103094A RU2008103094A RU 2008103094 A RU2008103094 A RU 2008103094A RU 2008103094/04 A RU2008103094/04 A RU 2008103094/04A RU 2008103094 A RU2008103094 A RU 2008103094A RU 2008103094 A RU2008103094 A RU 2008103094A
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fullerenes
dihydro
cycloalcoxy
alcoxy
producing
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RU2008103094/04A
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Russian (ru)
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RU2384561C2 (en
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Усеин Меметович Джемилев (RU)
Усеин Меметович Джемилев
Айрат Рамилевич Туктаров (RU)
Айрат Рамилевич Туктаров
Арслан Рифхатович Ахметов (RU)
Арслан Рифхатович Ахметов
Марко Пудас (FI)
Марко Пудас
Асхат Габдрахманович Ибрагимов (RU)
Асхат Габдрахманович Ибрагимов
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Институт Нефтехимии И Катализа Российская Академия Наук (Ru)
Институт Нефтехимии И Катализа Российская Академия Наук
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Abstract

Способ получения 1-алкокси(циклоалкокси)-1,2-дигидро[60]фуллеренов общей формулы (1) ! ! R=i-Рr, Bu, t-Bu, cyclo-Нех, Dec, ! отличающийся тем, что фуллерен С60 подвергают взаимодействию с насыщенными спиртами в присутствии катализатора цирконацендихлорида в мольном соотношении С60:ROH:Cp2ZrCl2, равном 0.01:(10-20):(0,0015-0,0025), в среде толуола в качестве растворителя при комнатной температуре (~20°С) в течение 20-28 ч.The method of obtaining 1-alkoxy (cycloalkoxy) -1,2-dihydro [60] fullerenes of the general formula (1)! ! R = i-Pr, Bu, t-Bu, cyclo-Neh, Dec,! characterized in that the fullerene C60 is reacted with saturated alcohols in the presence of a zirconacenedichloride catalyst in a molar ratio of C60: ROH: Cp2ZrCl2 equal to 0.01: (10-20) :( 0.0015-0.0025) in toluene as a solvent at room temperature (~ 20 ° C) for 20-28 hours

Claims (1)

Способ получения 1-алкокси(циклоалкокси)-1,2-дигидро[60]фуллеренов общей формулы (1)The method of obtaining 1-alkoxy (cycloalkoxy) -1,2-dihydro [60] fullerenes of the General formula (1)
Figure 00000001
Figure 00000001
 R=i-Рr, Bu, t-Bu, cyclo-Нех, Dec,R = i-Pr, Bu, t-Bu, cyclo-Neh, Dec, отличающийся тем, что фуллерен С60 подвергают взаимодействию с насыщенными спиртами в присутствии катализатора цирконацендихлорида в мольном соотношении С60:ROH:Cp2ZrCl2, равном 0.01:(10-20):(0,0015-0,0025), в среде толуола в качестве растворителя при комнатной температуре (~20°С) в течение 20-28 ч. characterized in that the fullerene C 60 is reacted with saturated alcohols in the presence of a zirconacene dichloride catalyst in a molar ratio of C 60 : ROH: Cp 2 ZrCl 2 equal to 0.01: (10-20) :( 0.0015-0.0025) in medium toluene as a solvent at room temperature (~ 20 ° C) for 20-28 hours
RU2008103094/04A 2008-01-28 2008-01-28 Method of producing 1-alkoxy- or 1-cycloalkoxy-1,2-dihydro[60]fullerene RU2384561C2 (en)

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JP2016017063A (en) * 2014-07-10 2016-02-01 国立大学法人大阪大学 Long-chain alkyl-etherified fullerene derivative and production method thereof, and resin composition prepared using the same
EP3141539B1 (en) * 2015-09-11 2019-11-20 Totai Co. Ltd. Long-chain alkyl-etherified fullerene derivative, production method for the same, and resin composition using the same
JP6576494B2 (en) * 2018-02-20 2019-09-18 国立大学法人大阪大学 Long-chain alkyl etherified fullerene derivative, process for producing the same, and resin composition using the same

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