RU2006105627A - Обессеривание и новый способ обессеривания - Google Patents

Обессеривание и новый способ обессеривания Download PDF

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Publication number
RU2006105627A
RU2006105627A RU2006105627/04A RU2006105627A RU2006105627A RU 2006105627 A RU2006105627 A RU 2006105627A RU 2006105627/04 A RU2006105627/04 A RU 2006105627/04A RU 2006105627 A RU2006105627 A RU 2006105627A RU 2006105627 A RU2006105627 A RU 2006105627A
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Russia
Prior art keywords
mixture
composition
promoter
dried
calcined
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RU2006105627/04A
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English (en)
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RU2336126C2 (ru
Inventor
Тусхар В. ЧАУДХАРИ (US)
Тусхар В. ЧАУДХАРИ
Джейсон Дж. ГИСГЛЭСОН (US)
Джейсон Дж. ГИСГЛЭСОН
Гленн В. ДОДВЕЛЛ (US)
Гленн В. ДОДВЕЛЛ
Уилль м Х. БИВЕР (US)
Уилльям Х. БИВЕР
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Конокофиллипс Компани (Us)
Конокофиллипс Компани
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Publication of RU2006105627A publication Critical patent/RU2006105627A/ru
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    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
    • C10G45/04—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used
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Claims (18)

1. Способ получения композиции, включающий
(а) примешивание: 1) жидкости, 2) содержащего цинк соединения, 3) содержащего кремнезем материала, 4) глинозема и 5) промотора для получения ее смеси;
(b) сушку упомянутой смеси для получения высушенной смеси;
(с) обжиг упомянутой высушенной смеси для получения обожженной смеси;
(d) восстановление упомянутой обожженной смеси подходящим восстановителем в подходящих условиях для получения композиции, содержащей промотор с пониженной валентностью; и
(е) регенерацию упомянутой композиции.
2. Способ получения композиции, включающий
(а) примешивание: 1) жидкости, 2) содержащего металл соединения, 3) содержащего кремнезем материала, 4) глинозема и 5)первый промотор для получения ее смеси;
(b) сушку упомянутой смеси для получения высушенной смеси;
(с) внесение второго промотора на или в упомянутую высушенную смесь для получения объединенной смеси;
(d) сушку упомянутой объединенной смеси для получения высушенной объединенной смеси;
(e) обжиг упомянутой высушенной объединенной смеси для получения обожженной объединенной смеси;
(f) восстановление упомянутой обожженной объединенной смеси подходящим восстановителем в подходящих условиях для получения композиции, содержащей промотор с пониженной валентностью; и
(g) регенерацию упомянутой композиции.
3. Способ по п. 1 или 2, в котором упомянутую обожженную смесь и упомянутую обожженную объединенную смесь восстанавливают на стадиях (d)и (f)соответственно таким образом, что упомянутая композиция со стадии (е) и стадии (g)соответственно влияет на удаление серы из потока углеводородов при контакте с ней (композицией) такого потока в условиях обессеривания.
4. Способ по п.1 или 2, в котором упомянутый промотор и упомянутый первый промотор соответственно включает металл, выбранный из группы, включающей никель, кобальт, железо, марганец, медь, цинк, молибден, вольфрам, серебро, олово, сурьму, ванадий, золото, платину, рутений, иридий, хром, палладий, титан, цирконий, родий, рений, а также сочетания любых двух или более из них особенно когда упомянутый промотор и упомянутый первый промотор соответственно включают никель.
5. Способ по п. 1 или 2, в котором упомянутый содержащий кремнезем материал имеет вид раздробленного экспандированного перлита.
6. Способ по п. 1 или 2, в котором упомянутая смесь со стадии (а) имеет вид влажной смеси, теста, пасты или взвеси в особенности когда упомянутая смесь со стадии (а) находится в форме взвеси.
7. Способ по п. 1 или 2, в котором упомянутую смесь со стадии (а) подвергают микроизмельчению перед упомянутой сушкой на стадии (b); или где упомянутую смесь со стадии (а) подвергают микроизмельчению для получения гранул, экструдатов, таблеток, шариков, окатышей или микрошариков; или где упомянутую смесь со стадии (а) подвергают микроизмельчению путем сушки распылением на стадии (b) таким образом, чтобы получить упомянутую высушенную смесь.
8. Способ по п. 1 или 2, в котором упомянутую смесь и упомянутую объединенную смесь каждую сушат на стадии (b) и стадии (d) соответственно при температуре приблизительно от 65,5 до 550°С; или когда упомянутую высушенную смесь и упомянутую объединенную высушенную смесь обжигают на стадии (с) и стадии (е) соответственно при температуре приблизительно от 204,4 до 815,5°С.
9. Способ по п. 1 или 2, в котором упомянутую обожженную смесь упомянутую обожженную объединенную смесь восстанавливают на стадиях (d) и (а) соответственно при температуре приблизительно от 37,8 до 815,5°С, давлении приблизительно от 103 кПа до 10,33 МПа (приблизительно от 15 до 1500 абс. фунтов на кв.дюйм) и в течение периода времени, достаточного чтобы обеспечить образование промотора с пониженной валентностью; или когда во время упомянутого обжига на стадиях (с) и (е) соответственно по меньшей мере часть упомянутого глинозема превращают в алюминат.
10. Способ по п.2, в котором упомянутое металлсодержащее соединение включает металл, выбранный из группы, включающей цинк, марганец, серебро, медь, кадмий, олово, лантан, скандий, церий, вольфрам, молибден, железо, ниобий, тантал, галий, индий, а также сочетания любых двух или более из них, в особенности, когда упомянутое металл-содержащее соединение включает цинк.
11. Способ по п.2, в котором упомянутый второй промотор включает по меньшей мере один металл, выбранный из группы, включающей никель, кобальт, железо, марганец, медь, цинк, молибден, вольфрам, серебро, олово, сурьму, ванадий, золото, платину, рутений, иридий, хром, палладий, титан, цирконий, родий, рений, а также сочетания любых двух или более из них в особенности когда упомянутый второй промотор включает никель.
12. Способ по п.2, в котором упомянутую высушенную смесь со стадии (b) обжигают перед упомянутым введением на стадии (с),в особенности когда упомянутую высушенную смесь обжигают при температуре приблизительно от 204,4 до 815,5°С.
13. Композиция, полученная по способу по п.1 или 2.
14. Способ удаления серы из углеводородного потока, включающий
(а) контакт упомянутого углеводородного потока с композицией, полученной способом по любому из предыдущих пунктов, в зоне обессеривания в условиях, при которых происходит образование по меньшей мере частично обессеренного углеводородного потока и осерненной композиции;
(b) отделение упомянутого по меньшей мере частично обессеренного углеводородного потока от упомянутой осерненной композиции с получением в результате отделенного обессеренного углеводородного потока и отделенной осерненной композиции;
(с) регенерацию по меньшей мере части упомянутой отделенной осерненной композиции в зоне регенерации таким образом, чтобы удалить по меньшей мере часть содержащейся в ней и/или на ней серы с получением в результате регенерированной композиции;
(d) восстановление упомянутой регенерированной композиции в зоне восстановления таким образом, чтобы получить восстановленную композицию, содержащую такое количество промотора с пониженной валентностью, которое влияет на удаление серы из серосодержащих углеводородов потока при контакте с ней; а затем
(е) возвращение по меньшей мере части восстановленной композиции в зону обессеривания.
15. Способ по п.14, в котором упомянутый углеводородный поток включает топливо, выбранное из группы, включающей крекинг-бензин, дизельное топливо и их сочетания.
16. Способ по п.14, в котором упомянутое обессеривание на стадии (а) осуществляют при температуре приблизительно от 37,8 до 537,8°С, давлении приблизительно от 103 кПа до 10,33 МПа (приблизительно от 15 до 1500 абс. фунтов на кв.дюйм) и в течение периода времени, достаточного чтобы осуществить удаление серы из упомянутого потока; или когда упомянутую регенерацию на стадии (с) осуществляют при температуре приблизительно от 37,8 до 815,5°С, давлении приблизительно от 68,9 кПа до 10,33 МПа (приблизительно от 10 до 1500 абс. фунтов на кв.дюйм) и в течение периода времени, достаточного чтобы осуществить удаление по меньшей мере части серы из упомянутой отделенной осерненной композиции; или когда воздух используют на стадии (с) в качестве регенерирующего агента в упомянутой зоне регенерации; или когда упомянутая регенерированная композиция со стадии (с) подвергают восстановлению водородом на стадии (d) в упомянутой зоне регенерации, температуру в которой поддерживают на уровне приблизительно от 37,8 до 815,5°С, давление - на уровне приблизительно от 103 кПа до 10,33 МПа (приблизительно от 15 до 1500 абс. фунтов на кв.дюйм) в течение периода времени, достаточного чтобы осуществить снижение валентности промотора, содержащегося в упомянутой регенерированной композиции.
17. Способ по п.14, в котором упомянутую регенерированную композицию со стадии (b) подвергают отгонке до подачи в упомянутую восстановительную зону на стадии (с) или когда упомянутую регенерированную композицию со стадии (с) подвергают отгонке до подачи в упомянутую восстановительную зону на стадии (d).
18. Крекинг-бензин или дизельное топливо, полученное в результате использования способа по п.15.
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US20080039318A1 (en) 2008-02-14
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