RO84500B - Procedeu de prepararea a unor derivati ai n-trifluoracetil-n-fosfonometilglicina - Google Patents
Procedeu de prepararea a unor derivati ai n-trifluoracetil-n-fosfonometilglicinaInfo
- Publication number
- RO84500B RO84500B RO107609A RO10760979A RO84500B RO 84500 B RO84500 B RO 84500B RO 107609 A RO107609 A RO 107609A RO 10760979 A RO10760979 A RO 10760979A RO 84500 B RO84500 B RO 84500B
- Authority
- RO
- Romania
- Prior art keywords
- excess
- thionyl chloride
- trifluoracetyl
- preparing
- general formula
- Prior art date
Links
- 238000004519 manufacturing process Methods 0.000 title 1
- FYSNRJHAOHDILO-UHFFFAOYSA-N thionyl chloride Chemical compound ClS(Cl)=O FYSNRJHAOHDILO-UHFFFAOYSA-N 0.000 abstract 6
- QAEDZJGFFMLHHQ-UHFFFAOYSA-N trifluoroacetic anhydride Chemical compound FC(F)(F)C(=O)OC(=O)C(F)(F)F QAEDZJGFFMLHHQ-UHFFFAOYSA-N 0.000 abstract 4
- 125000003545 alkoxy group Chemical group 0.000 abstract 2
- 239000007795 chemical reaction product Substances 0.000 abstract 2
- MKJBZNABCZRVPC-UHFFFAOYSA-N 2-[phosphonomethyl-(2,2,2-trifluoroacetyl)amino]acetic acid Chemical compound OC(=O)CN(CP(O)(O)=O)C(=O)C(F)(F)F MKJBZNABCZRVPC-UHFFFAOYSA-N 0.000 abstract 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 abstract 1
- 125000005083 alkoxyalkoxy group Chemical group 0.000 abstract 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 1
- 229910052801 chlorine Inorganic materials 0.000 abstract 1
- 239000000460 chlorine Substances 0.000 abstract 1
- 125000001309 chloro group Chemical group Cl* 0.000 abstract 1
- 150000002148 esters Chemical class 0.000 abstract 1
- XDDAORKBJWWYJS-UHFFFAOYSA-N glyphosate Chemical compound OC(=O)CNCP(O)(O)=O XDDAORKBJWWYJS-UHFFFAOYSA-N 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 238000002360 preparation method Methods 0.000 abstract 1
- 238000010992 reflux Methods 0.000 abstract 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
- A01N57/34—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-halogen bonds; Phosphonium salts
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
- C07F9/42—Halides thereof
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Dentistry (AREA)
- Engineering & Computer Science (AREA)
- Plant Pathology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Biochemistry (AREA)
- Molecular Biology (AREA)
- Agronomy & Crop Science (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
Conform inventiei, procedeul de preparare a unor derivati ai diclorurii de N-trifluoracetil-N-fosfonometil-glicina cu formula generala I: (vezi formula) în care R reprezinta clor, o grupa alcoxi cu 1 pîna la 10 atomi de carbon, o grupa alcoxialcoxi cu 3 pîna la 6 atomi de carbon sau o grupa cloralcoxi inferior, consta în aceea ca se trateaza o N-fosfonometilglicina cu formula generala III: (vezi formula) sau un ester al acesteia, în care R' reprezinta o grupa R definita mai sus, cu exceptia faptului ca R' nu poate fi clor, cu anhidrida trifluoracetica la temperaturi cuprinse între 10 si 35 degree C, dupa care produsul de reactie se trateaza cu un exces de clorura de tionil în conditii de reflux, de preferinta produsul de reactie intermediar fiindseparat de excesul de anhidrida trifluoracetica înainte de adaugarea clorurii de tionil, iar excesul de clorura de tionil este îndepartat dupa terminarea reactiei.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US89407078A | 1978-04-06 | 1978-04-06 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| RO84500A RO84500A (ro) | 1984-09-29 |
| RO84500B true RO84500B (ro) | 1984-10-30 |
Family
ID=25402560
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RO97135A RO77976B (ro) | 1978-04-06 | 1979-04-05 | Compozitie erbicida lichida |
| RO107609A RO84500B (ro) | 1978-04-06 | 1979-04-05 | Procedeu de prepararea a unor derivati ai n-trifluoracetil-n-fosfonometilglicina |
Family Applications Before (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RO97135A RO77976B (ro) | 1978-04-06 | 1979-04-05 | Compozitie erbicida lichida |
Country Status (21)
| Country | Link |
|---|---|
| EP (1) | EP0005321B1 (ro) |
| JP (1) | JPS54135725A (ro) |
| AR (1) | AR219587A1 (ro) |
| AU (1) | AU518313B2 (ro) |
| BG (1) | BG29270A3 (ro) |
| BR (1) | BR7902086A (ro) |
| CA (1) | CA1134383A (ro) |
| CS (1) | CS208496B2 (ro) |
| DD (2) | DD147112A5 (ro) |
| DE (1) | DE2962495D1 (ro) |
| DK (1) | DK147578C (ro) |
| ES (1) | ES479305A1 (ro) |
| HU (1) | HU185005B (ro) |
| IL (1) | IL57017A (ro) |
| IT (1) | IT1112954B (ro) |
| PH (1) | PH14617A (ro) |
| PL (1) | PL114130B1 (ro) |
| RO (2) | RO77976B (ro) |
| SU (1) | SU1220560A3 (ro) |
| YU (1) | YU41153B (ro) |
| ZA (1) | ZA791631B (ro) |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3853530A (en) * | 1971-03-10 | 1974-12-10 | Monsanto Co | Regulating plants with n-phosphonomethylglycine and derivatives thereof |
| PH16509A (en) * | 1971-03-10 | 1983-11-08 | Monsanto Co | N-phosphonomethylglycine phytotoxicant composition |
| US3970695A (en) * | 1975-05-23 | 1976-07-20 | Monsanto Company | N-(perfluoroacyl)-N-phosphonomethyl glycine compounds, method of preparing same |
-
1979
- 1979-04-04 ES ES479305A patent/ES479305A1/es not_active Expired
- 1979-04-04 DE DE7979300555T patent/DE2962495D1/de not_active Expired
- 1979-04-04 EP EP79300555A patent/EP0005321B1/en not_active Expired
- 1979-04-05 CS CS792337A patent/CS208496B2/cs unknown
- 1979-04-05 SU SU792749004A patent/SU1220560A3/ru active
- 1979-04-05 DD DD79216616A patent/DD147112A5/de unknown
- 1979-04-05 AR AR276078A patent/AR219587A1/es active
- 1979-04-05 DK DK140179A patent/DK147578C/da active
- 1979-04-05 IL IL57017A patent/IL57017A/xx unknown
- 1979-04-05 RO RO97135A patent/RO77976B/ro unknown
- 1979-04-05 JP JP4190579A patent/JPS54135725A/ja active Pending
- 1979-04-05 ZA ZA791631A patent/ZA791631B/xx unknown
- 1979-04-05 PL PL1979214707A patent/PL114130B1/pl unknown
- 1979-04-05 BG BG7943137A patent/BG29270A3/xx unknown
- 1979-04-05 PH PH22353A patent/PH14617A/en unknown
- 1979-04-05 BR BR7902086A patent/BR7902086A/pt unknown
- 1979-04-05 DD DD79212039A patent/DD143554A5/de unknown
- 1979-04-05 RO RO107609A patent/RO84500B/ro unknown
- 1979-04-05 CA CA000324992A patent/CA1134383A/en not_active Expired
- 1979-04-05 IT IT7921624A patent/IT1112954B/it active
- 1979-04-05 AU AU45850/79A patent/AU518313B2/en not_active Ceased
- 1979-04-05 HU HU79MO1041A patent/HU185005B/hu unknown
- 1979-04-06 YU YU826/79A patent/YU41153B/xx unknown
Also Published As
| Publication number | Publication date |
|---|---|
| HU185005B (en) | 1984-11-28 |
| AR219587A1 (es) | 1980-08-29 |
| BR7902086A (pt) | 1979-11-27 |
| SU1220560A3 (ru) | 1986-03-23 |
| PH14617A (en) | 1981-10-12 |
| EP0005321A1 (en) | 1979-11-14 |
| PL214707A1 (pl) | 1979-12-17 |
| DE2962495D1 (en) | 1982-05-27 |
| CS208496B2 (en) | 1981-09-15 |
| IL57017A0 (en) | 1979-07-25 |
| EP0005321B1 (en) | 1982-04-14 |
| RO77976A (ro) | 1984-01-14 |
| DD147112A5 (de) | 1981-03-18 |
| IL57017A (en) | 1982-12-31 |
| AU518313B2 (en) | 1981-09-24 |
| PL114130B1 (en) | 1981-01-31 |
| CA1134383A (en) | 1982-10-26 |
| RO84500A (ro) | 1984-09-29 |
| ES479305A1 (es) | 1980-01-01 |
| JPS54135725A (en) | 1979-10-22 |
| DK147578B (da) | 1984-10-08 |
| YU41153B (en) | 1986-12-31 |
| IT1112954B (it) | 1986-01-20 |
| DD143554A5 (de) | 1980-09-03 |
| IT7921624A0 (it) | 1979-04-05 |
| ZA791631B (en) | 1980-04-30 |
| AU4585079A (en) | 1979-10-11 |
| BG29270A3 (en) | 1980-10-15 |
| DK140179A (da) | 1979-10-07 |
| RO77976B (ro) | 1985-01-30 |
| YU82679A (en) | 1983-12-31 |
| DK147578C (da) | 1985-03-18 |
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