PL79289B1 - - Google Patents
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- Publication number
- PL79289B1 PL79289B1 PL1968125584A PL12558468A PL79289B1 PL 79289 B1 PL79289 B1 PL 79289B1 PL 1968125584 A PL1968125584 A PL 1968125584A PL 12558468 A PL12558468 A PL 12558468A PL 79289 B1 PL79289 B1 PL 79289B1
- Authority
- PL
- Poland
- Prior art keywords
- glucose
- fructose
- crystallization
- solution
- sugar
- Prior art date
Links
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 111
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 claims description 98
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 claims description 97
- 239000008103 glucose Substances 0.000 claims description 97
- 239000005715 Fructose Substances 0.000 claims description 94
- 229930091371 Fructose Natural products 0.000 claims description 93
- RFSUNEUAIZKAJO-ARQDHWQXSA-N Fructose Chemical compound OC[C@H]1O[C@](O)(CO)[C@@H](O)[C@@H]1O RFSUNEUAIZKAJO-ARQDHWQXSA-N 0.000 claims description 92
- 238000002425 crystallisation Methods 0.000 claims description 69
- 230000008025 crystallization Effects 0.000 claims description 69
- 239000000243 solution Substances 0.000 claims description 60
- 238000000034 method Methods 0.000 claims description 46
- 239000000203 mixture Substances 0.000 claims description 43
- 239000013078 crystal Substances 0.000 claims description 38
- 235000000346 sugar Nutrition 0.000 claims description 35
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 33
- 239000012452 mother liquor Substances 0.000 claims description 32
- 229960004903 invert sugar Drugs 0.000 claims description 31
- 229930006000 Sucrose Natural products 0.000 claims description 19
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 claims description 19
- 230000007062 hydrolysis Effects 0.000 claims description 19
- 238000006460 hydrolysis reaction Methods 0.000 claims description 19
- 239000005720 sucrose Substances 0.000 claims description 19
- 239000002253 acid Substances 0.000 claims description 13
- XNWFRZJHXBZDAG-UHFFFAOYSA-N 2-METHOXYETHANOL Chemical compound COCCO XNWFRZJHXBZDAG-UHFFFAOYSA-N 0.000 claims description 8
- 239000007864 aqueous solution Substances 0.000 claims description 7
- 238000000926 separation method Methods 0.000 claims description 7
- 150000007513 acids Chemical class 0.000 claims description 6
- 102000004190 Enzymes Human genes 0.000 claims description 5
- 108090000790 Enzymes Proteins 0.000 claims description 5
- 238000004519 manufacturing process Methods 0.000 claims description 5
- 239000003960 organic solvent Substances 0.000 claims description 5
- 239000002904 solvent Substances 0.000 claims description 5
- 150000008163 sugars Chemical class 0.000 claims description 5
- 235000021309 simple sugar Nutrition 0.000 claims description 4
- 230000002378 acidificating effect Effects 0.000 claims description 3
- 238000006386 neutralization reaction Methods 0.000 claims description 3
- 229960001031 glucose Drugs 0.000 description 92
- 239000000047 product Substances 0.000 description 20
- 238000011081 inoculation Methods 0.000 description 8
- 238000003756 stirring Methods 0.000 description 8
- 238000005406 washing Methods 0.000 description 8
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 7
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 6
- 238000002360 preparation method Methods 0.000 description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 5
- 230000018044 dehydration Effects 0.000 description 5
- 238000006297 dehydration reaction Methods 0.000 description 5
- 238000004821 distillation Methods 0.000 description 5
- 238000013019 agitation Methods 0.000 description 4
- 239000006227 byproduct Substances 0.000 description 4
- 150000001768 cations Chemical class 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 4
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- 229920002125 Sokalan® Polymers 0.000 description 3
- 238000009835 boiling Methods 0.000 description 3
- -1 fructose compound Chemical class 0.000 description 3
- 239000011521 glass Substances 0.000 description 3
- 229910000041 hydrogen chloride Inorganic materials 0.000 description 3
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 description 3
- 150000002772 monosaccharides Chemical class 0.000 description 3
- 229910000029 sodium carbonate Inorganic materials 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- AEMRFAOFKBGASW-UHFFFAOYSA-N Glycolic acid Chemical compound OCC(O)=O AEMRFAOFKBGASW-UHFFFAOYSA-N 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- 150000001450 anions Chemical class 0.000 description 2
- 238000005119 centrifugation Methods 0.000 description 2
- 238000009833 condensation Methods 0.000 description 2
- 230000005494 condensation Effects 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- 239000002244 precipitate Substances 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 239000006188 syrup Substances 0.000 description 2
- 235000020357 syrup Nutrition 0.000 description 2
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 1
- 241000272814 Anser sp. Species 0.000 description 1
- WKBOTKDWSSQWDR-AHCXROLUSA-N Bromine-79 Chemical compound [76Br] WKBOTKDWSSQWDR-AHCXROLUSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 238000006887 Ullmann reaction Methods 0.000 description 1
- 230000001476 alcoholic effect Effects 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 1
- LKDRXBCSQODPBY-ZXXMMSQZSA-N alpha-D-fructopyranose Chemical compound OC[C@]1(O)OC[C@@H](O)[C@@H](O)[C@@H]1O LKDRXBCSQODPBY-ZXXMMSQZSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 159000000007 calcium salts Chemical class 0.000 description 1
- 238000004587 chromatography analysis Methods 0.000 description 1
- 238000004440 column chromatography Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000011549 crystallization solution Substances 0.000 description 1
- 230000029087 digestion Effects 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 150000002016 disaccharides Chemical class 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 230000003301 hydrolyzing effect Effects 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 229910052740 iodine Inorganic materials 0.000 description 1
- 239000011630 iodine Substances 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 238000013048 microbiological method Methods 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 230000001473 noxious effect Effects 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 238000001953 recrystallisation Methods 0.000 description 1
- 239000012088 reference solution Substances 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C13—SUGAR INDUSTRY
- C13K—SACCHARIDES OBTAINED FROM NATURAL SOURCES OR BY HYDROLYSIS OF NATURALLY OCCURRING DISACCHARIDES, OLIGOSACCHARIDES OR POLYSACCHARIDES
- C13K3/00—Invert sugar; Separation of glucose or fructose from invert sugar
Landscapes
- Chemical & Material Sciences (AREA)
- Analytical Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- Organic Chemistry (AREA)
- Saccharide Compounds (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| AT251267A AT271344B (de) | 1967-03-15 | 1967-03-15 | Verfahren zur Herstellung von Fructose und Glucose aus Saccharose |
| AT95068A AT278676B (de) | 1968-01-31 | 1968-01-31 | Verfahren zur Herstellung von Fructose und Glucose aus Saccharose |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| PL79289B1 true PL79289B1 (en:Method) | 1975-06-30 |
Family
ID=25594413
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PL1968125584A PL79289B1 (en:Method) | 1967-03-15 | 1968-03-02 |
Country Status (12)
| Country | Link |
|---|---|
| BE (1) | BE712041A (en:Method) |
| CH (1) | CH505202A (en:Method) |
| CS (1) | CS153456B2 (en:Method) |
| DE (1) | DE1642535C3 (en:Method) |
| ES (1) | ES351106A1 (en:Method) |
| FR (1) | FR1563168A (en:Method) |
| GB (1) | GB1204243A (en:Method) |
| IT (1) | IT1030506B (en:Method) |
| NL (1) | NL6803072A (en:Method) |
| OA (1) | OA02770A (en:Method) |
| PL (1) | PL79289B1 (en:Method) |
| SE (1) | SE336991B (en:Method) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5135442A (en) * | 1974-09-17 | 1976-03-25 | Kazuo Hara | Budoototokatotoo ganjusurufunmatsukotaikongobutsu no shorihoho |
| DE2520173C3 (de) * | 1975-05-06 | 1989-08-10 | Südzucker AG Mannheim/Ochsenfurt, 6800 Mannheim | Verfahren zur Herstellung von Glucopyranosido-1,6-mannit sowie seine Verwendung als Zuckeraustauschstoff |
| RU2347818C1 (ru) * | 2007-10-16 | 2009-02-27 | Валерий Петрович Данильчук | Способ получения фруктозосодержащего сиропа |
| CN109219591A (zh) | 2016-04-13 | 2019-01-15 | 阿科玛法国公司 | 制造2,3,3,3-四氟丙烯的方法 |
| FR3055014B1 (fr) | 2016-08-10 | 2020-03-13 | Arkema France | Composition azeotrope ou quasi-azeotrope comprenant 1,1,1,2,2-pentafluoropropane et trans-1,3,3,3-tetrafluoropropene |
-
1968
- 1968-02-09 DE DE1642535A patent/DE1642535C3/de not_active Expired
- 1968-02-13 CH CH213068A patent/CH505202A/de not_active IP Right Cessation
- 1968-02-29 FR FR1563168D patent/FR1563168A/fr not_active Expired
- 1968-03-01 ES ES351106A patent/ES351106A1/es not_active Expired
- 1968-03-02 PL PL1968125584A patent/PL79289B1/pl unknown
- 1968-03-04 IT IT13498/68A patent/IT1030506B/it active
- 1968-03-05 NL NL6803072A patent/NL6803072A/xx unknown
- 1968-03-12 BE BE712041D patent/BE712041A/xx unknown
- 1968-03-13 CS CS196668A patent/CS153456B2/cs unknown
- 1968-03-13 GB GB02174/68A patent/GB1204243A/en not_active Expired
- 1968-03-14 SE SE03358/68A patent/SE336991B/xx unknown
- 1968-03-15 OA OA53217A patent/OA02770A/xx unknown
Also Published As
| Publication number | Publication date |
|---|---|
| FR1563168A (en:Method) | 1969-04-11 |
| CS153456B2 (en:Method) | 1974-02-25 |
| GB1204243A (en) | 1970-09-03 |
| IT1030506B (it) | 1979-04-10 |
| NL6803072A (en:Method) | 1968-09-16 |
| BE712041A (en:Method) | 1968-09-12 |
| DE1642535B2 (de) | 1973-07-26 |
| ES351106A1 (es) | 1969-05-16 |
| SE336991B (en:Method) | 1971-07-19 |
| CH505202A (de) | 1971-03-31 |
| OA02770A (fr) | 1970-12-15 |
| DE1642535A1 (de) | 1972-04-27 |
| DE1642535C3 (de) | 1974-03-07 |
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