PL112437B1 - Method of manufacturing a catalyst for carbon monoxide reduction - Google Patents
Method of manufacturing a catalyst for carbon monoxide reduction Download PDFInfo
- Publication number
- PL112437B1 PL112437B1 PL1977202449A PL20244977A PL112437B1 PL 112437 B1 PL112437 B1 PL 112437B1 PL 1977202449 A PL1977202449 A PL 1977202449A PL 20244977 A PL20244977 A PL 20244977A PL 112437 B1 PL112437 B1 PL 112437B1
- Authority
- PL
- Poland
- Prior art keywords
- catalyst
- volume
- iron
- copper
- carrier
- Prior art date
Links
- 239000003054 catalyst Substances 0.000 title claims description 36
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 title claims description 8
- 229910002091 carbon monoxide Inorganic materials 0.000 title claims description 7
- 238000004519 manufacturing process Methods 0.000 title description 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 32
- 239000000203 mixture Substances 0.000 claims description 22
- 238000000034 method Methods 0.000 claims description 16
- 239000001257 hydrogen Substances 0.000 claims description 13
- 229910052739 hydrogen Inorganic materials 0.000 claims description 13
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 12
- 229910052742 iron Inorganic materials 0.000 claims description 12
- 239000012876 carrier material Substances 0.000 claims description 11
- 239000010949 copper Substances 0.000 claims description 10
- 150000003839 salts Chemical class 0.000 claims description 10
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 8
- 229910052802 copper Inorganic materials 0.000 claims description 8
- 239000004480 active ingredient Substances 0.000 claims description 6
- 229910000323 aluminium silicate Inorganic materials 0.000 claims description 5
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical group O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 5
- 238000001035 drying Methods 0.000 claims description 5
- 238000005979 thermal decomposition reaction Methods 0.000 claims description 5
- 229930195733 hydrocarbon Natural products 0.000 claims description 4
- 150000002430 hydrocarbons Chemical class 0.000 claims description 4
- 238000002360 preparation method Methods 0.000 claims description 4
- JPVYNHNXODAKFH-UHFFFAOYSA-N Cu2+ Chemical compound [Cu+2] JPVYNHNXODAKFH-UHFFFAOYSA-N 0.000 claims description 3
- 125000004432 carbon atom Chemical group C* 0.000 claims description 3
- 229910001431 copper ion Inorganic materials 0.000 claims description 3
- 238000001125 extrusion Methods 0.000 claims description 3
- 238000002156 mixing Methods 0.000 claims description 3
- 238000001556 precipitation Methods 0.000 claims description 3
- 238000007669 thermal treatment Methods 0.000 claims description 3
- 239000000047 product Substances 0.000 description 11
- 239000007864 aqueous solution Substances 0.000 description 9
- 239000002244 precipitate Substances 0.000 description 9
- 239000000243 solution Substances 0.000 description 9
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- 150000001879 copper Chemical class 0.000 description 5
- 239000007789 gas Substances 0.000 description 5
- 239000000276 potassium ferrocyanide Substances 0.000 description 5
- XOGGUFAVLNCTRS-UHFFFAOYSA-N tetrapotassium;iron(2+);hexacyanide Chemical compound [K+].[K+].[K+].[K+].[Fe+2].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-] XOGGUFAVLNCTRS-UHFFFAOYSA-N 0.000 description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
- XFXPMWWXUTWYJX-UHFFFAOYSA-N Cyanide Chemical compound N#[C-] XFXPMWWXUTWYJX-UHFFFAOYSA-N 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- 239000012065 filter cake Substances 0.000 description 4
- 239000012452 mother liquor Substances 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 238000005984 hydrogenation reaction Methods 0.000 description 3
- 239000002912 waste gas Substances 0.000 description 3
- 239000005909 Kieselgur Substances 0.000 description 2
- 229910004298 SiO 2 Inorganic materials 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- QKDIMNPUZPNYGB-UHFFFAOYSA-N [Cu](C#N)C#N.[Fe] Chemical class [Cu](C#N)C#N.[Fe] QKDIMNPUZPNYGB-UHFFFAOYSA-N 0.000 description 2
- -1 alkali metal iron cyanide Chemical class 0.000 description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
- 229910021529 ammonia Inorganic materials 0.000 description 2
- 239000010425 asbestos Substances 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 239000003365 glass fiber Substances 0.000 description 2
- 159000000014 iron salts Chemical class 0.000 description 2
- PANJMBIFGCKWBY-UHFFFAOYSA-N iron tricyanide Chemical compound N#C[Fe](C#N)C#N PANJMBIFGCKWBY-UHFFFAOYSA-N 0.000 description 2
- 150000002825 nitriles Chemical class 0.000 description 2
- 210000002741 palatine tonsil Anatomy 0.000 description 2
- 230000001376 precipitating effect Effects 0.000 description 2
- 239000008262 pumice Substances 0.000 description 2
- 229910052895 riebeckite Inorganic materials 0.000 description 2
- 229920006395 saturated elastomer Polymers 0.000 description 2
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 2
- 235000012239 silicon dioxide Nutrition 0.000 description 2
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 241000640882 Condea Species 0.000 description 1
- NAVJNPDLSKEXSP-UHFFFAOYSA-N Fe(CN)2 Chemical class N#C[Fe]C#N NAVJNPDLSKEXSP-UHFFFAOYSA-N 0.000 description 1
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- BVYFGGZPLVYOQU-UHFFFAOYSA-N [K].N#C[Fe]C#N Chemical compound [K].N#C[Fe]C#N BVYFGGZPLVYOQU-UHFFFAOYSA-N 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 239000007900 aqueous suspension Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000012018 catalyst precursor Substances 0.000 description 1
- 239000002734 clay mineral Substances 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- ORTQZVOHEJQUHG-UHFFFAOYSA-L copper(II) chloride Chemical compound Cl[Cu]Cl ORTQZVOHEJQUHG-UHFFFAOYSA-L 0.000 description 1
- DOBRDRYODQBAMW-UHFFFAOYSA-N copper(i) cyanide Chemical compound [Cu+].N#[C-] DOBRDRYODQBAMW-UHFFFAOYSA-N 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 239000003546 flue gas Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 150000002505 iron Chemical class 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- NNFCIKHAZHQZJG-UHFFFAOYSA-N potassium cyanide Chemical compound [K+].N#[C-] NNFCIKHAZHQZJG-UHFFFAOYSA-N 0.000 description 1
- 230000000750 progressive effect Effects 0.000 description 1
- 238000009738 saturating Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000009489 vacuum treatment Methods 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/74—Iron group metals
- B01J23/745—Iron
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
- C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
- C07C1/04—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen
- C07C1/0425—Catalysts; their physical properties
- C07C1/0445—Preparation; Activation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
- C07C2521/12—Silica and alumina
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
- C07C2523/72—Copper
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
- C07C2523/74—Iron group metals
- C07C2523/745—Iron
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Catalysts (AREA)
- Carbon And Carbon Compounds (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE2653986A DE2653986C2 (de) | 1976-11-27 | 1976-11-27 | Katalysator zur Reduktion von Kohlenmonoxid |
| DE2704575A DE2704575C2 (de) | 1977-02-04 | 1977-02-04 | Katalysator zur Reduktion von Kohlenmonoxid |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| PL202449A1 PL202449A1 (pl) | 1978-09-25 |
| PL112437B1 true PL112437B1 (en) | 1980-10-31 |
Family
ID=25771193
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PL1977202449A PL112437B1 (en) | 1976-11-27 | 1977-11-26 | Method of manufacturing a catalyst for carbon monoxide reduction |
Country Status (6)
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4349462A (en) * | 1980-12-24 | 1982-09-14 | Sohio | Catalytic material |
| US4663355A (en) * | 1984-06-27 | 1987-05-05 | Union Carbide Corporation | Catalyst and process for converting synthesis gas to liquid motor fuels |
| US4617283A (en) * | 1984-06-27 | 1986-10-14 | Union Carbide Corporation | Catalyst for converting synthesis gas to liquid motor fuels |
| US5198592A (en) * | 1987-12-11 | 1993-03-30 | Engelhard De Meern B.V. | Hydrogenolysis reaction and catalyst suitable therefor |
| GB9005964D0 (en) * | 1990-03-16 | 1990-05-09 | Shell Int Research | Catalyst preparation process |
| JP5610900B2 (ja) * | 2009-07-28 | 2014-10-22 | 新日鐵住金株式会社 | Ｆｔ合成用触媒の製造方法、及び当該触媒を用いた炭化水素の製造方法 |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2234246A (en) * | 1937-12-09 | 1941-03-11 | Celanese Corp | Metallic composition |
| US2767202A (en) * | 1952-01-30 | 1956-10-16 | Ruhrchemie Ag | Catalytic hydrogenation of carbon monoxides |
| US2753367A (en) * | 1952-07-09 | 1956-07-03 | Ruhrchemie Ag | Catalytic hydrogenation of carbon monoxide |
-
1977
- 1977-11-17 GB GB47906/77A patent/GB1548527A/en not_active Expired
- 1977-11-17 CA CA291,145A patent/CA1084894A/en not_active Expired
- 1977-11-23 US US05/854,147 patent/US4146503A/en not_active Expired - Lifetime
- 1977-11-25 FR FR7735591A patent/FR2371960A2/fr active Granted
- 1977-11-26 PL PL1977202449A patent/PL112437B1/pl unknown
- 1977-11-28 JP JP14257177A patent/JPS5368692A/ja active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| FR2371960A2 (fr) | 1978-06-23 |
| FR2371960B2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1983-06-03 |
| US4146503A (en) | 1979-03-27 |
| GB1548527A (en) | 1979-07-18 |
| JPS5368692A (en) | 1978-06-19 |
| CA1084894A (en) | 1980-09-02 |
| PL202449A1 (pl) | 1978-09-25 |
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