NZ212092A - Preparation of supported hydroconversion catalysts and catalysts thus prepared - Google Patents
Preparation of supported hydroconversion catalysts and catalysts thus preparedInfo
- Publication number
- NZ212092A NZ212092A NZ212092A NZ21209285A NZ212092A NZ 212092 A NZ212092 A NZ 212092A NZ 212092 A NZ212092 A NZ 212092A NZ 21209285 A NZ21209285 A NZ 21209285A NZ 212092 A NZ212092 A NZ 212092A
- Authority
- NZ
- New Zealand
- Prior art keywords
- support
- catalyst
- molybdenum
- solution
- nickel
- Prior art date
Links
- 239000003054 catalyst Substances 0.000 title claims description 89
- 238000002360 preparation method Methods 0.000 title claims description 3
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 45
- 229910052750 molybdenum Inorganic materials 0.000 claims description 30
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 28
- 238000000034 method Methods 0.000 claims description 28
- 239000011733 molybdenum Substances 0.000 claims description 27
- 150000001412 amines Chemical class 0.000 claims description 26
- 229910052751 metal Inorganic materials 0.000 claims description 25
- 239000002184 metal Substances 0.000 claims description 25
- 230000000694 effects Effects 0.000 claims description 20
- 238000005470 impregnation Methods 0.000 claims description 20
- 229910052759 nickel Inorganic materials 0.000 claims description 19
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 16
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 16
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 16
- 150000002739 metals Chemical class 0.000 claims description 16
- 229910052698 phosphorus Inorganic materials 0.000 claims description 16
- 239000011574 phosphorus Substances 0.000 claims description 15
- 229910052721 tungsten Inorganic materials 0.000 claims description 15
- 229910017052 cobalt Inorganic materials 0.000 claims description 14
- 239000010941 cobalt Substances 0.000 claims description 14
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 14
- 239000000203 mixture Substances 0.000 claims description 14
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 13
- -1 amine compound Chemical class 0.000 claims description 13
- DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Chemical compound NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 claims description 12
- 229910052739 hydrogen Inorganic materials 0.000 claims description 11
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims description 11
- 239000010937 tungsten Substances 0.000 claims description 11
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 claims description 9
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 9
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 8
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 8
- MGFYIUFZLHCRTH-UHFFFAOYSA-N nitrilotriacetic acid Chemical compound OC(=O)CN(CC(O)=O)CC(O)=O MGFYIUFZLHCRTH-UHFFFAOYSA-N 0.000 claims description 7
- 239000004471 Glycine Substances 0.000 claims description 6
- 238000011068 loading method Methods 0.000 claims description 6
- 239000003921 oil Substances 0.000 claims description 6
- 238000005984 hydrogenation reaction Methods 0.000 claims description 5
- 238000004519 manufacturing process Methods 0.000 claims description 5
- 238000002156 mixing Methods 0.000 claims description 5
- HXKKHQJGJAFBHI-UHFFFAOYSA-N 1-aminopropan-2-ol Chemical compound CC(O)CN HXKKHQJGJAFBHI-UHFFFAOYSA-N 0.000 claims description 4
- 239000002253 acid Substances 0.000 claims description 4
- 238000001354 calcination Methods 0.000 claims description 4
- 229920000768 polyamine Polymers 0.000 claims description 4
- 239000000377 silicon dioxide Substances 0.000 claims description 4
- 230000000087 stabilizing effect Effects 0.000 claims description 4
- 238000012360 testing method Methods 0.000 claims description 4
- 238000009827 uniform distribution Methods 0.000 claims description 4
- WUGQZFFCHPXWKQ-UHFFFAOYSA-N Propanolamine Chemical compound NCCCO WUGQZFFCHPXWKQ-UHFFFAOYSA-N 0.000 claims description 3
- 238000001035 drying Methods 0.000 claims description 3
- 239000000654 additive Substances 0.000 claims description 2
- 230000000996 additive effect Effects 0.000 claims description 2
- 239000002131 composite material Substances 0.000 claims description 2
- 150000001875 compounds Chemical class 0.000 claims description 2
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 2
- 239000000295 fuel oil Substances 0.000 claims description 2
- 239000008188 pellet Substances 0.000 claims description 2
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 claims 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims 1
- 229910021536 Zeolite Inorganic materials 0.000 claims 1
- 239000000428 dust Substances 0.000 claims 1
- 229910000476 molybdenum oxide Inorganic materials 0.000 claims 1
- PQQKPALAQIIWST-UHFFFAOYSA-N oxomolybdenum Chemical compound [Mo]=O PQQKPALAQIIWST-UHFFFAOYSA-N 0.000 claims 1
- 239000010457 zeolite Substances 0.000 claims 1
- 239000000243 solution Substances 0.000 description 59
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 10
- 239000001257 hydrogen Substances 0.000 description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 9
- JKQOBWVOAYFWKG-UHFFFAOYSA-N molybdenum trioxide Inorganic materials O=[Mo](=O)=O JKQOBWVOAYFWKG-UHFFFAOYSA-N 0.000 description 5
- 239000012153 distilled water Substances 0.000 description 4
- 239000007789 gas Substances 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- 238000003756 stirring Methods 0.000 description 4
- 229910000008 nickel(II) carbonate Inorganic materials 0.000 description 3
- ZULUUIKRFGGGTL-UHFFFAOYSA-L nickel(ii) carbonate Chemical compound [Ni+2].[O-]C([O-])=O ZULUUIKRFGGGTL-UHFFFAOYSA-L 0.000 description 3
- 239000011148 porous material Substances 0.000 description 3
- 239000002002 slurry Substances 0.000 description 3
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 2
- 238000013019 agitation Methods 0.000 description 2
- 239000000908 ammonium hydroxide Substances 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 238000004517 catalytic hydrocracking Methods 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- 150000002815 nickel Chemical class 0.000 description 2
- AOPCKOPZYFFEDA-UHFFFAOYSA-N nickel(2+);dinitrate;hexahydrate Chemical compound O.O.O.O.O.O.[Ni+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O AOPCKOPZYFFEDA-UHFFFAOYSA-N 0.000 description 2
- KBJMLQFLOWQJNF-UHFFFAOYSA-N nickel(ii) nitrate Chemical compound [Ni+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O KBJMLQFLOWQJNF-UHFFFAOYSA-N 0.000 description 2
- 238000001556 precipitation Methods 0.000 description 2
- YGEXTFPNVFGFFB-UHFFFAOYSA-N 2,2,3-triaminopropan-1-ol Chemical compound NCC(N)(N)CO YGEXTFPNVFGFFB-UHFFFAOYSA-N 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 1
- 229910003296 Ni-Mo Inorganic materials 0.000 description 1
- 229910021586 Nickel(II) chloride Inorganic materials 0.000 description 1
- HSNVNALJRSJDHT-UHFFFAOYSA-N P(=O)(=O)[Mo] Chemical compound P(=O)(=O)[Mo] HSNVNALJRSJDHT-UHFFFAOYSA-N 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- MQRWBMAEBQOWAF-UHFFFAOYSA-N acetic acid;nickel Chemical compound [Ni].CC(O)=O.CC(O)=O MQRWBMAEBQOWAF-UHFFFAOYSA-N 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 125000003158 alcohol group Chemical group 0.000 description 1
- 229910000323 aluminium silicate Inorganic materials 0.000 description 1
- QGAVSDVURUSLQK-UHFFFAOYSA-N ammonium heptamolybdate Chemical compound N.N.N.N.N.N.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.[Mo].[Mo].[Mo].[Mo].[Mo].[Mo].[Mo] QGAVSDVURUSLQK-UHFFFAOYSA-N 0.000 description 1
- 238000004523 catalytic cracking Methods 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 125000003916 ethylene diamine group Chemical group 0.000 description 1
- 229910052733 gallium Inorganic materials 0.000 description 1
- 239000008246 gaseous mixture Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- MEFBJEMVZONFCJ-UHFFFAOYSA-N molybdate Chemical compound [O-][Mo]([O-])(=O)=O MEFBJEMVZONFCJ-UHFFFAOYSA-N 0.000 description 1
- DDTIGTPWGISMKL-UHFFFAOYSA-N molybdenum nickel Chemical compound [Ni].[Mo] DDTIGTPWGISMKL-UHFFFAOYSA-N 0.000 description 1
- 229940078494 nickel acetate Drugs 0.000 description 1
- QMMRZOWCJAIUJA-UHFFFAOYSA-L nickel dichloride Chemical compound Cl[Ni]Cl QMMRZOWCJAIUJA-UHFFFAOYSA-L 0.000 description 1
- 229910000480 nickel oxide Inorganic materials 0.000 description 1
- 229910000159 nickel phosphate Inorganic materials 0.000 description 1
- LGQLOGILCSXPEA-UHFFFAOYSA-L nickel sulfate Chemical compound [Ni+2].[O-]S([O-])(=O)=O LGQLOGILCSXPEA-UHFFFAOYSA-L 0.000 description 1
- HZPNKQREYVVATQ-UHFFFAOYSA-L nickel(2+);diformate Chemical compound [Ni+2].[O-]C=O.[O-]C=O HZPNKQREYVVATQ-UHFFFAOYSA-L 0.000 description 1
- JOCJYBPHESYFOK-UHFFFAOYSA-K nickel(3+);phosphate Chemical compound [Ni+3].[O-]P([O-])([O-])=O JOCJYBPHESYFOK-UHFFFAOYSA-K 0.000 description 1
- BFDHFSHZJLFAMC-UHFFFAOYSA-L nickel(ii) hydroxide Chemical compound [OH-].[OH-].[Ni+2] BFDHFSHZJLFAMC-UHFFFAOYSA-L 0.000 description 1
- GNRSAWUEBMWBQH-UHFFFAOYSA-N oxonickel Chemical compound [Ni]=O GNRSAWUEBMWBQH-UHFFFAOYSA-N 0.000 description 1
- 125000002467 phosphate group Chemical group [H]OP(=O)(O[H])O[*] 0.000 description 1
- 150000003018 phosphorus compounds Chemical class 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0201—Impregnation
- B01J37/0203—Impregnation the impregnation liquid containing organic compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/14—Phosphorus; Compounds thereof
- B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J27/188—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum, tungsten or polonium
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
- C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
- C10G45/04—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used
- C10G45/06—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof
- C10G45/08—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof in combination with chromium, molybdenum, or tungsten metals, or compounds thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
- B01J23/88—Molybdenum
- B01J23/883—Molybdenum and nickel
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- General Chemical & Material Sciences (AREA)
- Catalysts (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US06/611,574 US4530911A (en) | 1984-05-18 | 1984-05-18 | Hydrodenitrification catalyst |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| NZ212092A true NZ212092A (en) | 1987-10-30 |
Family
ID=24449561
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| NZ212092A NZ212092A (en) | 1984-05-18 | 1985-05-15 | Preparation of supported hydroconversion catalysts and catalysts thus prepared |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US4530911A (enExample) |
| EP (1) | EP0164162B1 (enExample) |
| JP (1) | JPS60255143A (enExample) |
| AU (1) | AU567475B2 (enExample) |
| CA (1) | CA1240978A (enExample) |
| DE (1) | DE3574568D1 (enExample) |
| NZ (1) | NZ212092A (enExample) |
| ZA (1) | ZA853675B (enExample) |
Families Citing this family (40)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4663023A (en) * | 1984-04-02 | 1987-05-05 | Exxon Research And Engineering Company | Hydrotreating with self-promoted molybdenum and tungsten sulfide catalyst |
| CA1261815A (en) * | 1984-11-05 | 1989-09-26 | Mark S. Thompson | Preparation of high activity silica-supported hydrotreating catalysts and catalysts thus prepared |
| FR2596407B1 (fr) * | 1986-03-28 | 1988-06-17 | Rhone Poulenc Chimie | Compositions aqueuses stabilisees de polymeres hydrosolubles |
| JPS62199687A (ja) * | 1986-04-28 | 1987-09-03 | ユニオン・オイル・コンパニ−・オブ・カリフオルニア | 細孔の大きい触媒を用いる水素化法 |
| US4738944A (en) * | 1986-12-05 | 1988-04-19 | Union Oil Company Of California | Ni-P-Mo catalyst and hydroprocessing use thereof |
| US5068025A (en) * | 1990-06-27 | 1991-11-26 | Shell Oil Company | Aromatics saturation process for diesel boiling-range hydrocarbons |
| ATE137686T1 (de) * | 1990-08-03 | 1996-05-15 | Akzo Nobel Nv | Verfahren zur hydrierende entschwefelung |
| US5116484A (en) * | 1990-10-31 | 1992-05-26 | Shell Oil Company | Hydrodenitrification process |
| US5507940A (en) * | 1991-08-30 | 1996-04-16 | Shell Oil Company | Hydrodenitrification catalyst and process |
| US5565091A (en) * | 1993-02-15 | 1996-10-15 | Idemitsu Kosan Co., Ltd. | Catalyst composition manufacturing method and sulfur-containing hydrocarbon hydrodesulfurization method using the same catalyst composition |
| US6093309A (en) * | 1993-05-04 | 2000-07-25 | Cri International, Inc. | Method of treating spontaneously combustible catalysts |
| ZA942966B (en) * | 1993-05-04 | 1995-01-19 | Cri Int Inc | A method of treating spontaneously combustible catalysts. |
| US6015485A (en) * | 1994-05-13 | 2000-01-18 | Cytec Technology Corporation | High activity catalysts having a bimodal mesopore structure |
| US5786293A (en) * | 1996-06-17 | 1998-07-28 | Shell Oil Company | Process for presulfiding hydrocarbon processing catalysts |
| US5821191A (en) * | 1996-06-17 | 1998-10-13 | Shell Oil Company | Process for presulfiding hydrocarbon processing catalysts |
| EP1043069B1 (en) | 1999-04-08 | 2005-05-25 | Albemarle Netherlands B.V. | Process for sulphiding a hydrotreating catalyst comprising an organic compound comprising N and carbonyl |
| US6508999B1 (en) | 2000-11-21 | 2003-01-21 | Shell Oil Company | Aluminum trihydroxide phase |
| US6589908B1 (en) | 2000-11-28 | 2003-07-08 | Shell Oil Company | Method of making alumina having bimodal pore structure, and catalysts made therefrom |
| FR2841798B1 (fr) * | 2002-07-03 | 2005-03-04 | Inst Francais Du Petrole | Catalyseur d'hydrotraitement contenant un compose organique azote et son utilisation |
| CN100448952C (zh) | 2005-04-29 | 2009-01-07 | 中国石油化工股份有限公司 | 一种含沸石的加氢裂化催化剂组合物 |
| US8883669B2 (en) * | 2005-04-29 | 2014-11-11 | China Petroleum & Chemical Corporation | Hydrocracking catalyst, a process for producing the same, and the use of the same |
| CN100425676C (zh) * | 2005-04-29 | 2008-10-15 | 中国石油化工股份有限公司 | 一种加氢裂化催化剂组合物 |
| US7605107B2 (en) * | 2005-09-29 | 2009-10-20 | Exxonmobil Research And Engineering Company | Method of preparing a supported hydrotreating catalyst |
| US7538066B2 (en) * | 2005-09-29 | 2009-05-26 | Exxonmobil Research And Engineering Company | Method of preparing a hydrotreating catalyst on a support containing a rare earth metal |
| RU2311959C1 (ru) * | 2006-10-13 | 2007-12-10 | Институт Катализа Им. Г.К. Борескова Сибирского Отделения Российской Академии Наук | Катализатор, способ получения носителя, способ получения катализатора и процесс гидрообессеривания дизельных фракций |
| SG178430A1 (en) | 2009-08-24 | 2012-04-27 | Albemarle Europe Sprl | Solutions and catalysts comprising group vi metal, group viii metal, phosphorous and an additive |
| CN102166521B (zh) * | 2010-02-25 | 2013-03-27 | 中国石油天然气股份有限公司 | 一种加氢精制催化剂制备方法 |
| CZ302215B6 (cs) * | 2010-05-14 | 2010-12-22 | Výzkumný@ústav@anorganické@chemie@@a@@s | Zpusob@výroby@aluminosilikátového@hydrokrakovacího@katalyzátoru |
| CN102397790A (zh) * | 2010-09-09 | 2012-04-04 | 中国石油化工股份有限公司 | 一种重油加氢处理催化剂、制备及其应用 |
| CN103007949B (zh) * | 2011-09-27 | 2015-02-04 | 中国石油天然气集团公司 | 一种加氢催化剂的制备方法 |
| CN104324723B (zh) * | 2013-07-22 | 2016-06-29 | 中国石油化工股份有限公司 | 一种加氢保护催化剂及其制备方法与应用 |
| EP3685917A1 (en) * | 2013-09-06 | 2020-07-29 | Reliance Industries Limited | A catalyst composition and a catalytic process for conversion of biomass to crude bio oil |
| US10077406B2 (en) * | 2013-10-17 | 2018-09-18 | Shell Oil Company | Catalyst for the hydrotreatment of a heavy hydrocarbon feedstock |
| CN103752324B (zh) * | 2014-01-27 | 2016-07-06 | 辽宁大学 | 一种汽、柴油加氢精制负载型催化剂及其制备方法和应用 |
| CZ305662B6 (cs) * | 2014-06-30 | 2016-01-27 | Unipetrol Výzkumně Vzdělávací Centrum, A. S. | Způsob výroby molybdenového katalyzátoru s dalším aktivním kovem |
| CN105778979B (zh) * | 2014-12-22 | 2017-11-07 | 中国石油天然气股份有限公司 | 一种降低催化裂化汽油硫含量的催化剂及其制备方法 |
| CN104492502B (zh) * | 2014-12-25 | 2016-09-14 | 江西科帕克环保化工有限责任公司 | 加氢保护剂及其制备方法 |
| CN106582734A (zh) * | 2015-10-15 | 2017-04-26 | 中国石油化工股份有限公司 | 轻循环油加氢脱氮催化剂及其制备方法 |
| CN112742405B (zh) * | 2019-10-29 | 2023-05-05 | 中国石油化工股份有限公司 | 一种催化剂浸渍液及加氢处理催化剂的制备方法 |
| BR102019028121B1 (pt) * | 2019-12-27 | 2021-12-14 | Petróleo Brasileiro S.A. - Petrobras | Método de obtenção de um suporte para catalisadores de hidrorrefino, processo de obtenção de catalisadores de hidrorrefino, catalisadores de hidrorrefino e uso do suporte |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL68368C (enExample) * | 1949-03-31 | |||
| US2946739A (en) * | 1958-11-13 | 1960-07-26 | Phillips Petroleum Co | Hydrocracking catalyst and process |
| US3156641A (en) * | 1960-06-15 | 1964-11-10 | Standard Oil Co | Hydrocracking of hydrocarbons with the use of a catalyst comprising nickel metal and a heteropoly acid on alumina |
| US3629146A (en) * | 1969-03-24 | 1971-12-21 | Shell Oil Co | Catalyst impregnation method |
| GB1357918A (en) * | 1971-06-30 | 1974-06-26 | Union Oil Co | Hydrogenative hydrocarbon conversion catalysts therefore and methods of preparation |
| NL7315573A (nl) * | 1973-11-14 | 1975-05-16 | Shell Int Research | Katalysatorbereiding. |
| US4018706A (en) * | 1975-07-21 | 1977-04-19 | Nippon Shokubai Kagaku Kogyo Co., Ltd. | Catalysts for purifying exhaust and waste gases |
| US4407726A (en) * | 1981-05-28 | 1983-10-04 | The Halcon Sd Group, Inc. | Preparation of carboxylic acids |
| US4444906A (en) * | 1981-06-08 | 1984-04-24 | The Standard Oil Company | Method for the preparation of high activity phosphomolybdic acid based catalysts |
| US4446248A (en) * | 1982-08-16 | 1984-05-01 | Union Oil Company Of California | Hydrotreating catalyst |
-
1984
- 1984-05-18 US US06/611,574 patent/US4530911A/en not_active Expired - Lifetime
-
1985
- 1985-04-24 CA CA000479892A patent/CA1240978A/en not_active Expired
- 1985-05-14 DE DE8585200766T patent/DE3574568D1/de not_active Expired - Lifetime
- 1985-05-14 EP EP85200766A patent/EP0164162B1/en not_active Expired
- 1985-05-15 ZA ZA853675A patent/ZA853675B/xx unknown
- 1985-05-15 AU AU42484/85A patent/AU567475B2/en not_active Ceased
- 1985-05-15 NZ NZ212092A patent/NZ212092A/en unknown
- 1985-05-15 JP JP60101710A patent/JPS60255143A/ja active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| DE3574568D1 (de) | 1990-01-11 |
| JPH0582260B2 (enExample) | 1993-11-18 |
| EP0164162A1 (en) | 1985-12-11 |
| US4530911A (en) | 1985-07-23 |
| EP0164162B1 (en) | 1989-12-06 |
| ZA853675B (en) | 1985-12-24 |
| JPS60255143A (ja) | 1985-12-16 |
| CA1240978A (en) | 1988-08-23 |
| AU4248485A (en) | 1985-11-21 |
| AU567475B2 (en) | 1987-11-19 |
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