NO794183L - Fremgangsmaate til fremstilling av fosforsyre og fosforpentafluorid - Google Patents
Fremgangsmaate til fremstilling av fosforsyre og fosforpentafluoridInfo
- Publication number
- NO794183L NO794183L NO794183A NO794183A NO794183L NO 794183 L NO794183 L NO 794183L NO 794183 A NO794183 A NO 794183A NO 794183 A NO794183 A NO 794183A NO 794183 L NO794183 L NO 794183L
- Authority
- NO
- Norway
- Prior art keywords
- accordance
- acid
- phosphorus
- fluorosulfonic acid
- hydrogen fluoride
- Prior art date
Links
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 title claims description 89
- 238000000034 method Methods 0.000 title claims description 74
- 229910000147 aluminium phosphate Inorganic materials 0.000 title claims description 39
- OBCUTHMOOONNBS-UHFFFAOYSA-N phosphorus pentafluoride Chemical compound FP(F)(F)(F)F OBCUTHMOOONNBS-UHFFFAOYSA-N 0.000 title claims description 37
- UQSQSQZYBQSBJZ-UHFFFAOYSA-N fluorosulfonic acid Chemical compound OS(F)(=O)=O UQSQSQZYBQSBJZ-UHFFFAOYSA-N 0.000 claims description 79
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 claims description 45
- 235000011007 phosphoric acid Nutrition 0.000 claims description 45
- 229910000040 hydrogen fluoride Inorganic materials 0.000 claims description 39
- 238000006243 chemical reaction Methods 0.000 claims description 36
- AKEJUJNQAAGONA-UHFFFAOYSA-N sulfur trioxide Chemical compound O=S(=O)=O AKEJUJNQAAGONA-UHFFFAOYSA-N 0.000 claims description 36
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 36
- 238000006460 hydrolysis reaction Methods 0.000 claims description 32
- 230000007062 hydrolysis Effects 0.000 claims description 31
- 229910052698 phosphorus Inorganic materials 0.000 claims description 31
- 239000011574 phosphorus Substances 0.000 claims description 31
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 30
- 238000004519 manufacturing process Methods 0.000 claims description 27
- 239000000463 material Substances 0.000 claims description 27
- 150000003018 phosphorus compounds Chemical class 0.000 claims description 24
- FFUQCRZBKUBHQT-UHFFFAOYSA-N phosphoryl fluoride Chemical compound FP(F)(F)=O FFUQCRZBKUBHQT-UHFFFAOYSA-N 0.000 claims description 24
- 239000007789 gas Substances 0.000 claims description 17
- 239000001506 calcium phosphate Substances 0.000 claims description 16
- 229910000389 calcium phosphate Inorganic materials 0.000 claims description 16
- 235000011010 calcium phosphates Nutrition 0.000 claims description 16
- QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 claims description 16
- 229910019142 PO4 Inorganic materials 0.000 claims description 14
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 14
- 239000010452 phosphate Substances 0.000 claims description 14
- 230000015572 biosynthetic process Effects 0.000 claims description 11
- 239000000047 product Substances 0.000 claims description 10
- 239000002002 slurry Substances 0.000 claims description 10
- 239000011737 fluorine Substances 0.000 claims description 9
- 229910052731 fluorine Inorganic materials 0.000 claims description 9
- DWYMPOCYEZONEA-UHFFFAOYSA-N fluorophosphoric acid Chemical compound OP(O)(F)=O DWYMPOCYEZONEA-UHFFFAOYSA-N 0.000 claims description 7
- 239000007795 chemical reaction product Substances 0.000 claims description 6
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 claims description 5
- UEZVMMHDMIWARA-UHFFFAOYSA-N Metaphosphoric acid Chemical compound OP(=O)=O UEZVMMHDMIWARA-UHFFFAOYSA-N 0.000 claims description 5
- 230000001105 regulatory effect Effects 0.000 claims description 4
- 238000000926 separation method Methods 0.000 claims description 4
- 239000007864 aqueous solution Substances 0.000 claims description 3
- 229910052739 hydrogen Inorganic materials 0.000 claims description 3
- 239000001257 hydrogen Substances 0.000 claims description 3
- 238000000197 pyrolysis Methods 0.000 claims description 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 2
- 238000013019 agitation Methods 0.000 claims 1
- 230000003197 catalytic effect Effects 0.000 claims 1
- 239000011541 reaction mixture Substances 0.000 claims 1
- 238000003756 stirring Methods 0.000 claims 1
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 20
- 238000009835 boiling Methods 0.000 description 12
- 239000002367 phosphate rock Substances 0.000 description 12
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 description 12
- 238000011084 recovery Methods 0.000 description 11
- 238000004821 distillation Methods 0.000 description 10
- 238000002474 experimental method Methods 0.000 description 9
- 235000021317 phosphate Nutrition 0.000 description 9
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 8
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 7
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical group [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 7
- QTZBTBLHYPSFMG-UHFFFAOYSA-N 5-chloro-3-methylpyridin-2-amine Chemical compound CC1=CC(Cl)=CN=C1N QTZBTBLHYPSFMG-UHFFFAOYSA-N 0.000 description 6
- 239000002253 acid Substances 0.000 description 6
- VSIIXMUUUJUKCM-UHFFFAOYSA-D pentacalcium;fluoride;triphosphate Chemical compound [F-].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O VSIIXMUUUJUKCM-UHFFFAOYSA-D 0.000 description 6
- 150000001875 compounds Chemical class 0.000 description 5
- 238000001704 evaporation Methods 0.000 description 5
- 230000008020 evaporation Effects 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- 229910052587 fluorapatite Inorganic materials 0.000 description 4
- 229940077441 fluorapatite Drugs 0.000 description 4
- -1 fluorine sulphonate salt Chemical class 0.000 description 4
- 238000004064 recycling Methods 0.000 description 4
- 239000000377 silicon dioxide Substances 0.000 description 4
- 238000004458 analytical method Methods 0.000 description 3
- 229910001634 calcium fluoride Inorganic materials 0.000 description 3
- 235000011132 calcium sulphate Nutrition 0.000 description 3
- 238000000605 extraction Methods 0.000 description 3
- 239000003337 fertilizer Substances 0.000 description 3
- 238000005194 fractionation Methods 0.000 description 3
- 239000011261 inert gas Substances 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 235000012239 silicon dioxide Nutrition 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- 229910052586 apatite Inorganic materials 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- WUKWITHWXAAZEY-UHFFFAOYSA-L calcium difluoride Chemical compound [F-].[F-].[Ca+2] WUKWITHWXAAZEY-UHFFFAOYSA-L 0.000 description 2
- 239000003575 carbonaceous material Substances 0.000 description 2
- 239000000470 constituent Substances 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000010440 gypsum Substances 0.000 description 2
- 229910052602 gypsum Inorganic materials 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 150000003016 phosphoric acids Chemical class 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 150000003377 silicon compounds Chemical class 0.000 description 2
- ABTOQLMXBSRXSM-UHFFFAOYSA-N silicon tetrafluoride Chemical compound F[Si](F)(F)F ABTOQLMXBSRXSM-UHFFFAOYSA-N 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 229910052717 sulfur Inorganic materials 0.000 description 2
- 239000011593 sulfur Substances 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- FYGKVENAJHIGPN-UHFFFAOYSA-N S(=O)(=O)=O.P(=O)(F)(F)F Chemical compound S(=O)(=O)=O.P(=O)(F)(F)F FYGKVENAJHIGPN-UHFFFAOYSA-N 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- QSWGECXKORMPAV-UHFFFAOYSA-M [F-].[P+]=O Chemical compound [F-].[P+]=O QSWGECXKORMPAV-UHFFFAOYSA-M 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 238000005054 agglomeration Methods 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 238000010923 batch production Methods 0.000 description 1
- 210000000988 bone and bone Anatomy 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 238000001354 calcination Methods 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 239000001175 calcium sulphate Substances 0.000 description 1
- YYRMJZQKEFZXMX-UHFFFAOYSA-N calcium;phosphoric acid Chemical compound [Ca+2].OP(O)(O)=O.OP(O)(O)=O YYRMJZQKEFZXMX-UHFFFAOYSA-N 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 239000000356 contaminant Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 230000006735 deficit Effects 0.000 description 1
- 238000006115 defluorination reaction Methods 0.000 description 1
- 230000018044 dehydration Effects 0.000 description 1
- 238000006297 dehydration reaction Methods 0.000 description 1
- 239000002274 desiccant Substances 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 150000002222 fluorine compounds Chemical class 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 239000013067 intermediate product Substances 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 238000009533 lab test Methods 0.000 description 1
- 229910001512 metal fluoride Inorganic materials 0.000 description 1
- 229910001463 metal phosphate Inorganic materials 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000002686 phosphate fertilizer Substances 0.000 description 1
- 230000001863 plant nutrition Effects 0.000 description 1
- 238000011027 product recovery Methods 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 239000002210 silicon-based material Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 239000002426 superphosphate Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 229910000391 tricalcium phosphate Inorganic materials 0.000 description 1
- 239000012808 vapor phase Substances 0.000 description 1
- 238000009834 vaporization Methods 0.000 description 1
- 230000008016 vaporization Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B25/00—Phosphorus; Compounds thereof
- C01B25/16—Oxyacids of phosphorus; Salts thereof
- C01B25/18—Phosphoric acid
- C01B25/22—Preparation by reacting phosphate-containing material with an acid, e.g. wet process
- C01B25/2208—Preparation by reacting phosphate-containing material with an acid, e.g. wet process with an acid or a mixture of acids other than sulfuric acid
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B25/00—Phosphorus; Compounds thereof
- C01B25/10—Halides or oxyhalides of phosphorus
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Catalysts (AREA)
- Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
- Saccharide Compounds (AREA)
- Luminescent Compositions (AREA)
- Polysaccharides And Polysaccharide Derivatives (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US06/000,987 US4202867A (en) | 1977-08-29 | 1979-01-04 | Process for manufacture of phosphoric acid and phosphorus pentafluoride |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| NO794183L true NO794183L (no) | 1980-07-07 |
Family
ID=21693845
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| NO794183A NO794183L (no) | 1979-01-04 | 1979-12-20 | Fremgangsmaate til fremstilling av fosforsyre og fosforpentafluorid |
| NO833144A NO833144L (no) | 1979-01-04 | 1983-09-02 | Fremgangsmaate til fremstilling av fosforpentafluorid |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| NO833144A NO833144L (no) | 1979-01-04 | 1983-09-02 | Fremgangsmaate til fremstilling av fosforpentafluorid |
Country Status (20)
| Country | Link |
|---|---|
| JP (1) | JPS55100207A (it) |
| AU (1) | AU533858B2 (it) |
| BE (1) | BE880913A (it) |
| BR (1) | BR8000025A (it) |
| CA (1) | CA1110823A (it) |
| DE (1) | DE2952060A1 (it) |
| DK (1) | DK3780A (it) |
| ES (3) | ES8100222A1 (it) |
| FI (1) | FI800021A (it) |
| FR (1) | FR2445816A1 (it) |
| GB (1) | GB2041344B (it) |
| IT (1) | IT1129701B (it) |
| JO (1) | JO1089B1 (it) |
| MA (1) | MA18691A1 (it) |
| MX (1) | MX152927A (it) |
| NL (1) | NL7909261A (it) |
| NO (2) | NO794183L (it) |
| OA (1) | OA06426A (it) |
| SE (1) | SE7910504L (it) |
| ZA (1) | ZA796847B (it) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP5960907B2 (ja) * | 2013-03-25 | 2016-08-02 | 三井化学株式会社 | 五フッ化リンの製造方法及び六フッ化リン酸リチウムの製造方法 |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3428422A (en) * | 1967-11-14 | 1969-02-18 | Uss Agri Chem Inc | Preparation of phosphoryl fluoride and difluorophosphoric acid |
-
1979
- 1979-12-11 GB GB7942612A patent/GB2041344B/en not_active Expired
- 1979-12-13 AU AU53784/79A patent/AU533858B2/en not_active Ceased
- 1979-12-18 ZA ZA00796847A patent/ZA796847B/xx unknown
- 1979-12-20 NO NO794183A patent/NO794183L/no unknown
- 1979-12-20 SE SE7910504A patent/SE7910504L/ not_active Application Discontinuation
- 1979-12-21 NL NL7909261A patent/NL7909261A/nl not_active Application Discontinuation
- 1979-12-22 DE DE19792952060 patent/DE2952060A1/de not_active Withdrawn
- 1979-12-24 JP JP16805279A patent/JPS55100207A/ja active Pending
- 1979-12-27 BE BE0/198792A patent/BE880913A/fr not_active IP Right Cessation
- 1979-12-28 CA CA342,705A patent/CA1110823A/en not_active Expired
-
1980
- 1980-01-03 JO JO19801089A patent/JO1089B1/en active
- 1980-01-03 MA MA18888A patent/MA18691A1/fr unknown
- 1980-01-03 FR FR8000068A patent/FR2445816A1/fr active Granted
- 1980-01-03 IT IT19019/80A patent/IT1129701B/it active
- 1980-01-03 DK DK3780A patent/DK3780A/da not_active Application Discontinuation
- 1980-01-03 ES ES487422A patent/ES8100222A1/es not_active Expired
- 1980-01-03 FI FI800021A patent/FI800021A/fi not_active Application Discontinuation
- 1980-01-03 BR BR8000025A patent/BR8000025A/pt unknown
- 1980-01-04 MX MX180697A patent/MX152927A/es unknown
- 1980-01-04 OA OA56986A patent/OA06426A/xx unknown
- 1980-02-20 ES ES488756A patent/ES488756A0/es active Granted
- 1980-02-20 ES ES488755A patent/ES488755A0/es active Granted
-
1983
- 1983-09-02 NO NO833144A patent/NO833144L/no unknown
Also Published As
| Publication number | Publication date |
|---|---|
| FI800021A (fi) | 1980-07-05 |
| ES8102986A1 (es) | 1981-02-16 |
| MA18691A1 (fr) | 1980-10-01 |
| ZA796847B (en) | 1980-12-31 |
| ES487422A0 (es) | 1980-11-01 |
| ES8100222A1 (es) | 1980-11-01 |
| CA1110823A (en) | 1981-10-20 |
| DK3780A (da) | 1980-07-05 |
| IT8019019A0 (it) | 1980-01-03 |
| BE880913A (fr) | 1980-06-27 |
| BR8000025A (pt) | 1980-09-23 |
| NO833144L (no) | 1980-07-07 |
| FR2445816B1 (it) | 1982-05-14 |
| JO1089B1 (en) | 1982-07-10 |
| JPS55100207A (en) | 1980-07-31 |
| DE2952060A1 (de) | 1980-07-24 |
| FR2445816A1 (fr) | 1980-08-01 |
| ES8102984A1 (es) | 1981-02-16 |
| AU5378479A (en) | 1980-07-10 |
| GB2041344A (en) | 1980-09-10 |
| GB2041344B (en) | 1982-10-06 |
| MX152927A (es) | 1986-07-03 |
| ES488755A0 (es) | 1981-02-16 |
| ES488756A0 (es) | 1981-02-16 |
| IT1129701B (it) | 1986-06-11 |
| NL7909261A (nl) | 1980-07-08 |
| SE7910504L (sv) | 1980-07-05 |
| OA06426A (fr) | 1981-09-30 |
| AU533858B2 (en) | 1983-12-15 |
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