NO319607B1 - Reologi-modifisert polyetylen - Google Patents
Reologi-modifisert polyetylen Download PDFInfo
- Publication number
- NO319607B1 NO319607B1 NO19984086A NO984086A NO319607B1 NO 319607 B1 NO319607 B1 NO 319607B1 NO 19984086 A NO19984086 A NO 19984086A NO 984086 A NO984086 A NO 984086A NO 319607 B1 NO319607 B1 NO 319607B1
- Authority
- NO
- Norway
- Prior art keywords
- polymer
- set forth
- rheology
- modified
- cross
- Prior art date
Links
- 229920000573 polyethylene Polymers 0.000 title claims description 79
- -1 polyethylene Polymers 0.000 title description 32
- 239000004698 Polyethylene Substances 0.000 title description 20
- 229920000642 polymer Polymers 0.000 claims description 257
- 238000000034 method Methods 0.000 claims description 76
- 239000003431 cross linking reagent Substances 0.000 claims description 47
- 230000004048 modification Effects 0.000 claims description 41
- 238000012986 modification Methods 0.000 claims description 41
- 238000009826 distribution Methods 0.000 claims description 31
- 239000000155 melt Substances 0.000 claims description 29
- 238000000518 rheometry Methods 0.000 claims description 29
- 125000004432 carbon atom Chemical group C* 0.000 claims description 28
- 230000008569 process Effects 0.000 claims description 24
- 238000002844 melting Methods 0.000 claims description 22
- 230000008018 melting Effects 0.000 claims description 22
- 238000004519 manufacturing process Methods 0.000 claims description 20
- 238000010128 melt processing Methods 0.000 claims description 19
- 239000000203 mixture Substances 0.000 claims description 17
- 239000008188 pellet Substances 0.000 claims description 16
- 238000004132 cross linking Methods 0.000 claims description 15
- 229920001169 thermoplastic Polymers 0.000 claims description 13
- 239000004416 thermosoftening plastic Substances 0.000 claims description 12
- 238000012545 processing Methods 0.000 claims description 8
- 239000013067 intermediate product Substances 0.000 claims description 7
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 6
- 229920002554 vinyl polymer Polymers 0.000 claims description 6
- 238000002156 mixing Methods 0.000 claims description 4
- 230000015572 biosynthetic process Effects 0.000 claims description 3
- 239000002131 composite material Substances 0.000 claims 1
- 150000002978 peroxides Chemical class 0.000 description 49
- 239000000463 material Substances 0.000 description 32
- 239000000499 gel Substances 0.000 description 30
- 238000001125 extrusion Methods 0.000 description 29
- 239000000047 product Substances 0.000 description 27
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 24
- 239000005977 Ethylene Substances 0.000 description 24
- 239000004711 α-olefin Substances 0.000 description 22
- 230000008859 change Effects 0.000 description 20
- 239000010410 layer Substances 0.000 description 20
- 229920000092 linear low density polyethylene Polymers 0.000 description 20
- 239000004707 linear low-density polyethylene Substances 0.000 description 20
- 239000011888 foil Substances 0.000 description 19
- 229920001577 copolymer Polymers 0.000 description 18
- 239000010408 film Substances 0.000 description 18
- 150000001875 compounds Chemical class 0.000 description 16
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 description 15
- 229920000098 polyolefin Polymers 0.000 description 15
- 230000000694 effects Effects 0.000 description 14
- 229920001684 low density polyethylene Polymers 0.000 description 14
- 239000000126 substance Substances 0.000 description 14
- 239000004702 low-density polyethylene Substances 0.000 description 13
- 238000010894 electron beam technology Methods 0.000 description 12
- 239000007789 gas Substances 0.000 description 12
- 239000003054 catalyst Substances 0.000 description 11
- 229920005989 resin Polymers 0.000 description 11
- 239000011347 resin Substances 0.000 description 11
- 239000000178 monomer Substances 0.000 description 10
- 239000000243 solution Substances 0.000 description 10
- 238000000576 coating method Methods 0.000 description 9
- 230000007547 defect Effects 0.000 description 9
- 238000005227 gel permeation chromatography Methods 0.000 description 9
- 238000006116 polymerization reaction Methods 0.000 description 9
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 8
- 239000003963 antioxidant agent Substances 0.000 description 8
- 239000008187 granular material Substances 0.000 description 8
- 229920003023 plastic Polymers 0.000 description 8
- 239000004033 plastic Substances 0.000 description 8
- 239000000654 additive Substances 0.000 description 7
- 238000010438 heat treatment Methods 0.000 description 7
- 239000007858 starting material Substances 0.000 description 7
- ZGEGCLOFRBLKSE-UHFFFAOYSA-N 1-Heptene Chemical compound CCCCCC=C ZGEGCLOFRBLKSE-UHFFFAOYSA-N 0.000 description 6
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 6
- 239000011248 coating agent Substances 0.000 description 6
- 229920001971 elastomer Polymers 0.000 description 6
- 229920001903 high density polyethylene Polymers 0.000 description 6
- 239000004700 high-density polyethylene Substances 0.000 description 6
- 238000001746 injection moulding Methods 0.000 description 6
- TVMXDCGIABBOFY-UHFFFAOYSA-N n-Octanol Natural products CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 6
- 238000004806 packaging method and process Methods 0.000 description 6
- 230000005855 radiation Effects 0.000 description 6
- 230000003078 antioxidant effect Effects 0.000 description 5
- 239000003795 chemical substances by application Substances 0.000 description 5
- 238000000113 differential scanning calorimetry Methods 0.000 description 5
- 239000003085 diluting agent Substances 0.000 description 5
- 238000005516 engineering process Methods 0.000 description 5
- QHZOMAXECYYXGP-UHFFFAOYSA-N ethene;prop-2-enoic acid Chemical compound C=C.OC(=O)C=C QHZOMAXECYYXGP-UHFFFAOYSA-N 0.000 description 5
- 238000001879 gelation Methods 0.000 description 5
- 230000000977 initiatory effect Effects 0.000 description 5
- 229920002959 polymer blend Polymers 0.000 description 5
- 150000003254 radicals Chemical class 0.000 description 5
- 239000002356 single layer Substances 0.000 description 5
- WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 4
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- 239000012141 concentrate Substances 0.000 description 4
- 238000001723 curing Methods 0.000 description 4
- 229920001519 homopolymer Polymers 0.000 description 4
- 239000003999 initiator Substances 0.000 description 4
- 238000005259 measurement Methods 0.000 description 4
- 239000003921 oil Substances 0.000 description 4
- YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical compound CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 description 4
- 239000002002 slurry Substances 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- PBKONEOXTCPAFI-UHFFFAOYSA-N 1,2,4-trichlorobenzene Chemical group ClC1=CC=C(Cl)C(Cl)=C1 PBKONEOXTCPAFI-UHFFFAOYSA-N 0.000 description 3
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- 229920000089 Cyclic olefin copolymer Polymers 0.000 description 3
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
- 238000005481 NMR spectroscopy Methods 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 239000012967 coordination catalyst Substances 0.000 description 3
- 230000000875 corresponding effect Effects 0.000 description 3
- 239000012895 dilution Substances 0.000 description 3
- 238000010790 dilution Methods 0.000 description 3
- 239000000806 elastomer Substances 0.000 description 3
- 239000000945 filler Substances 0.000 description 3
- 235000013305 food Nutrition 0.000 description 3
- 230000004927 fusion Effects 0.000 description 3
- 238000010348 incorporation Methods 0.000 description 3
- 238000003475 lamination Methods 0.000 description 3
- 238000000465 moulding Methods 0.000 description 3
- 150000001451 organic peroxides Chemical class 0.000 description 3
- 230000000704 physical effect Effects 0.000 description 3
- 230000000379 polymerizing effect Effects 0.000 description 3
- 229920006124 polyolefin elastomer Polymers 0.000 description 3
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 3
- 239000005060 rubber Substances 0.000 description 3
- 229910001220 stainless steel Inorganic materials 0.000 description 3
- 239000010935 stainless steel Substances 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- 229920001862 ultra low molecular weight polyethylene Polymers 0.000 description 3
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- 241000251730 Chondrichthyes Species 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- OWYWGLHRNBIFJP-UHFFFAOYSA-N Ipazine Chemical compound CCN(CC)C1=NC(Cl)=NC(NC(C)C)=N1 OWYWGLHRNBIFJP-UHFFFAOYSA-N 0.000 description 2
- 229920010126 Linear Low Density Polyethylene (LLDPE) Polymers 0.000 description 2
- 239000004677 Nylon Substances 0.000 description 2
- 239000004793 Polystyrene Substances 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 229910052771 Terbium Inorganic materials 0.000 description 2
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 2
- BEIOEBMXPVYLRY-UHFFFAOYSA-N [4-[4-bis(2,4-ditert-butylphenoxy)phosphanylphenyl]phenyl]-bis(2,4-ditert-butylphenoxy)phosphane Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=CC=C1OP(C=1C=CC(=CC=1)C=1C=CC(=CC=1)P(OC=1C(=CC(=CC=1)C(C)(C)C)C(C)(C)C)OC=1C(=CC(=CC=1)C(C)(C)C)C(C)(C)C)OC1=CC=C(C(C)(C)C)C=C1C(C)(C)C BEIOEBMXPVYLRY-UHFFFAOYSA-N 0.000 description 2
- 230000001133 acceleration Effects 0.000 description 2
- 230000004913 activation Effects 0.000 description 2
- 150000001336 alkenes Chemical class 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 230000004888 barrier function Effects 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 description 2
- IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 description 2
- 239000006227 byproduct Substances 0.000 description 2
- 239000003426 co-catalyst Substances 0.000 description 2
- 238000010924 continuous production Methods 0.000 description 2
- 230000002596 correlated effect Effects 0.000 description 2
- HGCIXCUEYOPUTN-UHFFFAOYSA-N cyclohexene Chemical compound C1CCC=CC1 HGCIXCUEYOPUTN-UHFFFAOYSA-N 0.000 description 2
- LPIQUOYDBNQMRZ-UHFFFAOYSA-N cyclopentene Chemical compound C1CC=CC1 LPIQUOYDBNQMRZ-UHFFFAOYSA-N 0.000 description 2
- 238000010828 elution Methods 0.000 description 2
- 229920001038 ethylene copolymer Polymers 0.000 description 2
- 238000007765 extrusion coating Methods 0.000 description 2
- 238000012685 gas phase polymerization Methods 0.000 description 2
- 229910052735 hafnium Inorganic materials 0.000 description 2
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 description 2
- 238000002347 injection Methods 0.000 description 2
- 239000007924 injection Substances 0.000 description 2
- 238000009413 insulation Methods 0.000 description 2
- 239000000543 intermediate Substances 0.000 description 2
- 229920005684 linear copolymer Polymers 0.000 description 2
- 239000003607 modifier Substances 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 239000012299 nitrogen atmosphere Substances 0.000 description 2
- 229920001778 nylon Polymers 0.000 description 2
- 239000005026 oriented polypropylene Substances 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000005022 packaging material Substances 0.000 description 2
- 239000002985 plastic film Substances 0.000 description 2
- 229920006255 plastic film Polymers 0.000 description 2
- 239000004014 plasticizer Substances 0.000 description 2
- 239000005020 polyethylene terephthalate Substances 0.000 description 2
- 229920000139 polyethylene terephthalate Polymers 0.000 description 2
- 239000002861 polymer material Substances 0.000 description 2
- 229920002223 polystyrene Polymers 0.000 description 2
- 239000000376 reactant Substances 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 230000003746 surface roughness Effects 0.000 description 2
- 229910052715 tantalum Inorganic materials 0.000 description 2
- 230000000930 thermomechanical effect Effects 0.000 description 2
- 229920002397 thermoplastic olefin Polymers 0.000 description 2
- ODBCKCWTWALFKM-UHFFFAOYSA-N 2,5-bis(tert-butylperoxy)-2,5-dimethylhex-3-yne Chemical compound CC(C)(C)OOC(C)(C)C#CC(C)(C)OOC(C)(C)C ODBCKCWTWALFKM-UHFFFAOYSA-N 0.000 description 1
- XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical compound C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 description 1
- ZUXNHFFVQWADJL-UHFFFAOYSA-N 3,4,5-trimethoxy-n-(2-methoxyethyl)-n-(4-phenyl-1,3-thiazol-2-yl)benzamide Chemical compound N=1C(C=2C=CC=CC=2)=CSC=1N(CCOC)C(=O)C1=CC(OC)=C(OC)C(OC)=C1 ZUXNHFFVQWADJL-UHFFFAOYSA-N 0.000 description 1
- OOVQLEHBRDIXDZ-UHFFFAOYSA-N 7-ethenylbicyclo[4.2.0]octa-1,3,5-triene Chemical compound C1=CC=C2C(C=C)CC2=C1 OOVQLEHBRDIXDZ-UHFFFAOYSA-N 0.000 description 1
- 239000004971 Cross linker Substances 0.000 description 1
- 229920002943 EPDM rubber Polymers 0.000 description 1
- IMROMDMJAWUWLK-UHFFFAOYSA-N Ethenol Chemical compound OC=C IMROMDMJAWUWLK-UHFFFAOYSA-N 0.000 description 1
- 238000004566 IR spectroscopy Methods 0.000 description 1
- 239000004594 Masterbatch (MB) Substances 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- 239000006057 Non-nutritive feed additive Substances 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 229920000034 Plastomer Polymers 0.000 description 1
- 239000005062 Polybutadiene Substances 0.000 description 1
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Natural products C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 1
- 229920010346 Very Low Density Polyethylene (VLDPE) Polymers 0.000 description 1
- 239000011954 Ziegler–Natta catalyst Substances 0.000 description 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 239000002998 adhesive polymer Substances 0.000 description 1
- 239000002671 adjuvant Substances 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- 238000000071 blow moulding Methods 0.000 description 1
- 150000001639 boron compounds Chemical class 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 238000003490 calendering Methods 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 238000012512 characterization method Methods 0.000 description 1
- 238000007385 chemical modification Methods 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 229910052570 clay Inorganic materials 0.000 description 1
- 229920006026 co-polymeric resin Polymers 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 150000001925 cycloalkenes Chemical class 0.000 description 1
- URYYVOIYTNXXBN-UPHRSURJSA-N cyclooctene Chemical compound C1CCC\C=C/CC1 URYYVOIYTNXXBN-UPHRSURJSA-N 0.000 description 1
- 239000004913 cyclooctene Substances 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 230000003111 delayed effect Effects 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000004512 die casting Methods 0.000 description 1
- 150000001993 dienes Chemical class 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 238000007580 dry-mixing Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 150000002118 epoxides Chemical class 0.000 description 1
- HEAMQYHBJQWOSS-UHFFFAOYSA-N ethene;oct-1-ene Chemical compound C=C.CCCCCCC=C HEAMQYHBJQWOSS-UHFFFAOYSA-N 0.000 description 1
- HQQADJVZYDDRJT-UHFFFAOYSA-N ethene;prop-1-ene Chemical group C=C.CC=C HQQADJVZYDDRJT-UHFFFAOYSA-N 0.000 description 1
- 125000000816 ethylene group Chemical group [H]C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 238000010101 extrusion blow moulding Methods 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 238000005194 fractionation Methods 0.000 description 1
- 238000010528 free radical solution polymerization reaction Methods 0.000 description 1
- 239000011953 free-radical catalyst Substances 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 229920001002 functional polymer Polymers 0.000 description 1
- 230000005251 gamma ray Effects 0.000 description 1
- 229910052738 indium Inorganic materials 0.000 description 1
- APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 description 1
- 239000012212 insulator Substances 0.000 description 1
- 230000010354 integration Effects 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 229920001912 maleic anhydride grafted polyethylene Polymers 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 238000000691 measurement method Methods 0.000 description 1
- 238000010309 melting process Methods 0.000 description 1
- 239000012968 metallocene catalyst Substances 0.000 description 1
- CPOFMOWDMVWCLF-UHFFFAOYSA-N methyl(oxo)alumane Chemical compound C[Al]=O CPOFMOWDMVWCLF-UHFFFAOYSA-N 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 230000003534 oscillatory effect Effects 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 238000005453 pelletization Methods 0.000 description 1
- RGSFGYAAUTVSQA-UHFFFAOYSA-N pentamethylene Natural products C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 239000011990 phillips catalyst Substances 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920002857 polybutadiene Polymers 0.000 description 1
- 229920001748 polybutylene Polymers 0.000 description 1
- 238000012667 polymer degradation Methods 0.000 description 1
- 229920006254 polymer film Polymers 0.000 description 1
- 239000002685 polymerization catalyst Substances 0.000 description 1
- 239000005033 polyvinylidene chloride Substances 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 125000001453 quaternary ammonium group Chemical group 0.000 description 1
- 238000003847 radiation curing Methods 0.000 description 1
- 230000000191 radiation effect Effects 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 239000000565 sealant Substances 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 239000004447 silicone coating Substances 0.000 description 1
- 238000001374 small-angle light scattering Methods 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 238000004611 spectroscopical analysis Methods 0.000 description 1
- 238000009987 spinning Methods 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 229920006132 styrene block copolymer Polymers 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 230000002522 swelling effect Effects 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 229920001897 terpolymer Polymers 0.000 description 1
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 description 1
- 238000003856 thermoforming Methods 0.000 description 1
- 238000009757 thermoplastic moulding Methods 0.000 description 1
- 150000003608 titanium Chemical class 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 150000003681 vanadium Chemical class 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000003643 water by type Substances 0.000 description 1
- 230000004584 weight gain Effects 0.000 description 1
- 235000019786 weight gain Nutrition 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/28—Treatment by wave energy or particle radiation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/24—Crosslinking, e.g. vulcanising, of macromolecules
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2810/00—Chemical modification of a polymer
- C08F2810/10—Chemical modification of a polymer including a reactive processing step which leads, inter alia, to morphological and/or rheological modifications, e.g. visbreaking
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2810/00—Chemical modification of a polymer
- C08F2810/20—Chemical modification of a polymer leading to a crosslinking, either explicitly or inherently
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2323/04—Homopolymers or copolymers of ethene
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US1287396P | 1996-03-05 | 1996-03-05 | |
PCT/US1997/002996 WO1997032922A2 (en) | 1996-03-05 | 1997-02-28 | Rheology-modified polyolefins |
Publications (3)
Publication Number | Publication Date |
---|---|
NO984086D0 NO984086D0 (no) | 1998-09-04 |
NO984086L NO984086L (no) | 1998-11-04 |
NO319607B1 true NO319607B1 (no) | 2005-08-29 |
Family
ID=21757149
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
NO19984086A NO319607B1 (no) | 1996-03-05 | 1998-09-04 | Reologi-modifisert polyetylen |
Country Status (23)
Country | Link |
---|---|
US (2) | US6114486A (xx) |
EP (1) | EP0885255B1 (xx) |
JP (1) | JP2000506210A (xx) |
KR (1) | KR100522494B1 (xx) |
CN (1) | CN1072241C (xx) |
AR (1) | AR006093A1 (xx) |
AT (1) | ATE206445T1 (xx) |
AU (1) | AU712018B2 (xx) |
BR (1) | BR9707803A (xx) |
CA (1) | CA2244999C (xx) |
DE (1) | DE69707107T2 (xx) |
ES (1) | ES2161444T3 (xx) |
HK (1) | HK1015390A1 (xx) |
ID (1) | ID19875A (xx) |
MY (1) | MY118496A (xx) |
NO (1) | NO319607B1 (xx) |
PL (1) | PL328725A1 (xx) |
PT (1) | PT885255E (xx) |
RU (1) | RU2184749C2 (xx) |
TR (1) | TR199700163A3 (xx) |
TW (1) | TW480273B (xx) |
WO (1) | WO1997032922A2 (xx) |
ZA (1) | ZA971859B (xx) |
Families Citing this family (72)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6506842B1 (en) | 1997-01-29 | 2003-01-14 | Dupont Dow Elastomers L.L.C. | Rheology-modified thermoplastic elastomer compositions and articles fabricated therefrom |
DE69807708T2 (de) | 1997-08-27 | 2003-01-02 | The Dow Chemical Co., Midland | Elastomere mit verbesserter verarbeitbarkeit |
GB0002192D0 (en) * | 2000-01-31 | 2000-03-22 | Borealis Polymers Oy | Rheometry |
CN1341670A (zh) * | 2000-08-10 | 2002-03-27 | 株式会社宏大化纤 | 改性聚丙烯、制备改性聚丙烯的方法、改性聚丙烯组合物和发泡产品 |
AU2001235686A1 (en) * | 2000-09-22 | 2002-04-02 | Atofina | Peroxide degradation of polymers in the presence of multifunctional stable free radicals |
US6548600B2 (en) | 2000-09-22 | 2003-04-15 | Dupont Dow Elastomers L.L.C. | Thermoplastic elastomer compositions rheology-modified using peroxides and free radical coagents |
US6593053B1 (en) * | 2000-10-23 | 2003-07-15 | Xerox Corporation | Method for controlling melt rheology of resin mixtures |
EP1225201A1 (en) * | 2001-01-12 | 2002-07-24 | ATOFINA Research | High shrink polyethylene films |
US6984698B2 (en) * | 2001-01-31 | 2006-01-10 | Fina Technology, Inc. | Polyethylene films for barrier applications |
US6433103B1 (en) | 2001-01-31 | 2002-08-13 | Fina Technology, Inc. | Method of producing polyethylene resins for use in blow molding |
MY137183A (en) * | 2001-03-16 | 2009-01-30 | Dow Global Technologies Inc | Method of making interpolymers and products made therefrom |
AU2003262390A1 (en) | 2002-04-19 | 2003-11-03 | Gammatron (Pty) Ltd | Method of increasing the hydrostatic stress strength of a polymer |
BR0311703B1 (pt) * | 2002-06-04 | 2013-11-19 | Composição polimérica, método para fabricar tubos, processo de polimerização e tubo | |
US6864195B2 (en) * | 2002-08-15 | 2005-03-08 | Bfs Diversified Products, Llc | Heat weldable roofing membrane |
US7338994B2 (en) * | 2002-10-01 | 2008-03-04 | Dow Global Technologies Inc. | Rheology-modified thermoplastic elastomer compositions for extruded profiles |
US20040116546A1 (en) * | 2002-12-13 | 2004-06-17 | Kosek John A. | Direct organic fuel cell proton exchange membrane and method of manufacturing the same |
US7101628B2 (en) * | 2003-03-20 | 2006-09-05 | Bfs Diversified Products, Llc | Thermoplastic vulcanizate and membrane for covering a roof made therefrom |
KR101178694B1 (ko) * | 2004-03-19 | 2012-08-30 | 다우 글로벌 테크놀로지스 엘엘씨 | 중합체 제형으로 제조한 필름층 |
WO2005095475A1 (en) | 2004-03-24 | 2005-10-13 | Exxonmobil Chemical Patents Inc. | Process for making ethylene interpolymers and interpolymers made thereby; compositions and electrical devices containing such interpolymers |
US20060020063A1 (en) * | 2004-07-22 | 2006-01-26 | Guenther Gerhard K | Controlled finishes for free surface polyethylene resins |
US7285617B2 (en) * | 2004-10-08 | 2007-10-23 | Exxonmobil Chemical Patents Inc. | Oxygen tailoring of polyethylene blow molding resins |
MX2007014763A (es) * | 2005-05-24 | 2008-02-12 | Chevron Phillips Chemical Co | Un metodo bidimensional en linea integrado y dispositivo para fraccionamiento de elucion de elevacion de temperatura analitica sincronizada y cromatografia de permeacion de gel. |
KR100655973B1 (ko) | 2005-10-28 | 2006-12-08 | 현대자동차주식회사 | 활석 함유 폴리프로필렌 복합재료의 스크랩 함유량의유변물성을 이용한 측정방법 |
KR101396058B1 (ko) * | 2006-05-17 | 2014-05-15 | 다우 글로벌 테크놀로지스 엘엘씨 | 폴리올레핀 용액 중합 방법 및 중합체 |
US7714035B1 (en) * | 2006-07-05 | 2010-05-11 | Nibco, Inc. | Plumbing manifolds |
US20090035594A1 (en) * | 2007-08-01 | 2009-02-05 | Lee Chun D | Rheology-modified grafts and adhesive blends |
EP2075125A1 (en) | 2007-12-19 | 2009-07-01 | Total Petrochemicals Research Feluy | Corona treated polyethylene films |
KR101254374B1 (ko) * | 2009-02-19 | 2013-04-12 | 주식회사 엘지화학 | 메탈로센 촉매를 이용하여 제조되는 가공성이 개선된 올레핀 중합체의 제조방법 |
DE102009001145A1 (de) | 2009-02-25 | 2010-09-09 | Leibniz-Institut Für Polymerforschung Dresden E.V. | Verfahren zur Aushärtung und Oberflächenfunktionalisierung von Formteilen |
PL2256158T3 (pl) | 2009-05-26 | 2014-09-30 | Borealis Ag | Kompozycja polimerowa do usieciowanych wyrobów |
EP2256159A1 (en) * | 2009-05-26 | 2010-12-01 | Borealis AG | Polymer composition for crosslinked pipes |
EP2348057A1 (en) * | 2010-01-21 | 2011-07-27 | INEOS Manufacturing Belgium NV | Novel polymers |
JP5527252B2 (ja) * | 2010-02-25 | 2014-06-18 | 日立金属株式会社 | ノンハロゲン難燃樹脂組成物及びそれを用いたケーブル |
CN102918659B (zh) * | 2010-05-31 | 2016-04-27 | 大日本印刷株式会社 | 太阳能电池模块用密封材料及其制造方法 |
US9175119B2 (en) | 2011-12-14 | 2015-11-03 | Ineos Europe Ag | Polymers |
US20150030852A1 (en) | 2012-01-26 | 2015-01-29 | Ineos Europe Ag | Copolymers for wire and cable applications |
US9624019B2 (en) * | 2012-11-09 | 2017-04-18 | Winpak Films Inc. | High oxygen and water barrier multilayer film |
US9346897B2 (en) | 2013-05-14 | 2016-05-24 | Chevron Phillips Chemical Company Lp | Peroxide treated metallocene-based polyolefins with improved melt strength |
MX370854B (es) * | 2013-09-30 | 2020-01-08 | Dow Global Technologies Llc | Proceso para aumentar la resistencia a la fusión de una resina de polietileno, composición de mezcla madre y composición polimérica. |
MX2016005967A (es) * | 2013-11-08 | 2016-08-11 | Arkema Inc | Modificacion de poliamidas. |
US9645066B1 (en) * | 2015-12-04 | 2017-05-09 | Chevron Phillips Chemical Company Lp | Polymer compositions having improved processability and methods of making and using same |
US9645131B1 (en) | 2015-12-04 | 2017-05-09 | Chevron Phillips Chemical Company Lp | Polymer compositions having improved processability and methods of making and using same |
EP3464439A1 (en) | 2016-05-26 | 2019-04-10 | Borealis AG | Molecular modification of polyethylene resin |
BR112019013895A2 (pt) * | 2017-01-05 | 2020-02-04 | General Cable Technologies Corporation | polímeros de polietileno linear de baixa densidade apropriado para o uso em cabos |
US9963529B1 (en) | 2017-04-19 | 2018-05-08 | Nova Chemicals (International) S.A. | Multi reactor solution polymerization |
US10538654B2 (en) | 2017-04-19 | 2020-01-21 | Nova Chemicals (International) S.A. | Multi reactor solution polymerization, polyethylene and polyethylene film |
CA3011050A1 (en) | 2018-07-11 | 2020-01-11 | Nova Chemicals Corporation | Polyethylene composition and film having high stiffness, outstanding sealability and high permeability |
CA3011041A1 (en) | 2018-07-11 | 2020-01-11 | Nova Chemicals Corporation | Polyethylene composition and film |
CA3011030A1 (en) | 2018-07-11 | 2020-01-11 | Nova Chemicals Corporation | Polyethylene composition and film having retained dart impact |
CA3011031A1 (en) | 2018-07-11 | 2020-01-11 | Nova Chemicals Corporation | Polyethylene composition and film having outstanding properties |
CA3011038A1 (en) | 2018-07-11 | 2020-01-11 | Nova Chemicals Corporation | Polyethylene composition and film having a good permeability, stiffness and sealability |
CA3026098A1 (en) | 2018-12-03 | 2020-06-03 | Nova Chemicals Corporation | Narrow polyethylene homopolymer compositions having good barrier properties |
CA3026095A1 (en) | 2018-12-03 | 2020-06-03 | Nova Chemicals Corporation | Polyethylene homopolymer compositions having good barrier properties |
CA3028157A1 (en) | 2018-12-20 | 2020-06-20 | Nova Chemicals Corporation | Polyethylene copolymer compositions and their barrier properties |
CA3032082A1 (en) | 2019-01-31 | 2020-07-31 | Nova Chemicals Corporation | Polyethylene compositions and articles with good barrier properties |
WO2020214453A1 (en) | 2019-04-17 | 2020-10-22 | Dow Global Technologies Llc | Thermoplastic olefin composition |
CN114761240B (zh) | 2019-08-06 | 2024-03-15 | 陶氏环球技术有限责任公司 | 具有至少三层的多层膜及其生产方法 |
MX2022001400A (es) | 2019-08-06 | 2022-05-19 | Dow Global Technologies Llc | Películas multicapa que incluyen al menos cinco capas y métodos para producirlas. |
EP3772414A1 (en) | 2019-08-06 | 2021-02-10 | Dow Global Technologies Llc | Thermoformable multilayer films and methods of producing the same |
US20220275181A1 (en) | 2019-08-06 | 2022-09-01 | Dow Global Technologies Llc | Polyethylene compositions |
EP4058491A1 (en) | 2019-11-14 | 2022-09-21 | ExxonMobil Chemical Patents Inc. | Gas phase polyethylene copolymers |
WO2021144615A1 (en) | 2020-01-17 | 2021-07-22 | Nova Chemicals (International) S.A. | Polyethylene copolymer compositions and articles with barrier properties |
US20230212378A1 (en) | 2020-05-27 | 2023-07-06 | Dow Global Technologies Llc | Polymer formulations and irrigation tubing including polymer formulations |
EP4172251A1 (en) | 2020-06-30 | 2023-05-03 | Dow Global Technologies LLC | Polyethylene compositions and films including polyethylene compositions |
JP2023532894A (ja) | 2020-06-30 | 2023-08-01 | ダウ グローバル テクノロジーズ エルエルシー | ポリエチレン組成物 |
CA3185818A1 (en) | 2020-07-14 | 2022-01-20 | Nova Chemicals Corporation | Solution phase polymerization process |
EP4222181A1 (en) | 2020-09-30 | 2023-08-09 | Borealis AG | Ethylene-octene copolymers with improved property profile |
US11560468B2 (en) | 2020-10-01 | 2023-01-24 | Nova Chemicals (International) S.A. | Thermoformable film |
US11643531B2 (en) | 2020-10-01 | 2023-05-09 | Nova Chemicals (International) S.A. | Thermoformable film |
US12018141B2 (en) | 2021-02-24 | 2024-06-25 | Chevron Phillips Chemical Company Lp | Extrusion coating with enhanced performance via polymeric blends |
JP2024518293A (ja) * | 2021-05-12 | 2024-05-01 | ダウ グローバル テクノロジーズ エルエルシー | レオロジー改質オレフィン系ポリマー組成物及びその製造方法 |
WO2023136825A1 (en) | 2022-01-13 | 2023-07-20 | Dow Global Technologies Llc | Polyethylene compositions |
Family Cites Families (25)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB678527A (en) | 1950-01-14 | 1952-09-03 | Gkn Group Services Ltd | Apparatus for testing the hardness of materials |
US3909463A (en) * | 1968-11-29 | 1975-09-30 | Allied Chem | Grafted block copolymers of synthetic rubbers and polyolefins |
NL7201239A (xx) * | 1971-02-04 | 1972-08-08 | ||
US3953655A (en) * | 1972-04-03 | 1976-04-27 | Exxon Research And Engineering Company | Polymers with improved properties and process therefor |
FR2508047B1 (fr) * | 1981-06-22 | 1985-10-11 | Bp Chimie Sa | Procede de traitement de polyethylene de basse densite lineaire par des peroxydes organiques, generateurs de radicaux libres |
CA1203948A (en) * | 1982-05-10 | 1986-04-29 | David A. Harbourne | Cross-linkable composition of polyethylene |
JPS596241A (ja) * | 1982-07-05 | 1984-01-13 | Asahi Chem Ind Co Ltd | 押出しコ−テイング用樹脂組成物 |
US4525257A (en) * | 1982-12-27 | 1985-06-25 | Union Carbide Corporation | Low level irradiated linear low density ethylene/alpha-olefin copolymers and film extruded therefrom |
US4598128A (en) * | 1983-03-14 | 1986-07-01 | Phillips Petroleum Company | Polymer composition and preparation method |
US4578431A (en) * | 1983-08-31 | 1986-03-25 | Mobil Oil Corporation | Process for improving melt strength of ethylene polymers by treatment with organic peroxide |
GB8332952D0 (en) * | 1983-12-09 | 1984-01-18 | Ward I M | Polymer irradiation |
FR2562546B1 (fr) * | 1984-04-09 | 1987-01-23 | Bp Chimie Sa | Procede de traitement de polyethylene de basse densite lineaire destine a la fabrication par extrusion de corps creux, tubes et gaines |
IL75719A (en) * | 1984-07-18 | 1988-11-30 | Du Pont Canada | Polyolefin blends containing reactive agents |
US4722973A (en) * | 1985-04-10 | 1988-02-02 | Nippon Oil Co., Ltd. | Thermoplastic elastomer composition |
US5200439A (en) * | 1990-04-13 | 1993-04-06 | Mitsui Toatsu Chemicals, Inc. | Method for increasing intrinsic viscosity of syndiotactic polypropylene |
US5272236A (en) * | 1991-10-15 | 1993-12-21 | The Dow Chemical Company | Elastic substantially linear olefin polymers |
JP3016880B2 (ja) * | 1991-02-01 | 2000-03-06 | 三菱化学株式会社 | フィルム成形用高結晶性ポリプロピレン |
TW275636B (xx) * | 1991-06-21 | 1996-05-11 | Himont Inc | |
US5246783A (en) * | 1991-08-15 | 1993-09-21 | Exxon Chemical Patents Inc. | Electrical devices comprising polymeric insulating or semiconducting members |
AU4928993A (en) * | 1992-09-29 | 1994-04-26 | Exxon Chemical Patents Inc. | Long chain branched polymers and a process to make long chain branched polymers |
JP3171422B2 (ja) * | 1994-04-20 | 2001-05-28 | 日本原子力研究所 | 改質ポリプロピレンを製造する方法および成形品 |
GB9507321D0 (en) * | 1995-04-07 | 1995-05-31 | Exxon Chemical Patents Inc | Method to reduce gel in polyolefins |
US5824718A (en) * | 1995-04-20 | 1998-10-20 | The Dow Chemical Company | Silane-crosslinkable, substantially linear ethylene polymers and their uses |
US5736618A (en) * | 1995-05-05 | 1998-04-07 | Poloso; Anthony | High density polyethylene with improved thermoforming characteristics |
US5578682A (en) * | 1995-05-25 | 1996-11-26 | Exxon Chemical Patents Inc. | Bimodalization of polymer molecular weight distribution |
-
1997
- 1997-02-28 CA CA002244999A patent/CA2244999C/en not_active Expired - Fee Related
- 1997-02-28 ES ES97907876T patent/ES2161444T3/es not_active Expired - Lifetime
- 1997-02-28 US US08/807,554 patent/US6114486A/en not_active Expired - Lifetime
- 1997-02-28 PL PL97328725A patent/PL328725A1/xx unknown
- 1997-02-28 BR BR9707803A patent/BR9707803A/pt not_active IP Right Cessation
- 1997-02-28 AT AT97907876T patent/ATE206445T1/de not_active IP Right Cessation
- 1997-02-28 CN CN97192775A patent/CN1072241C/zh not_active Expired - Fee Related
- 1997-02-28 AU AU19765/97A patent/AU712018B2/en not_active Ceased
- 1997-02-28 EP EP97907876A patent/EP0885255B1/en not_active Expired - Lifetime
- 1997-02-28 JP JP9531824A patent/JP2000506210A/ja active Pending
- 1997-02-28 RU RU98118022/04A patent/RU2184749C2/ru not_active IP Right Cessation
- 1997-02-28 DE DE69707107T patent/DE69707107T2/de not_active Expired - Lifetime
- 1997-02-28 WO PCT/US1997/002996 patent/WO1997032922A2/en not_active Application Discontinuation
- 1997-02-28 KR KR10-1998-0706994A patent/KR100522494B1/ko not_active IP Right Cessation
- 1997-02-28 PT PT97907876T patent/PT885255E/pt unknown
- 1997-03-03 ID IDP970645A patent/ID19875A/id unknown
- 1997-03-04 ZA ZA971859A patent/ZA971859B/xx unknown
- 1997-03-04 TW TW086102588A patent/TW480273B/zh not_active IP Right Cessation
- 1997-03-04 AR ARP970100854A patent/AR006093A1/es active IP Right Grant
- 1997-03-04 MY MYPI97000866A patent/MY118496A/en unknown
- 1997-03-05 TR TR97/00163A patent/TR199700163A3/tr unknown
-
1998
- 1998-09-04 NO NO19984086A patent/NO319607B1/no unknown
-
1999
- 1999-01-19 HK HK99100250A patent/HK1015390A1/xx not_active IP Right Cessation
-
2000
- 2000-07-11 US US09/614,030 patent/US6689851B1/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
WO1997032922A2 (en) | 1997-09-12 |
CN1212714A (zh) | 1999-03-31 |
PT885255E (pt) | 2002-03-28 |
DE69707107D1 (de) | 2001-11-08 |
DE69707107T2 (de) | 2002-03-07 |
HK1015390A1 (en) | 1999-10-15 |
CA2244999C (en) | 2007-03-27 |
TW480273B (en) | 2002-03-21 |
US6114486A (en) | 2000-09-05 |
JP2000506210A (ja) | 2000-05-23 |
RU2184749C2 (ru) | 2002-07-10 |
PL328725A1 (en) | 1999-02-15 |
NO984086L (no) | 1998-11-04 |
AU712018B2 (en) | 1999-10-28 |
ID19875A (id) | 1998-08-13 |
CN1072241C (zh) | 2001-10-03 |
ES2161444T3 (es) | 2001-12-01 |
KR100522494B1 (ko) | 2005-11-25 |
ZA971859B (en) | 1998-09-04 |
MY118496A (en) | 2004-11-30 |
US6689851B1 (en) | 2004-02-10 |
WO1997032922A3 (en) | 1997-10-16 |
KR19990087556A (ko) | 1999-12-27 |
TR199700163A2 (tr) | 1997-09-21 |
BR9707803A (pt) | 1999-07-27 |
EP0885255A2 (en) | 1998-12-23 |
CA2244999A1 (en) | 1997-09-12 |
EP0885255B1 (en) | 2001-10-04 |
AU1976597A (en) | 1997-09-22 |
ATE206445T1 (de) | 2001-10-15 |
TR199700163A3 (tr) | 1997-09-21 |
NO984086D0 (no) | 1998-09-04 |
AR006093A1 (es) | 1999-08-11 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
NO319607B1 (no) | Reologi-modifisert polyetylen | |
EP1007586B1 (en) | Rheology modification of low density polyethylene | |
JP3582836B2 (ja) | 高いドローダウンと実質的に低下したネックインを示す押出し加工用組成物 | |
CA2142122C (en) | Formulated ethylene/.alpha.-olefin elastomeric compounds | |
US5874139A (en) | Multilayer polyolefin with balanced sealant properties | |
JP5551362B2 (ja) | ポリオレフィン組成物、それから作製された物品、ならびにそれらを調製するための方法 | |
MXPA97003565A (en) | Compositions of extrusion that have standing and rebordeo towards adustrosustantially reduc | |
EP0717759A1 (en) | Batch inclusion packages | |
KR20000053255A (ko) | 밀봉성과 개선된 모듈러스가 균형잡힌 폴리올레핀 조성물 및 이의 제조 방법 | |
NO313145B1 (no) | Formingsblanding, fremgangsmåte for fremstilling av blandingen, samt anvendelse av formingsblandingen | |
WO1999051433A1 (en) | Polymeric adhesive composition for polyvinylidene chloride interpolymers | |
MXPA00002017A (en) | Rheology modification of polymers prepared using metallocenes |