NO311251B1 - Fremgangsmåte ved fjerning av kalsiumioner og silisiumforbindelser fra en v¶ske i en alkalimetallklorat-prosess - Google Patents
Fremgangsmåte ved fjerning av kalsiumioner og silisiumforbindelser fra en v¶ske i en alkalimetallklorat-prosess Download PDFInfo
- Publication number
- NO311251B1 NO311251B1 NO19940762A NO940762A NO311251B1 NO 311251 B1 NO311251 B1 NO 311251B1 NO 19940762 A NO19940762 A NO 19940762A NO 940762 A NO940762 A NO 940762A NO 311251 B1 NO311251 B1 NO 311251B1
- Authority
- NO
- Norway
- Prior art keywords
- liquid
- ions
- calcium
- iron
- carbonate
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims description 65
- 239000007788 liquid Substances 0.000 title claims description 63
- XTEGARKTQYYJKE-UHFFFAOYSA-M chlorate Inorganic materials [O-]Cl(=O)=O XTEGARKTQYYJKE-UHFFFAOYSA-M 0.000 title claims description 57
- -1 Alkali Metal Chlorate Chemical class 0.000 title claims description 39
- 150000003377 silicon compounds Chemical class 0.000 title claims description 37
- 230000008569 process Effects 0.000 title claims description 21
- BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 title claims description 20
- 229910001424 calcium ion Inorganic materials 0.000 title claims description 20
- 229910052783 alkali metal Inorganic materials 0.000 title claims description 12
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 79
- 229910052742 iron Inorganic materials 0.000 claims description 46
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 35
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims description 34
- 238000001556 precipitation Methods 0.000 claims description 34
- 150000001875 compounds Chemical class 0.000 claims description 27
- 239000002244 precipitate Substances 0.000 claims description 23
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims description 20
- 238000000926 separation method Methods 0.000 claims description 19
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 18
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 15
- 229910052791 calcium Inorganic materials 0.000 claims description 15
- 239000011575 calcium Substances 0.000 claims description 15
- 239000001569 carbon dioxide Substances 0.000 claims description 10
- 229910002092 carbon dioxide Inorganic materials 0.000 claims description 10
- 239000012267 brine Substances 0.000 claims description 8
- HPALAKNZSZLMCH-UHFFFAOYSA-M sodium;chloride;hydrate Chemical compound O.[Na+].[Cl-] HPALAKNZSZLMCH-UHFFFAOYSA-M 0.000 claims description 8
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 claims description 7
- 238000004519 manufacturing process Methods 0.000 claims description 7
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 claims description 6
- 239000000347 magnesium hydroxide Substances 0.000 claims description 6
- 229910001862 magnesium hydroxide Inorganic materials 0.000 claims description 6
- BZSXEZOLBIJVQK-UHFFFAOYSA-N 2-methylsulfonylbenzoic acid Chemical group CS(=O)(=O)C1=CC=CC=C1C(O)=O BZSXEZOLBIJVQK-UHFFFAOYSA-N 0.000 claims description 5
- 238000006243 chemical reaction Methods 0.000 claims description 5
- 238000005406 washing Methods 0.000 claims description 5
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 4
- 229910001514 alkali metal chloride Inorganic materials 0.000 claims description 4
- 125000002091 cationic group Chemical group 0.000 claims description 4
- 239000007789 gas Substances 0.000 claims description 4
- 238000005342 ion exchange Methods 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 4
- 238000000746 purification Methods 0.000 claims description 4
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 3
- 239000001257 hydrogen Substances 0.000 claims description 3
- 229910052739 hydrogen Inorganic materials 0.000 claims description 3
- 230000008929 regeneration Effects 0.000 claims description 3
- 238000011069 regeneration method Methods 0.000 claims description 3
- 230000015572 biosynthetic process Effects 0.000 claims description 2
- 239000000356 contaminant Substances 0.000 claims description 2
- 239000003792 electrolyte Substances 0.000 description 25
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 20
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 18
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 17
- 239000010703 silicon Substances 0.000 description 17
- 229910052710 silicon Inorganic materials 0.000 description 17
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 14
- 239000012535 impurity Substances 0.000 description 11
- 239000000243 solution Substances 0.000 description 11
- 238000001914 filtration Methods 0.000 description 10
- 229910000029 sodium carbonate Inorganic materials 0.000 description 10
- 238000005868 electrolysis reaction Methods 0.000 description 8
- 239000011780 sodium chloride Substances 0.000 description 7
- 239000000126 substance Substances 0.000 description 6
- 229910021577 Iron(II) chloride Inorganic materials 0.000 description 5
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 5
- 238000002474 experimental method Methods 0.000 description 5
- NMCUIPGRVMDVDB-UHFFFAOYSA-L iron dichloride Chemical compound Cl[Fe]Cl NMCUIPGRVMDVDB-UHFFFAOYSA-L 0.000 description 5
- 229910052749 magnesium Inorganic materials 0.000 description 5
- 239000011777 magnesium Substances 0.000 description 5
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 4
- 238000005341 cation exchange Methods 0.000 description 4
- 150000001768 cations Chemical class 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 229910001385 heavy metal Inorganic materials 0.000 description 4
- WQYVRQLZKVEZGA-UHFFFAOYSA-N hypochlorite Chemical compound Cl[O-] WQYVRQLZKVEZGA-UHFFFAOYSA-N 0.000 description 4
- 150000002500 ions Chemical class 0.000 description 4
- NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 description 3
- 229910021578 Iron(III) chloride Inorganic materials 0.000 description 3
- 239000003729 cation exchange resin Substances 0.000 description 3
- 238000004140 cleaning Methods 0.000 description 3
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 description 3
- 230000009467 reduction Effects 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- 229910001420 alkaline earth metal ion Inorganic materials 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 239000001110 calcium chloride Substances 0.000 description 2
- 229910001628 calcium chloride Inorganic materials 0.000 description 2
- WUKWITHWXAAZEY-UHFFFAOYSA-L calcium difluoride Chemical compound [F-].[F-].[Ca+2] WUKWITHWXAAZEY-UHFFFAOYSA-L 0.000 description 2
- 229910001634 calcium fluoride Inorganic materials 0.000 description 2
- 235000011132 calcium sulphate Nutrition 0.000 description 2
- 238000000975 co-precipitation Methods 0.000 description 2
- 230000001066 destructive effect Effects 0.000 description 2
- OSVXSBDYLRYLIG-UHFFFAOYSA-N dioxidochlorine(.) Chemical compound O=Cl=O OSVXSBDYLRYLIG-UHFFFAOYSA-N 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 description 2
- 229910021653 sulphate ion Inorganic materials 0.000 description 2
- 229920003043 Cellulose fiber Polymers 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- 239000004155 Chlorine dioxide Substances 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 229910002588 FeOOH Inorganic materials 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical class Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 229910020489 SiO3 Inorganic materials 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 229910000288 alkali metal carbonate Inorganic materials 0.000 description 1
- 150000008041 alkali metal carbonates Chemical class 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 1
- 150000001342 alkaline earth metals Chemical class 0.000 description 1
- 239000012670 alkaline solution Substances 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 229910052788 barium Inorganic materials 0.000 description 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
- 238000004061 bleaching Methods 0.000 description 1
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 1
- 239000000920 calcium hydroxide Substances 0.000 description 1
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 1
- 239000001175 calcium sulphate Substances 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- XTEGARKTQYYJKE-UHFFFAOYSA-N chloric acid Chemical compound OCl(=O)=O XTEGARKTQYYJKE-UHFFFAOYSA-N 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 235000019398 chlorine dioxide Nutrition 0.000 description 1
- 230000001276 controlling effect Effects 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 229910052840 fayalite Inorganic materials 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 235000011167 hydrochloric acid Nutrition 0.000 description 1
- 150000004679 hydroxides Chemical class 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 238000010979 pH adjustment Methods 0.000 description 1
- VKJKEPKFPUWCAS-UHFFFAOYSA-M potassium chlorate Chemical compound [K+].[O-]Cl(=O)=O VKJKEPKFPUWCAS-UHFFFAOYSA-M 0.000 description 1
- 229940088417 precipitated calcium carbonate Drugs 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 238000009938 salting Methods 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 229910052712 strontium Inorganic materials 0.000 description 1
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B11/00—Oxides or oxyacids of halogens; Salts thereof
- C01B11/12—Chloric acid
- C01B11/14—Chlorates
- C01B11/145—Separation; Crystallisation; Purification, After-treatment; Stabilisation by additives
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Removal Of Specific Substances (AREA)
- Silicon Compounds (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
- Treatment Of Water By Ion Exchange (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
SE9300780A SE512074C2 (sv) | 1993-03-09 | 1993-03-09 | Metod att avlägsna kalciumjoner och kiselföreningar från vätska i en alkalimetallkloratprocess |
Publications (3)
Publication Number | Publication Date |
---|---|
NO940762D0 NO940762D0 (no) | 1994-03-04 |
NO940762L NO940762L (no) | 1994-09-12 |
NO311251B1 true NO311251B1 (no) | 2001-11-05 |
Family
ID=20389164
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
NO19940762A NO311251B1 (no) | 1993-03-09 | 1994-03-04 | Fremgangsmåte ved fjerning av kalsiumioner og silisiumforbindelser fra en v¶ske i en alkalimetallklorat-prosess |
Country Status (8)
Country | Link |
---|---|
US (1) | US5356610A (fi) |
BR (1) | BR9400842A (fi) |
CA (1) | CA2095062C (fi) |
ES (1) | ES2095181B1 (fi) |
FI (1) | FI114645B (fi) |
FR (1) | FR2702466B1 (fi) |
NO (1) | NO311251B1 (fi) |
SE (1) | SE512074C2 (fi) |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2009102817A2 (en) * | 2008-02-11 | 2009-08-20 | Auxsol, Inc. | Methods for removing dissolved metallic ions from aqueous solutions |
WO2012143393A1 (en) * | 2011-04-20 | 2012-10-26 | Solvay Sa | Process of purifying a residue with calcium ions |
CN109972163B (zh) * | 2019-01-17 | 2021-02-12 | 广东鑫国泰科技有限公司 | 一种氯酸钠的制备方法 |
CN113800540B (zh) * | 2021-09-30 | 2023-06-02 | 浙江镇洋发展股份有限公司 | 一种离子膜烧碱盐水一次精制除去硅铝的方法 |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CA947010A (en) * | 1971-02-23 | 1974-05-14 | Erco Envirotech Ltd. | Chlorination of alkali metal carbonates recovered from the production of pulp |
JPS5943556B2 (ja) * | 1977-04-20 | 1984-10-23 | 旭化成株式会社 | イオン交換膜を用いた食塩水の電解方法 |
SE461988B (sv) * | 1987-10-21 | 1990-04-23 | Eka Nobel Ab | Saett vid framstaellning av alkalimetallklorat varvid kiselfoeroreningar avlaegsnas |
EP0492727B1 (en) * | 1990-12-28 | 1997-01-29 | Akzo Nobel N.V. | Process for the preparation of sodium chloride |
FR2673423B1 (fr) * | 1991-03-01 | 1994-04-15 | Krebs Cie | Procede d'elimination de sulfates contenus dans des solutions de chlorates alcalins et production desdits chlorates alcalins. |
-
1993
- 1993-03-09 SE SE9300780A patent/SE512074C2/sv not_active IP Right Cessation
- 1993-04-28 CA CA002095062A patent/CA2095062C/en not_active Expired - Lifetime
- 1993-05-06 US US08/057,558 patent/US5356610A/en not_active Expired - Lifetime
-
1994
- 1994-03-04 NO NO19940762A patent/NO311251B1/no not_active IP Right Cessation
- 1994-03-04 FI FI941045A patent/FI114645B/fi not_active IP Right Cessation
- 1994-03-07 FR FR9402591A patent/FR2702466B1/fr not_active Expired - Lifetime
- 1994-03-08 ES ES09400473A patent/ES2095181B1/es not_active Expired - Fee Related
- 1994-03-08 BR BR9400842A patent/BR9400842A/pt not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
FI941045A0 (fi) | 1994-03-04 |
FR2702466A1 (fr) | 1994-09-16 |
NO940762L (no) | 1994-09-12 |
CA2095062A1 (en) | 1994-09-10 |
ES2095181B1 (es) | 1997-09-01 |
FI941045A (fi) | 1994-09-10 |
BR9400842A (pt) | 1994-10-18 |
CA2095062C (en) | 1999-12-21 |
FR2702466B1 (fr) | 1997-01-03 |
SE512074C2 (sv) | 2000-01-24 |
SE9300780L (sv) | 1994-09-10 |
US5356610A (en) | 1994-10-18 |
FI114645B (fi) | 2004-11-30 |
SE9300780D0 (sv) | 1993-03-09 |
NO940762D0 (no) | 1994-03-04 |
ES2095181A1 (es) | 1997-02-01 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
MK1K | Patent expired |