NO119132B - - Google Patents
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- Publication number
- NO119132B NO119132B NO161434A NO16143466A NO119132B NO 119132 B NO119132 B NO 119132B NO 161434 A NO161434 A NO 161434A NO 16143466 A NO16143466 A NO 16143466A NO 119132 B NO119132 B NO 119132B
- Authority
- NO
- Norway
- Prior art keywords
- autoclave
- amorphous
- crystalline
- catalysts
- polymers
- Prior art date
Links
- 229920000642 polymer Polymers 0.000 claims description 129
- 239000003054 catalyst Substances 0.000 claims description 100
- 238000006116 polymerization reaction Methods 0.000 claims description 65
- 239000007787 solid Substances 0.000 claims description 61
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 57
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 57
- 239000002904 solvent Substances 0.000 claims description 37
- 238000004519 manufacturing process Methods 0.000 claims description 32
- 229910052782 aluminium Inorganic materials 0.000 claims description 30
- 239000007788 liquid Substances 0.000 claims description 27
- 229910052751 metal Inorganic materials 0.000 claims description 26
- 239000002184 metal Substances 0.000 claims description 26
- 238000000034 method Methods 0.000 claims description 26
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 23
- 150000001875 compounds Chemical class 0.000 claims description 20
- 230000000737 periodic effect Effects 0.000 claims description 20
- 125000000217 alkyl group Chemical group 0.000 claims description 19
- 229920006125 amorphous polymer Polymers 0.000 claims description 19
- 238000006243 chemical reaction Methods 0.000 claims description 18
- 150000002739 metals Chemical class 0.000 claims description 18
- 150000002902 organometallic compounds Chemical class 0.000 claims description 17
- 125000004432 carbon atom Chemical group C* 0.000 claims description 14
- 238000001914 filtration Methods 0.000 claims description 13
- 229920000098 polyolefin Polymers 0.000 claims description 13
- 229920001580 isotactic polymer Polymers 0.000 claims description 10
- 150000001336 alkenes Chemical class 0.000 claims description 8
- 239000000725 suspension Substances 0.000 claims description 8
- 239000010936 titanium Substances 0.000 claims description 8
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 7
- 238000002425 crystallisation Methods 0.000 claims description 7
- 230000008025 crystallization Effects 0.000 claims description 7
- 238000002360 preparation method Methods 0.000 claims description 7
- 229910052719 titanium Inorganic materials 0.000 claims description 7
- 125000003545 alkoxy group Chemical group 0.000 claims description 6
- 239000004711 α-olefin Substances 0.000 claims description 6
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims description 5
- 239000006185 dispersion Substances 0.000 claims description 5
- 125000005843 halogen group Chemical group 0.000 claims description 5
- 239000001257 hydrogen Substances 0.000 claims description 5
- 229910052739 hydrogen Inorganic materials 0.000 claims description 5
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims description 5
- 230000008569 process Effects 0.000 claims description 5
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 claims description 5
- 229910052726 zirconium Inorganic materials 0.000 claims description 5
- ZSLUVFAKFWKJRC-IGMARMGPSA-N 232Th Chemical compound [232Th] ZSLUVFAKFWKJRC-IGMARMGPSA-N 0.000 claims description 4
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 4
- 229910052776 Thorium Inorganic materials 0.000 claims description 4
- 229910052770 Uranium Inorganic materials 0.000 claims description 4
- 229910052804 chromium Inorganic materials 0.000 claims description 4
- 239000011651 chromium Substances 0.000 claims description 4
- 150000002894 organic compounds Chemical class 0.000 claims description 4
- DNYWZCXLKNTFFI-UHFFFAOYSA-N uranium Chemical compound [U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U] DNYWZCXLKNTFFI-UHFFFAOYSA-N 0.000 claims description 4
- 229910052720 vanadium Inorganic materials 0.000 claims description 4
- 238000005119 centrifugation Methods 0.000 claims description 3
- 238000010908 decantation Methods 0.000 claims description 3
- 238000009826 distribution Methods 0.000 claims description 3
- 150000004820 halides Chemical class 0.000 claims description 3
- 238000004062 sedimentation Methods 0.000 claims description 3
- 230000003068 static effect Effects 0.000 claims description 3
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 2
- 239000010419 fine particle Substances 0.000 claims description 2
- 229910052749 magnesium Inorganic materials 0.000 claims description 2
- 239000011777 magnesium Substances 0.000 claims description 2
- 238000010297 mechanical methods and process Methods 0.000 claims description 2
- 238000000053 physical method Methods 0.000 claims description 2
- 239000011949 solid catalyst Substances 0.000 claims description 2
- 229910052725 zinc Inorganic materials 0.000 claims description 2
- 239000011701 zinc Substances 0.000 claims description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims 1
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 191
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 99
- 239000000047 product Substances 0.000 description 78
- -1 polypropylenes Polymers 0.000 description 65
- 229920001155 polypropylene Polymers 0.000 description 62
- 239000004743 Polypropylene Substances 0.000 description 59
- 229910001385 heavy metal Inorganic materials 0.000 description 43
- 230000033001 locomotion Effects 0.000 description 43
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 42
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 38
- 238000000605 extraction Methods 0.000 description 37
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 36
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 30
- 239000003708 ampul Substances 0.000 description 30
- 239000000203 mixture Substances 0.000 description 26
- YONPGGFAJWQGJC-UHFFFAOYSA-K titanium(iii) chloride Chemical compound Cl[Ti](Cl)Cl YONPGGFAJWQGJC-UHFFFAOYSA-K 0.000 description 25
- 150000002736 metal compounds Chemical class 0.000 description 24
- VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 22
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 21
- 229910052757 nitrogen Inorganic materials 0.000 description 21
- CXWXQJXEFPUFDZ-UHFFFAOYSA-N tetralin Chemical compound C1=CC=C2CCCCC2=C1 CXWXQJXEFPUFDZ-UHFFFAOYSA-N 0.000 description 21
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 21
- 239000011521 glass Substances 0.000 description 20
- 239000012299 nitrogen atmosphere Substances 0.000 description 19
- 238000003756 stirring Methods 0.000 description 18
- 239000000284 extract Substances 0.000 description 17
- 239000000126 substance Substances 0.000 description 17
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 16
- 229910000831 Steel Inorganic materials 0.000 description 15
- 239000010959 steel Substances 0.000 description 15
- 229910052799 carbon Inorganic materials 0.000 description 13
- 239000007795 chemical reaction product Substances 0.000 description 13
- 230000015572 biosynthetic process Effects 0.000 description 12
- 239000003245 coal Substances 0.000 description 12
- RYPKRALMXUUNKS-UHFFFAOYSA-N 2-Hexene Natural products CCCC=CC RYPKRALMXUUNKS-UHFFFAOYSA-N 0.000 description 10
- 239000007789 gas Substances 0.000 description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 10
- 239000012259 ether extract Substances 0.000 description 8
- 229920001083 polybutene Polymers 0.000 description 8
- 238000000746 purification Methods 0.000 description 8
- 229910001220 stainless steel Inorganic materials 0.000 description 7
- 239000010935 stainless steel Substances 0.000 description 7
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 6
- 229910010062 TiCl3 Inorganic materials 0.000 description 6
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
- 229910021552 Vanadium(IV) chloride Inorganic materials 0.000 description 6
- IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 description 6
- 239000000178 monomer Substances 0.000 description 6
- 239000002244 precipitate Substances 0.000 description 6
- 150000003609 titanium compounds Chemical class 0.000 description 6
- JTJFQBNJBPPZRI-UHFFFAOYSA-J vanadium tetrachloride Chemical compound Cl[V](Cl)(Cl)Cl JTJFQBNJBPPZRI-UHFFFAOYSA-J 0.000 description 6
- 230000008859 change Effects 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- UBZYKBZMAMTNKW-UHFFFAOYSA-J titanium tetrabromide Chemical compound Br[Ti](Br)(Br)Br UBZYKBZMAMTNKW-UHFFFAOYSA-J 0.000 description 5
- MTAYDNKNMILFOK-UHFFFAOYSA-K titanium(3+);tribromide Chemical compound Br[Ti](Br)Br MTAYDNKNMILFOK-UHFFFAOYSA-K 0.000 description 5
- 238000005406 washing Methods 0.000 description 5
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 4
- 229910003074 TiCl4 Inorganic materials 0.000 description 4
- 238000009835 boiling Methods 0.000 description 4
- 239000000706 filtrate Substances 0.000 description 4
- 238000010907 mechanical stirring Methods 0.000 description 4
- 239000011148 porous material Substances 0.000 description 4
- 239000011541 reaction mixture Substances 0.000 description 4
- 239000007790 solid phase Substances 0.000 description 4
- 239000007858 starting material Substances 0.000 description 4
- 125000001424 substituent group Chemical group 0.000 description 4
- ZWYDDDAMNQQZHD-UHFFFAOYSA-L titanium(ii) chloride Chemical compound [Cl-].[Cl-].[Ti+2] ZWYDDDAMNQQZHD-UHFFFAOYSA-L 0.000 description 4
- 229910021551 Vanadium(III) chloride Inorganic materials 0.000 description 3
- 239000013078 crystal Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 229920001971 elastomer Polymers 0.000 description 3
- 239000000806 elastomer Substances 0.000 description 3
- 238000001704 evaporation Methods 0.000 description 3
- 230000008020 evaporation Effects 0.000 description 3
- 238000002474 experimental method Methods 0.000 description 3
- 238000002329 infrared spectrum Methods 0.000 description 3
- 238000002844 melting Methods 0.000 description 3
- 230000008018 melting Effects 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 239000002685 polymerization catalyst Substances 0.000 description 3
- 239000012265 solid product Substances 0.000 description 3
- HUYLAMJIPCOVOM-UHFFFAOYSA-K triiodotitanium Chemical compound [Ti+3].[I-].[I-].[I-] HUYLAMJIPCOVOM-UHFFFAOYSA-K 0.000 description 3
- 230000007306 turnover Effects 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 229910021556 Chromium(III) chloride Inorganic materials 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 150000001450 anions Chemical class 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 229960000359 chromic chloride Drugs 0.000 description 2
- QSWDMMVNRMROPK-UHFFFAOYSA-K chromium(3+) trichloride Chemical compound [Cl-].[Cl-].[Cl-].[Cr+3] QSWDMMVNRMROPK-UHFFFAOYSA-K 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 230000015271 coagulation Effects 0.000 description 2
- 238000005345 coagulation Methods 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 238000005188 flotation Methods 0.000 description 2
- 238000005194 fractionation Methods 0.000 description 2
- 229910052735 hafnium Inorganic materials 0.000 description 2
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 description 2
- 229910052736 halogen Inorganic materials 0.000 description 2
- 150000002367 halogens Chemical class 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- 229910052750 molybdenum Inorganic materials 0.000 description 2
- 239000011733 molybdenum Substances 0.000 description 2
- 229910052758 niobium Inorganic materials 0.000 description 2
- 239000010955 niobium Substances 0.000 description 2
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 description 2
- 125000002524 organometallic group Chemical group 0.000 description 2
- 229920001748 polybutylene Polymers 0.000 description 2
- 229920001289 polyvinyl ether Polymers 0.000 description 2
- 239000012429 reaction media Substances 0.000 description 2
- 229920006395 saturated elastomer Polymers 0.000 description 2
- 229910052715 tantalum Inorganic materials 0.000 description 2
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 description 2
- IAQRGUVFOMOMEM-ONEGZZNKSA-N trans-but-2-ene Chemical compound C\C=C\C IAQRGUVFOMOMEM-ONEGZZNKSA-N 0.000 description 2
- ORYGRKHDLWYTKX-UHFFFAOYSA-N trihexylalumane Chemical compound CCCCCC[Al](CCCCCC)CCCCCC ORYGRKHDLWYTKX-UHFFFAOYSA-N 0.000 description 2
- CNWZYDSEVLFSMS-UHFFFAOYSA-N tripropylalumane Chemical compound CCC[Al](CCC)CCC CNWZYDSEVLFSMS-UHFFFAOYSA-N 0.000 description 2
- USJZIJNMRRNDPO-UHFFFAOYSA-N tris-decylalumane Chemical compound CCCCCCCCCC[Al](CCCCCCCCCC)CCCCCCCCCC USJZIJNMRRNDPO-UHFFFAOYSA-N 0.000 description 2
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 2
- 229910052721 tungsten Inorganic materials 0.000 description 2
- 239000010937 tungsten Substances 0.000 description 2
- HQYCOEXWFMFWLR-UHFFFAOYSA-K vanadium(iii) chloride Chemical compound [Cl-].[Cl-].[Cl-].[V+3] HQYCOEXWFMFWLR-UHFFFAOYSA-K 0.000 description 2
- 229920002554 vinyl polymer Polymers 0.000 description 2
- PFXYQVJESZAMSV-UHFFFAOYSA-K zirconium(iii) chloride Chemical compound Cl[Zr](Cl)Cl PFXYQVJESZAMSV-UHFFFAOYSA-K 0.000 description 2
- WPWHSFAFEBZWBB-UHFFFAOYSA-N 1-butyl radical Chemical compound [CH2]CCC WPWHSFAFEBZWBB-UHFFFAOYSA-N 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 229910011011 Ti(OH)4 Inorganic materials 0.000 description 1
- 101100497923 Viola odorata Voc1 gene Proteins 0.000 description 1
- 238000002441 X-ray diffraction Methods 0.000 description 1
- 229910007926 ZrCl Inorganic materials 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 125000002723 alicyclic group Chemical group 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 125000002947 alkylene group Chemical group 0.000 description 1
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical compound [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 229910052790 beryllium Inorganic materials 0.000 description 1
- ATBAMAFKBVZNFJ-UHFFFAOYSA-N beryllium atom Chemical compound [Be] ATBAMAFKBVZNFJ-UHFFFAOYSA-N 0.000 description 1
- 230000033228 biological regulation Effects 0.000 description 1
- KKSAZXGYGLKVSV-UHFFFAOYSA-N butan-1-ol;titanium Chemical compound [Ti].CCCCO KKSAZXGYGLKVSV-UHFFFAOYSA-N 0.000 description 1
- VJVUKRSEEMNRCM-UHFFFAOYSA-L butan-1-olate titanium(4+) dichloride Chemical compound [Cl-].[Cl-].CCCCO[Ti+2]OCCCC VJVUKRSEEMNRCM-UHFFFAOYSA-L 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 229910052793 cadmium Inorganic materials 0.000 description 1
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 1
- 150000001721 carbon Chemical group 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- UGWBWPXTGFPEFG-UHFFFAOYSA-N chloro hypochlorite chromium Chemical compound [Cr].ClOCl UGWBWPXTGFPEFG-UHFFFAOYSA-N 0.000 description 1
- AHXGRMIPHCAXFP-UHFFFAOYSA-L chromyl dichloride Chemical compound Cl[Cr](Cl)(=O)=O AHXGRMIPHCAXFP-UHFFFAOYSA-L 0.000 description 1
- 239000010724 circulating oil Substances 0.000 description 1
- 238000001246 colloidal dispersion Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- YNLAOSYQHBDIKW-UHFFFAOYSA-M diethylaluminium chloride Chemical compound CC[Al](Cl)CC YNLAOSYQHBDIKW-UHFFFAOYSA-M 0.000 description 1
- CQYBWJYIKCZXCN-UHFFFAOYSA-N diethylaluminum Chemical compound CC[Al]CC CQYBWJYIKCZXCN-UHFFFAOYSA-N 0.000 description 1
- XNMQEEKYCVKGBD-UHFFFAOYSA-N dimethylacetylene Natural products CC#CC XNMQEEKYCVKGBD-UHFFFAOYSA-N 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 230000036571 hydration Effects 0.000 description 1
- 238000006703 hydration reaction Methods 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 description 1
- 150000002484 inorganic compounds Chemical class 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 238000002386 leaching Methods 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 239000012263 liquid product Substances 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 150000005309 metal halides Chemical class 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 230000002085 persistent effect Effects 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 239000005373 porous glass Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- JTXAHXNXKFGXIT-UHFFFAOYSA-N propane;prop-1-ene Chemical group CCC.CC=C JTXAHXNXKFGXIT-UHFFFAOYSA-N 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 238000000638 solvent extraction Methods 0.000 description 1
- 230000002269 spontaneous effect Effects 0.000 description 1
- LLZRNZOLAXHGLL-UHFFFAOYSA-J titanic acid Chemical compound O[Ti](O)(O)O LLZRNZOLAXHGLL-UHFFFAOYSA-J 0.000 description 1
- NLLZTRMHNHVXJJ-UHFFFAOYSA-J titanium tetraiodide Chemical compound I[Ti](I)(I)I NLLZTRMHNHVXJJ-UHFFFAOYSA-J 0.000 description 1
- VXUYXOFXAQZZMF-UHFFFAOYSA-N titanium(IV) isopropoxide Chemical compound CC(C)O[Ti](OC(C)C)(OC(C)C)OC(C)C VXUYXOFXAQZZMF-UHFFFAOYSA-N 0.000 description 1
- SQBBHCOIQXKPHL-UHFFFAOYSA-N tributylalumane Chemical compound CCCC[Al](CCCC)CCCC SQBBHCOIQXKPHL-UHFFFAOYSA-N 0.000 description 1
- NHADXUOUFVKVEB-UHFFFAOYSA-N trihexadecylalumane Chemical compound CCCCCCCCCCCCCCCC[Al](CCCCCCCCCCCCCCCC)CCCCCCCCCCCCCCCC NHADXUOUFVKVEB-UHFFFAOYSA-N 0.000 description 1
- MCULRUJILOGHCJ-UHFFFAOYSA-N triisobutylaluminium Chemical compound CC(C)C[Al](CC(C)C)CC(C)C MCULRUJILOGHCJ-UHFFFAOYSA-N 0.000 description 1
- JBIQAPKSNFTACH-UHFFFAOYSA-K vanadium oxytrichloride Chemical compound Cl[V](Cl)(Cl)=O JBIQAPKSNFTACH-UHFFFAOYSA-K 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- DUNKXUFBGCUVQW-UHFFFAOYSA-J zirconium tetrachloride Chemical compound Cl[Zr](Cl)(Cl)Cl DUNKXUFBGCUVQW-UHFFFAOYSA-J 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D5/00—Rigid or semi-rigid containers of polygonal cross-section, e.g. boxes, cartons or trays, formed by folding or erecting one or more blanks made of paper
- B65D5/02—Rigid or semi-rigid containers of polygonal cross-section, e.g. boxes, cartons or trays, formed by folding or erecting one or more blanks made of paper by folding or erecting a single blank to form a tubular body with or without subsequent folding operations, or the addition of separate elements, to close the ends of the body
- B65D5/06—Rigid or semi-rigid containers of polygonal cross-section, e.g. boxes, cartons or trays, formed by folding or erecting one or more blanks made of paper by folding or erecting a single blank to form a tubular body with or without subsequent folding operations, or the addition of separate elements, to close the ends of the body with end-closing or contents-supporting elements formed by folding inwardly a wall extending from, and continuously around, an end of the tubular body
- B65D5/064—Rectangular containers having a body with gusset-flaps folded outwardly or adhered to the side or the top of the container
- B65D5/065—Rectangular containers having a body with gusset-flaps folded outwardly or adhered to the side or the top of the container with supplemental means facilitating the opening, e.g. tear lines, tear tabs
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CH125565A CH429571A (de) | 1965-01-29 | 1965-01-29 | Parallelepipedisches Paket aus einem biegsamen, relativ steifen, zu einer Röhre geformten Bahnmaterial |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| NO119132B true NO119132B (de) | 1970-03-23 |
Family
ID=4206101
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| NO161434A NO119132B (de) | 1965-01-29 | 1966-01-26 |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US3347444A (de) |
| BE (1) | BE675250A (de) |
| BR (1) | BR6676791D0 (de) |
| CH (1) | CH429571A (de) |
| DE (1) | DE1298929B (de) |
| DK (1) | DK113549B (de) |
| FI (1) | FI44208B (de) |
| GB (1) | GB1078901A (de) |
| NL (1) | NL149757B (de) |
| NO (1) | NO119132B (de) |
Families Citing this family (33)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| SE332386C (sv) * | 1969-10-20 | 1972-05-10 | Tetra Pak Int | Öppningsanordning vid förpackningar |
| CH546184A (de) * | 1971-01-11 | 1974-02-28 | Altstaedter Verpack Vertrieb | Verpackung fuer fluessigkeiten aus karton oder papier und verfahren zur herstellung der verpackung. |
| US3795359A (en) * | 1971-11-19 | 1974-03-05 | Tetra Pak Int | Parallellepipedic package |
| DE2520569C2 (de) * | 1975-05-09 | 1982-10-21 | Altstädter Verpackungs-Vertriebsgesellschaft mbH, 6102 Pfungstadt | Verpackung für Flüssigkeiten mit Ausgießtülle |
| SE422672B (sv) * | 1976-07-08 | 1982-03-22 | Ziristor Ab | Med oppningsanordning forsedd forpackningsbehallare |
| JPS5390530U (de) * | 1976-12-24 | 1978-07-25 | ||
| DE2707321C2 (de) * | 1977-02-19 | 1979-04-26 | Papier- Und Kunststoff-Werke Linnich Gmbh, 4000 Duesseldorf | Faltschachtel für Schüttgüter |
| SE404005B (sv) * | 1977-05-26 | 1978-09-18 | Tetra Pak Int | Forpackning med vetsketet rivoppningsperforering |
| SE406177B (sv) * | 1977-06-20 | 1979-01-29 | Tetra Pak Int | Forpackningsbehallare med utvikbar hellpip |
| DE2854775C2 (de) * | 1978-12-19 | 1984-09-06 | Tetra Pak International AB, Lund | Quaderförmige Verpackung |
| SE418164B (sv) * | 1979-08-22 | 1981-05-11 | Tetra Pak Int | Forpacknigsbehallare av det slag som uppvisar en forseglingsfena |
| SE451317B (sv) * | 1982-03-18 | 1987-09-28 | Tetra Pak Ab | Forpackning |
| DE3226879A1 (de) * | 1982-07-17 | 1984-01-19 | Altstädter Verpackungsvertriebs Gesellschaft mbH, 6102 Pfungstadt | Oeffnungsmittel an einer parallelepipedischen packung fuer fliessfaehiges fuellgut |
| DE3301086C2 (de) * | 1983-01-14 | 1985-10-03 | PKL Papier- und Kunststoff-Werke Linnich GmbH, 4000 Düsseldorf | Packung auf flächigem Material, wie z.B. Papier, Karton o.dgl. insbesondere quaderförmige Flüssigkeitspackung aus Papier-Kunststoff- Verbund-Material |
| SE451320B (sv) * | 1983-02-07 | 1987-09-28 | Tetra Pak Ab | Oppningsanordning for forpackning |
| IL71516A0 (en) * | 1983-05-04 | 1984-07-31 | Int Paper Co | Carton with hinged opening and perforated hinged opening |
| US4771916A (en) * | 1983-06-08 | 1988-09-20 | Ocean Spray Corporation | Pivotal spout with cutter for dispensing liquids from multi-layered laminate containers |
| DE3406962C1 (de) * | 1984-02-25 | 1985-11-14 | PKL Papier- und Kunststoff-Werke Linnich GmbH, 4000 Düsseldorf | Packung aus flaechenfoermigem Material,wie z.B. Papier,Karton o.dgl.,insbesondere quaderfoermige Fluessigkeitspackung aus Papier-Kunststoff- Verbundmaterial |
| USRE32891E (en) * | 1984-05-10 | 1989-03-21 | International Paper Company | Pouring spout opening configuration for a gable top of a container |
| GB2190658B (en) * | 1986-03-24 | 1989-12-13 | Hans Rausing | Packing containers and blanks therefor |
| EP0300211A1 (de) * | 1987-07-23 | 1989-01-25 | PKL Verpackungssysteme GmbH | Packung aus flächigem Material, wie Papier, Karton oder dergleichen, insbesondere quaderförmige Flüssigkeitspackung aus Karton-Kunststoff-Verbundmaterial |
| US5080233A (en) * | 1990-11-21 | 1992-01-14 | Minnesota Mining And Manufacturing Company | Gable top container having reduced opening force and method for construction therefor |
| FR2704519B1 (fr) * | 1993-04-26 | 1995-08-04 | Marin Jean Jacques | Perfectionnements aux boites en carton du type soude. |
| EP0709294A1 (de) * | 1994-10-27 | 1996-05-01 | Jean-Jacques Marin | Verschweisste Faltschachtel |
| US5601233A (en) * | 1994-10-28 | 1997-02-11 | Kao Corporation | Container |
| US5694746A (en) * | 1994-12-20 | 1997-12-09 | Chung; Yun H. | Paperboard package and method for forming same |
| SE508859C2 (sv) | 1997-03-21 | 1998-11-09 | Tetra Laval Holdings & Finance | Metod för tillverkning av perforeringsverktyg samt perforeringsverktyg enligt metoden |
| BR9808463A (pt) * | 1997-04-04 | 2000-08-29 | Sig Combibloc Inc | Embalagem e processos para fabricar uma embalagem possuindo uma abertura por rasgamento e para abrir uma embalagem |
| US6766941B1 (en) | 1998-02-09 | 2004-07-27 | Sig Combibloc, Inc. | Tear-away container top |
| US6098874A (en) * | 1998-02-09 | 2000-08-08 | Sig Combibloc Inc. | Tear-away container top |
| US6241646B1 (en) | 1998-02-09 | 2001-06-05 | Sig Combibloc Inc. | Tear-away container spout |
| US6622892B2 (en) | 2002-01-28 | 2003-09-23 | Tetra Laval Holdings & Finance, Sa | Sleeve and dispenser for brick-type package |
| WO2005110869A1 (en) * | 2004-05-17 | 2005-11-24 | Sealed Air (New Zealand) | Improvements to packages and packaging methods |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2305631A (en) * | 1940-07-06 | 1942-12-22 | Shellmar Products Co | Package opening device |
| GB1008353A (en) * | 1963-01-16 | 1965-10-27 | Tetra Pak Ab | Improvements in and relating to filled and sealed packages |
| US3279678A (en) * | 1963-01-16 | 1966-10-18 | Lindh Thorsten Lennartson | Filled and sealed package having reinforcing side panels |
| BE642600A (de) * | 1964-01-16 | 1964-05-15 |
-
1965
- 1965-01-29 CH CH125565A patent/CH429571A/de unknown
-
1966
- 1966-01-03 GB GB12066A patent/GB1078901A/en not_active Expired
- 1966-01-03 US US518236A patent/US3347444A/en not_active Expired - Lifetime
- 1966-01-18 DE DET30274A patent/DE1298929B/de active Pending
- 1966-01-18 BE BE675250D patent/BE675250A/xx not_active IP Right Cessation
- 1966-01-18 FI FI0130/66A patent/FI44208B/fi active
- 1966-01-19 NL NL666600713A patent/NL149757B/xx not_active IP Right Cessation
- 1966-01-26 NO NO161434A patent/NO119132B/no unknown
- 1966-01-28 DK DK47366AA patent/DK113549B/da unknown
- 1966-01-28 BR BR176791/66A patent/BR6676791D0/pt unknown
Also Published As
| Publication number | Publication date |
|---|---|
| US3347444A (en) | 1967-10-17 |
| GB1078901A8 (en) | 1969-01-01 |
| GB1078901A (en) | 1967-08-09 |
| CH429571A (de) | 1967-01-31 |
| NL149757B (nl) | 1976-06-15 |
| FI44208B (de) | 1971-06-01 |
| BR6676791D0 (pt) | 1973-02-06 |
| DE1298929B (de) | 1969-07-03 |
| DK113549B (da) | 1969-03-31 |
| NL6600713A (de) | 1966-08-01 |
| BE675250A (de) | 1966-05-16 |
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