NL181806C - Werkwijze voor het bereiden van asymmetrische difosfinen, werkwijze voor het bereiden van katalytische rhodiumhalogenide-complexen met toepassing van ten minste een aldus bereid difosfine alsmede werkwijze voor het asymmetrisch hydrogeneren van gesubstitueerde acrylzuren en -esters met toepassing van een aldus bereid rhodiumhalogenide-complex. - Google Patents
Werkwijze voor het bereiden van asymmetrische difosfinen, werkwijze voor het bereiden van katalytische rhodiumhalogenide-complexen met toepassing van ten minste een aldus bereid difosfine alsmede werkwijze voor het asymmetrisch hydrogeneren van gesubstitueerde acrylzuren en -esters met toepassing van een aldus bereid rhodiumhalogenide-complex.Info
- Publication number
- NL181806C NL181806C NLAANVRAGE7406409,A NL7406409A NL181806C NL 181806 C NL181806 C NL 181806C NL 7406409 A NL7406409 A NL 7406409A NL 181806 C NL181806 C NL 181806C
- Authority
- NL
- Netherlands
- Prior art keywords
- methyl
- preparing
- methycles
- hydroxydry
- hydroscry
- Prior art date
Links
- 230000003197 catalytic effect Effects 0.000 title 1
- 238000004519 manufacturing process Methods 0.000 title 1
- 238000000034 method Methods 0.000 title 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
- B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
- B01J31/2409—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring with more than one complexing phosphine-P atom
- B01J31/2414—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring with more than one complexing phosphine-P atom comprising aliphatic or saturated rings
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
- B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
- B01J31/2442—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising condensed ring systems
- B01J31/2447—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising condensed ring systems and phosphine-P atoms as substituents on a ring of the condensed system or on a further attached ring
- B01J31/2452—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising condensed ring systems and phosphine-P atoms as substituents on a ring of the condensed system or on a further attached ring with more than one complexing phosphine-P atom
- B01J31/2457—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising condensed ring systems and phosphine-P atoms as substituents on a ring of the condensed system or on a further attached ring with more than one complexing phosphine-P atom comprising aliphatic or saturated rings, e.g. Xantphos
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
- C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
- C07F15/0073—Rhodium compounds
- C07F15/008—Rhodium compounds without a metal-carbon linkage
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/50—Organo-phosphines
- C07F9/5027—Polyphosphines
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/60—Reduction reactions, e.g. hydrogenation
- B01J2231/64—Reductions in general of organic substrates, e.g. hydride reductions or hydrogenations
- B01J2231/641—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes
- B01J2231/645—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes of C=C or C-C triple bonds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/82—Metals of the platinum group
- B01J2531/822—Rhodium
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Heterocyclic Compounds That Contain Two Or More Ring Oxygen Atoms (AREA)
- Indole Compounds (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR7318319A FR2230654B1 (ja) | 1973-05-21 | 1973-05-21 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| NL7406409A NL7406409A (ja) | 1974-11-25 |
| NL181806B NL181806B (nl) | 1987-06-01 |
| NL181806C true NL181806C (nl) | 1987-11-02 |
Family
ID=9119644
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| NLAANVRAGE7406409,A NL181806C (nl) | 1973-05-21 | 1974-05-13 | Werkwijze voor het bereiden van asymmetrische difosfinen, werkwijze voor het bereiden van katalytische rhodiumhalogenide-complexen met toepassing van ten minste een aldus bereid difosfine alsmede werkwijze voor het asymmetrisch hydrogeneren van gesubstitueerde acrylzuren en -esters met toepassing van een aldus bereid rhodiumhalogenide-complex. |
Country Status (12)
| Country | Link |
|---|---|
| US (3) | US3949000A (ja) |
| JP (2) | JPS5835999B2 (ja) |
| AT (2) | AT327948B (ja) |
| BE (1) | BE815299A (ja) |
| CH (1) | CH588890A5 (ja) |
| DE (1) | DE2424543C2 (ja) |
| FR (1) | FR2230654B1 (ja) |
| GB (1) | GB1452196A (ja) |
| HU (2) | HU174375B (ja) |
| IT (1) | IT1017624B (ja) |
| NL (1) | NL181806C (ja) |
| SU (1) | SU615852A3 (ja) |
Families Citing this family (38)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4008281A (en) * | 1973-12-03 | 1977-02-15 | Monsanto Company | Asymmetric catalysis |
| US4115417A (en) * | 1975-10-16 | 1978-09-19 | Hoffmann-La Roche Inc. | Asymmetric hydrogenation catalyzed by rhodium complexes of chiral tertiary phosphines |
| US4193943A (en) * | 1976-01-19 | 1980-03-18 | Celanese Corporation | Hydroformylation catalysts |
| US4139565A (en) * | 1977-03-31 | 1979-02-13 | Celanese Corporation | Hydroformylation using improved catalysts comprising rhodium and diphosphino ligands |
| JPS6056984B2 (ja) * | 1977-04-07 | 1985-12-12 | 日立プラント建設株式会社 | 冷凍庫 |
| US4166824A (en) * | 1977-06-14 | 1979-09-04 | American Cyanamid Company | Chiral rhodium-diphosphine catalyst capable of catalytic reduction of a tetramisole precursor to give a significant excess of the desired S-(-)isomer, levamisole |
| US4168381A (en) * | 1977-06-14 | 1979-09-18 | American Cyanamid Company | Enhancement of enantioselectivity by iodide salts of Rh(I) complexes in the reduction of prochiral imidazolinones |
| US4120870A (en) * | 1977-07-18 | 1978-10-17 | Hoffmann-La Roche Inc. | Metal phosphine complex |
| FR2422676A1 (fr) * | 1977-07-18 | 1979-11-09 | Hoffmann La Roche | Complexes catalytiques de phosphorines metalliques |
| US4201714A (en) * | 1977-08-19 | 1980-05-06 | Celanese Corporation | Stabilized catalyst complex of rhodium metal, bidentate ligand and monodentate ligand |
| US4137404A (en) * | 1977-12-20 | 1979-01-30 | Hoffmann-La Roche Inc. | Synthesis of tryptophans |
| US4216008A (en) * | 1978-05-22 | 1980-08-05 | Hoffmann-La Roche Inc. | Butenoic acid derivatives |
| US4616038A (en) * | 1978-07-24 | 1986-10-07 | Merck & Co., Inc. | Combination of thienamycin-type antibiotics with dipeptidase inhibitors |
| US4880793A (en) * | 1978-07-24 | 1989-11-14 | Merck & Co., Inc. | Combination of thienamycin-type antibiotics with dipeptidase inhibitors |
| US5147868A (en) * | 1978-07-24 | 1992-09-15 | Merck & Co., Inc. | Thienamycin renal peptidase inhibitors |
| US4230860A (en) * | 1978-11-06 | 1980-10-28 | American Cyanamid Company | Processes for the separation of enantiomers by selective crystallization |
| US4221744A (en) * | 1978-12-01 | 1980-09-09 | Celanese Corporation | Hydroformylation process employing rhodium-based catalysts comprising ligands having electronegative substituents |
| DE2908358A1 (de) * | 1979-03-03 | 1980-09-11 | Basf Ag | Optisch aktive tertiaere phosphinoxide und tertiaere phosphine, verfahren zu deren herstellung und verwendung der optisch aktiven tertiaeren phosphine fuer asymmetrische synthesen |
| US4539208A (en) * | 1980-09-17 | 1985-09-03 | Merck & Co., Inc. | Combination of thienamycin-type antibiotics with dipeptidase inhibitors |
| US4316847A (en) * | 1979-07-30 | 1982-02-23 | Hoffmann-La Roche Inc. | Pyrroles and pyrrolidines |
| DE3000445C2 (de) * | 1980-01-08 | 1982-12-02 | Degussa Ag, 6000 Frankfurt | Rhodiumkomplexe und deren Verwendung |
| US4331818A (en) * | 1980-03-19 | 1982-05-25 | The Procter & Gamble Company | Chiral phospine ligand |
| US4376870A (en) * | 1980-12-05 | 1983-03-15 | Monsanto Company | Optically active phosphine compounds |
| US4393240A (en) * | 1981-07-06 | 1983-07-12 | Stille John K | Optically active phosphines |
| FR2549840B1 (fr) * | 1983-07-28 | 1986-03-21 | Rhone Poulenc Sante | Nouvelles phosphines chirales sulfonees, leur preparation et leur emploi en catalyse asymetrique |
| JPS6061587A (ja) * | 1983-09-16 | 1985-04-09 | Takasago Corp | ロジウム−ホスフイン錯体 |
| JPS60199898A (ja) * | 1984-03-22 | 1985-10-09 | Takasago Corp | ロジウム−ホスフイン錯体 |
| US4694109A (en) * | 1986-06-13 | 1987-09-15 | Eastman Kodak Company | Chelate ligands for low pressure hydroformylation catalyst and process employing same |
| US4879398A (en) * | 1987-12-31 | 1989-11-07 | Monsanto Company | Process for producing 2,6-disubstituted tyrosine |
| US4912221A (en) * | 1988-10-27 | 1990-03-27 | Occidental Chemical Corporation | Chiral 1,2,3,4-tetrahydroisoquinoline-3-carboxylic acid and precursors and preparation thereof |
| SG43803A1 (en) * | 1991-01-25 | 1997-11-14 | Ciba Geigy Ag | Diphosphines containing silane groups immobilised diphosphines and the use thereof as hydrogenation catalyst |
| WO1993021192A1 (en) * | 1992-04-13 | 1993-10-28 | Research Corporation Technologies, Inc. | Process for the hydrogenation of aryl phosphines and products obttained therefrom |
| US5334791A (en) * | 1992-05-22 | 1994-08-02 | Ligands Inc. | Hydrogenation process with transition metal catalysts derived from bifunctional phosphorus-nitrogen ligands |
| US5288912A (en) * | 1993-02-12 | 1994-02-22 | Eastman Kodak Company | Process for the preparation of lithium diarylphosphides and alkylated derivatives thereof |
| US5332846A (en) * | 1993-06-01 | 1994-07-26 | Eastman Kodak Company | Hydroformylation process using novel phosphine-rhodium catalyst system |
| US5481006A (en) * | 1994-01-11 | 1996-01-02 | E. I. Du Pont De Nemours And Company | Selective asymmetric hydrogenation of dehydroamino acid derivatives using rhodium and iridium diphosphinite carbohydrate catalyst compositions |
| DE19619527A1 (de) * | 1996-05-15 | 1997-11-20 | Hoechst Ag | Katalysatorsysteme auf der Basis von Rhodium-Komplexverbindungen mit Diphosphin-Liganden und ihre Verwendung bei der Herstellung von Aldehyden |
| US5567856A (en) * | 1995-05-30 | 1996-10-22 | Hoechst Celanese Corporation | Synthesis of and hydroformylation with fluoro-substituted bidentate phosphine ligands |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3489786A (en) * | 1964-12-10 | 1970-01-13 | Shell Oil Co | Hydrogenation process |
| US3849480A (en) * | 1968-09-09 | 1974-11-19 | Monsanto Co | Catalytic asymmetric hydrogenation |
| FR2116904A5 (fr) | 1970-12-09 | 1972-07-21 | Crouzet Sa | Element temporisateur modulaire pour programmateur |
| FR2116905A5 (fr) * | 1970-12-10 | 1972-07-21 | Inst Francais Du Petrole | Nouveaux coordinats bidentes,leur fabrication et leurs applications |
-
1973
- 1973-05-21 FR FR7318319A patent/FR2230654B1/fr not_active Expired
-
1974
- 1974-05-13 NL NLAANVRAGE7406409,A patent/NL181806C/xx not_active IP Right Cessation
- 1974-05-17 JP JP49055328A patent/JPS5835999B2/ja not_active Expired
- 1974-05-17 US US05/470,866 patent/US3949000A/en not_active Expired - Lifetime
- 1974-05-20 HU HU74RO905A patent/HU174375B/hu unknown
- 1974-05-20 BE BE144545A patent/BE815299A/xx not_active IP Right Cessation
- 1974-05-20 HU HURO782A patent/HU170057B/hu unknown
- 1974-05-20 GB GB2234374A patent/GB1452196A/en not_active Expired
- 1974-05-20 CH CH689774A patent/CH588890A5/xx not_active IP Right Cessation
- 1974-05-21 IT IT23037/74A patent/IT1017624B/it active
- 1974-05-21 DE DE2424543A patent/DE2424543C2/de not_active Expired
- 1974-05-21 AT AT420774A patent/AT327948B/de not_active IP Right Cessation
- 1974-10-18 AT AT839174A patent/AT339287B/de not_active IP Right Cessation
-
1975
- 1975-01-14 SU SU752093088A patent/SU615852A3/ru active
- 1975-06-25 US US05/590,091 patent/US4010181A/en not_active Expired - Lifetime
- 1975-06-25 US US05/590,319 patent/US3978101A/en not_active Expired - Lifetime
-
1981
- 1981-10-28 JP JP56172663A patent/JPS57102853A/ja active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| AT339287B (de) | 1977-10-10 |
| JPS5835999B2 (ja) | 1983-08-05 |
| NL7406409A (ja) | 1974-11-25 |
| ATA420774A (de) | 1975-05-15 |
| IT1017624B (it) | 1977-08-10 |
| HU174375B (hu) | 1979-12-28 |
| BE815299A (fr) | 1974-11-20 |
| JPS5052049A (ja) | 1975-05-09 |
| DE2424543A1 (de) | 1974-12-12 |
| GB1452196A (en) | 1976-10-13 |
| SU615852A3 (ru) | 1978-07-15 |
| AT327948B (de) | 1976-02-25 |
| JPS57102853A (en) | 1982-06-26 |
| ATA839174A (de) | 1977-02-15 |
| NL181806B (nl) | 1987-06-01 |
| FR2230654B1 (ja) | 1975-11-21 |
| US3978101A (en) | 1976-08-31 |
| DE2424543C2 (de) | 1983-01-27 |
| FR2230654A1 (ja) | 1975-11-21 |
| HU170057B (ja) | 1977-03-28 |
| CH588890A5 (ja) | 1977-06-15 |
| US4010181A (en) | 1977-03-01 |
| US3949000A (en) | 1976-04-06 |
| JPS6152139B2 (ja) | 1986-11-12 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| BA | A request for search or an international-type search has been filed | ||
| BB | A search report has been drawn up | ||
| BC | A request for examination has been filed | ||
| A85 | Still pending on 85-01-01 | ||
| V1 | Lapsed because of non-payment of the annual fee |