MXPA03010693A - Halogenacion oxidante y deshidreogenacion opcional de hidrocarburos de c3+. - Google Patents
Halogenacion oxidante y deshidreogenacion opcional de hidrocarburos de c3+.Info
- Publication number
- MXPA03010693A MXPA03010693A MXPA03010693A MXPA03010693A MXPA03010693A MX PA03010693 A MXPA03010693 A MX PA03010693A MX PA03010693 A MXPA03010693 A MX PA03010693A MX PA03010693 A MXPA03010693 A MX PA03010693A MX PA03010693 A MXPA03010693 A MX PA03010693A
- Authority
- MX
- Mexico
- Prior art keywords
- rare earth
- process according
- catalyst
- hydrocarbon
- source
- Prior art date
Links
- 229930195733 hydrocarbon Natural products 0.000 title claims abstract description 84
- 150000002430 hydrocarbons Chemical class 0.000 title claims abstract description 84
- 238000005658 halogenation reaction Methods 0.000 title claims abstract description 32
- 230000026030 halogenation Effects 0.000 title claims abstract description 31
- 230000001590 oxidative effect Effects 0.000 title claims abstract description 23
- 238000006356 dehydrogenation reaction Methods 0.000 title claims abstract description 14
- 238000000034 method Methods 0.000 claims abstract description 121
- 230000008569 process Effects 0.000 claims abstract description 99
- 229910052761 rare earth metal Inorganic materials 0.000 claims abstract description 97
- 239000003054 catalyst Substances 0.000 claims abstract description 72
- 239000004215 Carbon black (E152) Substances 0.000 claims abstract description 68
- 150000002367 halogens Chemical class 0.000 claims abstract description 64
- QQONPFPTGQHPMA-UHFFFAOYSA-N Propene Chemical compound CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims abstract description 54
- -1 rare earth halide Chemical class 0.000 claims abstract description 51
- 229910052736 halogen Inorganic materials 0.000 claims abstract description 50
- 150000008282 halocarbons Chemical class 0.000 claims abstract description 47
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 44
- 229910052760 oxygen Inorganic materials 0.000 claims abstract description 44
- 239000001301 oxygen Substances 0.000 claims abstract description 44
- 150000002910 rare earth metals Chemical class 0.000 claims abstract description 44
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 claims abstract description 38
- 125000004432 carbon atom Chemical group C* 0.000 claims abstract description 37
- 150000001336 alkenes Chemical class 0.000 claims abstract description 23
- 239000001294 propane Substances 0.000 claims abstract description 19
- OSDWBNJEKMUWAV-UHFFFAOYSA-N Allyl chloride Chemical compound ClCC=C OSDWBNJEKMUWAV-UHFFFAOYSA-N 0.000 claims abstract description 18
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims abstract description 17
- 238000004519 manufacturing process Methods 0.000 claims abstract description 9
- 239000000203 mixture Substances 0.000 claims description 25
- 229910052684 Cerium Inorganic materials 0.000 claims description 19
- 238000006243 chemical reaction Methods 0.000 claims description 18
- 229910052746 lanthanum Inorganic materials 0.000 claims description 18
- FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 claims description 18
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 14
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims description 14
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 14
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 13
- 239000000460 chlorine Substances 0.000 claims description 13
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 12
- 229910052801 chlorine Inorganic materials 0.000 claims description 12
- 239000003085 diluting agent Substances 0.000 claims description 12
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 claims description 12
- 229910000041 hydrogen chloride Inorganic materials 0.000 claims description 12
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 12
- 229910002092 carbon dioxide Inorganic materials 0.000 claims description 10
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims description 7
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 7
- CPELXLSAUQHCOX-UHFFFAOYSA-N Hydrogen bromide Chemical compound Br CPELXLSAUQHCOX-UHFFFAOYSA-N 0.000 claims description 7
- 239000001569 carbon dioxide Substances 0.000 claims description 7
- 229910002091 carbon monoxide Inorganic materials 0.000 claims description 7
- 150000001805 chlorine compounds Chemical group 0.000 claims description 7
- 229910052802 copper Inorganic materials 0.000 claims description 7
- 239000010949 copper Substances 0.000 claims description 7
- 229910052742 iron Inorganic materials 0.000 claims description 7
- 229910052757 nitrogen Inorganic materials 0.000 claims description 7
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 claims description 6
- 229910052779 Neodymium Inorganic materials 0.000 claims description 6
- 229910052777 Praseodymium Inorganic materials 0.000 claims description 6
- 150000001875 compounds Chemical class 0.000 claims description 6
- XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical group I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 claims description 6
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 6
- QEFYFXOXNSNQGX-UHFFFAOYSA-N neodymium atom Chemical compound [Nd] QEFYFXOXNSNQGX-UHFFFAOYSA-N 0.000 claims description 6
- PUDIUYLPXJFUGB-UHFFFAOYSA-N praseodymium atom Chemical compound [Pr] PUDIUYLPXJFUGB-UHFFFAOYSA-N 0.000 claims description 6
- 229910052723 transition metal Inorganic materials 0.000 claims description 6
- 150000003624 transition metals Chemical class 0.000 claims description 6
- 229910052727 yttrium Inorganic materials 0.000 claims description 6
- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 claims description 6
- 238000004438 BET method Methods 0.000 claims description 5
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 5
- 229910052692 Dysprosium Inorganic materials 0.000 claims description 5
- 229910052691 Erbium Inorganic materials 0.000 claims description 5
- 229910052693 Europium Inorganic materials 0.000 claims description 5
- 229910052688 Gadolinium Inorganic materials 0.000 claims description 5
- 229910052772 Samarium Inorganic materials 0.000 claims description 5
- 229910052771 Terbium Inorganic materials 0.000 claims description 5
- 229910052769 Ytterbium Inorganic materials 0.000 claims description 5
- KBQHZAAAGSGFKK-UHFFFAOYSA-N dysprosium atom Chemical compound [Dy] KBQHZAAAGSGFKK-UHFFFAOYSA-N 0.000 claims description 5
- UYAHIZSMUZPPFV-UHFFFAOYSA-N erbium Chemical compound [Er] UYAHIZSMUZPPFV-UHFFFAOYSA-N 0.000 claims description 5
- OGPBJKLSAFTDLK-UHFFFAOYSA-N europium atom Chemical compound [Eu] OGPBJKLSAFTDLK-UHFFFAOYSA-N 0.000 claims description 5
- UIWYJDYFSGRHKR-UHFFFAOYSA-N gadolinium atom Chemical compound [Gd] UIWYJDYFSGRHKR-UHFFFAOYSA-N 0.000 claims description 5
- KZUNJOHGWZRPMI-UHFFFAOYSA-N samarium atom Chemical compound [Sm] KZUNJOHGWZRPMI-UHFFFAOYSA-N 0.000 claims description 5
- GZCRRIHWUXGPOV-UHFFFAOYSA-N terbium atom Chemical compound [Tb] GZCRRIHWUXGPOV-UHFFFAOYSA-N 0.000 claims description 5
- NAWDYIZEMPQZHO-UHFFFAOYSA-N ytterbium Chemical compound [Yb] NAWDYIZEMPQZHO-UHFFFAOYSA-N 0.000 claims description 5
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical group [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 claims description 4
- 229910052689 Holmium Inorganic materials 0.000 claims description 4
- 229910052765 Lutetium Inorganic materials 0.000 claims description 4
- 229910052775 Thulium Inorganic materials 0.000 claims description 4
- KJZYNXUDTRRSPN-UHFFFAOYSA-N holmium atom Chemical compound [Ho] KJZYNXUDTRRSPN-UHFFFAOYSA-N 0.000 claims description 4
- OHSVLFRHMCKCQY-UHFFFAOYSA-N lutetium atom Chemical compound [Lu] OHSVLFRHMCKCQY-UHFFFAOYSA-N 0.000 claims description 4
- 229910052786 argon Inorganic materials 0.000 claims description 3
- 239000001307 helium Substances 0.000 claims description 3
- 229910052734 helium Inorganic materials 0.000 claims description 3
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 claims description 3
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 claims description 2
- 229910052799 carbon Inorganic materials 0.000 claims description 2
- 229910001882 dioxygen Inorganic materials 0.000 claims description 2
- 239000001257 hydrogen Substances 0.000 claims description 2
- 229910052739 hydrogen Inorganic materials 0.000 claims description 2
- ZMIGMASIKSOYAM-UHFFFAOYSA-N cerium Chemical compound [Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce] ZMIGMASIKSOYAM-UHFFFAOYSA-N 0.000 claims 5
- 150000001335 aliphatic alkanes Chemical class 0.000 claims 1
- 239000000376 reactant Substances 0.000 abstract 2
- 239000000047 product Substances 0.000 description 76
- 230000003647 oxidation Effects 0.000 description 19
- 238000007254 oxidation reaction Methods 0.000 description 19
- GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 description 14
- 239000002585 base Substances 0.000 description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 9
- 229910001868 water Inorganic materials 0.000 description 9
- 239000003153 chemical reaction reagent Substances 0.000 description 7
- KNKRKFALVUDBJE-UHFFFAOYSA-N 1,2-dichloropropane Chemical compound CC(Cl)CCl KNKRKFALVUDBJE-UHFFFAOYSA-N 0.000 description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 6
- 239000006227 byproduct Substances 0.000 description 6
- 239000007789 gas Substances 0.000 description 6
- 229910052751 metal Inorganic materials 0.000 description 6
- 239000002184 metal Substances 0.000 description 6
- JEROREPODAPBAY-UHFFFAOYSA-N [La].ClOCl Chemical group [La].ClOCl JEROREPODAPBAY-UHFFFAOYSA-N 0.000 description 5
- 230000008901 benefit Effects 0.000 description 5
- 150000002739 metals Chemical class 0.000 description 5
- 239000002244 precipitate Substances 0.000 description 5
- 238000001556 precipitation Methods 0.000 description 5
- 239000002904 solvent Substances 0.000 description 5
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 4
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 4
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 4
- 239000000908 ammonium hydroxide Substances 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 4
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 4
- 229910052794 bromium Inorganic materials 0.000 description 4
- 238000001354 calcination Methods 0.000 description 4
- 238000005660 chlorination reaction Methods 0.000 description 4
- SNMVRZFUUCLYTO-UHFFFAOYSA-N n-propyl chloride Chemical class CCCCl SNMVRZFUUCLYTO-UHFFFAOYSA-N 0.000 description 4
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 4
- 239000012071 phase Substances 0.000 description 4
- HYOAGWAIGJXNQH-UHFFFAOYSA-N 1-bromo-1-chloropropane Chemical compound CCC(Cl)Br HYOAGWAIGJXNQH-UHFFFAOYSA-N 0.000 description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- 125000000217 alkyl group Chemical group 0.000 description 3
- 230000003197 catalytic effect Effects 0.000 description 3
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 3
- 239000000446 fuel Substances 0.000 description 3
- 229910000042 hydrogen bromide Inorganic materials 0.000 description 3
- 150000004679 hydroxides Chemical class 0.000 description 3
- ICAKDTKJOYSXGC-UHFFFAOYSA-K lanthanum(iii) chloride Chemical group Cl[La](Cl)Cl ICAKDTKJOYSXGC-UHFFFAOYSA-K 0.000 description 3
- 239000007791 liquid phase Substances 0.000 description 3
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 3
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 3
- 239000000377 silicon dioxide Substances 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 3
- 239000002699 waste material Substances 0.000 description 3
- BBEAZDGZMVABIC-UHFFFAOYSA-N 1,1,1,3,3,3-hexachloropropane Chemical compound ClC(Cl)(Cl)CC(Cl)(Cl)Cl BBEAZDGZMVABIC-UHFFFAOYSA-N 0.000 description 2
- ATWLRNODAYAMQS-UHFFFAOYSA-N 1,1-dibromopropane Chemical compound CCC(Br)Br ATWLRNODAYAMQS-UHFFFAOYSA-N 0.000 description 2
- CYNYIHKIEHGYOZ-UHFFFAOYSA-N 1-bromopropane Chemical compound CCCBr CYNYIHKIEHGYOZ-UHFFFAOYSA-N 0.000 description 2
- OWXJKYNZGFSVRC-UHFFFAOYSA-N 1-chloroprop-1-ene Chemical class CC=CCl OWXJKYNZGFSVRC-UHFFFAOYSA-N 0.000 description 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- KZBUYRJDOAKODT-UHFFFAOYSA-N Chlorine Chemical compound ClCl KZBUYRJDOAKODT-UHFFFAOYSA-N 0.000 description 2
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 2
- YNQLUTRBYVCPMQ-UHFFFAOYSA-N Ethylbenzene Chemical compound CCC1=CC=CC=C1 YNQLUTRBYVCPMQ-UHFFFAOYSA-N 0.000 description 2
- 239000005977 Ethylene Substances 0.000 description 2
- 238000002441 X-ray diffraction Methods 0.000 description 2
- XXROGKLTLUQVRX-UHFFFAOYSA-N allyl alcohol Chemical compound OCC=C XXROGKLTLUQVRX-UHFFFAOYSA-N 0.000 description 2
- BHELZAPQIKSEDF-UHFFFAOYSA-N allyl bromide Chemical compound BrCC=C BHELZAPQIKSEDF-UHFFFAOYSA-N 0.000 description 2
- 229910000323 aluminium silicate Inorganic materials 0.000 description 2
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 2
- DIKBFYAXUHHXCS-UHFFFAOYSA-N bromoform Chemical compound BrC(Br)Br DIKBFYAXUHHXCS-UHFFFAOYSA-N 0.000 description 2
- MKJXYGKVIBWPFZ-UHFFFAOYSA-L calcium lactate Chemical compound [Ca+2].CC(O)C([O-])=O.CC(O)C([O-])=O MKJXYGKVIBWPFZ-UHFFFAOYSA-L 0.000 description 2
- 239000001527 calcium lactate Substances 0.000 description 2
- 229960002401 calcium lactate Drugs 0.000 description 2
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- 230000000875 corresponding effect Effects 0.000 description 2
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- 150000004820 halides Chemical class 0.000 description 2
- 125000005843 halogen group Chemical group 0.000 description 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 2
- 229910000043 hydrogen iodide Inorganic materials 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 2
- 239000003701 inert diluent Substances 0.000 description 2
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- 239000000395 magnesium oxide Substances 0.000 description 2
- 230000033116 oxidation-reduction process Effects 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
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- HJUGFYREWKUQJT-UHFFFAOYSA-N tetrabromomethane Chemical compound BrC(Br)(Br)Br HJUGFYREWKUQJT-UHFFFAOYSA-N 0.000 description 2
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- PNDPGZBMCMUPRI-UHFFFAOYSA-N iodine Chemical compound II PNDPGZBMCMUPRI-UHFFFAOYSA-N 0.000 description 1
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- 239000012035 limiting reagent Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 239000011572 manganese Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 235000010755 mineral Nutrition 0.000 description 1
- 150000005673 monoalkenes Chemical class 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- BMMGVYCKOGBVEV-UHFFFAOYSA-N oxo(oxoceriooxy)cerium Chemical compound [Ce]=O.O=[Ce]=O BMMGVYCKOGBVEV-UHFFFAOYSA-N 0.000 description 1
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 229910001404 rare earth metal oxide Inorganic materials 0.000 description 1
- 230000036632 reaction speed Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 239000012266 salt solution Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 229930195734 saturated hydrocarbon Natural products 0.000 description 1
- 239000012047 saturated solution Substances 0.000 description 1
- 229910052706 scandium Inorganic materials 0.000 description 1
- SIXSYDAISGFNSX-UHFFFAOYSA-N scandium atom Chemical compound [Sc] SIXSYDAISGFNSX-UHFFFAOYSA-N 0.000 description 1
- 238000007086 side reaction Methods 0.000 description 1
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 1
- 229910010271 silicon carbide Inorganic materials 0.000 description 1
- 239000011877 solvent mixture Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 238000004230 steam cracking Methods 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 229930195735 unsaturated hydrocarbon Natural products 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
- 229910001928 zirconium oxide Inorganic materials 0.000 description 1
- GFQYVLUOOAAOGM-UHFFFAOYSA-N zirconium(iv) silicate Chemical compound [Zr+4].[O-][Si]([O-])([O-])[O-] GFQYVLUOOAAOGM-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/093—Preparation of halogenated hydrocarbons by replacement by halogens
- C07C17/15—Preparation of halogenated hydrocarbons by replacement by halogens with oxygen as auxiliary reagent, e.g. oxychlorination
- C07C17/152—Preparation of halogenated hydrocarbons by replacement by halogens with oxygen as auxiliary reagent, e.g. oxychlorination of hydrocarbons
- C07C17/156—Preparation of halogenated hydrocarbons by replacement by halogens with oxygen as auxiliary reagent, e.g. oxychlorination of hydrocarbons of unsaturated hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/093—Preparation of halogenated hydrocarbons by replacement by halogens
- C07C17/15—Preparation of halogenated hydrocarbons by replacement by halogens with oxygen as auxiliary reagent, e.g. oxychlorination
- C07C17/152—Preparation of halogenated hydrocarbons by replacement by halogens with oxygen as auxiliary reagent, e.g. oxychlorination of hydrocarbons
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/06—Halogens; Compounds thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/06—Halogens; Compounds thereof
- B01J27/08—Halides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/06—Halogens; Compounds thereof
- B01J27/125—Halogens; Compounds thereof with scandium, yttrium, aluminium, gallium, indium or thallium
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
- C07C1/26—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only halogen atoms as hetero-atoms
- C07C1/30—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only halogen atoms as hetero-atoms by splitting-off the elements of hydrogen halide from a single molecule
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/093—Preparation of halogenated hydrocarbons by replacement by halogens
- C07C17/10—Preparation of halogenated hydrocarbons by replacement by halogens of hydrogen atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/093—Preparation of halogenated hydrocarbons by replacement by halogens
- C07C17/15—Preparation of halogenated hydrocarbons by replacement by halogens with oxygen as auxiliary reagent, e.g. oxychlorination
- C07C17/152—Preparation of halogenated hydrocarbons by replacement by halogens with oxygen as auxiliary reagent, e.g. oxychlorination of hydrocarbons
- C07C17/154—Preparation of halogenated hydrocarbons by replacement by halogens with oxygen as auxiliary reagent, e.g. oxychlorination of hydrocarbons of saturated hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
- C07C5/42—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with a hydrogen acceptor
- C07C5/48—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with a hydrogen acceptor with oxygen as an acceptor
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/10—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of rare earths
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- C07C2527/06—Halogens; Compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- C07C2527/06—Halogens; Compounds thereof
- C07C2527/08—Halides
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
Applications Claiming Priority (2)
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| US29312301P | 2001-05-23 | 2001-05-23 | |
| PCT/US2002/013011 WO2002094750A1 (en) | 2001-05-23 | 2002-04-23 | Oxidative halogenation and optional dehydrogenation of c3+ hydrocarbons |
Publications (1)
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|---|---|
| MXPA03010693A true MXPA03010693A (es) | 2004-07-01 |
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| MXPA03010693A MXPA03010693A (es) | 2001-05-23 | 2002-04-23 | Halogenacion oxidante y deshidreogenacion opcional de hidrocarburos de c3+. |
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| JP (1) | JP4275952B2 (enExample) |
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| CN (1) | CN100424056C (enExample) |
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| BR (1) | BR0210049A (enExample) |
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| MX (1) | MXPA03010693A (enExample) |
| MY (1) | MY128603A (enExample) |
| NO (1) | NO20035181D0 (enExample) |
| RU (1) | RU2284984C2 (enExample) |
| WO (1) | WO2002094750A1 (enExample) |
Families Citing this family (33)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6680415B1 (en) | 1999-11-22 | 2004-01-20 | Dow Global Technologies Inc. | Oxyhalogenation process using catalyst having porous rare earth halide support |
| US7838708B2 (en) | 2001-06-20 | 2010-11-23 | Grt, Inc. | Hydrocarbon conversion process improvements |
| EP1682465A1 (en) | 2003-07-15 | 2006-07-26 | GRT, Inc. | Hydrocarbon synthesis |
| US20050171393A1 (en) | 2003-07-15 | 2005-08-04 | Lorkovic Ivan M. | Hydrocarbon synthesis |
| US8642822B2 (en) | 2004-04-16 | 2014-02-04 | Marathon Gtf Technology, Ltd. | Processes for converting gaseous alkanes to liquid hydrocarbons using microchannel reactor |
| US20080275284A1 (en) * | 2004-04-16 | 2008-11-06 | Marathon Oil Company | Process for converting gaseous alkanes to liquid hydrocarbons |
| US7244867B2 (en) | 2004-04-16 | 2007-07-17 | Marathon Oil Company | Process for converting gaseous alkanes to liquid hydrocarbons |
| US20060100469A1 (en) | 2004-04-16 | 2006-05-11 | Waycuilis John J | Process for converting gaseous alkanes to olefins and liquid hydrocarbons |
| US8173851B2 (en) | 2004-04-16 | 2012-05-08 | Marathon Gtf Technology, Ltd. | Processes for converting gaseous alkanes to liquid hydrocarbons |
| US7674941B2 (en) | 2004-04-16 | 2010-03-09 | Marathon Gtf Technology, Ltd. | Processes for converting gaseous alkanes to liquid hydrocarbons |
| DE102004055826A1 (de) * | 2004-11-19 | 2006-05-24 | Basf Ag | Verfahren und Vorrichtung zur Vollhydrierung eines Kohlenwasserstoffstromes |
| CN101171217A (zh) * | 2005-05-04 | 2008-04-30 | 陶氏环球技术公司 | C1烃转化成卤代c1烃的氧化卤化反应 |
| KR101368416B1 (ko) | 2006-02-03 | 2014-03-05 | 리액션 35, 엘엘씨 | 천연 가스를 액체 탄화수소로 변환시키는 연속 공정 |
| WO2007092410A2 (en) * | 2006-02-03 | 2007-08-16 | Grt, Inc. | Separation of light gases from halogens |
| EA201200888A1 (ru) * | 2007-05-14 | 2013-02-28 | Грт, Инк. | Способ конверсии углеводородного сырья с электролитическим извлечением галогенов |
| CN101765574A (zh) | 2007-05-24 | 2010-06-30 | Grt公司 | 使卤化氢可逆性俘获与释放相结合的区域反应器 |
| US8282810B2 (en) | 2008-06-13 | 2012-10-09 | Marathon Gtf Technology, Ltd. | Bromine-based method and system for converting gaseous alkanes to liquid hydrocarbons using electrolysis for bromine recovery |
| KR101740419B1 (ko) | 2008-07-18 | 2017-05-26 | 지알티, 인코포레이티드 | 천연 가스를 액체 탄화수소로 변환시키는 연속 공정 |
| US20100270167A1 (en) * | 2009-04-22 | 2010-10-28 | Mcfarland Eric | Process for converting hydrocarbon feedstocks with electrolytic and photoelectrocatalytic recovery of halogens |
| US8198495B2 (en) | 2010-03-02 | 2012-06-12 | Marathon Gtf Technology, Ltd. | Processes and systems for the staged synthesis of alkyl bromides |
| US8367884B2 (en) | 2010-03-02 | 2013-02-05 | Marathon Gtf Technology, Ltd. | Processes and systems for the staged synthesis of alkyl bromides |
| RU2446877C2 (ru) * | 2010-07-16 | 2012-04-10 | Учреждение Российской Академии наук Институт катализа им. Г.К. Борескова Сибирского отделения Российской Академии наук | Каталитическая система для гетерогенных реакций |
| US8815050B2 (en) | 2011-03-22 | 2014-08-26 | Marathon Gtf Technology, Ltd. | Processes and systems for drying liquid bromine |
| US8436220B2 (en) | 2011-06-10 | 2013-05-07 | Marathon Gtf Technology, Ltd. | Processes and systems for demethanization of brominated hydrocarbons |
| US8829256B2 (en) | 2011-06-30 | 2014-09-09 | Gtc Technology Us, Llc | Processes and systems for fractionation of brominated hydrocarbons in the conversion of natural gas to liquid hydrocarbons |
| US8802908B2 (en) | 2011-10-21 | 2014-08-12 | Marathon Gtf Technology, Ltd. | Processes and systems for separate, parallel methane and higher alkanes' bromination |
| US9193641B2 (en) | 2011-12-16 | 2015-11-24 | Gtc Technology Us, Llc | Processes and systems for conversion of alkyl bromides to higher molecular weight hydrocarbons in circulating catalyst reactor-regenerator systems |
| EP3000800A1 (en) | 2014-09-23 | 2016-03-30 | Borealis AG | An endothermic gas phase catalytic dehydrogenation process |
| CN104447164B (zh) * | 2014-12-29 | 2016-07-06 | 厦门大学 | 一种从丙烷氧化脱氢制备丙烯的方法 |
| WO2017216653A1 (en) * | 2016-06-17 | 2017-12-21 | Sabic Global Technologies B.V. | Mixed cerium-lanthanum oxide catalysts and systems for oxidative halogenation of an alkane |
| CN108067263B (zh) * | 2016-11-11 | 2020-09-11 | 中国石油化工股份有限公司抚顺石油化工研究院 | 一种具有壳核结构的催化剂及其制备方法和应用 |
| CN108067261B (zh) * | 2016-11-11 | 2020-09-11 | 中国石油化工股份有限公司抚顺石油化工研究院 | 一种甲烷卤氧化转化催化剂及其制备方法和应用 |
| CN108067258B (zh) * | 2016-11-11 | 2020-08-11 | 中国石油化工股份有限公司抚顺石油化工研究院 | 一种甲烷卤氧化催化剂的制备方法 |
Family Cites Families (132)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US402546A (en) * | 1889-04-30 | Shoe-lace fastener | ||
| US2204733A (en) | 1938-06-03 | 1940-06-18 | Air Reduction | Production of chlorine |
| US3149171A (en) | 1960-01-04 | 1964-09-15 | Monsanto Co | Production of chloroprene |
| NL132331C (enExample) | 1962-06-01 | 1971-04-15 | ||
| NL129920C (enExample) * | 1963-06-05 | |||
| US3488398A (en) | 1964-04-23 | 1970-01-06 | Goodrich Co B F | Method of preparing 1,2-dichloroethane |
| NL130969C (enExample) | 1964-06-01 | 1900-01-01 | ||
| GB1039369A (en) | 1964-07-22 | 1966-08-17 | Princeton Chemical Res Inc | Catalytic conversion of ethane to vinyl chloride |
| DE1793805C3 (de) | 1967-02-06 | 1978-04-27 | The Lummus Co., Bloomfield, N.J. (V.St.A.) | Verfahren zur Herstellung von Vinylchlorid |
| FR1594693A (enExample) | 1967-11-01 | 1970-06-08 | ||
| US3968178A (en) | 1967-11-08 | 1976-07-06 | Stauffer Chemical Company | Chlorination of hydrocarbons |
| FR1579562A (enExample) | 1968-04-24 | 1969-08-29 | ||
| US3657367A (en) | 1968-10-31 | 1972-04-18 | Stauffer Chemical Co | Oxychlorination of saturated and unsaturated hydrocarbons in the presence of a fluidized catalyst containing lanthanum and didymium |
| US3629354A (en) | 1969-07-14 | 1971-12-21 | Ethyl Corp | Halogenated hydrocarbons |
| US3658933A (en) | 1969-07-14 | 1972-04-25 | Ethyl Corp | Ethylene from ethane halogen and hydrogen halide through fluidized catalyst |
| US3702311A (en) | 1969-07-14 | 1972-11-07 | Ethyl Corp | Halodehydrogenation catalyst |
| US3658934A (en) | 1969-07-14 | 1972-04-25 | Ethyl Corp | Ethylene from ethane and halogen through fluidized rare earth catalyst |
| US3644561A (en) | 1969-07-14 | 1972-02-22 | Ethyl Corp | Oxydehydrogenation of ethane |
| US4046821A (en) | 1969-12-31 | 1977-09-06 | Petro-Tex Chemical Corporation | Oxychlorination of hydrocarbons in the presence of non-halide copper containing catalysts |
| US4025461A (en) | 1969-12-31 | 1977-05-24 | Petro-Tex Chemical Corporation | Oxychlorination of hydrocarbons in the presence of non-halide copper containing catalysts |
| NL7004356A (enExample) * | 1970-03-26 | 1971-09-28 | ||
| US3646330A (en) * | 1970-05-28 | 1972-02-29 | Atomic Energy Commission | Continuous digital ratemeter |
| US3658634A (en) * | 1970-08-20 | 1972-04-25 | Toray Industries | Fire-retardant sheath and core type conjugate fiber |
| US4046823A (en) | 1971-03-15 | 1977-09-06 | Continental Oil Company | Process for producing 1,2-dichloroethane |
| US3769362A (en) | 1971-06-17 | 1973-10-30 | Ethyl Corp | Oxydehydrogenation of ethane |
| IT958619B (it) | 1971-06-30 | 1973-10-30 | Sumitomo Chemical Co | Procedimento per preparare idrocarburi clorurati |
| US3968200A (en) | 1972-03-27 | 1976-07-06 | The Lummus Company | Reactor effluent quench system |
| DE2440864C2 (de) | 1973-08-29 | 1983-12-15 | The Dow Chemical Co., 48640 Midland, Mich. | Verfahren zur Herstellung von gesättigten polychlorierten aliphatischen Kohlenwasserstoffen durch Oxychlorierung |
| US3927131A (en) | 1974-06-10 | 1975-12-16 | Dow Chemical Co | Dehydrohalogenation of halogenated hydrocarbons |
| GB1492945A (en) | 1974-09-20 | 1977-11-23 | British Petroleum Co | Process for producing vinyl chloride |
| US4375569A (en) | 1975-04-03 | 1983-03-01 | The B. F. Goodrich Company | Process for the oxychlorination of an alkane using a solid solution catalyst containing iron cations |
| BE840444A (fr) | 1975-04-08 | 1976-10-07 | Compositions catalytiques d'oxyhalogenures de metaux ayant une structure de perovskite | |
| US4042640A (en) | 1975-11-06 | 1977-08-16 | The Lummus Company | Oxychlorination of hydrocarbons |
| US4230668A (en) | 1976-02-19 | 1980-10-28 | The Badger Company, Inc. | Process and apparatus for producing halogenated unsaturated hydrocarbons |
| US4100211A (en) | 1976-05-17 | 1978-07-11 | The Bf Goodrich Company | Process for preparation of ethylene and vinyl chloride from ethane |
| US4319062A (en) | 1976-08-02 | 1982-03-09 | The Dow Chemical Company | Allyl chloride process |
| US4300005A (en) | 1977-12-02 | 1981-11-10 | Monsanto Co. | Preparation of vinyl chloride |
| US4329525A (en) | 1978-02-21 | 1982-05-11 | The Lummus Company | Production of chlorinated compounds by use of molten salts |
| US4323482A (en) | 1979-08-14 | 1982-04-06 | University Of Delaware | Catalyst and method of preparation |
| FR2472601A1 (fr) | 1979-12-27 | 1981-07-03 | Rhone Poulenc Ind | Procede de fabrication de compositions de polissage a base de cerium |
| SE430885B (sv) | 1980-03-24 | 1983-12-19 | Ferring Ab | Oxytocin-derivat |
| US4405500A (en) | 1980-12-23 | 1983-09-20 | Ec Erdolchemie Gmbh | Halogen compound promoted Al2 O3 and/or SiO2 for the preparation of isoalkenes |
| GB2095242B (en) | 1981-03-19 | 1985-05-15 | Ici Plc | Preparations of monochloro-olefins by oxychlorination of alkanes |
| GB2101596B (en) | 1981-07-14 | 1985-11-06 | Ici Plc | Oxychlorination of alkanes to monochlorinated olefins |
| US4462970A (en) | 1981-08-19 | 1984-07-31 | Hughes Aircraft Company | Process for preparation of water-free oxychloride material |
| US4523040A (en) | 1981-09-01 | 1985-06-11 | Olah George A | Methyl halides and methyl alcohol from methane |
| US4460669A (en) * | 1981-11-26 | 1984-07-17 | Canon Kabushiki Kaisha | Photoconductive member with α-Si and C, U or D and dopant |
| FR2529883A1 (fr) | 1982-07-06 | 1984-01-13 | Ugine Kuhlmann | Procede de fabrication de chlorure de vinyle |
| US4460699A (en) | 1982-08-04 | 1984-07-17 | Conoco Inc. | Fixed bed catalyst for oxychlorination |
| DE3331962A1 (de) | 1983-09-05 | 1985-03-21 | Wacker-Chemie GmbH, 8000 München | Verfahren zur aufbereitung von chlorwasserstoff als einsatzstoff fuer den ethylenoxichlorierungsprozess |
| CA1244481A (en) | 1984-05-24 | 1988-11-08 | Angelo J. Magistro | Catalytic dehydrohalogenation process |
| US5008225A (en) | 1984-05-24 | 1991-04-16 | The B. F. Goodrich Company | Catalytic dehydrohalogenation catalyst |
| US4590216A (en) | 1984-09-07 | 1986-05-20 | Union Carbide Corporation | Process for the manufacture of alcohols using ruthenium and lanthanide catalysts |
| DE3445896C1 (de) | 1984-12-15 | 1986-04-10 | Dynamit Nobel Ag, 5210 Troisdorf | Verfahren zur kontinuierlichen Herstellung von 1.2-Dichlorethan |
| US5663472A (en) | 1985-07-22 | 1997-09-02 | University Of Southern California | Production of alkenes |
| DE3608043A1 (de) | 1986-03-11 | 1987-09-17 | Wacker Chemie Gmbh | Verbessertes verfahren zur herstellung von 1,2-dichlorethan durch gasphasenchlorierung von ethylenhaltigen gasen |
| US4766103A (en) | 1986-07-07 | 1988-08-23 | Phillips Petroleum Company | Preparation of 1,4-dichlorobenzene |
| US4727201A (en) | 1986-07-07 | 1988-02-23 | Phillips Petroleum Company | Preparation of 1,4-dichlorobenzene |
| FR2608583B1 (fr) | 1986-12-19 | 1990-12-07 | Rhone Poulenc Chimie | Oxyde cerique a nouvelles caracteristiques morphologiques et son procede d'obtention |
| DE3700132A1 (de) | 1987-01-03 | 1988-07-14 | Dow Chemical Gmbh | Verfahren zum herstellen von ethylendichlorid |
| US4769504A (en) | 1987-03-04 | 1988-09-06 | The United States Of America As Represented By The United States Department Of Energy | Process for converting light alkanes to higher hydrocarbons |
| CA1322769C (en) | 1988-12-30 | 1993-10-05 | John E. Stauffer | Process for the chlorination of ethane |
| FR2616769B1 (fr) | 1987-06-17 | 1990-11-30 | Rhone Poulenc Chimie | Procede d'obtention d'un oxyde de terre rare et produit obtenu |
| FR2617153B1 (fr) | 1987-06-26 | 1991-04-05 | Rhone Poulenc Chimie | Procede d'obtention d'un oxyde cerique et oxyde cerique a nouvelles caracteristiques morphologiques |
| FR2617154B1 (fr) | 1987-06-29 | 1990-11-30 | Rhone Poulenc Chimie | Procede d'obtention d'oxyde cerique et oxyde cerique a nouvelles caracteristiques morphologiques |
| FR2634398B1 (fr) | 1988-06-29 | 1990-09-07 | Elf Aquitaine | Procede de preparation d'un catalyseur apte a promouvoir la conversion oxydante du methane en hydrocarbures superieurs |
| FR2633603B1 (fr) | 1988-07-01 | 1991-02-22 | Rhone Poulenc Chimie | Trifluorure de cerium a nouvelles caracteristiques morphologiques et son procede d'obtention |
| US5114702A (en) | 1988-08-30 | 1992-05-19 | Battelle Memorial Institute | Method of making metal oxide ceramic powders by using a combustible amino acid compound |
| DE3838811A1 (de) | 1988-11-17 | 1990-05-23 | Wacker Chemie Gmbh | Verwendung von wabenfoermigen monolithischen katalysatortraegern fuer chlorierungs- und oxichlorierungsreaktionen |
| DE68927703T2 (de) | 1988-12-07 | 1997-08-14 | Sumitomo Chemical Co | Verfahren zur Herstellung von 2,3-Dimethylbutenen |
| US4899000A (en) | 1989-01-27 | 1990-02-06 | Stauffer John E | Production of allyl chloride |
| FR2648802B1 (fr) | 1989-06-22 | 1991-09-20 | Rhone Poulenc Chimie | Melanges deshydrates d'halogenures de terres rares et d'alcalino-terreux ou d'alcalins |
| US5232889A (en) | 1989-11-27 | 1993-08-03 | Rhone-Poulenc Chimie | Supported catalysts |
| US5113027A (en) | 1989-12-15 | 1992-05-12 | Vulcan Materials Company | Oxychlorination process using a catalyst which comprises copper chloride supported on rare-earth modified alumina |
| US5072063A (en) | 1990-01-09 | 1991-12-10 | Dowelanco | Process for rearranging allylic geminal dihalogen compounds |
| FR2663245B1 (fr) | 1990-06-13 | 1992-09-18 | Rhone Poulenc Chimie | Composition a base d'alumine pour catalyseur et procede de fabrication. |
| US5243111A (en) | 1990-06-25 | 1993-09-07 | Atochem | Catalytic oxychlorination of hydrocarbons to produce chlorocarbons |
| US5210358A (en) | 1990-08-15 | 1993-05-11 | The B.F. Goodrich Company | Catalyst composition and process for the preparation of ethylene from ethane |
| GB9018409D0 (en) | 1990-08-22 | 1990-10-03 | Ici Plc | Catalysts |
| US5262547A (en) | 1990-10-31 | 1993-11-16 | The Boc Group, Inc. | Process for the production of petrochemicals |
| US5087791A (en) | 1990-11-19 | 1992-02-11 | The B. F. Goodrich Company | Process for the preparation of ethylene and vinyl chloride from ethane in the presence of water |
| JP3032577B2 (ja) | 1990-12-06 | 2000-04-17 | オクシデンタル ケミカル コーポレイション | エチレンの混合物及びエチレンを含む混合物の製造法 |
| FR2672887B1 (fr) | 1991-02-15 | 1993-05-07 | Atochem | Procede de synthese du 1,2-dichloroethane par oxychloration de l'ethylene au moyen du tetrachlorure de carbone. |
| US5179215A (en) | 1991-02-27 | 1993-01-12 | The Boc Group, Inc. | Process for the production of petrochemicals |
| JP3145175B2 (ja) | 1992-03-31 | 2001-03-12 | 三井金属鉱業株式会社 | 排ガス浄化用触媒及びその製造方法 |
| US5453557A (en) | 1992-10-01 | 1995-09-26 | The Dow Chemical Company | Processes for converting chlorinated byproducts and waste products to useful materials |
| WO1994028036A1 (en) | 1993-05-20 | 1994-12-08 | Exxon Chemical Patents Inc. | Heterogeneous lewis acid-type catalysts |
| US5580536A (en) | 1993-06-21 | 1996-12-03 | Santoku Metal Industry Co., Ltd. | Composite oxide having oxygen absorbing and desorbing capability and method for preparing same |
| GB9318501D0 (en) | 1993-09-07 | 1993-10-20 | Evc Tech Ag | Oxychlorination catalyst |
| GB9318505D0 (en) | 1993-09-07 | 1993-10-20 | Evc Tech Ag | By-product recycling in oxychlorination process |
| US5763710A (en) | 1993-09-07 | 1998-06-09 | Evc Technology Ag | Oxychlorination process |
| GB9318507D0 (en) | 1993-09-07 | 1993-10-20 | Evc Tech Ag | Vinyl chloride production process |
| US5466837A (en) | 1993-09-30 | 1995-11-14 | The Boc Group, Inc. | Process for the production of hydrocarbon partial oxidation products |
| DE69409463T2 (de) | 1993-11-02 | 1998-07-30 | Nippon Catalytic Chem Ind | Verfahren zur Herstellung von Alkanolamin, Katalysator für dieses Verfahren und Verfahren zur Herstellung des Katalysators |
| KR960010775B1 (ko) | 1993-12-01 | 1996-08-08 | 한국과학기술연구원 | 염화수소의 산화에 의한 염소제조용 염화세륨-삼산화이크롬 촉매 및 이의 제조방법 |
| RU2079478C1 (ru) * | 1994-01-12 | 1997-05-20 | Государственный научно-исследовательский институт химии и технологии элементоорганических соединений | Способ получения метилхлорида |
| DE69521990T2 (de) | 1994-03-31 | 2002-04-04 | Infineum Usa Lp | Aus supersäuren hergestellte lewissäure enthaltende trägerkatalysatoren, die für umwandlungsreaktionen von kohlenwasserstoffen verwendbar sind. |
| US5925590A (en) | 1994-05-25 | 1999-07-20 | Eltron Research, Inc. | Catalysts utilizing oxygen-deficient metal oxide compound for removal of exhaust gas constituents |
| FR2720295B1 (fr) | 1994-05-27 | 1996-07-12 | Rhone Poulenc Chimie | Composé dispersible à base d'une terre rare, suspension colloïdale obtenue à partir de ce composé, leurs procédés de préparation et utilisation à la fabrication de catalyseurs. |
| FR2720296B1 (fr) | 1994-05-27 | 1996-07-12 | Rhone Poulenc Chimie | Composés à base d'alumine, d'oxyde de cérium et d'oxyde de zirconium à réductibilité élevée, leur procédé de préparation et leur utilisation dans la préparation de catalyseurs. |
| JP3402542B2 (ja) | 1994-07-01 | 2003-05-06 | 株式会社豊田中央研究所 | 複合酸化物粉末の製造方法 |
| FR2727103B1 (fr) | 1994-11-23 | 1996-12-27 | Kodak Pathe | Procede de preparation des halogenures metalliques par voie sol-gel |
| JP3664182B2 (ja) | 1994-12-19 | 2005-06-22 | トヨタ自動車株式会社 | 高耐熱性排ガス浄化用触媒とその製造方法 |
| EP0720975A1 (en) | 1995-01-06 | 1996-07-10 | Dow Corning Corporation | Oxyhydrochlorination catalyst and process |
| JP3747491B2 (ja) | 1995-04-20 | 2006-02-22 | 東ソー株式会社 | １，２−ジクロルエタンの製造方法 |
| US5600042A (en) | 1995-04-27 | 1997-02-04 | Chen; Wu-Chi | Process for the production of vinyl chloride |
| TW338064B (en) | 1995-06-01 | 1998-08-11 | Boc Group Inc | Process for the production of petrochemicals |
| CN1055106C (zh) | 1995-06-16 | 2000-08-02 | 法国石油公司 | 用于烃转化反应的含有一种加入金属的催化剂 |
| US5646304A (en) | 1995-06-23 | 1997-07-08 | The Boc Group, Inc. | Process for the production of petrochemicals |
| US5510546A (en) | 1995-07-07 | 1996-04-23 | The Dow Chemical Company | Process for rearranging allylic geminal dihalogen compounds |
| DE19533484A1 (de) | 1995-09-12 | 1997-03-13 | Basf Ag | Monomodale und polymodale Katalysatorträger und Katalysatoren mit engen Porengrößenverteilungen und deren Herstellverfahren |
| DE19533486A1 (de) | 1995-09-12 | 1997-03-13 | Basf Ag | Monomodale und polymodale Katalysatorträger und Katalysatoren mit engen Porengrößenverteilungen und deren Herstellverfahren |
| US5773383A (en) | 1995-09-15 | 1998-06-30 | Suciu; George Dan | Method of making solid acid catalysts with metal cores |
| FR2741281B1 (fr) | 1995-11-22 | 1998-02-13 | Rhone Poulenc Chimie | Sol organique comportant au moins un compose oxygene de terre(s) rare(s), procede de synthese du dit sol et utilisation du dit sol pour la catalyse |
| FR2741869B1 (fr) | 1995-12-04 | 1998-02-06 | Rhone Poulenc Chimie | Oxyde de cerium a pores de structure lamellaire, procede de preparation et utilisation en catalyse |
| JP4094689B2 (ja) | 1996-04-05 | 2008-06-04 | 阿南化成株式会社 | 酸素吸収放出能を有する複合酸化物の製造法 |
| US6165931A (en) | 1996-04-16 | 2000-12-26 | E. I. Du Pont De Nemours And Company | Catalytic hydrofluorination processes and catalysts |
| RU2152920C2 (ru) * | 1996-05-13 | 2000-07-20 | Открытое акционерное общество "Кирово-Чепецкий химический комбинат им.Б.П.Константинова" | Способ получения метилхлорида |
| FR2748740B1 (fr) | 1996-05-15 | 1998-08-21 | Rhone Poulenc Chimie | Composition a base d'oxyde de cerium et d'oxyde de zirconium a haute surface specifique et a capacite elevee de stockage d'oxygene, procede de preparation et utilisation en catalyse |
| US5898014A (en) | 1996-09-27 | 1999-04-27 | Engelhard Corporation | Catalyst composition containing oxygen storage components |
| US5919727A (en) | 1996-11-14 | 1999-07-06 | W. R. Grace & Co.-Conn. | Ceric oxide washcoat |
| US6194345B1 (en) | 1996-12-09 | 2001-02-27 | Total Raffinage Distribution S.A. | Process for activating halogenated catalysts, catalysts obtained by this process, and use of these catalysts in acid catalyst processes |
| US5945573A (en) | 1997-01-31 | 1999-08-31 | E. I. Du Pont De Nemours And Company | Process for the manufacture of 1,1,1,3,3-pentafluoropropane |
| DE19721301C1 (de) | 1997-05-21 | 1998-10-01 | Basf Ag | Verfahren zur Hydrolyse von Alkylmonohalogeniden |
| FR2768725B1 (fr) | 1997-09-24 | 1999-11-12 | Solvay | Procede de preparation du 2-chloroprop-1-ene |
| DE19834083A1 (de) | 1998-07-29 | 2000-02-03 | Krupp Uhde Gmbh | Verfahren zur Energieschonung, insbesondere bei der Oxychlorierung von Ethylen |
| US6680415B1 (en) | 1999-11-22 | 2004-01-20 | Dow Global Technologies Inc. | Oxyhalogenation process using catalyst having porous rare earth halide support |
| CN101104147A (zh) * | 1999-11-22 | 2008-01-16 | 陶氏环球技术公司 | 一种具催化作用的组合物 |
| BR0015918A (pt) | 1999-11-22 | 2002-08-06 | Dow Chemical Co | Método e aparelhagem para manufaturar cloreto de vinila e cloreto de vinila obtido |
| US6452058B1 (en) | 2001-05-21 | 2002-09-17 | Dow Global Technologies Inc. | Oxidative halogenation of C1 hydrocarbons to halogenated C1 hydrocarbons and integrated processes related thereto |
| WO2002094752A1 (en) | 2001-05-23 | 2002-11-28 | Dow Global Technologies Inc. | Process for vinyl chloride manufacture from ethane and ethylene with air feed and alternative hcl processing methods |
| CN1649808A (zh) | 2001-05-23 | 2005-08-03 | 陶氏环球技术公司 | 从单碳原料的卤乙烯生产 |
-
2002
- 2002-04-23 WO PCT/US2002/013011 patent/WO2002094750A1/en not_active Ceased
- 2002-04-23 JP JP2002591425A patent/JP4275952B2/ja not_active Expired - Fee Related
- 2002-04-23 US US10/478,265 patent/US6984763B2/en not_active Expired - Fee Related
- 2002-04-23 CN CNB028105478A patent/CN100424056C/zh not_active Expired - Fee Related
- 2002-04-23 EP EP02771812A patent/EP1397330A1/en not_active Withdrawn
- 2002-04-23 RU RU2003136824/04A patent/RU2284984C2/ru not_active IP Right Cessation
- 2002-04-23 MX MXPA03010693A patent/MXPA03010693A/es active IP Right Grant
- 2002-04-23 BR BR0210049-5A patent/BR0210049A/pt not_active Application Discontinuation
- 2002-04-23 KR KR1020037015158A patent/KR100886284B1/ko not_active Expired - Fee Related
- 2002-04-23 CA CA002448500A patent/CA2448500C/en not_active Expired - Fee Related
- 2002-04-23 AU AU2002307548A patent/AU2002307548B2/en not_active Ceased
- 2002-05-22 MY MYPI20021883A patent/MY128603A/en unknown
- 2002-05-22 AR ARP020101896A patent/AR033909A1/es active IP Right Grant
-
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- 2003-11-21 NO NO20035181A patent/NO20035181D0/no unknown
Also Published As
| Publication number | Publication date |
|---|---|
| CA2448500A1 (en) | 2002-11-28 |
| MY128603A (en) | 2007-02-28 |
| KR20040002987A (ko) | 2004-01-07 |
| BR0210049A (pt) | 2004-08-17 |
| CA2448500C (en) | 2009-11-17 |
| RU2003136824A (ru) | 2005-04-10 |
| US6984763B2 (en) | 2006-01-10 |
| CN1511127A (zh) | 2004-07-07 |
| CN100424056C (zh) | 2008-10-08 |
| US20040158110A1 (en) | 2004-08-12 |
| WO2002094750A1 (en) | 2002-11-28 |
| EP1397330A1 (en) | 2004-03-17 |
| JP4275952B2 (ja) | 2009-06-10 |
| AU2002307548B2 (en) | 2007-06-28 |
| AR033909A1 (es) | 2004-01-07 |
| JP2004528386A (ja) | 2004-09-16 |
| KR100886284B1 (ko) | 2009-03-04 |
| NO20035181D0 (no) | 2003-11-21 |
| RU2284984C2 (ru) | 2006-10-10 |
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