MXPA02012667A - Dispersiones acuosas anionicas de poliuretano que contienen polifluorooxetanos. - Google Patents
Dispersiones acuosas anionicas de poliuretano que contienen polifluorooxetanos.Info
- Publication number
- MXPA02012667A MXPA02012667A MXPA02012667A MXPA02012667A MXPA02012667A MX PA02012667 A MXPA02012667 A MX PA02012667A MX PA02012667 A MXPA02012667 A MX PA02012667A MX PA02012667 A MXPA02012667 A MX PA02012667A MX PA02012667 A MXPA02012667 A MX PA02012667A
- Authority
- MX
- Mexico
- Prior art keywords
- polyurethane
- carbon atoms
- polyol
- copolymer
- composition according
- Prior art date
Links
- 229920003009 polyurethane dispersion Polymers 0.000 title claims abstract description 10
- 125000000129 anionic group Chemical group 0.000 title abstract description 6
- 239000000203 mixture Substances 0.000 claims abstract description 59
- 229920002635 polyurethane Polymers 0.000 claims abstract description 56
- 239000004814 polyurethane Substances 0.000 claims abstract description 56
- 239000000178 monomer Substances 0.000 claims abstract description 47
- 229920005862 polyol Polymers 0.000 claims abstract description 46
- 150000003077 polyols Chemical class 0.000 claims abstract description 43
- 229920000642 polymer Polymers 0.000 claims abstract description 37
- 238000000576 coating method Methods 0.000 claims abstract description 28
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 25
- 229920001577 copolymer Polymers 0.000 claims abstract description 22
- 239000002253 acid Substances 0.000 claims abstract description 21
- 230000005855 radiation Effects 0.000 claims abstract description 11
- 229920001567 vinyl ester resin Polymers 0.000 claims abstract description 8
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims abstract description 4
- 238000000034 method Methods 0.000 claims description 35
- 125000004432 carbon atom Chemical group C* 0.000 claims description 31
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 29
- 238000006243 chemical reaction Methods 0.000 claims description 24
- 239000000758 substrate Substances 0.000 claims description 23
- 229920000728 polyester Polymers 0.000 claims description 21
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 claims description 20
- 239000011248 coating agent Substances 0.000 claims description 20
- 239000002270 dispersing agent Substances 0.000 claims description 18
- 125000000217 alkyl group Chemical group 0.000 claims description 14
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims description 14
- 239000003795 chemical substances by application Substances 0.000 claims description 13
- 239000006185 dispersion Substances 0.000 claims description 13
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 claims description 12
- 239000005056 polyisocyanate Substances 0.000 claims description 12
- 229920001228 polyisocyanate Polymers 0.000 claims description 12
- 150000002148 esters Chemical class 0.000 claims description 10
- 239000001361 adipic acid Substances 0.000 claims description 9
- 235000011037 adipic acid Nutrition 0.000 claims description 9
- 229920001290 polyvinyl ester Polymers 0.000 claims description 9
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 claims description 8
- 239000004593 Epoxy Substances 0.000 claims description 7
- 239000001257 hydrogen Substances 0.000 claims description 7
- 229910052739 hydrogen Inorganic materials 0.000 claims description 7
- 239000007787 solid Substances 0.000 claims description 7
- 239000002023 wood Substances 0.000 claims description 7
- 239000005057 Hexamethylene diisocyanate Substances 0.000 claims description 6
- 125000003545 alkoxy group Chemical group 0.000 claims description 6
- 229910052731 fluorine Inorganic materials 0.000 claims description 6
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 claims description 6
- 239000000123 paper Substances 0.000 claims description 6
- 229920000098 polyolefin Polymers 0.000 claims description 6
- 239000004800 polyvinyl chloride Substances 0.000 claims description 6
- 229920000915 polyvinyl chloride Polymers 0.000 claims description 6
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 claims description 5
- 230000002378 acidificating effect Effects 0.000 claims description 5
- 229910052799 carbon Inorganic materials 0.000 claims description 5
- 238000004132 cross linking Methods 0.000 claims description 5
- AHHWIHXENZJRFG-UHFFFAOYSA-N oxetane Chemical compound C1COC1 AHHWIHXENZJRFG-UHFFFAOYSA-N 0.000 claims description 5
- 229920000515 polycarbonate Polymers 0.000 claims description 5
- 239000004417 polycarbonate Substances 0.000 claims description 5
- 229920005906 polyester polyol Polymers 0.000 claims description 5
- ORLQHILJRHBSAY-UHFFFAOYSA-N [1-(hydroxymethyl)cyclohexyl]methanol Chemical compound OCC1(CO)CCCCC1 ORLQHILJRHBSAY-UHFFFAOYSA-N 0.000 claims description 4
- 150000007513 acids Chemical class 0.000 claims description 4
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 4
- RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical compound O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 claims description 4
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 4
- 229910052751 metal Inorganic materials 0.000 claims description 4
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- 125000001931 aliphatic group Chemical group 0.000 claims description 3
- 125000003118 aryl group Chemical group 0.000 claims description 3
- 238000001035 drying Methods 0.000 claims description 3
- 239000011737 fluorine Substances 0.000 claims description 3
- NIMLQBUJDJZYEJ-UHFFFAOYSA-N isophorone diisocyanate Chemical group CC1(C)CC(N=C=O)CC(C)(CN=C=O)C1 NIMLQBUJDJZYEJ-UHFFFAOYSA-N 0.000 claims description 3
- 238000002156 mixing Methods 0.000 claims description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 2
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- 230000000379 polymerizing effect Effects 0.000 claims description 2
- 229920002554 vinyl polymer Polymers 0.000 claims description 2
- 239000004721 Polyphenylene oxide Substances 0.000 claims 6
- 125000004429 atom Chemical group 0.000 claims 6
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims 6
- 229920000570 polyether Polymers 0.000 claims 6
- 150000004292 cyclic ethers Chemical group 0.000 claims 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims 4
- 150000008064 anhydrides Chemical class 0.000 claims 4
- 125000001153 fluoro group Chemical group F* 0.000 claims 4
- BGJSXRVXTHVRSN-UHFFFAOYSA-N 1,3,5-trioxane Chemical compound C1OCOCO1 BGJSXRVXTHVRSN-UHFFFAOYSA-N 0.000 claims 3
- VDFVNEFVBPFDSB-UHFFFAOYSA-N 1,3-dioxane Chemical compound C1COCOC1 VDFVNEFVBPFDSB-UHFFFAOYSA-N 0.000 claims 3
- 229930182556 Polyacetal Natural products 0.000 claims 3
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- 229920006295 polythiol Polymers 0.000 claims 3
- 150000005846 sugar alcohols Polymers 0.000 claims 3
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 claims 2
- UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 claims 2
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims 2
- LGRFSURHDFAFJT-UHFFFAOYSA-N Phthalic anhydride Natural products C1=CC=C2C(=O)OC(=O)C2=C1 LGRFSURHDFAFJT-UHFFFAOYSA-N 0.000 claims 2
- JHIWVOJDXOSYLW-UHFFFAOYSA-N butyl 2,2-difluorocyclopropane-1-carboxylate Chemical compound CCCCOC(=O)C1CC1(F)F JHIWVOJDXOSYLW-UHFFFAOYSA-N 0.000 claims 2
- PAPBSGBWRJIAAV-UHFFFAOYSA-N ε-Caprolactone Chemical compound O=C1CCCCCO1 PAPBSGBWRJIAAV-UHFFFAOYSA-N 0.000 claims 2
- 125000001963 4 membered heterocyclic group Chemical group 0.000 claims 1
- 125000002373 5 membered heterocyclic group Chemical group 0.000 claims 1
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 claims 1
- 239000012736 aqueous medium Substances 0.000 claims 1
- 125000004433 nitrogen atom Chemical group N* 0.000 claims 1
- 125000000466 oxiranyl group Chemical group 0.000 claims 1
- 150000001252 acrylic acid derivatives Chemical class 0.000 abstract description 16
- 239000000126 substance Substances 0.000 abstract description 9
- 238000005299 abrasion Methods 0.000 abstract description 5
- 238000002360 preparation method Methods 0.000 description 60
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 27
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- 239000004480 active ingredient Substances 0.000 description 21
- 230000003111 delayed effect Effects 0.000 description 19
- LISFMEBWQUVKPJ-UHFFFAOYSA-N quinolin-2-ol Chemical compound C1=CC=C2NC(=O)C=CC2=C1 LISFMEBWQUVKPJ-UHFFFAOYSA-N 0.000 description 17
- 150000001875 compounds Chemical class 0.000 description 16
- MYSWGUAQZAJSOK-UHFFFAOYSA-N ciprofloxacin Chemical compound C12=CC(N3CCNCC3)=C(F)C=C2C(=O)C(C(=O)O)=CN1C1CC1 MYSWGUAQZAJSOK-UHFFFAOYSA-N 0.000 description 14
- 235000010979 hydroxypropyl methyl cellulose Nutrition 0.000 description 13
- 229920003088 hydroxypropyl methyl cellulose Polymers 0.000 description 13
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 12
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- HQKMJHAJHXVSDF-UHFFFAOYSA-L magnesium stearate Chemical compound [Mg+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O HQKMJHAJHXVSDF-UHFFFAOYSA-L 0.000 description 10
- 239000007864 aqueous solution Substances 0.000 description 9
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- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 8
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- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/0804—Manufacture of polymers containing ionic or ionogenic groups
- C08G18/0819—Manufacture of polymers containing ionic or ionogenic groups containing anionic or anionogenic groups
- C08G18/0823—Manufacture of polymers containing ionic or ionogenic groups containing anionic or anionogenic groups containing carboxylate salt groups or groups forming them
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/10—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
- C08G18/12—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step using two or more compounds having active hydrogen in the first polymerisation step
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/30—Low-molecular-weight compounds
- C08G18/38—Low-molecular-weight compounds having heteroatoms other than oxygen
- C08G18/3802—Low-molecular-weight compounds having heteroatoms other than oxygen having halogens
- C08G18/3804—Polyhydroxy compounds
- C08G18/3812—Polyhydroxy compounds having fluorine atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
- C08G18/46—Polycondensates having carboxylic or carbonic ester groups in the main chain having heteroatoms other than oxygen
- C08G18/4607—Polycondensates having carboxylic or carbonic ester groups in the main chain having heteroatoms other than oxygen having halogens
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31551—Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Polyurethanes Or Polyureas (AREA)
- Paints Or Removers (AREA)
- Macromonomer-Based Addition Polymer (AREA)
- Laminated Bodies (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Medicinal Preparation (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US09/610,743 US6465565B1 (en) | 2000-07-06 | 2000-07-06 | Anionic waterborne polyurethane dispersions containing polyfluorooxetanes |
| US09/833,383 US6465566B2 (en) | 2000-07-06 | 2001-04-12 | Anionic waterborne polyurethane dispersions containing polyfluorooxetanes |
| PCT/US2001/019725 WO2002004538A2 (en) | 2000-07-06 | 2001-06-20 | Anionic waterborne polyurethane dispersions containing polyfluorooxetanes |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| MXPA02012667A true MXPA02012667A (es) | 2003-05-14 |
Family
ID=27086342
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MXPA02012667A MXPA02012667A (es) | 2000-07-06 | 2001-06-20 | Dispersiones acuosas anionicas de poliuretano que contienen polifluorooxetanos. |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US6465566B2 (https=) |
| EP (1) | EP1297047B1 (https=) |
| JP (1) | JP2004502844A (https=) |
| AT (1) | ATE345358T1 (https=) |
| BR (1) | BR0112219A (https=) |
| DE (1) | DE60124548T2 (https=) |
| MX (1) | MXPA02012667A (https=) |
| WO (1) | WO2002004538A2 (https=) |
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| US6673889B1 (en) * | 1999-06-28 | 2004-01-06 | Omnova Solutions Inc. | Radiation curable coating containing polyfuorooxetane |
| US7081277B1 (en) * | 1999-10-22 | 2006-07-25 | Fujitsu Limited | Magnetic disk drive having a surface coating on a magnetic disk |
| US6962966B2 (en) * | 1999-12-28 | 2005-11-08 | Omnova Solutions Inc. | Monohydric polyfluorooxetane oligomers, polymers, and copolymers and coatings containing the same |
| WO2002092660A2 (en) | 2001-05-14 | 2002-11-21 | Omnova Soltions Inc | Polymeric surfactants derived from cyclic monomers having pendant fluorinated carbon groups |
| GB2383332B (en) * | 2001-12-20 | 2005-08-17 | Whitford Plastics Ltd | Coating system for flexible extrusions |
| DE10208567A1 (de) | 2002-02-27 | 2003-09-11 | Degussa Construction Chem Gmbh | Wässriges fluormodifiziertes Polyurethansystem für Anti-Graffiti- und Anti-Soiling-Beschichtungen |
| US20030207629A1 (en) * | 2002-05-01 | 2003-11-06 | Sobieski Robert T. | Highly durable, coated fabrics exhibiting hydrophobicity, oleophobicity and stain resistance and related methods |
| ITMI20021228A1 (it) * | 2002-06-06 | 2003-12-09 | Ausimont Spa | Composizioni di poliuretani reticolabili |
| DE10256494A1 (de) * | 2002-12-03 | 2004-06-24 | Basf Ag | Stabilisierte Zusammensetzungen, enthaltend polyfunktionelle Aziridinverbindungen |
| US7217440B2 (en) * | 2003-06-13 | 2007-05-15 | Essilor International Compagnie Generale D'optique | Process for replacing an initial outermost coating layer of a coated optical lens with a different coating layer or by depositing thereon a different coating layer |
| WO2005010074A1 (en) * | 2003-07-23 | 2005-02-03 | Omnova Solutions Inc. | Radiation polymerization of fluorooxetanes |
| DE102005013767A1 (de) * | 2005-03-22 | 2006-09-28 | Relius Coatings Gmbh & Co. Kg | Zubereitung zur Beschichtung von Substratoberflächen |
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| US20100189809A1 (en) * | 2006-08-23 | 2010-07-29 | The Clorox Company | Foamable Compositions Containing Alcohol |
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| US8343631B2 (en) | 2010-11-03 | 2013-01-01 | Toyota Motor Engineering & Manufacturing North America, Inc. | Low-gloss, two-component clear coats, articles of manufacture having low-gloss, two-component clear coats, and methods for applying the same |
| WO2013081892A1 (en) * | 2011-11-30 | 2013-06-06 | U.S. Coatings Ip Co. Llc | Coating composition |
| US9822275B2 (en) | 2013-03-15 | 2017-11-21 | Valspar Sourcing, Inc. | Water-based compositions that resist dirt pick-up |
| US10196537B2 (en) | 2013-03-15 | 2019-02-05 | The Sherwin-Williams Company | Dirt pick-up resistant composition |
| US10221322B2 (en) | 2013-03-15 | 2019-03-05 | The Sherwin-Williams Company | Dirt pick-up resistant composition |
| US9975295B2 (en) | 2014-08-12 | 2018-05-22 | Carbon, Inc. | Acceleration of stereolithography |
| EP3191553A4 (en) | 2014-09-12 | 2018-08-22 | Valspar Sourcing, Inc. | Water-based coating compositions that resist dirt pickup |
| WO2017116612A2 (en) * | 2015-12-04 | 2017-07-06 | United States Of America As Represented By The Administrator Of The National Aeronautics And Space Administration | Synthesis and development of polyurethane coatings containing flourine groups for abhesive applications |
| WO2017112483A2 (en) * | 2015-12-22 | 2017-06-29 | Carbon, Inc. | Accelerants for additive manufacturing with dual cure resins |
| CN105482680B (zh) * | 2016-01-06 | 2017-08-22 | 天津科技大学 | 紫外光固化超支化全氟聚醚聚氨酯丙烯酸酯涂料 |
| CN108885415B (zh) | 2016-03-29 | 2021-11-09 | 三菱化学株式会社 | 电子照相感光体、电子照相感光体盒、成像装置和氟系树脂用分散剂 |
| CN110770271B (zh) | 2017-05-19 | 2023-04-18 | 埃特纳科技有限公司 | 官能化氟化单体的制备方法、氟化单体及用于制备其的组合物 |
| US20190040181A1 (en) * | 2017-08-02 | 2019-02-07 | Covestro Llc | One component polyurethane dispersion for vinyl windows |
| US11059935B2 (en) | 2017-08-02 | 2021-07-13 | Covestro Llc | One component polyurethane dispersion for vinyl windows and other substrates |
| US11028296B2 (en) | 2017-08-02 | 2021-06-08 | Covestro Llc | One component polyurethane dispersion for vinyl windows and other substrates |
| WO2019232051A1 (en) | 2018-05-29 | 2019-12-05 | Swimc Llc | Water-based compositions with long term gloss retention |
| CN111704851B (zh) * | 2018-11-07 | 2021-11-30 | 苏州太湖电工新材料股份有限公司 | 一种电动汽车用耐atf油的阻燃型绝缘漆的制备方法 |
| CN109666124B (zh) * | 2018-12-12 | 2020-12-22 | 合众（佛山）化工有限公司 | 一种聚苯乙烯微球改性聚氨酯水性树脂及制备方法 |
| CN110041488B (zh) * | 2019-04-09 | 2021-04-16 | 安徽大学 | 一种含氟酰亚胺改性水性聚氨酯的制备方法 |
| US20230159789A1 (en) * | 2020-02-18 | 2023-05-25 | Akzo Nobel Coatings International B.V. | Waterborne UV Curable Coating Composition for Anti-Stain and Anti-Scratch Coatings |
| CN111234166A (zh) * | 2020-04-02 | 2020-06-05 | 昆山万杰新材料科技有限公司 | 一种弹性树脂及其制备方法和应用 |
| CN111234158A (zh) * | 2020-04-02 | 2020-06-05 | 昆山万杰新材料科技有限公司 | 一种基于多元醇的弹性树脂及其制备方法和应用 |
| US11725079B2 (en) | 2020-07-20 | 2023-08-15 | The Boeing Company | Polyimide compositions and articles incorporating the same |
| US11845834B2 (en) | 2020-09-23 | 2023-12-19 | The Boeing Company | Polyamide compositions and articles incorporating the same |
| US11697709B2 (en) * | 2020-10-07 | 2023-07-11 | The Boeing Company | Poly(arylene ether) compositions and articles incorporating the same |
| CN116535022B (zh) * | 2023-05-15 | 2024-09-03 | 江苏聚凯环保科技有限公司 | 一种防堵孔的抗结垢膜片微孔曝气器及其制备方法 |
| CN117467304A (zh) * | 2023-10-30 | 2024-01-30 | 厦门市太昱环保材料有限公司 | 一种人造革水性易去污处理剂、制备方法及应用 |
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| US3834823A (en) | 1972-05-25 | 1974-09-10 | Gillette Co | Marking boards and erasable ink compositions therefor |
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| WO1996023828A1 (en) | 1995-01-30 | 1996-08-08 | Dsm N.V. | Radiation curable composition comprising fluorinated urethane oligomer |
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| DE19634721C2 (de) * | 1996-08-28 | 2002-09-12 | Alfred Krueger | Beschichtungsmittel mit einem Gehalt von Fluor enthaltendem modifizierten Polyester und die Verwendung der Beschichtungsmittel |
| US6313335B1 (en) * | 1997-11-25 | 2001-11-06 | 3M Innovative Properties | Room temperature curable silane terminated and stable waterborne polyurethane dispersions which contain fluorine and/or silicone and low surface energy coatings prepared therefrom |
| JP2002505218A (ja) | 1998-03-05 | 2002-02-19 | オムノヴア ソリユーシヨンズ インコーポレーテツド | 清掃容易なポリマーラミネート |
| US6383651B1 (en) | 1998-03-05 | 2002-05-07 | Omnova Solutions Inc. | Polyester with partially fluorinated side chains |
| US6168866B1 (en) | 1998-08-19 | 2001-01-02 | 3M Innovative Properties Company | Abrasion and stain resistant curable fluorinated coating |
| JP3275859B2 (ja) | 1998-12-15 | 2002-04-22 | 村田機械株式会社 | コンベア装置 |
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2001
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- 2001-06-20 EP EP20010948526 patent/EP1297047B1/en not_active Expired - Lifetime
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- 2001-06-20 JP JP2002509396A patent/JP2004502844A/ja active Pending
- 2001-06-20 BR BR0112219A patent/BR0112219A/pt not_active IP Right Cessation
- 2001-06-20 WO PCT/US2001/019725 patent/WO2002004538A2/en not_active Ceased
- 2001-06-20 DE DE2001624548 patent/DE60124548T2/de not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| WO2002004538A2 (en) | 2002-01-17 |
| JP2004502844A (ja) | 2004-01-29 |
| WO2002004538A3 (en) | 2002-08-22 |
| EP1297047A2 (en) | 2003-04-02 |
| BR0112219A (pt) | 2003-05-06 |
| DE60124548D1 (de) | 2006-12-28 |
| US6465566B2 (en) | 2002-10-15 |
| DE60124548T2 (de) | 2007-05-24 |
| US20020026006A1 (en) | 2002-02-28 |
| ATE345358T1 (de) | 2006-12-15 |
| EP1297047B1 (en) | 2006-11-15 |
| WO2002004538A8 (en) | 2002-02-21 |
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