MXPA02012242A - Proceso de epoxidacion directa utilizando un sistema de catalizador mezclado. - Google Patents
Proceso de epoxidacion directa utilizando un sistema de catalizador mezclado.Info
- Publication number
- MXPA02012242A MXPA02012242A MXPA02012242A MXPA02012242A MXPA02012242A MX PA02012242 A MXPA02012242 A MX PA02012242A MX PA02012242 A MXPA02012242 A MX PA02012242A MX PA02012242 A MXPA02012242 A MX PA02012242A MX PA02012242 A MXPA02012242 A MX PA02012242A
- Authority
- MX
- Mexico
- Prior art keywords
- catalyst system
- mixed catalyst
- epoxidation process
- direct epoxidation
- titanium zeolite
- Prior art date
Links
- 239000003054 catalyst Substances 0.000 title abstract 4
- 238000006735 epoxidation reaction Methods 0.000 title abstract 2
- 238000000034 method Methods 0.000 title 1
- 150000001336 alkenes Chemical class 0.000 abstract 3
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 abstract 2
- 229910021536 Zeolite Inorganic materials 0.000 abstract 2
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 abstract 2
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 abstract 2
- 239000010931 gold Substances 0.000 abstract 2
- 229910052737 gold Inorganic materials 0.000 abstract 2
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 abstract 2
- 229910052719 titanium Inorganic materials 0.000 abstract 2
- 239000010936 titanium Substances 0.000 abstract 2
- 239000010457 zeolite Substances 0.000 abstract 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 150000002118 epoxides Chemical class 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 abstract 1
- 239000007791 liquid phase Substances 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 239000001301 oxygen Substances 0.000 abstract 1
- 229910052760 oxygen Inorganic materials 0.000 abstract 1
- 230000001131 transforming effect Effects 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D301/00—Preparation of oxiranes
- C07D301/02—Synthesis of the oxirane ring
- C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
- C07D301/04—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen
- C07D301/06—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the liquid phase
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
- B01J21/063—Titanium; Oxides or hydroxides thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/48—Silver or gold
- B01J23/52—Gold
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/89—Silicates, aluminosilicates or borosilicates of titanium, zirconium or hafnium
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Epoxy Compounds (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
Una mezcla de catalizador que contiene una zeolita de titanio y un catalizador que contiene oro soportado es altamente selectiva y productiva para transformar las olefinas a epoxidos en la reaccion de fase líquida de una olefina, hidrogeno, y oxígeno. Esto es particularmente sorprendente debido a que ni la zeolita de titanio ni el catalizador que contiene oro soportado solo es eficaz en la epoxidacion de olefina.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US09/624,942 US6307073B1 (en) | 2000-07-25 | 2000-07-25 | Direct epoxidation process using a mixed catalyst system |
PCT/US2001/018949 WO2002008214A1 (en) | 2000-07-25 | 2001-06-13 | Direct epoxidation process using a mixed catalyst system |
Publications (1)
Publication Number | Publication Date |
---|---|
MXPA02012242A true MXPA02012242A (es) | 2003-06-06 |
Family
ID=24503955
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
MXPA02012242A MXPA02012242A (es) | 2000-07-25 | 2001-06-13 | Proceso de epoxidacion directa utilizando un sistema de catalizador mezclado. |
Country Status (13)
Country | Link |
---|---|
US (1) | US6307073B1 (es) |
EP (1) | EP1303504B2 (es) |
JP (1) | JP4303957B2 (es) |
KR (1) | KR100795213B1 (es) |
CN (1) | CN1214019C (es) |
AT (1) | ATE274503T1 (es) |
AU (1) | AU2001268369A1 (es) |
BR (1) | BR0112736A (es) |
CA (1) | CA2410214A1 (es) |
DE (1) | DE60105169T3 (es) |
ES (1) | ES2225567T5 (es) |
MX (1) | MXPA02012242A (es) |
WO (1) | WO2002008214A1 (es) |
Families Citing this family (23)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE19717320A1 (de) * | 1997-04-24 | 1998-10-29 | Basf Ag | Einstufiges Verfahren zur Herstellung von Glykolmonoethern aus Olefinen |
JP2000228006A (ja) * | 1999-02-05 | 2000-08-15 | Alps Electric Co Ltd | ボンディングパットおよびバンプを用いた接合体、および磁気ヘッド装置 |
US6534661B1 (en) * | 2000-12-28 | 2003-03-18 | Hydrocarbon Technologies, Inc. | Integrated process and dual-function catalyst for olefin epoxidation |
US20030092921A1 (en) * | 2001-06-05 | 2003-05-15 | Stangland Eric E. | Method of making gold-titania catalyst for oxidation of hydrocarbons |
US6441204B1 (en) | 2001-10-19 | 2002-08-27 | Arco Chemical Technology, L.P. | Direct epoxidation process using a mixed catalyst system |
US6498259B1 (en) | 2001-10-19 | 2002-12-24 | Arco Chemical Technology L.P. | Direct epoxidation process using a mixed catalyst system |
US6403815B1 (en) * | 2001-11-29 | 2002-06-11 | Arco Chemical Technology, L.P. | Direct epoxidation process using a mixed catalyst system |
US6819111B2 (en) | 2002-11-22 | 2004-11-16 | Baker Hughes Incorporated | Method of determining vertical and horizontal resistivity, and relative dip in anisotropic earth formations having an arbitrary electro-magnetic antenna combination and orientation with additional rotation and position measurements |
US7067103B2 (en) | 2003-03-28 | 2006-06-27 | Headwaters Nanokinetix, Inc. | Direct hydrogen peroxide production using staged hydrogen addition |
DE10320634A1 (de) * | 2003-05-08 | 2004-11-18 | Basf Ag | Verfahren zur Umsetzung einer organischen Verbindung mit einem Hydroperoxid |
US7011807B2 (en) * | 2003-07-14 | 2006-03-14 | Headwaters Nanokinetix, Inc. | Supported catalysts having a controlled coordination structure and methods for preparing such catalysts |
US7045479B2 (en) | 2003-07-14 | 2006-05-16 | Headwaters Nanokinetix, Inc. | Intermediate precursor compositions used to make supported catalysts having a controlled coordination structure and methods for preparing such compositions |
US7144565B2 (en) | 2003-07-29 | 2006-12-05 | Headwaters Nanokinetix, Inc. | Process for direct catalytic hydrogen peroxide production |
US20050171365A1 (en) | 2004-02-03 | 2005-08-04 | Grey Roger A. | Epoxidation process using a mixed catalyst system |
US6972337B1 (en) * | 2004-08-12 | 2005-12-06 | Lyondell Chemical Technology, L.P. | Epoxidation catalyst |
ES2261080B1 (es) * | 2005-04-19 | 2007-12-16 | Universidad Politecnica De Valencia | Procedimiento y catalizadores para la expoxidacion de compuestos olefinicos en presencia de oxigeno. |
US7718710B2 (en) | 2006-03-17 | 2010-05-18 | Headwaters Technology Innovation, Llc | Stable concentrated metal colloids and methods of making same |
US7696367B2 (en) | 2007-04-10 | 2010-04-13 | Lyondell Chemical Technology, L.P. | Direct epoxidation process using a mixed catalyst system |
US7387981B1 (en) * | 2007-06-28 | 2008-06-17 | Lyondell Chemical Technology, L.P. | Direct epoxidation catalyst and process |
US20090042718A1 (en) * | 2007-08-10 | 2009-02-12 | Kaminsky Mark P | Direct epoxidation catalyst and process |
JP5182849B2 (ja) * | 2007-08-27 | 2013-04-17 | 独立行政法人産業技術総合研究所 | アルカンからのアルキレンオキシドの直接製造 |
KR102315612B1 (ko) | 2021-01-27 | 2021-10-21 | 주식회사 청림이앤씨 | 조립이 용이한 광어댑터 패널이 구비된 광케이블 단자함 |
CN116174031B (zh) * | 2023-02-15 | 2024-08-06 | 四川九天五洋新材料有限责任公司 | 一种催化剂及其制备方法和应用 |
Family Cites Families (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3351635A (en) | 1966-03-14 | 1967-11-07 | Halcon International Inc | Epoxidation process |
US4367342A (en) | 1969-04-02 | 1983-01-04 | Shell Oil Company | Olefin epoxidation |
IT1127311B (it) | 1979-12-21 | 1986-05-21 | Anic Spa | Materiale sintetico,cristallino,poroso costituito da ossidi di silicio e titanio,metodo per la sua preparazione e suoi usi |
IT1152299B (it) | 1982-07-28 | 1986-12-31 | Anic Spa | Procedimento per l'espossidazione di composti olefinici |
IT1216500B (it) | 1988-03-23 | 1990-03-08 | Eniricerche S P A Milano Enich | Procedimento per la preparazione di materiali sintetici cristallini porosi costituiti da ossidi di silicio e titanio. |
JP3044836B2 (ja) | 1991-05-28 | 2000-05-22 | 東ソー株式会社 | プロピレンオキシドの製法 |
DE4425672A1 (de) † | 1994-07-20 | 1996-01-25 | Basf Ag | Oxidationskatalysator, Verfahren zu seiner Herstellung und Oxidationsverfahren unter Verwendung des Oxidationskatalysators |
JP2615432B2 (ja) † | 1994-10-28 | 1997-05-28 | 工業技術院長 | 金−酸化チタン含有触媒による炭化水素の部分酸化方法 |
DE19607577A1 (de) * | 1996-02-29 | 1997-09-04 | Basf Ag | Netzkatalysator auf Basis von Titan- oder Vanadiumzeolithen und inerten Netzgeweben zur Beschleunigung von Oxidationsreaktionen |
DE19623609A1 (de) * | 1996-06-13 | 1997-12-18 | Basf Ag | Oxidationskatalysator und Verfahren zur Herstellung von Epoxiden aus Olefinen, Wasserstoff und Sauerstoff unter Verwendung des Oxidationskatalysators |
EP0918762B1 (en) | 1996-07-01 | 2001-05-16 | The Dow Chemical Company | Process for the direct oxidation of olefins to olefin oxides |
US6008388A (en) * | 1998-04-16 | 1999-12-28 | Arco Chemical Technology, L.P. | Epoxidation process |
US6005123A (en) * | 1998-04-16 | 1999-12-21 | Arco Chemical Technology, L.P. | Epoxidation process |
US6255499B1 (en) † | 1999-04-08 | 2001-07-03 | The Dow Chemical Company | Process for the hydro-oxidation of olefins to olefin oxides using oxidized gold catalyst |
US6063942A (en) * | 1999-09-27 | 2000-05-16 | Arco Chemical Technology, L.P. | Catalyst preparation and epoxidation process |
-
2000
- 2000-07-25 US US09/624,942 patent/US6307073B1/en not_active Expired - Fee Related
-
2001
- 2001-06-13 KR KR1020037000952A patent/KR100795213B1/ko not_active IP Right Cessation
- 2001-06-13 MX MXPA02012242A patent/MXPA02012242A/es not_active Application Discontinuation
- 2001-06-13 DE DE60105169T patent/DE60105169T3/de not_active Expired - Lifetime
- 2001-06-13 ES ES01946299T patent/ES2225567T5/es not_active Expired - Lifetime
- 2001-06-13 CA CA002410214A patent/CA2410214A1/en not_active Abandoned
- 2001-06-13 AT AT01946299T patent/ATE274503T1/de not_active IP Right Cessation
- 2001-06-13 EP EP01946299A patent/EP1303504B2/en not_active Expired - Lifetime
- 2001-06-13 WO PCT/US2001/018949 patent/WO2002008214A1/en active IP Right Grant
- 2001-06-13 JP JP2002514120A patent/JP4303957B2/ja not_active Expired - Fee Related
- 2001-06-13 AU AU2001268369A patent/AU2001268369A1/en not_active Abandoned
- 2001-06-13 CN CNB018133282A patent/CN1214019C/zh not_active Expired - Fee Related
- 2001-06-13 BR BR0112736-5A patent/BR0112736A/pt not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
EP1303504A1 (en) | 2003-04-23 |
CN1214019C (zh) | 2005-08-10 |
BR0112736A (pt) | 2003-06-24 |
KR20030024802A (ko) | 2003-03-26 |
DE60105169T3 (de) | 2008-08-14 |
ATE274503T1 (de) | 2004-09-15 |
US6307073B1 (en) | 2001-10-23 |
CN1444574A (zh) | 2003-09-24 |
EP1303504B2 (en) | 2008-02-20 |
DE60105169T2 (de) | 2005-09-08 |
EP1303504B1 (en) | 2004-08-25 |
JP2004504392A (ja) | 2004-02-12 |
AU2001268369A1 (en) | 2002-02-05 |
ES2225567T5 (es) | 2008-06-16 |
WO2002008214A1 (en) | 2002-01-31 |
CA2410214A1 (en) | 2002-01-31 |
JP4303957B2 (ja) | 2009-07-29 |
KR100795213B1 (ko) | 2008-01-16 |
DE60105169D1 (de) | 2004-09-30 |
ES2225567T3 (es) | 2005-03-16 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
FA | Abandonment or withdrawal |