MX9303429A - Proceso para remover iones de soluciones usando un complejo con hidrocarburos que contienen azufre, que contienen tambien grupo de retiro de electrones ligados a una matriz hidrofilica solida. - Google Patents

Proceso para remover iones de soluciones usando un complejo con hidrocarburos que contienen azufre, que contienen tambien grupo de retiro de electrones ligados a una matriz hidrofilica solida.

Info

Publication number
MX9303429A
MX9303429A MX9303429A MX9303429A MX9303429A MX 9303429 A MX9303429 A MX 9303429A MX 9303429 A MX9303429 A MX 9303429A MX 9303429 A MX9303429 A MX 9303429A MX 9303429 A MX9303429 A MX 9303429A
Authority
MX
Mexico
Prior art keywords
sulfur
compound
ions
group containing
withdrawing group
Prior art date
Application number
MX9303429A
Other languages
English (en)
Inventor
Ronald L Bruening
Bryon J Tarbet
Reed M Izatt
Jerald S Bradshaw
Original Assignee
Univ Brigham Young
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Univ Brigham Young filed Critical Univ Brigham Young
Publication of MX9303429A publication Critical patent/MX9303429A/es

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J45/00—Ion-exchange in which a complex or a chelate is formed; Use of material as complex or chelate forming ion-exchangers; Treatment of material for improving the complex or chelate forming ion-exchange properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/32—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
    • B01J20/3231—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating characterised by the coating or impregnating layer
    • B01J20/3242—Layers with a functional group, e.g. an affinity material, a ligand, a reactant or a complexing group
    • B01J20/3244—Non-macromolecular compounds
    • B01J20/3246—Non-macromolecular compounds having a well defined chemical structure
    • B01J20/3257—Non-macromolecular compounds having a well defined chemical structure the functional group or the linking, spacer or anchoring group as a whole comprising at least one of the heteroatoms nitrogen, oxygen or sulfur together with at least one silicon atom, these atoms not being part of the carrier as such
    • B01J20/3261—Non-macromolecular compounds having a well defined chemical structure the functional group or the linking, spacer or anchoring group as a whole comprising at least one of the heteroatoms nitrogen, oxygen or sulfur together with at least one silicon atom, these atoms not being part of the carrier as such comprising a cyclic structure not containing any of the heteroatoms nitrogen, oxygen or sulfur, e.g. aromatic structures
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/32—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
    • B01J20/3231—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating characterised by the coating or impregnating layer
    • B01J20/3242—Layers with a functional group, e.g. an affinity material, a ligand, a reactant or a complexing group
    • B01J20/3244—Non-macromolecular compounds
    • B01J20/3246—Non-macromolecular compounds having a well defined chemical structure
    • B01J20/3257—Non-macromolecular compounds having a well defined chemical structure the functional group or the linking, spacer or anchoring group as a whole comprising at least one of the heteroatoms nitrogen, oxygen or sulfur together with at least one silicon atom, these atoms not being part of the carrier as such
    • B01J20/3263—Non-macromolecular compounds having a well defined chemical structure the functional group or the linking, spacer or anchoring group as a whole comprising at least one of the heteroatoms nitrogen, oxygen or sulfur together with at least one silicon atom, these atoms not being part of the carrier as such comprising a cyclic structure containing at least one of the heteroatoms nitrogen, oxygen or sulfur, e.g. an heterocyclic or heteroaromatic structure
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2913—Rod, strand, filament or fiber
    • Y10T428/2933—Coated or with bond, impregnation or core
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2913—Rod, strand, filament or fiber
    • Y10T428/2933—Coated or with bond, impregnation or core
    • Y10T428/2938—Coating on discrete and individual rods, strands or filaments
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2913—Rod, strand, filament or fiber
    • Y10T428/2933—Coated or with bond, impregnation or core
    • Y10T428/2962—Silane, silicone or siloxane in coating
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]
    • Y10T428/2991—Coated
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]
    • Y10T428/2991—Coated
    • Y10T428/2993—Silicic or refractory material containing [e.g., tungsten oxide, glass, cement, etc.]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]
    • Y10T428/2991—Coated
    • Y10T428/2993—Silicic or refractory material containing [e.g., tungsten oxide, glass, cement, etc.]
    • Y10T428/2995—Silane, siloxane or silicone coating

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Analytical Chemistry (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Treatment Of Water By Ion Exchange (AREA)
  • Manufacture And Refinement Of Metals (AREA)
  • Physical Water Treatments (AREA)
  • Treatment Of Liquids With Adsorbents In General (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Physical Or Chemical Processes And Apparatus (AREA)
  • Removal Of Specific Substances (AREA)
  • Pyridine Compounds (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Extraction Or Liquid Replacement (AREA)

Abstract

Un método para la remoción y concentración de iones deseados tales como Pd(II), Ru(III), Pd(IV), Au(I), Ag(I), y Hg(II) de una solución de una fuente de iones múltiple que puede contener concentraciones más grandes de otros iones indeseados incluyendo H+ que comprende poner la solución de fuente en contacto con un compuesto que comprende un grupo de retiro de electrones y azufre que contiene un grupo coordinador ligado covalentemente a través de un agrupamiento de silicio separador orgánico hacia un soporte inorgánico sólido. El grupo de retiro de azufre y electrones que contienen la porción(es) del grupo coordinador del compuesto que tiene una afinidad para los iones deseados a fin de formar un complejo removiendo de esta manera los iones deseados de solución de fuente o procedencia. Los iones deseados se remueven del compuesto poniendo en contacto el compuesto con un volumen mucho más pequeño de una solución receptora que tiene una mayor afinidad para los iones deseados que el grupo de retiro de azufre y electrones que contienen la porción del grupo coordinador del compuesto. El proceso es útil para remover los iones deseados e indeseados de las corrientes residuales acídicas, corrientes de refinación de metal y otras corrientes industriales o ambientales. La invención es también atraída hacia el grupo de retiro de azufre y electrones que contiene grupos coordinadores ligados covalentamente a través de un agrupamiento separador a un material de soporte sólido inorgánico hidrofílico.
MX9303429A 1992-06-08 1993-06-08 Proceso para remover iones de soluciones usando un complejo con hidrocarburos que contienen azufre, que contienen tambien grupo de retiro de electrones ligados a una matriz hidrofilica solida. MX9303429A (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US07/895,341 US5190661A (en) 1992-06-08 1992-06-08 Process of removing ions from solutions using a complex with sulfur-containing hydrocarbons

Publications (1)

Publication Number Publication Date
MX9303429A true MX9303429A (es) 1993-12-01

Family

ID=25404367

Family Applications (1)

Application Number Title Priority Date Filing Date
MX9303429A MX9303429A (es) 1992-06-08 1993-06-08 Proceso para remover iones de soluciones usando un complejo con hidrocarburos que contienen azufre, que contienen tambien grupo de retiro de electrones ligados a una matriz hidrofilica solida.

Country Status (19)

Country Link
US (3) US5190661A (es)
EP (1) EP0644799B1 (es)
JP (1) JP3307934B2 (es)
KR (1) KR100282687B1 (es)
CN (3) CN1050362C (es)
AT (1) ATE175133T1 (es)
AU (1) AU661917B2 (es)
BR (1) BR9306504A (es)
CA (1) CA2136635C (es)
DE (1) DE69322864T2 (es)
ES (1) ES2128430T3 (es)
FI (1) FI107534B (es)
HU (1) HUT69074A (es)
MX (1) MX9303429A (es)
NO (1) NO944702D0 (es)
PL (1) PL171797B1 (es)
RU (1) RU2116828C1 (es)
WO (1) WO1993025306A1 (es)
ZA (1) ZA934034B (es)

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Also Published As

Publication number Publication date
BR9306504A (pt) 1998-09-15
CN1152477A (zh) 1997-06-25
US5446182A (en) 1995-08-29
US5190661A (en) 1993-03-02
DE69322864D1 (de) 1999-02-11
FI945746A (fi) 1994-12-07
US5318846A (en) 1994-06-07
CN1087194C (zh) 2002-07-10
JP3307934B2 (ja) 2002-07-29
ATE175133T1 (de) 1999-01-15
CN1154875A (zh) 1997-07-23
CA2136635C (en) 2005-01-18
CN1090794A (zh) 1994-08-17
NO944702L (no) 1994-12-06
DE69322864T2 (de) 1999-05-27
HUT69074A (en) 1995-08-28
EP0644799B1 (en) 1998-12-30
CN1050362C (zh) 2000-03-15
EP0644799A4 (en) 1995-06-07
WO1993025306A1 (en) 1993-12-23
FI945746A0 (fi) 1994-12-07
ZA934034B (en) 1994-01-06
RU2116828C1 (ru) 1998-08-10
KR950701839A (ko) 1995-05-17
PL171797B1 (en) 1997-06-30
AU4530593A (en) 1994-01-04
FI107534B (fi) 2001-08-31
AU661917B2 (en) 1995-08-10
EP0644799A1 (en) 1995-03-29
NO944702D0 (no) 1994-12-06
RU94046331A (ru) 1996-10-27
JPH08500766A (ja) 1996-01-30
ES2128430T3 (es) 1999-05-16
CA2136635A1 (en) 1993-12-23
KR100282687B1 (ko) 2001-02-15
CN1093779C (zh) 2002-11-06

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