MX375856B - Proceso de polimerizacion cationica para la sintesis de polimeros nano-estructurados que contienen grafeno. - Google Patents
Proceso de polimerizacion cationica para la sintesis de polimeros nano-estructurados que contienen grafeno.Info
- Publication number
- MX375856B MX375856B MX2015014236A MX2015014236A MX375856B MX 375856 B MX375856 B MX 375856B MX 2015014236 A MX2015014236 A MX 2015014236A MX 2015014236 A MX2015014236 A MX 2015014236A MX 375856 B MX375856 B MX 375856B
- Authority
- MX
- Mexico
- Prior art keywords
- cationic polymerization
- nano
- synthesis
- polymerization process
- polymers containing
- Prior art date
Links
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title abstract 5
- 238000010538 cationic polymerization reaction Methods 0.000 title abstract 3
- 230000015572 biosynthetic process Effects 0.000 title abstract 2
- 229910021389 graphene Inorganic materials 0.000 title abstract 2
- 238000000034 method Methods 0.000 title abstract 2
- 229920000642 polymer Polymers 0.000 title abstract 2
- 238000003786 synthesis reaction Methods 0.000 title abstract 2
- 239000000178 monomer Substances 0.000 abstract 5
- 229920002554 vinyl polymer Polymers 0.000 abstract 5
- 229910002804 graphite Inorganic materials 0.000 abstract 3
- 239000010439 graphite Substances 0.000 abstract 3
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 abstract 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 2
- 229910052760 oxygen Inorganic materials 0.000 abstract 2
- 239000001301 oxygen Substances 0.000 abstract 2
- 230000003213 activating effect Effects 0.000 abstract 1
- 150000007522 mineralic acids Chemical class 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
- 238000002604 ultrasonography Methods 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
- C08F212/02—Monomers containing only one unsaturated aliphatic radical
- C08F212/04—Monomers containing only one unsaturated aliphatic radical containing one ring
- C08F212/06—Hydrocarbons
- C08F212/08—Styrene
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B32/00—Carbon; Compounds thereof
- C01B32/15—Nano-sized carbon materials
- C01B32/182—Graphene
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B32/00—Carbon; Compounds thereof
- C01B32/15—Nano-sized carbon materials
- C01B32/182—Graphene
- C01B32/184—Preparation
- C01B32/19—Preparation by exfoliation
- C01B32/192—Preparation by exfoliation starting from graphitic oxides
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B32/00—Carbon; Compounds thereof
- C01B32/20—Graphite
- C01B32/21—After-treatment
- C01B32/23—Oxidation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y40/00—Manufacture or treatment of nanostructures
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2204/00—Structure or properties of graphene
- C01B2204/04—Specific amount of layers or specific thickness
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2204/00—Structure or properties of graphene
- C01B2204/20—Graphene characterized by its properties
- C01B2204/30—Purity
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2204/00—Structure or properties of graphene
- C01B2204/20—Graphene characterized by its properties
- C01B2204/32—Size or surface area
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Nanotechnology (AREA)
- Inorganic Chemistry (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Composite Materials (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- General Physics & Mathematics (AREA)
- Physics & Mathematics (AREA)
- Polymerisation Methods In General (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Carbon And Carbon Compounds (AREA)
- Graft Or Block Polymers (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Other Resins Obtained By Reactions Not Involving Carbon-To-Carbon Unsaturated Bonds (AREA)
Abstract
Un proceso de polimerización catiónica para la síntesis de polímeros nano-estructurados que contienen grafeno que comprende hacer reaccionar óxido de grafito dispersado en un solvente por medio de ultrasonidos, con al menos un monómero de vinilo y al menos un monómero aromático de vinilo, en la presencia de al menos un ácido inorgánico fuerte y adecuado para la activación de una polimerización catiónica, en donde: - el óxido de grafito contiene el 5% a 60% en peso de oxígeno unido, - el monómero de vinilo contiene al menos un grupo de carboxílico en donde la relación entre el oxígeno unido al óxido y los grupos carboxílicos varía de 1:10 a 10:1 en moles por mol, y - la relación entre el monómero aromático de vinilo y la suma de la cantidad de óxido de grafito y el monómero de vinilo que contiene grupos carboxílicos varía de 50% a 99% en peso.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IT000834A ITMI20130834A1 (it) | 2013-05-22 | 2013-05-22 | Procedimento di polimerizzazione cationica per la sintesi di polimeri nano-strutturati contenenti grafene |
| PCT/EP2014/060291 WO2014187796A1 (en) | 2013-05-22 | 2014-05-20 | Cationic polymerization process for the synthesis of nano-structured polymers containing graphene |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| MX2015014236A MX2015014236A (es) | 2016-03-03 |
| MX375856B true MX375856B (es) | 2025-03-07 |
Family
ID=48670714
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MX2015014236A MX375856B (es) | 2013-05-22 | 2014-05-20 | Proceso de polimerizacion cationica para la sintesis de polimeros nano-estructurados que contienen grafeno. |
Country Status (17)
| Country | Link |
|---|---|
| US (1) | US9493594B2 (es) |
| EP (1) | EP2999723B1 (es) |
| JP (1) | JP6457496B2 (es) |
| KR (1) | KR102152233B1 (es) |
| CN (1) | CN105246927B (es) |
| BR (1) | BR112015029147B1 (es) |
| ES (1) | ES2702043T3 (es) |
| HU (1) | HUE041865T2 (es) |
| IT (1) | ITMI20130834A1 (es) |
| MX (1) | MX375856B (es) |
| MY (1) | MY171990A (es) |
| PL (1) | PL2999723T3 (es) |
| PT (1) | PT2999723T (es) |
| RU (1) | RU2652115C2 (es) |
| TR (1) | TR201900461T4 (es) |
| TW (1) | TWI633054B (es) |
| WO (1) | WO2014187796A1 (es) |
Families Citing this family (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9583358B2 (en) | 2014-05-30 | 2017-02-28 | Samsung Electronics Co., Ltd. | Hardmask composition and method of forming pattern by using the hardmask composition |
| KR102287343B1 (ko) | 2014-07-04 | 2021-08-06 | 삼성전자주식회사 | 하드마스크 조성물 및 이를 이용한 패턴의 형성방법 |
| KR102287344B1 (ko) | 2014-07-25 | 2021-08-06 | 삼성전자주식회사 | 하드마스크 조성물 및 이를 이용한 패턴의 형성방법 |
| KR102384226B1 (ko) | 2015-03-24 | 2022-04-07 | 삼성전자주식회사 | 하드마스크 조성물 및 이를 이용한 패턴 형성방법 |
| KR102463893B1 (ko) | 2015-04-03 | 2022-11-04 | 삼성전자주식회사 | 하드마스크 조성물 및 이를 이용한 패턴의 형성방법 |
| ITUB20160159A1 (it) * | 2016-01-27 | 2017-07-27 | Versalis Spa | Composizione contenente grafene e nano piastrine grafeniche e loro procedimento di preparazione. |
| US11034847B2 (en) | 2017-07-14 | 2021-06-15 | Samsung Electronics Co., Ltd. | Hardmask composition, method of forming pattern using hardmask composition, and hardmask formed from hardmask composition |
| KR102433666B1 (ko) | 2017-07-27 | 2022-08-18 | 삼성전자주식회사 | 하드마스크 조성물, 이를 이용한 패턴의 형성방법 및 상기 하드마스크 조성물을 이용하여 형성된 하드마스크 |
| KR102486388B1 (ko) | 2017-07-28 | 2023-01-09 | 삼성전자주식회사 | 그래핀 양자점의 제조방법, 상기 제조방법에 따라 얻어진 그래핀 양자점을 포함한 하드마스크 조성물, 이를 이용한 패턴의 형성방법 및 상기 하드마스크 조성물을 이용하여 형성된 하드마스크 |
| US10882024B2 (en) * | 2018-11-26 | 2021-01-05 | Saudi Arabian Oil Company | Adsorbent polymeric structures for separating polar liquids from non-polar hydrocarbons |
| EP3997047A4 (en) | 2019-07-08 | 2023-08-02 | Alter Biota Inc. | Preparation of hydrous graphene oxide for use as a concrete admixture |
| AU2020333760A1 (en) | 2019-08-20 | 2022-04-07 | Cti Consulting, Llc | Low porosity, functionalized, carbon micro-powders |
| KR102644774B1 (ko) * | 2021-05-04 | 2024-03-08 | 티엠티피 랩스, 아이엔씨. | 흑연을 박리하기 위한 장치 및 방법 |
Family Cites Families (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2798878A (en) | 1954-07-19 | 1957-07-09 | Nat Lead Co | Preparation of graphitic acid |
| JPS541703B2 (es) * | 1971-10-26 | 1979-01-27 | ||
| KR100573636B1 (ko) * | 1998-07-27 | 2006-04-26 | 바스프 악티엔게젤샤프트 | 팽창된 흑연 입자를 함유하는 발포성 스티렌 중합체의 제조 방법 |
| US7658901B2 (en) * | 2005-10-14 | 2010-02-09 | The Trustees Of Princeton University | Thermally exfoliated graphite oxide |
| WO2010042912A1 (en) | 2008-10-11 | 2010-04-15 | Vorbeck Materials Corp. | Process for the preparation of graphite oxide and graphene sheets |
| WO2010141348A1 (en) | 2009-05-31 | 2010-12-09 | College Of William And Mary | Method for making polymer composites containing graphene sheets |
| US8287699B2 (en) * | 2009-07-27 | 2012-10-16 | Nanotek Instruments, Inc. | Production of chemically functionalized nano graphene materials |
| US20110189452A1 (en) | 2009-07-31 | 2011-08-04 | Vorbeck Materials Corp. | Crosslinked Graphene and Graphite Oxide |
| IT1396918B1 (it) * | 2009-11-03 | 2012-12-20 | Polimeri Europa Spa | Procedimento per la preparazione di nanopiastrine grafeniche ad elevata disperdibilita' in matrici polimeriche a bassa polarita' e relative composizioni polimeriche |
| CN102712779A (zh) * | 2009-12-22 | 2012-10-03 | 徐光锡 | 石墨烯分散液以及石墨烯-离子液体聚合物复合材料 |
| US8728578B2 (en) | 2010-05-13 | 2014-05-20 | The Research Foundation For The State University Of New York | Chemical synthesis for graphene sheets greater than 1 μm in length |
| JP2012051993A (ja) * | 2010-08-31 | 2012-03-15 | Kumamoto Univ | グラフェン−ポリマー複合材料の製造方法およびそれを用いて製造されるグラフェン−ポリマー複合材料 |
| WO2012075294A2 (en) * | 2010-12-01 | 2012-06-07 | The University Of Houston System | Polymer nanocomposite precursors with carbon nanotubes and/or graphene and related thin films and patterning |
| KR20130125388A (ko) * | 2011-02-08 | 2013-11-18 | 그라페아, 인크. | 중합용 카보촉매 |
| JP5775366B2 (ja) * | 2011-06-06 | 2015-09-09 | 積水化学工業株式会社 | 炭素質材料−ポリマー複合材料の製造方法 |
| CN102391632B (zh) * | 2011-09-14 | 2013-02-27 | 中国林业科学研究院林产化学工业研究所 | 氧化石墨烯/不饱和聚酯复合材料及其制备方法 |
| CN102603958B (zh) * | 2012-01-13 | 2013-10-23 | 陕西科技大学 | 一种丙烯酸树脂/氧化石墨烯纳米复合皮革涂饰剂的制备方法 |
-
2013
- 2013-05-22 IT IT000834A patent/ITMI20130834A1/it unknown
-
2014
- 2014-05-20 JP JP2016514365A patent/JP6457496B2/ja not_active Expired - Fee Related
- 2014-05-20 MY MYPI2015002538A patent/MY171990A/en unknown
- 2014-05-20 WO PCT/EP2014/060291 patent/WO2014187796A1/en not_active Ceased
- 2014-05-20 KR KR1020157031760A patent/KR102152233B1/ko not_active Expired - Fee Related
- 2014-05-20 RU RU2015143044A patent/RU2652115C2/ru active
- 2014-05-20 TR TR2019/00461T patent/TR201900461T4/tr unknown
- 2014-05-20 BR BR112015029147-3A patent/BR112015029147B1/pt not_active IP Right Cessation
- 2014-05-20 ES ES14725431T patent/ES2702043T3/es active Active
- 2014-05-20 TW TW103117686A patent/TWI633054B/zh not_active IP Right Cessation
- 2014-05-20 PT PT14725431T patent/PT2999723T/pt unknown
- 2014-05-20 MX MX2015014236A patent/MX375856B/es active IP Right Grant
- 2014-05-20 PL PL14725431T patent/PL2999723T3/pl unknown
- 2014-05-20 HU HUE14725431A patent/HUE041865T2/hu unknown
- 2014-05-20 CN CN201480028874.6A patent/CN105246927B/zh active Active
- 2014-05-20 US US14/892,787 patent/US9493594B2/en not_active Expired - Fee Related
- 2014-05-20 EP EP14725431.2A patent/EP2999723B1/en active Active
Also Published As
| Publication number | Publication date |
|---|---|
| JP6457496B2 (ja) | 2019-01-23 |
| KR20160010441A (ko) | 2016-01-27 |
| US20160152748A1 (en) | 2016-06-02 |
| JP2016519201A (ja) | 2016-06-30 |
| RU2015143044A (ru) | 2017-06-27 |
| TW201518207A (zh) | 2015-05-16 |
| HUE041865T2 (hu) | 2019-06-28 |
| WO2014187796A1 (en) | 2014-11-27 |
| RU2652115C2 (ru) | 2018-04-25 |
| ES2702043T3 (es) | 2019-02-27 |
| TR201900461T4 (tr) | 2019-02-21 |
| ITMI20130834A1 (it) | 2014-11-23 |
| MY171990A (en) | 2019-11-11 |
| BR112015029147B1 (pt) | 2021-06-29 |
| US9493594B2 (en) | 2016-11-15 |
| CN105246927A (zh) | 2016-01-13 |
| BR112015029147A2 (pt) | 2017-07-25 |
| EP2999723B1 (en) | 2018-10-17 |
| TWI633054B (zh) | 2018-08-21 |
| KR102152233B1 (ko) | 2020-09-07 |
| PL2999723T3 (pl) | 2019-05-31 |
| CN105246927B (zh) | 2017-10-17 |
| MX2015014236A (es) | 2016-03-03 |
| PT2999723T (pt) | 2018-11-28 |
| EP2999723A1 (en) | 2016-03-30 |
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| FG | Grant or registration |