MX367146B - Composición polimérica autoextinguible. - Google Patents

Composición polimérica autoextinguible.

Info

Publication number
MX367146B
MX367146B MX2015001920A MX2015001920A MX367146B MX 367146 B MX367146 B MX 367146B MX 2015001920 A MX2015001920 A MX 2015001920A MX 2015001920 A MX2015001920 A MX 2015001920A MX 367146 B MX367146 B MX 367146B
Authority
MX
Mexico
Prior art keywords
weight
polymeric composition
self
block copolymer
block
Prior art date
Application number
MX2015001920A
Other languages
English (en)
Other versions
MX2015001920A (es
Inventor
Ponticiello Antonio
Casalini Alessandro
Longo Aldo
Vannucci Giuditta
Original Assignee
Versalis Spa
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Versalis Spa filed Critical Versalis Spa
Publication of MX2015001920A publication Critical patent/MX2015001920A/es
Publication of MX367146B publication Critical patent/MX367146B/es

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
    • C08L25/02—Homopolymers or copolymers of hydrocarbons
    • C08L25/04—Homopolymers or copolymers of styrene
    • C08L25/06—Polystyrene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/0061—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof characterized by the use of several polymeric components
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F293/00—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule
    • C08F293/005—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule using free radical "living" or "controlled" polymerisation, e.g. using a complexing agent
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/06—Oxidation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/02—Elements
    • C08K3/04—Carbon
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
    • C08K5/0066—Flame-proofing or flame-retarding additives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L51/04—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L51/06—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to homopolymers or copolymers of aliphatic hydrocarbons containing only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F212/02—Monomers containing only one unsaturated aliphatic radical
    • C08F212/04—Monomers containing only one unsaturated aliphatic radical containing one ring
    • C08F212/06—Hydrocarbons
    • C08F212/08—Styrene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2438/00—Living radical polymerisation
    • C08F2438/02—Stable Free Radical Polymerisation [SFRP]; Nitroxide Mediated Polymerisation [NMP] for, e.g. using 2,2,6,6-tetramethylpiperidine-1-oxyl [TEMPO]
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F293/00—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2325/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Derivatives of such polymers
    • C08J2325/02—Homopolymers or copolymers of hydrocarbons
    • C08J2325/04—Homopolymers or copolymers of styrene
    • C08J2325/06—Polystyrene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2325/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Derivatives of such polymers
    • C08J2325/02—Homopolymers or copolymers of hydrocarbons
    • C08J2325/04—Homopolymers or copolymers of styrene
    • C08J2325/08—Copolymers of styrene
    • C08J2325/14—Copolymers of styrene with unsaturated esters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
    • C08L25/02—Homopolymers or copolymers of hydrocarbons
    • C08L25/04—Homopolymers or copolymers of styrene
    • C08L25/08—Copolymers of styrene

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Fire-Extinguishing Compositions (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
  • Inorganic Chemistry (AREA)

Abstract

La presente invención se refiere a una composición polimérica o auto-extinguible, que comprende; a) una composición polimérica estabilizadora que contiene i) de 80% a 99.5% en peso de uno o más polímeros vinilaromáticos compatibles entre sí; y ii) de 0.5% a 20% en peso de al menos un copolímero de bloque que contiene: 1) al menos un bloque de polímero vinilaromático compatible con (i) y que constituye una cantidad en peso igual a o mayor que 15% en peso con respecto al copolímero de bloque completo, y 2) al menos un bloque de copolímero de vinilo que contiene grupos epoxi de modo que hay de 0.7% a 19% en peso de oxígeno de oxirano calculado en el total de copolímero de bloque; y b) de 0.03 phr en peso a 10 phr en peso, calculado en base al componente (a), de al menos un retardante halogenado de la flama.
MX2015001920A 2012-11-20 2013-11-15 Composición polimérica autoextinguible. MX367146B (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
IT001973A ITMI20121973A1 (it) 2012-11-20 2012-11-20 Composizione polimerica autoestinguente
PCT/IB2013/060157 WO2014080326A1 (en) 2012-11-20 2013-11-15 Self-extinguishing polymeric composition

Publications (2)

Publication Number Publication Date
MX2015001920A MX2015001920A (es) 2015-06-22
MX367146B true MX367146B (es) 2019-08-07

Family

ID=47631657

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2015001920A MX367146B (es) 2012-11-20 2013-11-15 Composición polimérica autoextinguible.

Country Status (15)

Country Link
US (1) US10087297B2 (es)
EP (1) EP2922917B1 (es)
JP (1) JP2015535029A (es)
CN (1) CN104781338B (es)
BR (1) BR112015004249B1 (es)
ES (1) ES2619415T3 (es)
HR (1) HRP20170278T1 (es)
HU (1) HUE032417T2 (es)
IT (1) ITMI20121973A1 (es)
MX (1) MX367146B (es)
MY (1) MY169236A (es)
PL (1) PL2922917T3 (es)
PT (1) PT2922917T (es)
RU (1) RU2645485C2 (es)
WO (1) WO2014080326A1 (es)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ITMI20121808A1 (it) * 2012-10-24 2014-04-25 Versalis Spa Composizioni polimeriche concentrate di polimeri e/o copolimeri vinilaromatici
DE102021104714A1 (de) 2021-02-26 2022-09-01 Sunpor Kunststoff Gmbh Reaktive Flammschutzzusammensetzung
CN114516935B (zh) * 2021-12-07 2024-04-05 徐州耐威斯新材料有限公司 一种反应型阻燃剂改性聚苯乙烯泡沫材料和制备方法
CN115558216A (zh) * 2022-09-30 2023-01-03 江苏华永烯科技有限公司 一种石墨烯导电高分子复合材料

Family Cites Families (25)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4032481A (en) 1976-01-30 1977-06-28 Arco Polymers, Inc. Heat stabilizers for expandable styrene polymers
US4051199A (en) 1976-03-04 1977-09-27 Phillips Petroleum Company Epoxidized copolymers of styrene, butadiene and isoprene
US4131725A (en) 1977-08-08 1978-12-26 Phillips Petroleum Company Polymer epoxidation process
DE3122341A1 (de) 1981-06-05 1982-12-23 Chemische Werke Hüls AG, 4370 Marl Feinteilige expandierbare styrolpolymerisate
DE3402539C2 (de) 1983-02-02 1985-07-18 Chemische Fabrik Kalk GmbH, 5000 Köln Verfahren zur Stabilisierung von Tetrabrombisphenol A-bis-(dibrompropyl)-äther oder Hexabromcyclododecan
JPH0841351A (ja) * 1994-08-03 1996-02-13 Sumitomo Bakelite Co Ltd 熱可塑性樹脂組成物
US6576692B1 (en) 1994-10-06 2003-06-10 Daicel Chemical Industries, Ltd. Epoxidized block copolymer, its production, and its composition
IT1275915B1 (it) * 1995-03-16 1997-10-24 Enichem Spa Composizioni polimeriche autoestinguenti
DE69605807T2 (de) 1995-09-07 2000-07-20 Bromine Compounds Ltd., Beer-Sheva Thermisch stabile flammhemmnende hexabromocyclododecane
JPH09194739A (ja) * 1996-01-17 1997-07-29 Daicel Chem Ind Ltd 難燃性樹脂組成物
JPH10168273A (ja) * 1996-12-13 1998-06-23 Daicel Chem Ind Ltd 難燃性樹脂組成物
ITMI981156A1 (it) 1998-05-26 1999-11-26 Enichem Spa Composizioni polimeriche
JPH11343381A (ja) * 1998-06-01 1999-12-14 Daicel Chem Ind Ltd 熱可塑性樹脂組成物
JP3983388B2 (ja) * 1998-09-29 2007-09-26 出光興産株式会社 熱可塑性樹脂組成物および射出成形品
CN1259346C (zh) 2000-11-13 2006-06-14 大赛璐化学工业株式会社 环氧化热塑性聚合物
ITMI20012708A1 (it) 2001-12-20 2003-06-20 Enichem Spa Dispositivo per la granulazione a caldo di polimeri termolastici
ITMI20021495A1 (it) 2002-07-09 2002-10-08 Polimeri Europa Spa Procedimento per la preparazione di copolimeri a blocchi.
JP2006083282A (ja) * 2004-09-16 2006-03-30 Wintech Polymer Ltd 難燃性ポリブチレンテレフタレート樹脂組成物
US7468415B2 (en) 2007-01-04 2008-12-23 E. I. Du Pont De Nemours And Company Method for preparing glycidyloxystyrene monomers and polymers thereof
JP2008189823A (ja) * 2007-02-06 2008-08-21 Yokohama Rubber Co Ltd:The 熱硬化性接着剤組成物
ITMI20080823A1 (it) * 2008-05-07 2009-11-08 Polimeri Europa Spa Composizioni di polimeri vinilaromatici espansibili a migliorata capacita' di isolamento termico, procedimento per la loro preparazione ed articoli espansi da esse ottenuti
KR100975024B1 (ko) * 2008-08-14 2010-08-11 제일모직주식회사 내충격성 및 내화학성이 향상된 난연성 열가소성 수지 조성물
IT1392391B1 (it) * 2008-12-19 2012-03-02 Polimeri Europa Spa Composizioni di polimeri vinilaromatici espansibili a migliorata capacita' di isolamento termico, procedimento per la loro preparazione ed articoli espansi da loro ottenuti
IT1393962B1 (it) * 2009-05-05 2012-05-17 Polimeri Europa Spa Articoli espansi con ottima resistenza allo irraggiamento solare e ottime proprieta' termoisolanti e meccaniche
EP2448975B8 (en) 2009-06-30 2021-09-29 DDP Specialty Electronic Materials US, LLC Brominated and epoxidized flame retardants

Also Published As

Publication number Publication date
RU2015105039A (ru) 2017-01-10
ITMI20121973A1 (it) 2014-05-21
EP2922917A1 (en) 2015-09-30
MY169236A (en) 2019-03-19
HRP20170278T1 (hr) 2017-06-16
PL2922917T3 (pl) 2017-07-31
US20150299410A1 (en) 2015-10-22
JP2015535029A (ja) 2015-12-07
BR112015004249B1 (pt) 2021-02-02
EP2922917B1 (en) 2017-01-04
US10087297B2 (en) 2018-10-02
WO2014080326A1 (en) 2014-05-30
MX2015001920A (es) 2015-06-22
HUE032417T2 (en) 2017-10-30
ES2619415T3 (es) 2017-06-26
PT2922917T (pt) 2017-03-21
CN104781338A (zh) 2015-07-15
CN104781338B (zh) 2017-07-25
RU2645485C2 (ru) 2018-02-21
BR112015004249A2 (pt) 2017-07-04

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