MX354650B - Composicion catalitica y proceso para la deshidrogenacion de butenos o de mezclas de butanos y de butenos para proporcionar 1,3-butadieno. - Google Patents
Composicion catalitica y proceso para la deshidrogenacion de butenos o de mezclas de butanos y de butenos para proporcionar 1,3-butadieno.Info
- Publication number
- MX354650B MX354650B MX2014008002A MX2014008002A MX354650B MX 354650 B MX354650 B MX 354650B MX 2014008002 A MX2014008002 A MX 2014008002A MX 2014008002 A MX2014008002 A MX 2014008002A MX 354650 B MX354650 B MX 354650B
- Authority
- MX
- Mexico
- Prior art keywords
- butenes
- catalytic composition
- oxides
- butanes
- dehydrogenation
- Prior art date
Links
- 239000000203 mixture Substances 0.000 title abstract 5
- 230000003197 catalytic effect Effects 0.000 title abstract 3
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 title 2
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 title 2
- 235000013844 butane Nutrition 0.000 title 1
- 238000006356 dehydrogenation reaction Methods 0.000 title 1
- 238000000034 method Methods 0.000 title 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical class CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 title 1
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical group [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 abstract 2
- GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 abstract 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 abstract 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 abstract 1
- 150000001342 alkaline earth metals Chemical class 0.000 abstract 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract 1
- 229910052733 gallium Inorganic materials 0.000 abstract 1
- 229910001195 gallium oxide Inorganic materials 0.000 abstract 1
- MUMZUERVLWJKNR-UHFFFAOYSA-N oxoplatinum Chemical class [Pt]=O MUMZUERVLWJKNR-UHFFFAOYSA-N 0.000 abstract 1
- 229910052697 platinum Inorganic materials 0.000 abstract 1
- 229910003446 platinum oxide Inorganic materials 0.000 abstract 1
- 229910001887 tin oxide Inorganic materials 0.000 abstract 1
- QHGNHLZPVBIIPX-UHFFFAOYSA-N tin(ii) oxide Chemical class [Sn]=O QHGNHLZPVBIIPX-UHFFFAOYSA-N 0.000 abstract 1
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/56—Platinum group metals
- B01J23/62—Platinum group metals with gallium, indium, thallium, germanium, tin or lead
- B01J23/622—Platinum group metals with gallium, indium, thallium, germanium, tin or lead with germanium, tin or lead
- B01J23/626—Platinum group metals with gallium, indium, thallium, germanium, tin or lead with germanium, tin or lead with tin
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/12—Silica and alumina
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/56—Platinum group metals
- B01J23/58—Platinum group metals with alkali- or alkaline earth metals
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/56—Platinum group metals
- B01J23/62—Platinum group metals with gallium, indium, thallium, germanium, tin or lead
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/56—Platinum group metals
- B01J23/62—Platinum group metals with gallium, indium, thallium, germanium, tin or lead
- B01J23/622—Platinum group metals with gallium, indium, thallium, germanium, tin or lead with germanium, tin or lead
- B01J23/624—Platinum group metals with gallium, indium, thallium, germanium, tin or lead with germanium, tin or lead with germanium
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/90—Regeneration or reactivation
- B01J23/96—Regeneration or reactivation of catalysts comprising metals, oxides or hydroxides of the noble metals
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/61—Surface area
- B01J35/615—100-500 m2/g
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
- B01J37/0027—Powdering
- B01J37/0045—Drying a slurry, e.g. spray drying
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J38/00—Regeneration or reactivation of catalysts, in general
- B01J38/04—Gas or vapour treating; Treating by using liquids vaporisable upon contacting spent catalyst
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C11/00—Aliphatic unsaturated hydrocarbons
- C07C11/12—Alkadienes
- C07C11/16—Alkadienes with four carbon atoms
- C07C11/167—1, 3-Butadiene
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
- C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
- C07C5/327—Formation of non-aromatic carbon-to-carbon double bonds only
- C07C5/333—Catalytic processes
- C07C5/3332—Catalytic processes with metal oxides or metal sulfides
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
- C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
- C07C5/327—Formation of non-aromatic carbon-to-carbon double bonds only
- C07C5/333—Catalytic processes
- C07C5/3335—Catalytic processes with metals
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
- C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
- C07C5/327—Formation of non-aromatic carbon-to-carbon double bonds only
- C07C5/333—Catalytic processes
- C07C5/3335—Catalytic processes with metals
- C07C5/3337—Catalytic processes with metals of the platinum group
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
- B01J21/04—Alumina
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
- C07C2521/02—Boron or aluminium; Oxides or hydroxides thereof
- C07C2521/04—Alumina
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
- C07C2521/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
- C07C2521/08—Silica
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
- C07C2521/12—Silica and alumina
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the alkali- or alkaline earth metals or beryllium
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the alkali- or alkaline earth metals or beryllium
- C07C2523/04—Alkali metals
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/08—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of gallium, indium or thallium
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/14—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of germanium, tin or lead
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
- C07C2523/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals of the platinum group metals
- C07C2523/42—Platinum
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
- C07C2523/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals combined with metals, oxides or hydroxides provided for in groups C07C2523/02 - C07C2523/36
- C07C2523/56—Platinum group metals
- C07C2523/58—Platinum group metals with alkali- or alkaline earth metals or beryllium
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
- C07C2523/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals combined with metals, oxides or hydroxides provided for in groups C07C2523/02 - C07C2523/36
- C07C2523/56—Platinum group metals
- C07C2523/62—Platinum group metals with gallium, indium, thallium, germanium, tin or lead
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
- C07C2523/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals combined with metals, oxides or hydroxides provided for in groups C07C2523/02 - C07C2523/36
- C07C2523/56—Platinum group metals
- C07C2523/63—Platinum group metals with rare earths or actinides
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
Abstract
La presente invención se relaciona con una composición catalítica la cual comprende alúmina microesferoide y un componente activo que contiene una mezcla que comprende galio y/u óxidos de galio, estaño y/u óxidos de estaño, una cantidad que tiene un intervalo de 1 ppm a 500 ppm con respecto al peso total de la composición catalítica de platino y/u óxidos de platino, y óxidos de metales alcalinos y/o alcalinotérreos.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
IT002403A ITMI20112403A1 (it) | 2011-12-28 | 2011-12-28 | Composizione catalitica e procedimento per la deidrogenazione di buteni o miscele di butani e buteni a dare 1-3 butadiene |
PCT/IB2012/057690 WO2013098761A2 (en) | 2011-12-28 | 2012-12-24 | Catalytic composition and process for the dehydrogenation of butenes or mixtures of butanes and butenes to give 1,3-butadiene |
Publications (2)
Publication Number | Publication Date |
---|---|
MX2014008002A MX2014008002A (es) | 2015-03-05 |
MX354650B true MX354650B (es) | 2018-03-14 |
Family
ID=45571691
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
MX2014008002A MX354650B (es) | 2011-12-28 | 2012-12-24 | Composicion catalitica y proceso para la deshidrogenacion de butenos o de mezclas de butanos y de butenos para proporcionar 1,3-butadieno. |
Country Status (20)
Country | Link |
---|---|
US (2) | US10646854B2 (es) |
EP (2) | EP3205397B1 (es) |
JP (1) | JP6442287B2 (es) |
KR (2) | KR102054534B1 (es) |
CN (1) | CN104023841B (es) |
BR (1) | BR112014015211B1 (es) |
ES (2) | ES2810862T3 (es) |
HK (1) | HK1199223A1 (es) |
HR (1) | HRP20171159T1 (es) |
HU (2) | HUE035767T2 (es) |
IT (1) | ITMI20112403A1 (es) |
MX (1) | MX354650B (es) |
MY (2) | MY187067A (es) |
PL (2) | PL3205397T3 (es) |
PT (2) | PT3205397T (es) |
RS (2) | RS60659B1 (es) |
RU (1) | RU2614977C2 (es) |
SI (1) | SI2797689T1 (es) |
TW (1) | TWI626083B (es) |
WO (1) | WO2013098761A2 (es) |
Families Citing this family (20)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US9834496B2 (en) * | 2011-07-13 | 2017-12-05 | Dow Global Technologies Llc | Reactivating propane dehydrogenation catalyst |
WO2015007698A1 (de) * | 2013-07-18 | 2015-01-22 | Basf Se | Verfahren zur herstellung von 1,3-butadien aus n-butenen durch oxidative dehydrierung |
KR101527845B1 (ko) * | 2013-12-04 | 2015-06-16 | 희성촉매 주식회사 | 스폰지형 담체를 이용한 탄화수소 탈수소화 촉매 제조방법 |
KR101699588B1 (ko) * | 2014-11-05 | 2017-02-13 | 한화토탈 주식회사 | 부탄의 탈수소 반응 생성물로부터 프로필렌을 제조하는 방법 |
JP2017165667A (ja) * | 2016-03-15 | 2017-09-21 | Jxtgエネルギー株式会社 | 共役ジエンの製造方法 |
JP6823319B2 (ja) * | 2016-04-22 | 2021-02-03 | Eneos株式会社 | 共役ジエンの製造方法 |
JP2017210461A (ja) * | 2016-05-27 | 2017-11-30 | Jxtgエネルギー株式会社 | 不飽和炭化水素の製造方法 |
KR101932328B1 (ko) * | 2016-12-29 | 2018-12-26 | 효성화학 주식회사 | 탈수소 반응 촉매재생장치 |
JP7083988B2 (ja) * | 2017-02-21 | 2022-06-14 | Eneos株式会社 | 共役ジエンの製造方法 |
JP6856212B2 (ja) * | 2017-02-21 | 2021-04-07 | Eneos株式会社 | 共役ジエンの製造方法 |
WO2019115627A1 (en) * | 2017-12-13 | 2019-06-20 | Versalis S.P.A. | Catalyst composition and process for the production of 1,3-butadiene |
CN108786801B (zh) * | 2018-04-28 | 2021-01-05 | 钦州学院 | Pt基脱氢催化剂及其制备方法 |
WO2019234553A2 (en) * | 2018-06-05 | 2019-12-12 | Sabic Global Technologies B.V. | Catalysts for single step double dehydrogenation of butadiene from n-butane |
KR20210029201A (ko) | 2018-07-05 | 2021-03-15 | 다우 글로벌 테크놀로지스 엘엘씨 | 유동화 촉매 반응기 시스템의 작동을 개시하기 위한 방법 |
CA3104490A1 (en) * | 2018-07-05 | 2020-01-09 | Dow Global Technologies Llc | Chemical processing utilizing hydrogen containing supplemental fuel for catalyst processing |
EP3818033B1 (en) | 2018-07-05 | 2023-08-02 | Dow Global Technologies LLC | Chemical processes and systems that include the combustion of supplemental fuels |
KR20210083280A (ko) * | 2018-10-30 | 2021-07-06 | 클라리언트 인터내셔널 리미티드 | 탈수소화 촉매 및 이의 제조 및 사용 방법 |
KR20210126414A (ko) | 2020-04-10 | 2021-10-20 | 에스케이이노베이션 주식회사 | 알칼리 금속 및/또는 알칼리토금속이 도핑된 전이금속-수소 활성화 금속 복합 산화물 촉매 및 이를 이용한 부타디엔의 제조방법 |
CA3202693A1 (en) * | 2020-12-18 | 2022-06-23 | Lin Luo | Methods for producing olefins |
JP2024503219A (ja) * | 2020-12-18 | 2024-01-25 | ダウ グローバル テクノロジーズ エルエルシー | 脱水素に有用な触媒系 |
Family Cites Families (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US467723A (en) * | 1892-01-26 | Friction-clutch | ||
US3308191A (en) | 1965-10-22 | 1967-03-07 | Petro Tex Chem Corp | Oxidative dehydrogenation process |
JPS55100323A (en) * | 1979-01-18 | 1980-07-31 | Inst Fuizuikoooruganichiesukoi | Unsaturated hydrocarbon manufacturing process |
US4677237A (en) * | 1984-11-29 | 1987-06-30 | Uop Inc. | Dehydrogenation catalyst compositions |
US4914075A (en) | 1988-12-05 | 1990-04-03 | Uop | Dehydrogenation catalyst composition |
KR0142305B1 (ko) | 1993-07-09 | 1998-06-01 | 구창남 | 파라핀계 탄화수소 탈수소반응 촉매조성물 |
IT1265047B1 (it) | 1993-08-06 | 1996-10-28 | Snam Progetti | Procedimento per ottenere olefine leggere dalla deidrogenazione delle corrispondenti paraffine |
US5677237A (en) * | 1996-06-21 | 1997-10-14 | Taiwan Semiconductor Manufacturing Company Ltd. | Process for removing seams in tungsten plugs |
FR2770421B1 (fr) | 1997-10-31 | 1999-12-10 | Inst Francais Du Petrole | Procede de preparation de catalyseurs utilisables dans les reactions de transformation de composes organiques |
FR2770521B1 (fr) | 1997-10-31 | 1999-12-10 | Inst Francais Du Petrole | Procede de deshydrogenation d'hydrocarbures aliphatiques satures en hydrocarbures olefiniques |
US6133192A (en) | 1998-12-29 | 2000-10-17 | Phillips Petroleum Company | Catalyst material, the preparation thereof and the use thereof in converting hydrocarbons |
ITMI20012709A1 (it) | 2001-12-20 | 2003-06-20 | Snam Progetti | Composizione catalitica per la deidrogenazione di idrocarburi alchilaromatici |
US6756340B2 (en) | 2002-04-08 | 2004-06-29 | Uop Llc | Dehydrogenation catalyst composition |
DE10361824A1 (de) | 2003-12-30 | 2005-07-28 | Basf Ag | Verfahren zur Herstellung von Butadien |
FR2910346B1 (fr) * | 2006-12-22 | 2010-10-15 | Inst Francais Du Petrole | Procede de deshydrogenation en presence d'un catalyseur bimetallique ou multi-metallique ayant un indice de bimetallicite et une capacite d'adsorption d'hydrogene optimises |
CN105859503A (zh) | 2009-03-19 | 2016-08-17 | 陶氏环球技术有限责任公司 | 脱氢方法和催化剂 |
JP2019100323A (ja) * | 2017-12-08 | 2019-06-24 | マツダ株式会社 | エンジンの制御装置 |
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