MX348762B - Estabilidad mejorada de mezclas de polioles poliuretánicos que contienen un agente de soplado olefínico halogenado. - Google Patents

Estabilidad mejorada de mezclas de polioles poliuretánicos que contienen un agente de soplado olefínico halogenado.

Info

Publication number
MX348762B
MX348762B MX2013010406A MX2013010406A MX348762B MX 348762 B MX348762 B MX 348762B MX 2013010406 A MX2013010406 A MX 2013010406A MX 2013010406 A MX2013010406 A MX 2013010406A MX 348762 B MX348762 B MX 348762B
Authority
MX
Mexico
Prior art keywords
acetylacetonate
octoate
blowing agent
metal salt
magnesium
Prior art date
Application number
MX2013010406A
Other languages
English (en)
Spanish (es)
Other versions
MX2013010406A (es
Inventor
B Chen Benjamin
S Costa Joseph
Abbas Laurent
Liu Haiming
R Seshadri Sri
D Honnick William
Original Assignee
Arkema Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Arkema Inc filed Critical Arkema Inc
Publication of MX2013010406A publication Critical patent/MX2013010406A/es
Publication of MX348762B publication Critical patent/MX348762B/es

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/12Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
    • C08J9/14Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
    • C08J9/143Halogen containing compounds
    • C08J9/147Halogen containing compounds containing carbon and halogen atoms only
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08Processes
    • C08G18/16Catalysts
    • C08G18/18Catalysts containing secondary or tertiary amines or salts thereof
    • C08G18/1808Catalysts containing secondary or tertiary amines or salts thereof having alkylene polyamine groups
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08Processes
    • C08G18/16Catalysts
    • C08G18/161Catalysts containing two or more components to be covered by at least two of the groups C08G18/166, C08G18/18 or C08G18/22
    • C08G18/163Catalysts containing two or more components to be covered by at least two of the groups C08G18/166, C08G18/18 or C08G18/22 covered by C08G18/18 and C08G18/22
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40High-molecular-weight compounds
    • C08G18/4009Two or more macromolecular compounds not provided for in one single group of groups C08G18/42 - C08G18/64
    • C08G18/4018Mixtures of compounds of group C08G18/42 with compounds of group C08G18/48
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/0014Use of organic additives
    • C08J9/0052Organo-metallic compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/02Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by the reacting monomers or modifying agents during the preparation or modification of macromolecules
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/12Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
    • C08J9/127Mixtures of organic and inorganic blowing agents
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/12Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
    • C08J9/14Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
    • C08J9/143Halogen containing compounds
    • C08J9/144Halogen containing compounds containing carbon, halogen and hydrogen only
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/12Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
    • C08J9/14Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
    • C08J9/149Mixtures of blowing agents covered by more than one of the groups C08J9/141 - C08J9/143
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L71/00Compositions of polyethers obtained by reactions forming an ether link in the main chain; Compositions of derivatives of such polymers
    • C08L71/02Polyalkylene oxides
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00Foam properties
    • C08G2110/0025Foam properties rigid
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2201/00Foams characterised by the foaming process
    • C08J2201/02Foams characterised by the foaming process characterised by mechanical pre- or post-treatments
    • C08J2201/022Foams characterised by the foaming process characterised by mechanical pre- or post-treatments premixing or pre-blending a part of the components of a foamable composition, e.g. premixing the polyol with the blowing agent, surfactant and catalyst and only adding the isocyanate at the time of foaming
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2203/00Foams characterized by the expanding agent
    • C08J2203/16Unsaturated hydrocarbons
    • C08J2203/162Halogenated unsaturated hydrocarbons, e.g. H2C=CF2
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2375/00Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
    • C08J2375/04Polyurethanes

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
MX2013010406A 2011-04-15 2012-03-06 Estabilidad mejorada de mezclas de polioles poliuretánicos que contienen un agente de soplado olefínico halogenado. MX348762B (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US201161475789P 2011-04-15 2011-04-15
PCT/US2012/027802 WO2012141822A1 (fr) 2011-04-15 2012-03-06 Stabilité améliorée de mélanges de polyuréthane et de polyol contenant un agent d'expansion à base d'oléfine halogénée

Publications (2)

Publication Number Publication Date
MX2013010406A MX2013010406A (es) 2013-10-17
MX348762B true MX348762B (es) 2017-06-28

Family

ID=47009633

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2013010406A MX348762B (es) 2011-04-15 2012-03-06 Estabilidad mejorada de mezclas de polioles poliuretánicos que contienen un agente de soplado olefínico halogenado.

Country Status (10)

Country Link
US (1) US20140051776A1 (fr)
EP (1) EP2702088B1 (fr)
JP (1) JP5890895B2 (fr)
CN (2) CN103415548B (fr)
BR (1) BR112013023136B1 (fr)
CA (1) CA2829347C (fr)
ES (1) ES2674330T3 (fr)
MX (1) MX348762B (fr)
PL (1) PL2702088T3 (fr)
WO (1) WO2012141822A1 (fr)

Families Citing this family (22)

* Cited by examiner, † Cited by third party
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ES2945639T3 (es) * 2013-02-26 2023-07-05 Honeywell Int Inc Premezclas de espuma de poliuretano que contienen agentes de expansión de olefina halogenada y espumas obtenidas a partir de las mismas
US20140275303A1 (en) * 2013-03-15 2014-09-18 Clayton Corporation Rodent resistant polyurethane foams
KR20240132524A (ko) 2015-05-21 2024-09-03 더 케무어스 컴퍼니 에프씨, 엘엘씨 SbF5에 의한 1233xf의 244bb로의 히드로플루오린화
ES2955664T3 (es) 2015-09-18 2023-12-05 Arkema Inc Premezclas de polioles que tienen vida en anaquel mejorada
US10350617B1 (en) * 2016-02-12 2019-07-16 Konstantin Dragan Composition of and nozzle for spraying a single-component polyurethane foam
JP6951012B2 (ja) * 2016-05-16 2021-10-20 積水ソフランウイズ株式会社 硬質ポリウレタンフォーム用ポリオール組成物、及び硬質ポリウレタンフォームの製造方法
US10815353B1 (en) 2016-06-03 2020-10-27 Konstantin Dragan Composition of and nozzle for spraying a single-component polyurethane foam
US10702876B2 (en) * 2016-06-03 2020-07-07 Konstantin Dragan System, composition, and method for dispensing a sprayable foamable product
JP6953509B2 (ja) * 2016-07-29 2021-10-27 アーケマ・インコーポレイテッド 改善された貯蔵寿命を有するポリオールプレミックス
WO2018189972A1 (fr) * 2017-04-11 2018-10-18 オートリブ ディベロップメント エービー Procédé de production d'une mousse de polyuréthanne, procédé de production d'un volant, et volant
EP3679108B1 (fr) * 2017-09-05 2022-03-09 Huntsman Petrochemical LLC Système catalyseur destiné à des prémélanges de polyols contenant des agents d'expansion d'hydrohalooléfine
US10525663B2 (en) * 2017-09-28 2020-01-07 Johns Manville Foam insulation with improved low temperature properties
EP3688060B1 (fr) * 2017-09-28 2024-10-02 Dow Global Technologies Llc Système de mousse rigide de polyuréthane présentant une durée de conservation et une stabilité de conservation de polyol améliorées
CN108276546A (zh) * 2017-12-28 2018-07-13 青岛海尔股份有限公司 聚氨酯硬质泡沫塑料及其制备方法
US10640600B2 (en) 2018-04-24 2020-05-05 Covestro Llc Rigid polyurethane foams suitable for use as panel insulation
US10752725B2 (en) 2018-04-24 2020-08-25 Covestro Llc Rigid polyurethane foams suitable for use as panel insulation
CN109294218A (zh) * 2018-09-28 2019-02-01 上海东大聚氨酯有限公司 组合聚醚、聚氨酯泡沫原料组合物、源自其的聚氨酯泡沫及其制备方法和应用
US11053340B2 (en) 2019-03-08 2021-07-06 Covestro Llc HCFO-containing isocyanate-reactive compositions, related foam-forming compositions and PUR-PIR foams
US11161931B2 (en) 2019-03-08 2021-11-02 Covestro Llc Polyol blends and their use in producing PUR-PIR foam-forming compositions
US10851196B2 (en) 2019-04-29 2020-12-01 Covestro Llc Rigid polyurethane foams suitable for use as panel insulation
US11932761B2 (en) 2021-02-08 2024-03-19 Covestro Llc HFCO-containing isocyanate-reactive compositions, polyurethane foams formed therefrom, and composite articles that include such foams
US11827735B1 (en) 2022-09-01 2023-11-28 Covestro Llc HFO-containing isocyanate-reactive compositions, related foam-forming compositions and flame retardant PUR-PIR foams

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JPS6067524A (ja) * 1983-09-22 1985-04-17 Mitui Toatsu Chem Inc 超軟質ポリウレタンエラストマ−の耐熱性改良方法
US5696306A (en) * 1992-11-10 1997-12-09 Daikin Industries, Ltd. Decomposition inhibitor for hydrogen- and fluorine-containing halogenated hydrocarbons and method of inhibiting decomposition using same
US6753357B2 (en) * 2001-12-18 2004-06-22 Foam Supplies, Inc. Rigid foam compositions and method employing methyl formate as a blowing agent
US20110152392A1 (en) * 2009-12-17 2011-06-23 Honeywell International Inc. Catalysts For Polyurethane Foam Polyol Premixes Containing Halogenated Olefin Blowing Agents
US9695267B2 (en) * 2009-08-11 2017-07-04 Honeywell International Inc. Foams and foamable compositions containing halogenated olefin blowing agents
EP2057247B1 (fr) * 2006-09-01 2016-04-13 E. I. du Pont de Nemours and Company Stabilisants d'acide ascorbique pour fluorooléfines
JP2009013247A (ja) * 2007-07-03 2009-01-22 Central Glass Co Ltd 安定化された硬質ポリウレタンフォーム用プレミックス
US9453115B2 (en) * 2007-10-12 2016-09-27 Honeywell International Inc. Stabilization of polyurethane foam polyol premixes containing halogenated olefin blowing agents
US20090099273A1 (en) * 2007-10-12 2009-04-16 Williams David J Non-silicone surfactants for polyurethane or polyisocyanurate foam containing halogenated olefins as blowing agents
US20090270522A1 (en) * 2008-04-25 2009-10-29 Honeywell International Inc. Blowing agents for polymeric foams
US20100016457A1 (en) * 2008-07-16 2010-01-21 Bowman James M Hfo-1234ze mixed isomers with hfc-245fa as a blowing agent, aerosol, and solvent
EP2678391B1 (fr) * 2011-02-21 2019-07-31 Honeywell International Inc. Prémélanges de mousse de polyuréthane contenant des agents gonflants à base d'oléfines halogénées, et mousses produites à partir de ces prémélanges
CA2829486C (fr) * 2011-03-11 2019-03-26 Arkema Inc. Stabilite amelioree de melanges de polyurethanne polyol contenant un agent gonflant d'olefine halogenee

Also Published As

Publication number Publication date
CN106046411B (zh) 2019-02-26
CN106046411A (zh) 2016-10-26
BR112013023136B1 (pt) 2020-12-15
MX2013010406A (es) 2013-10-17
PL2702088T3 (pl) 2018-08-31
JP2014511930A (ja) 2014-05-19
CA2829347C (fr) 2019-08-06
EP2702088B1 (fr) 2018-05-16
CN103415548A (zh) 2013-11-27
CA2829347A1 (fr) 2012-10-18
EP2702088A1 (fr) 2014-03-05
WO2012141822A1 (fr) 2012-10-18
CN103415548B (zh) 2017-05-17
EP2702088A4 (fr) 2015-11-04
JP5890895B2 (ja) 2016-03-22
BR112013023136A2 (pt) 2016-12-13
ES2674330T3 (es) 2018-06-28
US20140051776A1 (en) 2014-02-20

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