MX2015016372A - Mezcla de polioles para poliuretano estabilizadas que contienen agentes de soplado olefinicos halogenados. - Google Patents

Mezcla de polioles para poliuretano estabilizadas que contienen agentes de soplado olefinicos halogenados.

Info

Publication number
MX2015016372A
MX2015016372A MX2015016372A MX2015016372A MX2015016372A MX 2015016372 A MX2015016372 A MX 2015016372A MX 2015016372 A MX2015016372 A MX 2015016372A MX 2015016372 A MX2015016372 A MX 2015016372A MX 2015016372 A MX2015016372 A MX 2015016372A
Authority
MX
Mexico
Prior art keywords
blowing agent
present
catalyst
blends containing
polyurethane polyol
Prior art date
Application number
MX2015016372A
Other languages
English (en)
Inventor
Joseph S Costa
Benjamin Bin Chen
Original Assignee
Arkema Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Arkema Inc filed Critical Arkema Inc
Publication of MX2015016372A publication Critical patent/MX2015016372A/es

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/0061—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof characterized by the use of several polymeric components
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/16—Catalysts
    • C08G18/18—Catalysts containing secondary or tertiary amines or salts thereof
    • C08G18/20—Heterocyclic amines; Salts thereof
    • C08G18/2009—Heterocyclic amines; Salts thereof containing one heterocyclic ring
    • C08G18/2027—Heterocyclic amines; Salts thereof containing one heterocyclic ring having two nitrogen atoms in the ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30—Low-molecular-weight compounds
    • C08G18/32—Polyhydroxy compounds; Polyamines; Hydroxyamines
    • C08G18/3203—Polyhydroxy compounds
    • C08G18/3206—Polyhydroxy compounds aliphatic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/42—Block-or graft-polymers containing polysiloxane sequences
    • C08G77/46—Block-or graft-polymers containing polysiloxane sequences containing polyether sequences
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/0014—Use of organic additives
    • C08J9/0028—Use of organic additives containing nitrogen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
    • C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
    • C08J9/143—Halogen containing compounds
    • C08J9/144—Halogen containing compounds containing carbon, halogen and hydrogen only
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2101/00—Manufacture of cellular products
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2201/00—Foams characterised by the foaming process
    • C08J2201/02—Foams characterised by the foaming process characterised by mechanical pre- or post-treatments
    • C08J2201/022—Foams characterised by the foaming process characterised by mechanical pre- or post-treatments premixing or pre-blending a part of the components of a foamable composition, e.g. premixing the polyol with the blowing agent, surfactant and catalyst and only adding the isocyanate at the time of foaming
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2203/00—Foams characterized by the expanding agent
    • C08J2203/16—Unsaturated hydrocarbons
    • C08J2203/162—Halogenated unsaturated hydrocarbons, e.g. H2C=CF2
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2205/00—Foams characterised by their properties
    • C08J2205/04—Foams characterised by their properties characterised by the foam pores
    • C08J2205/046—Unimodal pore distribution
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2205/00—Foams characterised by their properties
    • C08J2205/04—Foams characterised by their properties characterised by the foam pores
    • C08J2205/052—Closed cells, i.e. more than 50% of the pores are closed
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2205/00—Foams characterised by their properties
    • C08J2205/10—Rigid foams
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2375/00—Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
    • C08J2375/04—Polyurethanes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2383/00—Characterised by the use of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen, or carbon only; Derivatives of such polymers
    • C08J2383/10—Block- or graft-copolymers containing polysiloxane sequences
    • C08J2383/12—Block- or graft-copolymers containing polysiloxane sequences containing polyether sequences
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2483/00—Characterised by the use of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen, or carbon only; Derivatives of such polymers
    • C08J2483/10—Block- or graft-copolymers containing polysiloxane sequences
    • C08J2483/12—Block- or graft-copolymers containing polysiloxane sequences containing polyether sequences

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Sustainable Development (AREA)

Abstract

La presente invención se refiere l imidazol y/o su derivado como catalizador para espumas de poliuretano o poliisocianurato en presencia de agentes de soplado olefínicos halogenados de Bajo Potencial de Calentamiento Global (GWP), tal como la hidroclorofluoroolefina (HCFO) HCFO-1233zd. Más particularmente, la presente invención se refiere a composiciones catalizadoras que comprenden imidazol y/o su derivado. La presente invención se refiere además a las formulaciones de premezcla estables y las espumas de poliuretano o poliisocianurato obtenidas. Un método para estabilizar mezclas para espumas termoendurecibles comprende combinar: (a) un poliisocianato y, opcionalmente, materias primas compatibles con isocianato; y (b) una composición de premezcla de polioles que comprende un agente de soplado olefínico halogenado, un poliol, un tensoactivo y un catalizador.
MX2015016372A 2013-05-28 2014-05-20 Mezcla de polioles para poliuretano estabilizadas que contienen agentes de soplado olefinicos halogenados. MX2015016372A (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US201361827816P 2013-05-28 2013-05-28
PCT/US2014/038690 WO2014193689A1 (en) 2013-05-28 2014-05-20 Stabilized polyurethane polyol blends containing halogenated olefin blowing agent

Publications (1)

Publication Number Publication Date
MX2015016372A true MX2015016372A (es) 2016-03-09

Family

ID=51989319

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2015016372A MX2015016372A (es) 2013-05-28 2014-05-20 Mezcla de polioles para poliuretano estabilizadas que contienen agentes de soplado olefinicos halogenados.

Country Status (9)

Country Link
US (2) US20160130416A1 (es)
EP (1) EP3004226A4 (es)
JP (1) JP6594297B2 (es)
KR (1) KR102292151B1 (es)
CN (1) CN105264000B (es)
BR (1) BR112015029728B1 (es)
CA (1) CA2913764C (es)
MX (1) MX2015016372A (es)
WO (1) WO2014193689A1 (es)

Families Citing this family (22)

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US9879164B2 (en) * 2013-01-25 2018-01-30 Trane International Inc. Refrigerant additives and compositions
JP6951012B2 (ja) * 2016-05-16 2021-10-20 積水ソフランウイズ株式会社 硬質ポリウレタンフォーム用ポリオール組成物、及び硬質ポリウレタンフォームの製造方法
US20190177465A1 (en) * 2016-07-29 2019-06-13 Arkema Inc. Polyol pre-mixes having improved shelf life
US11649315B2 (en) * 2017-09-14 2023-05-16 Huntsman International Llc Polyurethane insulation foam composition comprising halogenated olefins and a tertiary amine compound
US10640600B2 (en) 2018-04-24 2020-05-05 Covestro Llc Rigid polyurethane foams suitable for use as panel insulation
US10752725B2 (en) 2018-04-24 2020-08-25 Covestro Llc Rigid polyurethane foams suitable for use as panel insulation
US11453742B2 (en) * 2018-08-02 2022-09-27 Dow Global Technologies Llc Methods for reducing aldehyde emissions in polyurethane foams
KR20210044853A (ko) * 2018-08-16 2021-04-23 바스프 에스이 폴리이소시아네이트 조성물, 이로부터 수득된 폴리우레탄 폼 및 이의 용도
EP3849701A4 (en) 2018-09-13 2022-05-11 Huntsman International LLC POLYURETHANE INSULATION FOAM COMPOSITION COMPRISING A STABILIZING COMPOUND
KR102201507B1 (ko) 2018-10-29 2021-01-12 주식회사 티엠티에스 무독성 폴리우레탄 제조방법, 무독성 폴리우레탄, 무독성 폴리우레탄 오링 제조방법
EP4253442A3 (en) 2019-02-28 2024-01-17 Evonik Operations GmbH Amine composition useful for making stable polyurethane foam systems
US11161931B2 (en) 2019-03-08 2021-11-02 Covestro Llc Polyol blends and their use in producing PUR-PIR foam-forming compositions
US11053340B2 (en) 2019-03-08 2021-07-06 Covestro Llc HCFO-containing isocyanate-reactive compositions, related foam-forming compositions and PUR-PIR foams
EE05871B1 (et) * 2019-03-11 2024-08-15 Ddp Specialty Electronic Materials Us, Llc Säilitusstabiilne kahekomponendiline polüuretaani-või polüisotsüanuraadipõhine pihustusvahu kompositsioon
US10851196B2 (en) 2019-04-29 2020-12-01 Covestro Llc Rigid polyurethane foams suitable for use as panel insulation
FR3100543B1 (fr) * 2019-09-06 2022-07-15 Arkema France Procédé de récupération et de séparation d’hydrocarbures fluorés insaturés
MX2022009160A (es) * 2020-02-04 2022-08-16 Chemours Co Fc Llc Agentes de nucleacion para espumas de poliisocianurato (pir).
MX2022011987A (es) 2020-03-27 2023-01-05 Huntsman Petrochemical Llc Catalizadores de alquilaminopiridina bloqueadas con un acido para una espuma de poliuretano.
US11932761B2 (en) 2021-02-08 2024-03-19 Covestro Llc HFCO-containing isocyanate-reactive compositions, polyurethane foams formed therefrom, and composite articles that include such foams
US20230265234A1 (en) * 2022-01-13 2023-08-24 Honeywell International Inc. Low density thermosetting foams having improved properties
US11827735B1 (en) 2022-09-01 2023-11-28 Covestro Llc HFO-containing isocyanate-reactive compositions, related foam-forming compositions and flame retardant PUR-PIR foams
WO2024110395A1 (de) 2022-11-24 2024-05-30 Basf Se Verbesserung der lagerstabilität von hydrofluorolefinen in aminhaltigen polyolkomponenten für die herstellung von polyurethanen

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EP0410467B1 (en) * 1989-07-28 1996-12-18 Tosoh Corporation Process for producing high resilience Polyurethane foam
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Also Published As

Publication number Publication date
CN105264000B (zh) 2021-04-27
KR102292151B1 (ko) 2021-08-24
WO2014193689A1 (en) 2014-12-04
BR112015029728A2 (pt) 2017-07-25
US20160130416A1 (en) 2016-05-12
BR112015029728B1 (pt) 2021-08-24
US20190119461A1 (en) 2019-04-25
KR20160016867A (ko) 2016-02-15
EP3004226A4 (en) 2017-02-01
EP3004226A1 (en) 2016-04-13
JP6594297B2 (ja) 2019-10-23
CA2913764A1 (en) 2014-12-04
CA2913764C (en) 2021-05-11
CN105264000A (zh) 2016-01-20
JP2016520701A (ja) 2016-07-14

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