MX344453B - Proceso de alquilacion utilizando liquidos ionicos a base de fosfonio. - Google Patents
Proceso de alquilacion utilizando liquidos ionicos a base de fosfonio.Info
- Publication number
- MX344453B MX344453B MX2014003998A MX2014003998A MX344453B MX 344453 B MX344453 B MX 344453B MX 2014003998 A MX2014003998 A MX 2014003998A MX 2014003998 A MX2014003998 A MX 2014003998A MX 344453 B MX344453 B MX 344453B
- Authority
- MX
- Mexico
- Prior art keywords
- phosphonium
- based ionic
- ionic liquids
- alkylation process
- catalyst
- Prior art date
Links
- 238000005804 alkylation reaction Methods 0.000 title abstract 3
- 239000002608 ionic liquid Substances 0.000 title abstract 3
- XYFCBTPGUUZFHI-UHFFFAOYSA-O phosphonium Chemical compound [PH4+] XYFCBTPGUUZFHI-UHFFFAOYSA-O 0.000 title 1
- 230000029936 alkylation Effects 0.000 abstract 2
- 239000003054 catalyst Substances 0.000 abstract 2
- 238000006243 chemical reaction Methods 0.000 abstract 2
- 238000000034 method Methods 0.000 abstract 2
- 150000001336 alkenes Chemical class 0.000 abstract 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 abstract 1
- 125000005496 phosphonium group Chemical group 0.000 abstract 1
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/14—Phosphorus; Compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/54—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
- C07C2/56—Addition to acyclic hydrocarbons
- C07C2/58—Catalytic processes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/14—Phosphorus; Compounds thereof
- B01J27/16—Phosphorus; Compounds thereof containing oxygen, i.e. acids, anhydrides and their derivates with N, S, B or halogens without carriers or on carriers based on C, Si, Al or Zr; also salts of Si, Al and Zr
- B01J27/18—Phosphorus; Compounds thereof containing oxygen, i.e. acids, anhydrides and their derivates with N, S, B or halogens without carriers or on carriers based on C, Si, Al or Zr; also salts of Si, Al and Zr with metals other than Al or Zr
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/0277—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides comprising ionic liquids, as components in catalyst systems or catalysts per se, the ionic liquid compounds being used in the molten state at the respective reaction temperature
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C9/00—Aliphatic saturated hydrocarbons
- C07C9/14—Aliphatic saturated hydrocarbons with five to fifteen carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C9/00—Aliphatic saturated hydrocarbons
- C07C9/22—Aliphatic saturated hydrocarbons with more than fifteen carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/54—Quaternary phosphonium compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/54—Quaternary phosphonium compounds
- C07F9/5407—Acyclic saturated phosphonium compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/20—Olefin oligomerisation or telomerisation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/0277—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides comprising ionic liquids, as components in catalyst systems or catalysts per se, the ionic liquid compounds being used in the molten state at the respective reaction temperature
- B01J31/0287—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides comprising ionic liquids, as components in catalyst systems or catalysts per se, the ionic liquid compounds being used in the molten state at the respective reaction temperature containing atoms other than nitrogen as cationic centre
- B01J31/0288—Phosphorus
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- C07C2527/06—Halogens; Compounds thereof
- C07C2527/125—Compounds comprising a halogen and scandium, yttrium, aluminium, gallium, indium or thallium
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Biochemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
Abstract
La presente invención se refiere a un proceso para la fabricación de un alquilato. El proceso incluye mezclar una corriente de isoparafina con una corriente de olefinas en un reactor de alquilación. El reactor de alquilación incluye un catalizador para realizar la reacción. El catalizador es un líquido iónico que es un líquido iónico a base de fosfonio cuaternario, y la reacción se realiza a, o cerca de, la temperatura ambiente.
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201261664405P | 2012-06-26 | 2012-06-26 | |
| US201261664385P | 2012-06-26 | 2012-06-26 | |
| US201261664430P | 2012-06-26 | 2012-06-26 | |
| PCT/US2013/046702 WO2014004232A1 (en) | 2012-06-26 | 2013-06-20 | Alkylation process using phosphonium-based ionic liquids |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| MX2014003998A MX2014003998A (es) | 2014-05-07 |
| MX344453B true MX344453B (es) | 2016-12-16 |
Family
ID=49783756
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MX2014003998A MX344453B (es) | 2012-06-26 | 2013-06-20 | Proceso de alquilacion utilizando liquidos ionicos a base de fosfonio. |
| MX2015005487A MX356659B (es) | 2012-06-26 | 2013-06-20 | Proceso de alquilacion utilizando liquidos ionicos a base de fosfonio. |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MX2015005487A MX356659B (es) | 2012-06-26 | 2013-06-20 | Proceso de alquilacion utilizando liquidos ionicos a base de fosfonio. |
Country Status (17)
| Country | Link |
|---|---|
| EP (2) | EP2864277B1 (es) |
| KR (2) | KR101645108B1 (es) |
| CN (2) | CN103958447B (es) |
| AR (1) | AR091566A1 (es) |
| AU (1) | AU2013280781B2 (es) |
| BR (2) | BR112014007977A2 (es) |
| CA (1) | CA2851165C (es) |
| CL (1) | CL2014000804A1 (es) |
| DK (1) | DK2977380T3 (es) |
| ES (1) | ES2742380T3 (es) |
| MX (2) | MX344453B (es) |
| MY (2) | MY176998A (es) |
| RU (2) | RU2620085C2 (es) |
| SG (2) | SG10201503853WA (es) |
| TW (2) | TWI554514B (es) |
| WO (1) | WO2014004232A1 (es) |
| ZA (2) | ZA201405426B (es) |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20140173781A1 (en) * | 2012-12-13 | 2014-06-19 | Pioneer Hi-Bred International, Inc. | Methods and compositions for producing and selecting transgenic wheat plants |
| US9914675B2 (en) * | 2015-03-31 | 2018-03-13 | Uop Llc | Process for alkylation using ionic liquid catalysts |
| WO2017100493A1 (en) | 2015-12-10 | 2017-06-15 | Uop Llc | Reactor system for use with an ionic liquid catalyst |
| US10465950B2 (en) * | 2016-05-26 | 2019-11-05 | Yazaki Corporation | Guanidinium-based ionic liquids in absorption chillers |
| RU2675845C1 (ru) * | 2016-06-07 | 2018-12-25 | Юоп Ллк | Триалкилфосфониевые ионные жидкости, способы получения и способы алкилирования с использованием триалкилфосфониевых ионных жидкостей |
| WO2017214227A1 (en) * | 2016-06-07 | 2017-12-14 | Cytec Industries Inc. | Trialkylphosphonium ionic liquids, methods of making, and alkylation processes using trialkylphosphonium ionic liquids |
| CN109415290B (zh) | 2016-07-29 | 2022-03-08 | 宝洁公司 | 由乳酸或其衍生物在液相中制备丙烯酸的方法 |
| US10723687B2 (en) | 2016-07-29 | 2020-07-28 | The Procter & Gamble Company | Methods of making acrylic acid from lactic acid or its derivatives in liquid phase |
| JP6733036B2 (ja) | 2016-07-29 | 2020-07-29 | ザ プロクター アンド ギャンブル カンパニーＴｈｅ Ｐｒｏｃｔｅｒ ＆ Ｇａｍｂｌｅ Ｃｏｍｐａｎｙ | 乳酸又はその誘導体からアクリル酸を製造するための液相の触媒 |
| US10307744B2 (en) | 2016-07-29 | 2019-06-04 | The Procter & Gamble Company | Catalysts for making acrylic acid from lactic acid or its derivatives in liquid phase |
| WO2018165283A1 (en) * | 2017-03-07 | 2018-09-13 | The Procter & Gamble Company | Method of making acrylic acid from lactic acid or lactide using molten salt catalysts |
Family Cites Families (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4764440A (en) | 1987-05-05 | 1988-08-16 | Eveready Battery Company | Low temperature molten compositions |
| DD285090A5 (de) * | 1989-06-15 | 1990-12-05 | Ernst-Moritz-Arndt-Universitaet Greifswald,Dd | Verfahren zur erzeugung leichter alkylate |
| DK0464156T3 (da) * | 1990-01-25 | 1996-06-17 | Mobil Oil Corp | Isoparaffin-olefin-alkyleringsfremgangsmåde |
| FR2659871B1 (fr) | 1990-03-20 | 1992-06-05 | Inst Francais Du Petrole | Composition liquide non aqueuse a caractere ionique et son utilisation comme solvant. invention de mm. yves chauvin, dominique commereuc, isabelle guibard, andre hirschauer, helene olivier, lucien saussine. |
| US5824832A (en) | 1996-07-22 | 1998-10-20 | Akzo Nobel Nv | Linear alxylbenzene formation using low temperature ionic liquid |
| FR2795340B1 (fr) * | 1999-06-25 | 2001-09-14 | Inst Francais Du Petrole | Nouveaux catalyseurs contenant des heteropolyanions utilisables dans des procedes de conversion de paraffines |
| US8329603B2 (en) * | 2003-09-16 | 2012-12-11 | Uop Llc | Isoparaffin-olefin alkylation |
| US7569740B2 (en) * | 2005-12-20 | 2009-08-04 | Chevron U.S.A. Inc. | Alkylation of olefins with isoparaffins in ionic liquid to make lubricant or fuel blendstock |
| US7919664B2 (en) * | 2008-07-31 | 2011-04-05 | Chevron U.S.A. Inc. | Process for producing a jet fuel |
| US20100152027A1 (en) * | 2008-12-15 | 2010-06-17 | Chevron U.S.A., Inc. | Ionic liquid catalyst having a high molar ratio of aluminum to nitrogen |
| CN102050747B (zh) * | 2009-11-04 | 2013-11-06 | 中国科学院过程工程研究所 | 一种有机鎓四氟铝酸盐的制备方法、以及低温电解制备氧化铝的方法 |
| US20120136189A1 (en) * | 2010-03-09 | 2012-05-31 | Conocophillips Company - Ip Services Group | Buffered ionic liquids for olefin dimerization |
| DK2625251T3 (da) * | 2010-10-06 | 2021-02-15 | Exelus Inc | Fremstilling af et højoctanalkylat af ethylen og isobutan |
| US20140173781A1 (en) * | 2012-12-13 | 2014-06-19 | Pioneer Hi-Bred International, Inc. | Methods and compositions for producing and selecting transgenic wheat plants |
-
2013
- 2013-06-20 WO PCT/US2013/046702 patent/WO2014004232A1/en active Application Filing
- 2013-06-20 CN CN201380003331.4A patent/CN103958447B/zh active Active
- 2013-06-20 EP EP13810808.9A patent/EP2864277B1/en active Active
- 2013-06-20 KR KR1020147008516A patent/KR101645108B1/ko active IP Right Grant
- 2013-06-20 EP EP15174232.7A patent/EP2977380B1/en not_active Not-in-force
- 2013-06-20 BR BR112014007977A patent/BR112014007977A2/pt not_active Application Discontinuation
- 2013-06-20 SG SG10201503853WA patent/SG10201503853WA/en unknown
- 2013-06-20 DK DK15174232.7T patent/DK2977380T3/da active
- 2013-06-20 MY MYPI2015002600A patent/MY176998A/en unknown
- 2013-06-20 CN CN201510287759.7A patent/CN105153226B/zh not_active Expired - Fee Related
- 2013-06-20 ES ES13810808T patent/ES2742380T3/es active Active
- 2013-06-20 SG SG11201401174TA patent/SG11201401174TA/en unknown
- 2013-06-20 MX MX2014003998A patent/MX344453B/es active IP Right Grant
- 2013-06-20 RU RU2015124038A patent/RU2620085C2/ru active
- 2013-06-20 BR BR122015010598-6A patent/BR122015010598A2/pt not_active Application Discontinuation
- 2013-06-20 MY MYPI2014000793A patent/MY163955A/en unknown
- 2013-06-20 AU AU2013280781A patent/AU2013280781B2/en not_active Ceased
- 2013-06-20 KR KR1020157013667A patent/KR20150065908A/ko active IP Right Grant
- 2013-06-20 RU RU2014113317/04A patent/RU2570174C2/ru active
- 2013-06-20 MX MX2015005487A patent/MX356659B/es unknown
- 2013-06-20 CA CA2851165A patent/CA2851165C/en active Active
- 2013-06-26 AR ARP130102254 patent/AR091566A1/es active IP Right Grant
- 2013-06-26 TW TW104111838A patent/TWI554514B/zh not_active IP Right Cessation
- 2013-06-26 TW TW102122780A patent/TWI490185B/zh not_active IP Right Cessation
-
2014
- 2014-04-02 CL CL2014000804A patent/CL2014000804A1/es unknown
- 2014-07-23 ZA ZA2014/05426A patent/ZA201405426B/en unknown
-
2015
- 2015-07-22 ZA ZA2015/05278A patent/ZA201505278B/en unknown
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FG | Grant or registration |