AR091566A1 - Proceso de alquilacion por el uso de liquidos ionicos basados en fosfonio - Google Patents
Proceso de alquilacion por el uso de liquidos ionicos basados en fosfonioInfo
- Publication number
- AR091566A1 AR091566A1 ARP130102254A AR091566A1 AR 091566 A1 AR091566 A1 AR 091566A1 AR P130102254 A ARP130102254 A AR P130102254A AR 091566 A1 AR091566 A1 AR 091566A1
- Authority
- AR
- Argentina
- Prior art keywords
- alkylation reactor
- ionic liquid
- phosphonium
- isoparaffin
- catalyst
- Prior art date
Links
- 239000002608 ionic liquid Substances 0.000 title abstract 5
- 238000000034 method Methods 0.000 title abstract 4
- 230000029936 alkylation Effects 0.000 abstract 6
- 238000005804 alkylation reaction Methods 0.000 abstract 6
- 150000001336 alkenes Chemical class 0.000 abstract 3
- 125000000217 alkyl group Chemical group 0.000 abstract 3
- 125000004432 carbon atom Chemical group C* 0.000 abstract 3
- 239000003054 catalyst Substances 0.000 abstract 3
- 238000006243 chemical reaction Methods 0.000 abstract 3
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 abstract 3
- XYFCBTPGUUZFHI-UHFFFAOYSA-O phosphonium Chemical compound [PH4+] XYFCBTPGUUZFHI-UHFFFAOYSA-O 0.000 abstract 3
- 125000005496 phosphonium group Chemical group 0.000 abstract 2
- 150000001449 anionic compounds Chemical class 0.000 abstract 1
- 229910052799 carbon Inorganic materials 0.000 abstract 1
- 150000001768 cations Chemical class 0.000 abstract 1
- 229910001412 inorganic anion Inorganic materials 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/14—Phosphorus; Compounds thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/14—Phosphorus; Compounds thereof
- B01J27/16—Phosphorus; Compounds thereof containing oxygen, i.e. acids, anhydrides and their derivates with N, S, B or halogens without carriers or on carriers based on C, Si, Al or Zr; also salts of Si, Al and Zr
- B01J27/18—Phosphorus; Compounds thereof containing oxygen, i.e. acids, anhydrides and their derivates with N, S, B or halogens without carriers or on carriers based on C, Si, Al or Zr; also salts of Si, Al and Zr with metals other than Al or Zr
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/0277—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides comprising ionic liquids, as components in catalyst systems or catalysts per se, the ionic liquid compounds being used in the molten state at the respective reaction temperature
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/54—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
- C07C2/56—Addition to acyclic hydrocarbons
- C07C2/58—Catalytic processes
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C9/00—Aliphatic saturated hydrocarbons
- C07C9/14—Aliphatic saturated hydrocarbons with five to fifteen carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C9/00—Aliphatic saturated hydrocarbons
- C07C9/22—Aliphatic saturated hydrocarbons with more than fifteen carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/54—Quaternary phosphonium compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/54—Quaternary phosphonium compounds
- C07F9/5407—Acyclic saturated phosphonium compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/20—Olefin oligomerisation or telomerisation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/0277—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides comprising ionic liquids, as components in catalyst systems or catalysts per se, the ionic liquid compounds being used in the molten state at the respective reaction temperature
- B01J31/0287—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides comprising ionic liquids, as components in catalyst systems or catalysts per se, the ionic liquid compounds being used in the molten state at the respective reaction temperature containing atoms other than nitrogen as cationic centre
- B01J31/0288—Phosphorus
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- C07C2527/06—Halogens; Compounds thereof
- C07C2527/125—Compounds comprising a halogen and scandium, yttrium, aluminium, gallium, indium or thallium
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Health & Medical Sciences (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
Abstract
Se presenta un proceso para llevar a cabo un alquilato. El proceso incluye la mezcla de una corriente de isoparafina con una corriente de olefina en un reactor de alquilación. El reactor de alquilación incluye un catalizador para llevar a cabo la reacción. El catalizador es un líquido iónico que es un líquido iónico basado en fosfonio cuaternario, y la reacción se lleva a cabo en o cerca de temperaturas ambientes. Reivindicación 1: Un proceso para la alquilación de isoparafinas caracterizado porque comprende: pasar la isoparafina que tiene de 2 a 10 átomos de carbono a un reactor de alquilación; y pasar una olefina que tiene de 2 a 10 átomos de carbono al reactor de alquilación, en donde el reactor de alquilación se opera en condiciones de reacción y tiene un catalizador de líquido iónico basado en fosfonio para hacer reaccionar la olefina e isoparafina para generar un alquilato, en donde el líquido iónico basado en fosfonio es un haloaluminato de fosfonio cuaternario, que comprende un catión orgánico basado en fosfonio y un anión inorgánico, y que tiene una estructura de la forma PhR¹R²R³R⁴ en donde R¹, R² y R³ comprenden el mismo grupo alquilo, y el grupo alquilo R⁴ comprende al menos 1 átomo de carbono más que el grupo alquilo R¹.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201261664405P | 2012-06-26 | 2012-06-26 | |
| US201261664430P | 2012-06-26 | 2012-06-26 | |
| US201261664385P | 2012-06-26 | 2012-06-26 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| AR091566A1 true AR091566A1 (es) | 2015-02-11 |
Family
ID=49783756
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ARP130102254 AR091566A1 (es) | 2012-06-26 | 2013-06-26 | Proceso de alquilacion por el uso de liquidos ionicos basados en fosfonio |
Country Status (17)
| Country | Link |
|---|---|
| EP (2) | EP2864277B1 (es) |
| KR (2) | KR20150065908A (es) |
| CN (2) | CN103958447B (es) |
| AR (1) | AR091566A1 (es) |
| AU (1) | AU2013280781B2 (es) |
| BR (2) | BR122015010598A2 (es) |
| CA (1) | CA2851165C (es) |
| CL (1) | CL2014000804A1 (es) |
| DK (1) | DK2977380T3 (es) |
| ES (1) | ES2742380T3 (es) |
| MX (2) | MX356659B (es) |
| MY (2) | MY163955A (es) |
| RU (2) | RU2620085C2 (es) |
| SG (2) | SG11201401174TA (es) |
| TW (2) | TWI554514B (es) |
| WO (1) | WO2014004232A1 (es) |
| ZA (2) | ZA201405426B (es) |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20140173781A1 (en) * | 2012-12-13 | 2014-06-19 | Pioneer Hi-Bred International, Inc. | Methods and compositions for producing and selecting transgenic wheat plants |
| US9914675B2 (en) * | 2015-03-31 | 2018-03-13 | Uop Llc | Process for alkylation using ionic liquid catalysts |
| WO2017100493A1 (en) * | 2015-12-10 | 2017-06-15 | Uop Llc | Reactor system for use with an ionic liquid catalyst |
| US10465950B2 (en) * | 2016-05-26 | 2019-11-05 | Yazaki Corporation | Guanidinium-based ionic liquids in absorption chillers |
| US20170348680A1 (en) * | 2016-06-07 | 2017-12-07 | Cytec Industries Inc. | Trialkylphosphonium ionic liquids, methods of making, and alkylation processes using trialkylphosphonium ionic liquids |
| RU2675845C1 (ru) * | 2016-06-07 | 2018-12-25 | Юоп Ллк | Триалкилфосфониевые ионные жидкости, способы получения и способы алкилирования с использованием триалкилфосфониевых ионных жидкостей |
| US10723687B2 (en) | 2016-07-29 | 2020-07-28 | The Procter & Gamble Company | Methods of making acrylic acid from lactic acid or its derivatives in liquid phase |
| WO2018022828A1 (en) * | 2016-07-29 | 2018-02-01 | The Procter & Gamble Company | Catalysts for making acrylic acid from lactic acid or its derivatives in liquid phase |
| US10307744B2 (en) | 2016-07-29 | 2019-06-04 | The Procter & Gamble Company | Catalysts for making acrylic acid from lactic acid or its derivatives in liquid phase |
| US10717696B2 (en) | 2016-07-29 | 2020-07-21 | The Procter & Gamble Company | Methods of making acrylic acid from lactic acid or its derivatives in liquid phase |
| CN110392676A (zh) * | 2017-03-07 | 2019-10-29 | 宝洁公司 | 利用熔融盐催化剂由乳酸或丙交酯制备丙烯酸的方法 |
Family Cites Families (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4764440A (en) | 1987-05-05 | 1988-08-16 | Eveready Battery Company | Low temperature molten compositions |
| DD285090A5 (de) * | 1989-06-15 | 1990-12-05 | Ernst-Moritz-Arndt-Universitaet Greifswald,Dd | Verfahren zur erzeugung leichter alkylate |
| CA2042360A1 (en) * | 1990-01-25 | 1991-07-26 | Johnathan E. Child | Isoparaffin-olefin alkylation process |
| FR2659871B1 (fr) | 1990-03-20 | 1992-06-05 | Inst Francais Du Petrole | Composition liquide non aqueuse a caractere ionique et son utilisation comme solvant. invention de mm. yves chauvin, dominique commereuc, isabelle guibard, andre hirschauer, helene olivier, lucien saussine. |
| US5824832A (en) | 1996-07-22 | 1998-10-20 | Akzo Nobel Nv | Linear alxylbenzene formation using low temperature ionic liquid |
| FR2795340B1 (fr) * | 1999-06-25 | 2001-09-14 | Inst Francais Du Petrole | Nouveaux catalyseurs contenant des heteropolyanions utilisables dans des procedes de conversion de paraffines |
| US8329603B2 (en) * | 2003-09-16 | 2012-12-11 | Uop Llc | Isoparaffin-olefin alkylation |
| US7569740B2 (en) * | 2005-12-20 | 2009-08-04 | Chevron U.S.A. Inc. | Alkylation of olefins with isoparaffins in ionic liquid to make lubricant or fuel blendstock |
| US7919664B2 (en) * | 2008-07-31 | 2011-04-05 | Chevron U.S.A. Inc. | Process for producing a jet fuel |
| US20100152027A1 (en) * | 2008-12-15 | 2010-06-17 | Chevron U.S.A., Inc. | Ionic liquid catalyst having a high molar ratio of aluminum to nitrogen |
| CN102050747B (zh) * | 2009-11-04 | 2013-11-06 | 中国科学院过程工程研究所 | 一种有机鎓四氟铝酸盐的制备方法、以及低温电解制备氧化铝的方法 |
| US20120136189A1 (en) * | 2010-03-09 | 2012-05-31 | Conocophillips Company - Ip Services Group | Buffered ionic liquids for olefin dimerization |
| US9079815B2 (en) * | 2010-10-06 | 2015-07-14 | Exelus Inc | Production of a high octane alkylate from ethylene and isobutene |
| US20140173781A1 (en) * | 2012-12-13 | 2014-06-19 | Pioneer Hi-Bred International, Inc. | Methods and compositions for producing and selecting transgenic wheat plants |
-
2013
- 2013-06-20 EP EP13810808.9A patent/EP2864277B1/en active Active
- 2013-06-20 KR KR1020157013667A patent/KR20150065908A/ko active IP Right Grant
- 2013-06-20 CA CA2851165A patent/CA2851165C/en active Active
- 2013-06-20 BR BR122015010598-6A patent/BR122015010598A2/pt not_active Application Discontinuation
- 2013-06-20 RU RU2015124038A patent/RU2620085C2/ru active
- 2013-06-20 RU RU2014113317/04A patent/RU2570174C2/ru active
- 2013-06-20 SG SG11201401174TA patent/SG11201401174TA/en unknown
- 2013-06-20 KR KR1020147008516A patent/KR101645108B1/ko active IP Right Grant
- 2013-06-20 MX MX2015005487A patent/MX356659B/es unknown
- 2013-06-20 BR BR112014007977A patent/BR112014007977A2/pt not_active Application Discontinuation
- 2013-06-20 CN CN201380003331.4A patent/CN103958447B/zh active Active
- 2013-06-20 WO PCT/US2013/046702 patent/WO2014004232A1/en active Application Filing
- 2013-06-20 CN CN201510287759.7A patent/CN105153226B/zh not_active Expired - Fee Related
- 2013-06-20 DK DK15174232.7T patent/DK2977380T3/da active
- 2013-06-20 MX MX2014003998A patent/MX344453B/es active IP Right Grant
- 2013-06-20 MY MYPI2014000793A patent/MY163955A/en unknown
- 2013-06-20 EP EP15174232.7A patent/EP2977380B1/en not_active Not-in-force
- 2013-06-20 SG SG10201503853WA patent/SG10201503853WA/en unknown
- 2013-06-20 MY MYPI2015002600A patent/MY176998A/en unknown
- 2013-06-20 ES ES13810808T patent/ES2742380T3/es active Active
- 2013-06-20 AU AU2013280781A patent/AU2013280781B2/en not_active Ceased
- 2013-06-26 AR ARP130102254 patent/AR091566A1/es active IP Right Grant
- 2013-06-26 TW TW104111838A patent/TWI554514B/zh not_active IP Right Cessation
- 2013-06-26 TW TW102122780A patent/TWI490185B/zh not_active IP Right Cessation
-
2014
- 2014-04-02 CL CL2014000804A patent/CL2014000804A1/es unknown
- 2014-07-23 ZA ZA2014/05426A patent/ZA201405426B/en unknown
-
2015
- 2015-07-22 ZA ZA2015/05278A patent/ZA201505278B/en unknown
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FG | Grant, registration |