MX340192B - Un proceso para la produccion de acido (met)acrilico y derivados y polimeros producidos a partir del mismo. - Google Patents

Un proceso para la produccion de acido (met)acrilico y derivados y polimeros producidos a partir del mismo.

Info

Publication number
MX340192B
MX340192B MX2013009025A MX2013009025A MX340192B MX 340192 B MX340192 B MX 340192B MX 2013009025 A MX2013009025 A MX 2013009025A MX 2013009025 A MX2013009025 A MX 2013009025A MX 340192 B MX340192 B MX 340192B
Authority
MX
Mexico
Prior art keywords
meth
acrylic acid
reaction medium
derivatives
production
Prior art date
Application number
MX2013009025A
Other languages
English (en)
Other versions
MX2013009025A (es
Inventor
Ronald Eastham Graham
William Johnson David
Poliakoff Martyn
Andrew Huddle Thomas
Original Assignee
Lucite Int Uk Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from GBGB1102249.8A external-priority patent/GB201102249D0/en
Priority claimed from GBGB1110741.4A external-priority patent/GB201110741D0/en
Application filed by Lucite Int Uk Ltd filed Critical Lucite Int Uk Ltd
Publication of MX2013009025A publication Critical patent/MX2013009025A/es
Publication of MX340192B publication Critical patent/MX340192B/es

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/42Separation; Purification; Stabilisation; Use of additives
    • C07C51/48Separation; Purification; Stabilisation; Use of additives by liquid-liquid treatment
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/347Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups
    • C07C51/377Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups by splitting-off hydrogen or functional groups; by hydrogenolysis of functional groups
    • C07C51/38Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups by splitting-off hydrogen or functional groups; by hydrogenolysis of functional groups by decarboxylation
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C57/00Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms
    • C07C57/02Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms with only carbon-to-carbon double bonds as unsaturation
    • C07C57/03Monocarboxylic acids
    • C07C57/04Acrylic acid; Methacrylic acid
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F20/00Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
    • C08F20/02Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F20/00Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
    • C08F20/02Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
    • C08F20/04Acids, Metal salts or ammonium salts thereof
    • C08F20/06Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerisation Methods In General (AREA)

Abstract

Se describe un método para extraer ácido (met)acrílico de un medio de reacción acuoso a una fase orgánica en contacto con el mismo. El medio de reacción acuoso se forma de por lo menos un catalizador base y por lo menos un ácido dicarboxilico seleccionado de ácido maleico, fumárico, málico, itacónico, citracónico, mesacónico, y citramálico o mezclas de los mismos en solución acuosa y contiene los productos de descarboxilación base catalizada. El método incluye ya sea la adición de por lo menos uno de dichos ácidos dicarboxílicos y/o un precursor del mismo al medio de reacción acuoso para aumentar la extracción de solvente del ácido (met)acrílico al solvente orgánico o mantener el nivel del catalizador base al ácido dicarboxílico y/o al precursor a un nivel sub-estequiométrico durante el proceso de extracción. El método se extiende a un proceso para producir ácido (met)acrílico, sus ésteres y polímeros y copolímeros del mismo.
MX2013009025A 2011-02-09 2012-02-08 Un proceso para la produccion de acido (met)acrilico y derivados y polimeros producidos a partir del mismo. MX340192B (es)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
GBGB1102249.8A GB201102249D0 (en) 2011-02-09 2011-02-09 A process for the production of (meth)acrylic acid and derivatives and polymers produced therefrom
GBGB1110741.4A GB201110741D0 (en) 2011-06-24 2011-06-24 A process for the production of (meth)acrylic acid and derivatives and polymers produced therefrom
PCT/GB2012/050272 WO2012107758A1 (en) 2011-02-09 2012-02-08 A process for the production of (meth)acrylic acid and derivatives and polymers produced therefrom

Publications (2)

Publication Number Publication Date
MX2013009025A MX2013009025A (es) 2013-11-20
MX340192B true MX340192B (es) 2016-06-30

Family

ID=45768248

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2013009025A MX340192B (es) 2011-02-09 2012-02-08 Un proceso para la produccion de acido (met)acrilico y derivados y polimeros producidos a partir del mismo.

Country Status (17)

Country Link
US (2) US9216938B2 (es)
EP (1) EP2673253B1 (es)
JP (1) JP6046639B2 (es)
KR (1) KR102013910B1 (es)
CN (1) CN103370299B (es)
AR (1) AR085338A1 (es)
AU (1) AU2012215191B2 (es)
BR (1) BR112013019323B1 (es)
CA (1) CA2825258C (es)
EA (1) EA026117B1 (es)
ES (1) ES2677363T3 (es)
MX (1) MX340192B (es)
MY (1) MY165885A (es)
SG (1) SG191982A1 (es)
TW (1) TWI529157B (es)
UY (1) UY33901A (es)
WO (1) WO2012107758A1 (es)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB201207388D0 (en) * 2012-04-27 2012-06-13 Lucite Int Uk Ltd A process for the production of methacrylic acid and its derivatives and polymers produced therefrom
US9464024B2 (en) * 2013-08-26 2016-10-11 Stichting Dienst Landbouwkundig Onderzoek Process for the production of methacrylic acid
CN105001076A (zh) * 2015-07-09 2015-10-28 中国科学院过程工程研究所 一种离子液体萃取分离甲基丙烯酸的方法
WO2017165397A1 (en) 2016-03-22 2017-09-28 University Of Georgia Research Foundation, Inc. Genetically engineered microbes and methods for producing citramalate
GB201707034D0 (en) 2017-05-03 2017-06-14 Gradley Michell Lorraine Modified microorganisms and methods for production of useful products

Family Cites Families (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE550710A (es)
US2504049A (en) 1946-03-04 1950-04-11 Du Pont Preparation of polymethacrylic acid and of polymeric products containing polymethacrylic acid
US2930801A (en) * 1954-06-29 1960-03-29 Union Carbide Corp Production of organic acids from aldehydes
JPS5534784B2 (es) 1972-05-23 1980-09-09
DE2323328C2 (de) * 1973-05-09 1982-04-01 Basf Ag, 6700 Ludwigshafen Verfahren zur Abtrennung von Acrylsäure aus einer angesäuerten wäßrigen Butanol-Acrylsäure-Veresterungsablauge
US4142058A (en) 1977-12-08 1979-02-27 Mitsubishi Rayon Co., Ltd. Method of separating and purifying methacrylic acid
US4180681A (en) * 1978-08-17 1979-12-25 Atlantic Richfield Company Preparation and recovery of methacrylic acid from an aqueous sodium methacrylate solution
JPS6016927B2 (ja) * 1979-07-19 1985-04-30 三菱レイヨン株式会社 メタクリル酸の抽出分離法
JPS57168906A (en) * 1981-04-13 1982-10-18 Kao Corp Maleic acid/(meth)acrylic acid copolymer
US4879412A (en) 1985-03-14 1989-11-07 Mitsui Toatsu Chemicals, Inc. Purification process of methacrylic acid
CA1308737C (en) 1987-04-16 1992-10-13 Syoichi Matsumoto Process for producing methacrylic ester
US5196578A (en) 1987-10-09 1993-03-23 Mitsui Toatsu Chemicals, Incorporated Purification process of methacrylic acid
JPH01193740A (ja) 1988-01-29 1989-08-03 Konica Corp 熱現像画形成装置
US5849301A (en) 1993-09-22 1998-12-15 Henry M. Jackson Foundation For The Advancement Of Military Medicine Producing immunogenic constructs using soluable carbohydrates activated via organic cyanylating reagents
TW310322B (es) * 1994-05-25 1997-07-11 Nippon Catalytic Chem Ind
JPH08134011A (ja) 1994-11-04 1996-05-28 Mitsui Toatsu Chem Inc メタクリル酸の精製方法
DE4443557A1 (de) 1994-12-07 1996-06-13 Roehm Gmbh Hochwärmeformbeständige, spannungsrißbeständige Polymethacrylat-Formmassen
GB9425911D0 (en) 1994-12-22 1995-02-22 Ici Plc Process for the carbonylation of olefins and catalyst system for use therein
US5766439A (en) 1996-10-10 1998-06-16 A. E. Staley Manufacturing Co. Production and recovery of organic acids
DE10203565C1 (de) 2002-01-29 2003-07-10 Roehm Gmbh Verfahren zur Herstellung eines schlagzähen Polymethylmethacrylat- Formkörpers und Verwendung des so hergestellten Kunststoffformkörpers
EP2085376B1 (en) * 2008-01-30 2012-09-05 Evonik Röhm GmbH Process for preparation of high purity methacrylic acid
FR2938536B1 (fr) 2008-11-18 2012-07-13 Arkema France Procede de fabrication d'un methacrylate de methyle derive de la biomasse
GB0922255D0 (en) 2009-12-21 2010-02-03 Lucite Int Uk Ltd Method of producing acrylic and methacrylic acid
JP5857064B2 (ja) 2010-11-24 2016-02-10 ルーサイト インターナショナル ユーケー リミテッド メタクリル酸およびその誘導体を製造するための方法ならびにこれを用いて製造されるポリマー

Also Published As

Publication number Publication date
CA2825258C (en) 2019-03-26
JP2014513043A (ja) 2014-05-29
MX2013009025A (es) 2013-11-20
TWI529157B (zh) 2016-04-11
BR112013019323B1 (pt) 2019-12-24
US20150307433A1 (en) 2015-10-29
EA201391138A1 (ru) 2014-01-30
EA026117B1 (ru) 2017-03-31
SG191982A1 (en) 2013-08-30
CN103370299A (zh) 2013-10-23
EP2673253A1 (en) 2013-12-18
AR085338A1 (es) 2013-09-25
CN103370299B (zh) 2016-06-01
MY165885A (en) 2018-05-18
NZ613224A (en) 2015-01-30
US20140031501A1 (en) 2014-01-30
AU2012215191B2 (en) 2016-05-12
KR20140005961A (ko) 2014-01-15
JP6046639B2 (ja) 2016-12-21
EP2673253B1 (en) 2018-04-11
UY33901A (es) 2012-09-28
CA2825258A1 (en) 2012-08-16
US9216938B2 (en) 2015-12-22
KR102013910B1 (ko) 2019-08-23
US9890103B2 (en) 2018-02-13
TW201245139A (en) 2012-11-16
BR112013019323A2 (pt) 2018-07-17
WO2012107758A1 (en) 2012-08-16
ES2677363T3 (es) 2018-08-01

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