MX340192B - Un proceso para la produccion de acido (met)acrilico y derivados y polimeros producidos a partir del mismo. - Google Patents
Un proceso para la produccion de acido (met)acrilico y derivados y polimeros producidos a partir del mismo.Info
- Publication number
- MX340192B MX340192B MX2013009025A MX2013009025A MX340192B MX 340192 B MX340192 B MX 340192B MX 2013009025 A MX2013009025 A MX 2013009025A MX 2013009025 A MX2013009025 A MX 2013009025A MX 340192 B MX340192 B MX 340192B
- Authority
- MX
- Mexico
- Prior art keywords
- meth
- acrylic acid
- reaction medium
- derivatives
- production
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/42—Separation; Purification; Stabilisation; Use of additives
- C07C51/48—Separation; Purification; Stabilisation; Use of additives by liquid-liquid treatment
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/347—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups
- C07C51/377—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups by splitting-off hydrogen or functional groups; by hydrogenolysis of functional groups
- C07C51/38—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups by splitting-off hydrogen or functional groups; by hydrogenolysis of functional groups by decarboxylation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C57/00—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms
- C07C57/02—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms with only carbon-to-carbon double bonds as unsaturation
- C07C57/03—Monocarboxylic acids
- C07C57/04—Acrylic acid; Methacrylic acid
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
- C08F20/02—Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
- C08F20/02—Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
- C08F20/04—Acids, Metal salts or ammonium salts thereof
- C08F20/06—Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerisation Methods In General (AREA)
Abstract
Se describe un método para extraer ácido (met)acrílico de un medio de reacción acuoso a una fase orgánica en contacto con el mismo. El medio de reacción acuoso se forma de por lo menos un catalizador base y por lo menos un ácido dicarboxilico seleccionado de ácido maleico, fumárico, málico, itacónico, citracónico, mesacónico, y citramálico o mezclas de los mismos en solución acuosa y contiene los productos de descarboxilación base catalizada. El método incluye ya sea la adición de por lo menos uno de dichos ácidos dicarboxílicos y/o un precursor del mismo al medio de reacción acuoso para aumentar la extracción de solvente del ácido (met)acrílico al solvente orgánico o mantener el nivel del catalizador base al ácido dicarboxílico y/o al precursor a un nivel sub-estequiométrico durante el proceso de extracción. El método se extiende a un proceso para producir ácido (met)acrílico, sus ésteres y polímeros y copolímeros del mismo.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GBGB1102249.8A GB201102249D0 (en) | 2011-02-09 | 2011-02-09 | A process for the production of (meth)acrylic acid and derivatives and polymers produced therefrom |
| GBGB1110741.4A GB201110741D0 (en) | 2011-06-24 | 2011-06-24 | A process for the production of (meth)acrylic acid and derivatives and polymers produced therefrom |
| PCT/GB2012/050272 WO2012107758A1 (en) | 2011-02-09 | 2012-02-08 | A process for the production of (meth)acrylic acid and derivatives and polymers produced therefrom |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| MX2013009025A MX2013009025A (es) | 2013-11-20 |
| MX340192B true MX340192B (es) | 2016-06-30 |
Family
ID=45768248
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MX2013009025A MX340192B (es) | 2011-02-09 | 2012-02-08 | Un proceso para la produccion de acido (met)acrilico y derivados y polimeros producidos a partir del mismo. |
Country Status (17)
| Country | Link |
|---|---|
| US (2) | US9216938B2 (es) |
| EP (1) | EP2673253B1 (es) |
| JP (1) | JP6046639B2 (es) |
| KR (1) | KR102013910B1 (es) |
| CN (1) | CN103370299B (es) |
| AR (1) | AR085338A1 (es) |
| AU (1) | AU2012215191B2 (es) |
| BR (1) | BR112013019323B1 (es) |
| CA (1) | CA2825258C (es) |
| EA (1) | EA026117B1 (es) |
| ES (1) | ES2677363T3 (es) |
| MX (1) | MX340192B (es) |
| MY (1) | MY165885A (es) |
| SG (1) | SG191982A1 (es) |
| TW (1) | TWI529157B (es) |
| UY (1) | UY33901A (es) |
| WO (1) | WO2012107758A1 (es) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB201207388D0 (en) * | 2012-04-27 | 2012-06-13 | Lucite Int Uk Ltd | A process for the production of methacrylic acid and its derivatives and polymers produced therefrom |
| US9464024B2 (en) * | 2013-08-26 | 2016-10-11 | Stichting Dienst Landbouwkundig Onderzoek | Process for the production of methacrylic acid |
| CN105001076A (zh) * | 2015-07-09 | 2015-10-28 | 中国科学院过程工程研究所 | 一种离子液体萃取分离甲基丙烯酸的方法 |
| WO2017165397A1 (en) | 2016-03-22 | 2017-09-28 | University Of Georgia Research Foundation, Inc. | Genetically engineered microbes and methods for producing citramalate |
| GB201707034D0 (en) | 2017-05-03 | 2017-06-14 | Gradley Michell Lorraine | Modified microorganisms and methods for production of useful products |
Family Cites Families (24)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE550710A (es) | ||||
| US2504049A (en) | 1946-03-04 | 1950-04-11 | Du Pont | Preparation of polymethacrylic acid and of polymeric products containing polymethacrylic acid |
| US2930801A (en) * | 1954-06-29 | 1960-03-29 | Union Carbide Corp | Production of organic acids from aldehydes |
| JPS5534784B2 (es) | 1972-05-23 | 1980-09-09 | ||
| DE2323328C2 (de) * | 1973-05-09 | 1982-04-01 | Basf Ag, 6700 Ludwigshafen | Verfahren zur Abtrennung von Acrylsäure aus einer angesäuerten wäßrigen Butanol-Acrylsäure-Veresterungsablauge |
| US4142058A (en) | 1977-12-08 | 1979-02-27 | Mitsubishi Rayon Co., Ltd. | Method of separating and purifying methacrylic acid |
| US4180681A (en) * | 1978-08-17 | 1979-12-25 | Atlantic Richfield Company | Preparation and recovery of methacrylic acid from an aqueous sodium methacrylate solution |
| JPS6016927B2 (ja) * | 1979-07-19 | 1985-04-30 | 三菱レイヨン株式会社 | メタクリル酸の抽出分離法 |
| JPS57168906A (en) * | 1981-04-13 | 1982-10-18 | Kao Corp | Maleic acid/(meth)acrylic acid copolymer |
| US4879412A (en) | 1985-03-14 | 1989-11-07 | Mitsui Toatsu Chemicals, Inc. | Purification process of methacrylic acid |
| CA1308737C (en) | 1987-04-16 | 1992-10-13 | Syoichi Matsumoto | Process for producing methacrylic ester |
| US5196578A (en) | 1987-10-09 | 1993-03-23 | Mitsui Toatsu Chemicals, Incorporated | Purification process of methacrylic acid |
| JPH01193740A (ja) | 1988-01-29 | 1989-08-03 | Konica Corp | 熱現像画形成装置 |
| US5849301A (en) | 1993-09-22 | 1998-12-15 | Henry M. Jackson Foundation For The Advancement Of Military Medicine | Producing immunogenic constructs using soluable carbohydrates activated via organic cyanylating reagents |
| TW310322B (es) * | 1994-05-25 | 1997-07-11 | Nippon Catalytic Chem Ind | |
| JPH08134011A (ja) | 1994-11-04 | 1996-05-28 | Mitsui Toatsu Chem Inc | メタクリル酸の精製方法 |
| DE4443557A1 (de) | 1994-12-07 | 1996-06-13 | Roehm Gmbh | Hochwärmeformbeständige, spannungsrißbeständige Polymethacrylat-Formmassen |
| GB9425911D0 (en) | 1994-12-22 | 1995-02-22 | Ici Plc | Process for the carbonylation of olefins and catalyst system for use therein |
| US5766439A (en) | 1996-10-10 | 1998-06-16 | A. E. Staley Manufacturing Co. | Production and recovery of organic acids |
| DE10203565C1 (de) | 2002-01-29 | 2003-07-10 | Roehm Gmbh | Verfahren zur Herstellung eines schlagzähen Polymethylmethacrylat- Formkörpers und Verwendung des so hergestellten Kunststoffformkörpers |
| EP2085376B1 (en) * | 2008-01-30 | 2012-09-05 | Evonik Röhm GmbH | Process for preparation of high purity methacrylic acid |
| FR2938536B1 (fr) | 2008-11-18 | 2012-07-13 | Arkema France | Procede de fabrication d'un methacrylate de methyle derive de la biomasse |
| GB0922255D0 (en) | 2009-12-21 | 2010-02-03 | Lucite Int Uk Ltd | Method of producing acrylic and methacrylic acid |
| JP5857064B2 (ja) | 2010-11-24 | 2016-02-10 | ルーサイト インターナショナル ユーケー リミテッド | メタクリル酸およびその誘導体を製造するための方法ならびにこれを用いて製造されるポリマー |
-
2012
- 2012-02-08 ES ES12706094.5T patent/ES2677363T3/es active Active
- 2012-02-08 AU AU2012215191A patent/AU2012215191B2/en active Active
- 2012-02-08 KR KR1020137021245A patent/KR102013910B1/ko active IP Right Grant
- 2012-02-08 MY MYPI2013701383A patent/MY165885A/en unknown
- 2012-02-08 UY UY0001033901A patent/UY33901A/es not_active Application Discontinuation
- 2012-02-08 BR BR112013019323A patent/BR112013019323B1/pt active IP Right Grant
- 2012-02-08 JP JP2013553024A patent/JP6046639B2/ja active Active
- 2012-02-08 MX MX2013009025A patent/MX340192B/es active IP Right Grant
- 2012-02-08 WO PCT/GB2012/050272 patent/WO2012107758A1/en active Application Filing
- 2012-02-08 EA EA201391138A patent/EA026117B1/ru not_active IP Right Cessation
- 2012-02-08 SG SG2013054143A patent/SG191982A1/en unknown
- 2012-02-08 AR ARP120100415A patent/AR085338A1/es unknown
- 2012-02-08 US US13/984,473 patent/US9216938B2/en active Active
- 2012-02-08 CN CN201280008311.1A patent/CN103370299B/zh active Active
- 2012-02-08 CA CA2825258A patent/CA2825258C/en active Active
- 2012-02-08 EP EP12706094.5A patent/EP2673253B1/en active Active
- 2012-02-09 TW TW101104219A patent/TWI529157B/zh active
-
2015
- 2015-04-30 US US14/700,651 patent/US9890103B2/en active Active
Also Published As
| Publication number | Publication date |
|---|---|
| CA2825258C (en) | 2019-03-26 |
| JP2014513043A (ja) | 2014-05-29 |
| MX2013009025A (es) | 2013-11-20 |
| TWI529157B (zh) | 2016-04-11 |
| BR112013019323B1 (pt) | 2019-12-24 |
| US20150307433A1 (en) | 2015-10-29 |
| EA201391138A1 (ru) | 2014-01-30 |
| EA026117B1 (ru) | 2017-03-31 |
| SG191982A1 (en) | 2013-08-30 |
| CN103370299A (zh) | 2013-10-23 |
| EP2673253A1 (en) | 2013-12-18 |
| AR085338A1 (es) | 2013-09-25 |
| CN103370299B (zh) | 2016-06-01 |
| MY165885A (en) | 2018-05-18 |
| NZ613224A (en) | 2015-01-30 |
| US20140031501A1 (en) | 2014-01-30 |
| AU2012215191B2 (en) | 2016-05-12 |
| KR20140005961A (ko) | 2014-01-15 |
| JP6046639B2 (ja) | 2016-12-21 |
| EP2673253B1 (en) | 2018-04-11 |
| UY33901A (es) | 2012-09-28 |
| CA2825258A1 (en) | 2012-08-16 |
| US9216938B2 (en) | 2015-12-22 |
| KR102013910B1 (ko) | 2019-08-23 |
| US9890103B2 (en) | 2018-02-13 |
| TW201245139A (en) | 2012-11-16 |
| BR112013019323A2 (pt) | 2018-07-17 |
| WO2012107758A1 (en) | 2012-08-16 |
| ES2677363T3 (es) | 2018-08-01 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FG | Grant or registration |