MX336752B - Material de metal tratado en la superficie y agente acuoso de tratamiento de superficie de metal. - Google Patents
Material de metal tratado en la superficie y agente acuoso de tratamiento de superficie de metal.Info
- Publication number
- MX336752B MX336752B MX2013012423A MX2013012423A MX336752B MX 336752 B MX336752 B MX 336752B MX 2013012423 A MX2013012423 A MX 2013012423A MX 2013012423 A MX2013012423 A MX 2013012423A MX 336752 B MX336752 B MX 336752B
- Authority
- MX
- Mexico
- Prior art keywords
- solid content
- content weight
- compound
- metal material
- metal
- Prior art date
Links
- 239000007769 metal material Substances 0.000 title abstract 3
- 229910052751 metal Inorganic materials 0.000 title abstract 2
- 239000002184 metal Substances 0.000 title abstract 2
- 239000012756 surface treatment agent Substances 0.000 title 1
- 239000007787 solid Substances 0.000 abstract 6
- 150000002222 fluorine compounds Chemical class 0.000 abstract 3
- 239000002131 composite material Substances 0.000 abstract 2
- 150000002736 metal compounds Chemical class 0.000 abstract 2
- 150000003377 silicon compounds Chemical class 0.000 abstract 2
- 229910000147 aluminium phosphate Inorganic materials 0.000 abstract 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-N phosphoric acid Substances OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 abstract 1
- -1 phosphoric acid compound Chemical class 0.000 abstract 1
- 229910052719 titanium Inorganic materials 0.000 abstract 1
- 239000010936 titanium Substances 0.000 abstract 1
- 150000003609 titanium compounds Chemical class 0.000 abstract 1
- 229910052726 zirconium Inorganic materials 0.000 abstract 1
- 150000003755 zirconium compounds Chemical class 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
- C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
- C23C22/34—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing fluorides or complex fluorides
- C23C22/36—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing fluorides or complex fluorides containing also phosphates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
- B05D7/14—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials to metal, e.g. car bodies
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B9/00—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
- C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
- C23C22/34—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing fluorides or complex fluorides
- C23C22/36—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing fluorides or complex fluorides containing also phosphates
- C23C22/361—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing fluorides or complex fluorides containing also phosphates containing titanium, zirconium or hafnium compounds
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
- C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
- C23C22/40—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing molybdates, tungstates or vanadates
- C23C22/44—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing molybdates, tungstates or vanadates containing also fluorides or complex fluorides
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C2222/00—Aspects relating to chemical surface treatment of metallic material by reaction of the surface with a reactive medium
- C23C2222/20—Use of solutions containing silanes
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/12—All metal or with adjacent metals
- Y10T428/12493—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
- Y10T428/12535—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.] with additional, spatially distinct nonmetal component
- Y10T428/12556—Organic component
- Y10T428/12569—Synthetic resin
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/27—Web or sheet containing structurally defined element or component, the element or component having a specified weight per unit area [e.g., gms/sq cm, lbs/sq ft, etc.]
- Y10T428/273—Web or sheet containing structurally defined element or component, the element or component having a specified weight per unit area [e.g., gms/sq cm, lbs/sq ft, etc.] of coating
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31652—Of asbestos
- Y10T428/31663—As siloxane, silicone or silane
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Chemical Treatment Of Metals (AREA)
- Other Surface Treatments For Metallic Materials (AREA)
Abstract
Un material de metal tratado en la superficie de conformidad con la presente invención es un material de metal cuya superficie es revestida con una película mixta que comprende un compuesto de silicio orgánico (W) que tiene enlaces de siloxano cíclico, por lo menos un compuesto de metal (X) seleccionado del grupo que consiste de compuestos de titanio y compuestos de zirconio, un compuesto de ácido fosfórico (Y), y un compuesto de flúor (Z). En cada componente de la película mixta, la relación de (Xs/Ws) del peso del contenido de sólidos (Ws) de Si derivado del compuesto de silicio orgánico (W) y el peso del contenido de sólidos (Xs) del por lo menos un componente de metal seleccionado de un grupo que consiste de Ti y Zr contenido en el compuesto de metal (X) es entre 0.06 y 0.16, la relación de (Ys/Ws) del peso del contenido de sólidos (Ws) y el peso del contenido de sólidos (Ys) derivado del compuesto de flúor (Z) es entre 0.15 y 0.31, y la relación de (Zs/Ws) del peso del contenido de sólidos (Ws) y el peso del contenido de sólidos (Zs) de F derivado del compuesto de flúor (Z) es entre 0.08 y 0.50.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2011100126 | 2011-04-27 | ||
| PCT/JP2012/061233 WO2012147860A1 (ja) | 2011-04-27 | 2012-04-26 | 表面処理金属材及び水系金属表面処理剤 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| MX2013012423A MX2013012423A (es) | 2013-12-06 |
| MX336752B true MX336752B (es) | 2016-01-29 |
Family
ID=47072375
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MX2013012423A MX336752B (es) | 2011-04-27 | 2012-04-26 | Material de metal tratado en la superficie y agente acuoso de tratamiento de superficie de metal. |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US20140050939A1 (es) |
| JP (1) | JP5336002B2 (es) |
| KR (1) | KR101449359B1 (es) |
| CN (1) | CN103635607B (es) |
| AU (1) | AU2012248254B2 (es) |
| BR (1) | BR112013027461B1 (es) |
| CA (1) | CA2833367C (es) |
| MX (1) | MX336752B (es) |
| MY (1) | MY165503A (es) |
| WO (1) | WO2012147860A1 (es) |
Families Citing this family (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP6116953B2 (ja) * | 2013-03-21 | 2017-04-19 | 日新製鋼株式会社 | 耐熱性塗装鋼板 |
| DE102013215441A1 (de) | 2013-08-06 | 2015-02-12 | Henkel Ag & Co. Kgaa | Metallvorbehandlungszusammensetzungen umfassend Silane und Organophosphonsäuren |
| DE102013215440A1 (de) * | 2013-08-06 | 2015-02-12 | Henkel Ag & Co. Kgaa | Metallvorbehandlung mit sauren wasserhaltigen Zusammensetzungen umfassend Silane |
| CN104448999A (zh) * | 2014-11-18 | 2015-03-25 | 厦门建霖工业有限公司 | 一种耐指纹表面处理剂及其使用方法 |
| JP2017141485A (ja) * | 2016-02-09 | 2017-08-17 | 日本パーカライジング株式会社 | 表面処理剤、表面処理皮膜の製造方法、及び表面処理皮膜を有するアルミニウム材又はアルミニウム合金材 |
| BR112018072454B1 (pt) * | 2016-05-10 | 2023-05-16 | Hoden Seimitsu Kako Kenkyusyo Co., Ltd | Composição de tratamento de superfície antiferrugem aquosa e membro de metal com superfície revestida |
| CN105951085B (zh) * | 2016-06-27 | 2018-12-14 | 重庆新美鱼博洋铝业有限公司 | 航空铝合金防腐钝化剂及其制备方法 |
| CN108330478B (zh) * | 2018-03-06 | 2020-02-07 | 上海耀岩化学品有限公司 | 一种水性金属表面处理剂 |
| US11965249B2 (en) | 2019-03-19 | 2024-04-23 | Nippon Steel Corporation | Surface-treated metal material |
| JP7641726B2 (ja) | 2020-11-13 | 2025-03-07 | 日本製鉄株式会社 | 表面処理金属板 |
| WO2022185840A1 (ja) | 2021-03-01 | 2022-09-09 | 日本製鉄株式会社 | バッテリーユニット |
| EP4273283A4 (en) * | 2021-03-01 | 2025-08-13 | Nippon Steel Corp | BATTERY UNIT |
| AU2022249935A1 (en) * | 2021-03-29 | 2023-10-05 | Nippon Steel Corporation | Surface-treated steel sheet |
| CN117321838A (zh) | 2021-05-20 | 2023-12-29 | 日本制铁株式会社 | 冷却结构、电池装置及冷却结构的制造方法 |
| KR20230172535A (ko) | 2021-05-20 | 2023-12-22 | 닛폰세이테츠 가부시키가이샤 | 냉각 구조, 배터리 유닛, 및 냉각 구조의 제조 방법 |
| JPWO2022244570A1 (es) | 2021-05-20 | 2022-11-24 | ||
| TWI864496B (zh) * | 2021-11-22 | 2024-12-01 | 日商日本製鐵股份有限公司 | 表面處理鋼材 |
| AU2022444558B2 (en) * | 2022-03-03 | 2025-11-13 | Nippon Steel Corporation | Surface-treated steel sheet |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP3555800B2 (ja) * | 1996-04-30 | 2004-08-18 | 株式会社日鉱マテリアルズ | 新規有機ケイ素化合物およびその製造方法並びにそれを用いる表面処理剤および樹脂添加剤 |
| KR100382702B1 (ko) * | 2000-09-18 | 2003-05-09 | 주식회사 엘지화학 | 유기실리케이트 중합체의 제조방법 |
| JP2002234755A (ja) * | 2001-01-31 | 2002-08-23 | Dow Corning Toray Silicone Co Ltd | ガラス繊維基材用表面処理剤、ガラス繊維基材、プリプレグ、およびガラス繊維強化熱硬化性樹脂成形物 |
| WO2004038783A2 (en) * | 2002-10-21 | 2004-05-06 | Massachusetts Institute Of Technology | Pecvd of organosilicate thin films |
| JP2006328445A (ja) * | 2005-05-23 | 2006-12-07 | Nippon Parkerizing Co Ltd | プレコート金属材料用水系表面処理剤、表面処理方法及びプレコート金属材料の製造方法 |
| TW200716710A (en) * | 2005-09-30 | 2007-05-01 | Dow Corning Toray Co Ltd | Multi-component room-temperature curable silicone rubber composition |
| MY153410A (en) * | 2006-11-15 | 2015-02-13 | Nippon Steel Corp | Surface-treated material and method for producing the same |
| JP4907315B2 (ja) * | 2006-11-28 | 2012-03-28 | 新日本製鐵株式会社 | 表面処理金属材 |
| JP2008184659A (ja) * | 2007-01-30 | 2008-08-14 | Nippon Steel Corp | 表面処理金属材 |
| CN101747361B (zh) * | 2008-12-04 | 2012-06-13 | 中国科学院化学研究所 | 一种桥联聚倍半硅氧烷及其单体与它们的制备方法 |
| WO2011049238A1 (ja) * | 2009-10-20 | 2011-04-28 | 新日本製鐵株式会社 | クロムフリー表面処理亜鉛系めっき鋼板 |
-
2012
- 2012-04-26 JP JP2012542051A patent/JP5336002B2/ja active Active
- 2012-04-26 CN CN201280020105.2A patent/CN103635607B/zh active Active
- 2012-04-26 WO PCT/JP2012/061233 patent/WO2012147860A1/ja not_active Ceased
- 2012-04-26 MX MX2013012423A patent/MX336752B/es unknown
- 2012-04-26 KR KR1020137028525A patent/KR101449359B1/ko active Active
- 2012-04-26 MY MYPI2013701990A patent/MY165503A/en unknown
- 2012-04-26 CA CA2833367A patent/CA2833367C/en active Active
- 2012-04-26 US US14/113,502 patent/US20140050939A1/en not_active Abandoned
- 2012-04-26 AU AU2012248254A patent/AU2012248254B2/en active Active
- 2012-04-26 BR BR112013027461-1A patent/BR112013027461B1/pt active IP Right Grant
Also Published As
| Publication number | Publication date |
|---|---|
| CA2833367C (en) | 2015-08-18 |
| AU2012248254A1 (en) | 2013-11-07 |
| JPWO2012147860A1 (ja) | 2014-07-28 |
| CA2833367A1 (en) | 2012-11-01 |
| MY165503A (en) | 2018-03-27 |
| WO2012147860A1 (ja) | 2012-11-01 |
| JP5336002B2 (ja) | 2013-11-06 |
| KR101449359B1 (ko) | 2014-10-08 |
| AU2012248254B2 (en) | 2014-09-04 |
| US20140050939A1 (en) | 2014-02-20 |
| BR112013027461B1 (pt) | 2021-04-06 |
| KR20130136568A (ko) | 2013-12-12 |
| CN103635607B (zh) | 2015-12-02 |
| CN103635607A (zh) | 2014-03-12 |
| MX2013012423A (es) | 2013-12-06 |
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