MX336180B - Catalizador de hidrogenacion selectiva y metodos para elaborar y usar el mismo. - Google Patents

Catalizador de hidrogenacion selectiva y metodos para elaborar y usar el mismo.

Info

Publication number
MX336180B
MX336180B MX2014010761A MX2014010761A MX336180B MX 336180 B MX336180 B MX 336180B MX 2014010761 A MX2014010761 A MX 2014010761A MX 2014010761 A MX2014010761 A MX 2014010761A MX 336180 B MX336180 B MX 336180B
Authority
MX
Mexico
Prior art keywords
palladium
catalyst
hydrogenation catalyst
supported
composition
Prior art date
Application number
MX2014010761A
Other languages
English (en)
Inventor
Tin-Tack Peter Cheung
Zongxuan Hong
Original Assignee
Chevron Phillips Chemical Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Chevron Phillips Chemical Co filed Critical Chevron Phillips Chemical Co
Publication of MX336180B publication Critical patent/MX336180B/es

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
    • B01J31/28—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24 of the platinum group metals, iron group metals or copper
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/02—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation
    • C07C5/08—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation of carbon-to-carbon triple bonds
    • C07C5/09—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation of carbon-to-carbon triple bonds to carbon-to-carbon double bonds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/44—Palladium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/66—Silver or gold
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/06—Halogens; Compounds thereof
    • B01J27/128—Halogens; Compounds thereof with iron group metals or platinum group metals
    • B01J27/13—Platinum group metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
    • B01J31/0271—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds also containing elements or functional groups covered by B01J31/0201 - B01J31/0231
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/1616—Coordination complexes, e.g. organometallic complexes, immobilised on an inorganic support, e.g. ship-in-a-bottle type catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
    • B01J31/185—Phosphites ((RO)3P), their isomeric phosphonates (R(RO)2P=O) and RO-substitution derivatives thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
    • B01J31/1865—Phosphonites (RP(OR)2), their isomeric phosphinates (R2(RO)P=O) and RO-substitution derivatives thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
    • B01J31/1875—Phosphinites (R2P(OR), their isomeric phosphine oxides (R3P=O) and RO-substitution derivatives thereof)
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0203—Impregnation the impregnation liquid containing organic compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/28—Phosphorising
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/02—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation
    • C07C5/03—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation of non-aromatic carbon-to-carbon double bonds
    • C07C5/05—Partial hydrogenation
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/32—Selective hydrogenation of the diolefin or acetylene compounds
    • C10G45/34—Selective hydrogenation of the diolefin or acetylene compounds characterised by the catalyst used
    • C10G45/40—Selective hydrogenation of the diolefin or acetylene compounds characterised by the catalyst used containing platinum group metals or compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/60—Reduction reactions, e.g. hydrogenation
    • B01J2231/64—Reductions in general of organic substrates, e.g. hydride reductions or hydrogenations
    • B01J2231/641—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes
    • B01J2231/645—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes of C=C or C-C triple bonds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/824—Palladium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/396—Distribution of the active metal ingredient
    • B01J35/397—Egg shell like
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/40—Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/612—Surface area less than 10 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/613—10-100 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/024—Multiple impregnation or coating
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/02—Boron or aluminium; Oxides or hydroxides thereof
    • C07C2521/04—Alumina
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups C07C2531/02 - C07C2531/24
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/70—Catalyst aspects
    • C10G2300/703—Activation

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Abstract

La presente invención se relaciona con una composición que comprende un catalizador de hidrogenación soportado que comprende paladio y un compuesto de organofósforo, siendo el catalizador de hidrogenación soportado capaz de hidrogenar selectivamente hidrocarburos altamente insaturados a hidrocarburos insaturados. También se describe un método para elaborar un catalizador de hidrogenación selectiva que comprende poner en contacto un soporte con un compuesto que contiene paladio para formar una composición soportada de paladio, poner en contacto la composición soportada de paladio con un compuesto de organofósforo, para formar un precursor catalizador, y reducir el precursor catalizador para formar el catalizador. También se describe un método para hidrogenar selectivamente hidrocarburos altamente insaturados a una composición enriquecida en hidrocarburos insaturados, que comprende: poner en contacto un catalizador soportado que comprende paladio y un compuesto de organofósforo con una alimentación que comprende un hidrocarburo altamente insaturado, bajo condiciones apropiadas para hidrogenar por lo menos una porción de la alimentación de hidrocarburos altamente insaturados para formar la composición enriquecida en hidrocarburos insaturados.
MX2014010761A 2009-03-04 2010-02-23 Catalizador de hidrogenacion selectiva y metodos para elaborar y usar el mismo. MX336180B (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US15749109P 2009-03-04 2009-03-04
PCT/US2010/025038 WO2010101736A2 (en) 2009-03-04 2010-02-23 Selective hydrogenation catalyst and methods of making and using same

Publications (1)

Publication Number Publication Date
MX336180B true MX336180B (es) 2016-01-11

Family

ID=42078818

Family Applications (2)

Application Number Title Priority Date Filing Date
MX2014010761A MX336180B (es) 2009-03-04 2010-02-23 Catalizador de hidrogenacion selectiva y metodos para elaborar y usar el mismo.
MX2011009006A MX2011009006A (es) 2009-03-04 2010-02-23 Catalizador de hidrogenacion selectiva y metodos para elaborar y usar el mismo.

Family Applications After (1)

Application Number Title Priority Date Filing Date
MX2011009006A MX2011009006A (es) 2009-03-04 2010-02-23 Catalizador de hidrogenacion selectiva y metodos para elaborar y usar el mismo.

Country Status (14)

Country Link
US (3) US8633127B2 (es)
EP (2) EP3144064B1 (es)
JP (1) JP5511853B2 (es)
KR (1) KR101697799B1 (es)
AR (2) AR075638A1 (es)
AU (1) AU2010221662B2 (es)
BR (1) BRPI1009225A2 (es)
CA (2) CA2753442C (es)
ES (1) ES2645100T3 (es)
IL (1) IL214927A0 (es)
MX (2) MX336180B (es)
PH (1) PH12015500779B1 (es)
SG (3) SG10201505698TA (es)
WO (1) WO2010101736A2 (es)

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
MX336180B (es) 2009-03-04 2016-01-11 Chevron Phillips Chemical Co Catalizador de hidrogenacion selectiva y metodos para elaborar y usar el mismo.
US8969598B2 (en) 2011-06-24 2015-03-03 Eastman Chemical Company Production of cyclic acetals or ketals using liquid-phase acid catalysts
US9056313B2 (en) 2011-06-24 2015-06-16 Eastman Chemical Company Catalysts for the production of hydroxy ether hydrocarbons by vapor phase hydrogenolysis of cyclic acetals and ketals
US9000229B2 (en) 2011-06-24 2015-04-07 Eastman Chemical Company Production of hydroxy ether hydrocarbons by vapor phase hydrogenolysis of cyclic acetals and ketals
US9388105B2 (en) 2011-06-24 2016-07-12 Eastman Chemical Company Production of hydroxy ether hydrocarbons by liquid phase hydrogenolysis of cyclic acetals or cyclic ketals
US8829206B2 (en) 2011-06-24 2014-09-09 Eastman Chemical Company Production of cyclic acetals or ketals using solid acid catalysts
US8829207B2 (en) 2011-06-24 2014-09-09 Eastman Chemical Company Production of cyclic acetals by reactive distillation
US8785697B2 (en) 2011-06-24 2014-07-22 Eastman Chemical Company Nickel modified catalyst for the production of hydroxy ether hydrocarbons by vapor phase hydrogenolysis of cyclic acetals and ketals
US9108188B2 (en) 2012-03-07 2015-08-18 Chevoron Phillip Chemical Company, LP Selective hydrogenation catalyst and methods of making and using same
KR20160052588A (ko) * 2013-09-06 2016-05-12 셰브론 필립스 케미컬 컴퍼니 엘피 쌍봉 지지체를 포함하는 선택적 수소화 촉매 및 이의 제조 및 사용 방법
JP6075506B2 (ja) * 2014-04-22 2017-02-08 宇部興産株式会社 水素化触媒及びその製造方法、並びにそれを用いたシクロヘキサノン又はその誘導体の製造方法
US9511359B2 (en) * 2014-11-14 2016-12-06 Chevron Phillips Chemical Company Lp Selective hydrogenation catalyst and methods of making and using same
US9758446B2 (en) 2015-11-16 2017-09-12 Chevron Phillips Chemical Company Lp Selective hydrogenation using a flow index
US10232360B1 (en) * 2017-09-12 2019-03-19 Chevron Phillips Chemical Company, Lp Use of organic dopants to enhance acetylene hydrogenation catalysts
US10245583B1 (en) * 2017-09-12 2019-04-02 Chevron Phillips Chemical Company, Lp Use of charge-containing molecules linked with covalent bonds to enhance acetylene hydrogenation catalysts

Family Cites Families (56)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1154937A (en) * 1966-08-10 1969-06-11 Ici Ltd Hydrogenation Process
US3625755A (en) * 1969-04-14 1971-12-07 Du Pont Supported metal salt/phosphine complexes and metallized products therefrom
US3635841A (en) * 1969-06-16 1972-01-18 Engelhard Min & Chem Novel anthraquinone hydrogenation catalyst
US3947495A (en) * 1974-07-01 1976-03-30 National Distillers And Chemical Corporation Process for the preparation of acrylic and methacrylic acids
US4120901A (en) * 1977-08-31 1978-10-17 Monsanto Company Production of primary and secondary amines by reaction of ammonia with conjugated diene in the presence of Pd/phosphine catalyst and primary or secondary aliphatic alcohol solvent medium
US4204997A (en) * 1979-03-19 1980-05-27 Monsanto Company Asymmetric amination of 1,3-dienes
US4418227A (en) * 1979-08-29 1983-11-29 Allied Corporation Improved process for hydrogenating aldehydes and ketones by employing anionic group VIII metal hydride compositions as hydrogenation catalysts
US4325834A (en) * 1980-11-21 1982-04-20 Air Products And Chemicals, Inc. Heterogeneous catalyst supports
US4484015A (en) 1981-05-06 1984-11-20 Phillips Petroleum Company Selective hydrogenation
US4404124A (en) 1981-05-06 1983-09-13 Phillips Petroleum Company Selective hydrogenation catalyst
US4384981A (en) * 1981-08-24 1983-05-24 Occidental Research Corporation Hydrogenation process utilizing novel catalyst
GB8314001D0 (en) * 1983-05-20 1983-06-29 Shell Int Research Preparation of alphahaloalkyl esters
US4713363A (en) * 1984-12-27 1987-12-15 The Dow Chemical Company High surface area supported noble metal catalysts and process for their preparation
DE3538129A1 (de) * 1985-10-26 1987-04-30 Bayer Ag Traegerkatalysatoren und hydrierverfahren unter verwendung dieser traegerkatalysatoren
FR2596390B1 (fr) * 1986-03-27 1989-02-17 Rhone Poulenc Chimie Procede de (co)dimerisation catalytique d'un acrylate d'alkyle inferieur et composition catalytique
US5113022A (en) * 1988-08-05 1992-05-12 Union Carbide Chemicals & Plastics Technology Corporation Ionic phosphites used in homogeneous transition metal catalyzed processes
KR0148012B1 (ko) * 1989-03-03 1998-08-17 오노 알버어스 신규한 포스핀으로 구성되는 촉매시스템 및 이를 이용한 아세틸렌형 또는 올레핀형 불포화화합물의 카르보닐화방법
GB9002491D0 (en) * 1990-02-05 1990-04-04 Shell Int Research Carbonylation catalyst system
GB9111583D0 (en) * 1991-05-30 1991-07-24 Shell Int Research Carbonylation catalyst system
US5482596A (en) * 1994-01-27 1996-01-09 Albemarle Corporation Mixed ligand catalyst for preparing aryl-substituted aliphatic carboxylic esters
US5600032A (en) * 1994-06-29 1997-02-04 Mitsubishi Chemical Corporation Method for producing an unsaturated alcohol
US5475173A (en) * 1994-07-19 1995-12-12 Phillips Petroleum Company Hydrogenation process and catalyst therefor
EP0811629B1 (en) * 1995-02-24 2003-05-02 Nissan Chemical Industries, Limited Optically active bidentate phosphine ligand/palladium complex
FR2735399B1 (fr) * 1995-06-16 1997-07-25 Inst Francais Du Petrole Nouvelle composition catalytique a base de complexes de metaux de transition et procede pour l'hydrogenation des composes insatures
US6140265A (en) * 1995-07-25 2000-10-31 Clariant Gmbh Catalyst for cross-coupling reactions
KR100333350B1 (ko) * 1996-09-11 2002-05-25 즈도케미 쇼쿠바이 가부시키가이샤 올레핀 화합물류 중의 고불포화 탄화수소 화합물 선택 수소 첨가용 촉매
US5962741A (en) * 1996-11-19 1999-10-05 Novartis Ag Process for the production of aromatic halogen-amino compounds
EP0977628B1 (en) * 1997-04-07 2001-06-20 Dsm N.V. Carbonylation catalyst system
DE19734974A1 (de) * 1997-08-13 1999-02-25 Hoechst Ag Verfahren zur Herstellung von porös geträgerten Metall-Nanopartikel-haltigen Katalysatoren, insbesondere für die Gasphasenoxidation von Ethylen und Essigsäure zu Vinylacetat
DE19753464A1 (de) * 1997-12-02 1999-06-10 Basf Ag Palladium-Cluster und ihre Verwendung als Katalysatoren
US6005123A (en) 1998-04-16 1999-12-21 Arco Chemical Technology, L.P. Epoxidation process
FR2778341B1 (fr) * 1998-05-07 2000-06-09 Inst Francais Du Petrole Catalyseur a base d'un metal noble du groupe viii contenant du bore et/ou du silicium et son utilisation en hydrotraitement de charge hydrocarbonees
US6127588A (en) * 1998-10-21 2000-10-03 Phillips Petroleum Company Hydrocarbon hydrogenation catalyst and process
DE19913352A1 (de) * 1999-03-24 2000-09-28 Basf Ag Katalysator, umfassend einen Komplex eines Metalls der VIII. Nebengruppe auf Basis eines Phospinamiditliganden
EP1240942A4 (en) * 1999-08-30 2003-08-06 Cosmo Oil Co Ltd CATALYST AND METHOD FOR HYDROTREATING GAS OIL
AU1481301A (en) * 1999-11-10 2001-06-06 Penn State Research Foundation, The Chiral phosphines, transition metal complexes thereof and uses thereof in asymmetric reactions
DE10037961A1 (de) * 2000-07-27 2002-02-07 Aventis Res & Tech Gmbh & Co Neue Phosphanliganden, deren Herstellung und ihre Verwendung in katalytischen Reaktionen
CN1151888C (zh) 2001-12-06 2004-06-02 中国科学院大连化学物理研究所 一种由烯烃氢甲酰化制取各类有机醛的催化剂及其制备方法
US6921733B2 (en) * 2002-01-16 2005-07-26 Brookhaven Science Associates, Llc Liquid phase low temperature method for production of methanol from synthesis gas and catalyst formulations therefor
US6831035B2 (en) * 2002-01-22 2004-12-14 Eastman Kodak Company Stabilization of fluorophosphite-containing catalysts
JP4013217B2 (ja) * 2002-01-31 2007-11-28 高砂香料工業株式会社 新規なホスフィン化合物、その化合物を配位子とする遷移金属錯体並びに該錯体を含む不斉合成用触媒。
AU2003201857A1 (en) * 2002-03-22 2003-10-08 Kuraray Co., Ltd. Bisphosphine, process for producing the same, and use thereof
JP4148702B2 (ja) * 2002-06-04 2008-09-10 高砂香料工業株式会社 新規なジホスフィン化合物、その製造中間体、該化合物を配位子とする遷移金属錯体並びに該錯体を含む不斉水素化触媒
DE10247633A1 (de) * 2002-10-11 2004-04-29 Studiengesellschaft Kohle Mbh Mischungen von chiralen Monophosphor-Verbindungen als Ligandensysteme für die asymmetrische Übergangsmetallkatalyse
US8461072B2 (en) * 2002-10-25 2013-06-11 Exxonmobil Chemical Patents Inc. Late transition metal catalysts for olefin oligomerizations
JP4231274B2 (ja) * 2002-11-12 2009-02-25 高砂香料工業株式会社 ホスフィン化合物、該化合物を配位子とする遷移金属錯体及び該錯体を含む不斉合成用触媒
CN1207257C (zh) * 2002-12-31 2005-06-22 曲阜师范大学 一种强酸性离子交换树脂催化合成异山梨醇的方法
WO2004074220A1 (en) * 2003-02-18 2004-09-02 Chevron Phillips Chemical Company Acetylene hydrogenation catalyst with segregated palladium skin
CN1798725A (zh) * 2003-06-05 2006-07-05 伊斯曼化学公司 负载金属－膦－氨基膦催化剂
US20040260131A1 (en) * 2003-06-23 2004-12-23 Chevron Phillips Chemical Company ("Cpchem") Selective hydrocarbon hydrogenation catalyst and process
US7919431B2 (en) * 2003-09-03 2011-04-05 Synfuels International, Inc. Catalyst formulation for hydrogenation
US7199076B2 (en) * 2003-12-19 2007-04-03 Chevron Phillips Chemical Company Lp Methods of making and using a selective hydrogenation catalyst
US7408089B2 (en) * 2004-03-19 2008-08-05 Catalytic Distillation Technologies Ni catalyst, process for making catalysts and selective hydrogenation process
JP5108761B2 (ja) * 2005-07-27 2012-12-26 シェブロン フィリップス ケミカル カンパニー エルピー 選択水素化触媒及び同触媒の製造並びに使用方法
US7586010B2 (en) * 2006-12-21 2009-09-08 Eastman Chemical Company Phosphonite-containing catalysts for hydroformylation processes
MX336180B (es) 2009-03-04 2016-01-11 Chevron Phillips Chemical Co Catalizador de hidrogenacion selectiva y metodos para elaborar y usar el mismo.

Also Published As

Publication number Publication date
AR075638A1 (es) 2011-04-20
CN102341175A (zh) 2012-02-01
JP5511853B2 (ja) 2014-06-04
KR20110124758A (ko) 2011-11-17
CA2753442A1 (en) 2010-09-10
US9221727B2 (en) 2015-12-29
WO2010101736A3 (en) 2011-01-13
BRPI1009225A2 (pt) 2019-04-16
JP2012519582A (ja) 2012-08-30
US8633127B2 (en) 2014-01-21
ES2645100T3 (es) 2017-12-04
AU2010221662A1 (en) 2011-09-15
PH12015500779A1 (en) 2017-01-09
EP3144064B1 (en) 2021-07-28
SG10201505698TA (en) 2015-09-29
SG10201505688YA (en) 2015-09-29
US20150197464A1 (en) 2015-07-16
US20100228065A1 (en) 2010-09-09
WO2010101736A2 (en) 2010-09-10
EP3144064A3 (en) 2017-05-31
KR101697799B1 (ko) 2017-01-18
US20140107383A1 (en) 2014-04-17
AR108966A2 (es) 2018-10-17
AU2010221662B2 (en) 2015-04-02
CA3000442A1 (en) 2010-09-10
EP3144064A2 (en) 2017-03-22
US9012348B2 (en) 2015-04-21
CA2753442C (en) 2018-05-22
PH12015500779B1 (en) 2017-01-09
SG10201400330QA (en) 2014-05-29
IL214927A0 (en) 2011-11-30
EP2403642B1 (en) 2017-08-02
EP2403642A2 (en) 2012-01-11
MX2011009006A (es) 2011-09-26

Similar Documents

Publication Publication Date Title
MX336180B (es) Catalizador de hidrogenacion selectiva y metodos para elaborar y usar el mismo.
WO2010128137A3 (en) Improvements relating to hydrogenation of aromatics and other unsaturated organic compounds
PL2280920T3 (pl) Sposób wytwarzania mieszanin aldehydu C5 z dużą zawartością n-pentanu
MX2012004842A (es) Proceso para hacer etanol a partir de acido acetico utilizando catalizadores acidos.
SA112330939B1 (ar) عملية لتحويل تلقيمة بترولية لإنتاج وقود له محتوى منخفض من الكبريت
TW200732466A (en) Selective catalysts for naphtha hydrodesulfurization
WO2008145387A3 (de) Katalysator zur selektiven hydrierung acetylenischer kohlenwasserstoffe und verfahren zu seiner herstellung
MY155508A (en) Fuel compositions comprising isoprene derivatives
MY156519A (en) Process for the production of olefins
AR085850A1 (es) Produccion de etanol a partir del acido acetico utilizando un catalizador de carburo de molibdeno
WO2010089266A3 (de) Hydrierkatalysatoren, deren herstellung und verwendung
MY162457A (en) Hydrogenation refining catalyst and method for producing a hydrocarbon oil
MX2009013794A (es) Procedimiento para la preparacion de biarilos.
WO2012166530A3 (en) Bio-oil upgrading process
PL2501667T3 (pl) Sposób wytwarzania osadzonego na nośniku katalizatora uwodorniania o podwyższonej aktywności uwodorniania
WO2008079250A3 (en) Hydrogenation of caryophyllene
MY162505A (en) Process for ultra low benzene reformate using catalytic distillation
WO2011106277A3 (en) Method of starting up a hydrotreating process
MY170286A (en) Improved process for converting a heavy feedstock into middle distillates using a pretreatment upstream of the catalytic cracking unit
IN2013DN09841A (es)
UA100732C2 (ru) Гидрирование иминов
SA517390005B1 (ar) حفاز لهدرجة هيدروكربونات أروماتية، وطريقة معالجة بالهدرجة واستخداماتها فيها
WO2011004065A3 (en) Process for producing hydrocarbons by hydrodesulphurizing a crude turpentine feed
EP2390303A4 (en) SYSTEM AND METHOD FOR PRODUCING HIGH QUALITY PETROL AND CONNECTING HYDROGENATION OF CATALYTIC HYDROCARBONS
MY156541A (en) Process and system for the addition of promoter metal in situ in a catalytic reforming unit