MX336179B - Catalizadores para producir poliolefinas de distribucion de peso molecular ancho en ausencia de hidrogeno adicionado. - Google Patents

Catalizadores para producir poliolefinas de distribucion de peso molecular ancho en ausencia de hidrogeno adicionado.

Info

Publication number
MX336179B
MX336179B MX2012015222A MX2012015222A MX336179B MX 336179 B MX336179 B MX 336179B MX 2012015222 A MX2012015222 A MX 2012015222A MX 2012015222 A MX2012015222 A MX 2012015222A MX 336179 B MX336179 B MX 336179B
Authority
MX
Mexico
Prior art keywords
molecular weight
absence
weight distribution
added hydrogen
catalysts
Prior art date
Application number
MX2012015222A
Other languages
English (en)
Other versions
MX2012015222A (es
Inventor
Qing Yang
Youlu Yu
Tony R Crain
Max P Mcdaniel
Original Assignee
Chevron Phillips Chemical Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=44629227&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=MX336179(B) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Chevron Phillips Chemical Co filed Critical Chevron Phillips Chemical Co
Publication of MX2012015222A publication Critical patent/MX2012015222A/es
Publication of MX336179B publication Critical patent/MX336179B/es

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04Homopolymers or copolymers of ethene
    • C08L23/08Copolymers of ethene
    • C08L23/0807Copolymers of ethene with unsaturated hydrocarbons only containing more than three carbon atoms
    • C08L23/0815Copolymers of ethene with aliphatic 1-olefins
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65904Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with another component of C08F4/64
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65925Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually non-bridged
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65927Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2410/00Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
    • C08F2410/07Catalyst support treated by an anion, e.g. Cl-, F-, SO42-

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

La presente invención proporciona un proceso de polimerización que usa un sistema de catalizador de metaloceno dual para la producción de polímeros de distribución molecular ancho o bimodal, en general, en ausencia de hidrógeno adicionado. También se proporcionan polímeros producidos del proceso de polimerización, y estos polímeros pueden tener un Mn en un intervalo de aproximadamente 9,000 a aproximadamente 30,000 g/mol, y un contenido de ramificación de cadena corta que disminuye conforme aumenta el peso molecular.
MX2012015222A 2010-07-06 2011-07-05 Catalizadores para producir poliolefinas de distribucion de peso molecular ancho en ausencia de hidrogeno adicionado. MX336179B (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US12/830,571 US8288487B2 (en) 2010-07-06 2010-07-06 Catalysts for producing broad molecular weight distribution polyolefins in the absence of added hydrogen
PCT/US2011/042935 WO2012006272A2 (en) 2010-07-06 2011-07-05 Catalysts for producing broad molecular weight distribution polyolefins in the absence of added hydrogen

Publications (2)

Publication Number Publication Date
MX2012015222A MX2012015222A (es) 2013-06-28
MX336179B true MX336179B (es) 2016-01-06

Family

ID=44629227

Family Applications (2)

Application Number Title Priority Date Filing Date
MX2012015222A MX336179B (es) 2010-07-06 2011-07-05 Catalizadores para producir poliolefinas de distribucion de peso molecular ancho en ausencia de hidrogeno adicionado.
MX2019011352A MX2019011352A (es) 2010-07-06 2012-12-19 Catalizadores para producir poliolefinas de distribucion de peso molecular ancho en ausencia de hidrogeno adicionado.

Family Applications After (1)

Application Number Title Priority Date Filing Date
MX2019011352A MX2019011352A (es) 2010-07-06 2012-12-19 Catalizadores para producir poliolefinas de distribucion de peso molecular ancho en ausencia de hidrogeno adicionado.

Country Status (9)

Country Link
US (3) US8288487B2 (es)
EP (1) EP2591012B1 (es)
KR (2) KR101959694B1 (es)
CN (1) CN102958948B (es)
BR (1) BR112013000397B1 (es)
CA (3) CA2802498C (es)
MX (2) MX336179B (es)
SG (1) SG186217A1 (es)
WO (1) WO2012006272A2 (es)

Families Citing this family (90)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7226886B2 (en) * 2005-09-15 2007-06-05 Chevron Phillips Chemical Company, L.P. Polymerization catalysts and process for producing bimodal polymers in a single reactor
US7619047B2 (en) 2006-02-22 2009-11-17 Chevron Phillips Chemical Company, Lp Dual metallocene catalysts for polymerization of bimodal polymers
US8288487B2 (en) 2010-07-06 2012-10-16 Chevron Phillips Chemical Company Lp Catalysts for producing broad molecular weight distribution polyolefins in the absence of added hydrogen
US8609793B2 (en) 2010-10-07 2013-12-17 Chevron Phillips Chemical Company Lp Catalyst systems containing a bridged metallocene
US8637616B2 (en) 2010-10-07 2014-01-28 Chevron Philips Chemical Company Lp Bridged metallocene catalyst systems with switchable hydrogen and comonomer effects
US8629292B2 (en) 2010-10-07 2014-01-14 Chevron Phillips Chemical Company Lp Stereoselective synthesis of bridged metallocene complexes
MX2014011850A (es) 2012-04-02 2014-11-21 Chevron Phillips Chemical Co Sistemas catalizadores que contienen un metaloceno puenteado.
US8940842B2 (en) 2012-09-24 2015-01-27 Chevron Phillips Chemical Company Lp Methods for controlling dual catalyst olefin polymerizations
US8865846B2 (en) 2012-09-25 2014-10-21 Chevron Phillips Chemical Company Lp Metallocene and half sandwich dual catalyst systems for producing broad molecular weight distribution polymers
US8821800B2 (en) 2012-10-18 2014-09-02 Chevron Phillips Chemical Company Lp System and method for catalyst preparation
ES2606684T3 (es) 2012-11-07 2017-03-27 Chevron Phillips Chemical Company Lp Resinas de poliolefina de baja densidad y películas preparadas a partir de éstas
US8912285B2 (en) 2012-12-06 2014-12-16 Chevron Phillips Chemical Company Lp Catalyst system with three metallocenes for producing broad molecular weight distribution polymers
US8703886B1 (en) 2013-02-27 2014-04-22 Chevron Phillips Chemical Company Lp Dual activator-support catalyst systems
US9181370B2 (en) 2013-11-06 2015-11-10 Chevron Phillips Chemical Company Lp Low density polyolefin resins with low molecular weight and high molecular weight components, and films made therefrom
KR101549209B1 (ko) 2013-11-18 2015-09-02 주식회사 엘지화학 가공성이 우수한 올레핀계 중합체
WO2015072658A1 (ko) * 2013-11-18 2015-05-21 주식회사 엘지화학 가공성이 우수한 올레핀계 중합체
US9540465B2 (en) 2013-11-19 2017-01-10 Chevron Phillips Chemical Company Lp Boron-bridged metallocene catalyst systems and polymers produced therefrom
US9217049B2 (en) 2013-11-19 2015-12-22 Chevron Phillips Chemical Company Lp Dual catalyst systems for producing polymers with a broad molecular weight distribution and a uniform short chain branch distribution
US9303109B2 (en) 2013-11-19 2016-04-05 Chevron Phillips Chemical Company Lp Catalyst systems containing boron-bridged cyclopentadienyl-fluorenyl metallocene compounds with an alkenyl substituent
US9303110B2 (en) 2013-11-19 2016-04-05 Chevron Phillips Chemical Company Lp Boron-bridged bis-indenyl metallocene catalyst systems and polymers produced therefrom
CA2938740C (en) * 2014-02-11 2022-06-21 Univation Technologies, Llc Producing polyolefin products
ES2731585T3 (es) * 2014-05-22 2019-11-18 Chevron Phillips Chemical Co Lp Sistemas catalíticos duales para producir polímeros con una distribución de peso molecular amplia y una SCBD (distribución de ramificación de cadena corta) uniforme
BR112017003314A2 (pt) 2014-08-19 2018-01-23 Univation Tech Llc suportes de catalisador fluorados e sistemas de catalisador
BR112017003306B1 (pt) 2014-08-19 2022-03-03 Univation Technologies, Llc Método para preparar um suporte de catalisador fluorado e sistema de catalisador
SG11201701260WA (en) 2014-08-19 2017-03-30 Univation Tech Llc Fluorinated catalyst supports and catalyst systems
KR101617870B1 (ko) 2014-09-05 2016-05-03 주식회사 엘지화학 가공성이 우수한 올레핀계 중합체
WO2016036204A1 (ko) * 2014-09-05 2016-03-10 주식회사 엘지화학 가공성이 우수한 올레핀계 중합체
JP6420911B2 (ja) * 2014-09-05 2018-11-07 エルジー・ケム・リミテッド 混成担持触媒およびこれを用いるオレフィン系重合体の製造方法
KR101653356B1 (ko) 2014-10-17 2016-09-01 주식회사 엘지화학 고분자량 폴리올레핀 제조용 메탈로센 촉매 및 이의 제조방법
KR101653357B1 (ko) 2014-11-06 2016-09-01 주식회사 엘지화학 고분자량 폴리올레핀 제조용 메탈로센 촉매 및 이의 제조방법
KR101747401B1 (ko) * 2014-12-08 2017-06-14 주식회사 엘지화학 가공성이 우수한 에틸렌/알파-올레핀 공중합체
WO2016093580A1 (ko) * 2014-12-08 2016-06-16 주식회사 엘지화학 가공성이 우수한 에틸렌/알파-올레핀 공중합체
WO2016171807A1 (en) 2015-04-20 2016-10-27 Exxonmobil Chemical Patents Inc. Catalyst composition comprising fluorided support and processes for use thereof
US9796795B2 (en) 2015-01-14 2017-10-24 Exxonmobil Chemical Patents Inc. Tetrahydroindacenyl catalyst composition, catalyst system, and processes for use thereof
KR20160121045A (ko) * 2015-04-09 2016-10-19 주식회사 엘지화학 중공 성형용 고밀도 폴리에틸렌 공중합체
KR101831418B1 (ko) 2015-04-13 2018-02-22 주식회사 엘지화학 가공성 및 표면 특성이 우수한 에틸렌/알파-올레핀 공중합체
WO2016167548A1 (ko) * 2015-04-13 2016-10-20 주식회사 엘지화학 가공성 및 표면 특성이 우수한 에틸렌 /알파-올레핀 공중합체
KR20160121940A (ko) * 2015-04-13 2016-10-21 주식회사 엘지화학 내환경 응력 균열성이 우수한 에틸렌/알파-올레핀 공중합체
KR20160123172A (ko) * 2015-04-15 2016-10-25 주식회사 엘지화학 가공성이 우수한 에틸렌/알파-올레핀 공중합체
KR101891638B1 (ko) 2015-04-15 2018-08-24 주식회사 엘지화학 가공성이 우수한 에틸렌/알파-올레핀 공중합체 공중합체
EP3286231B1 (en) 2015-04-20 2019-10-09 ExxonMobil Chemical Patents Inc. Catalyst composition comprising fluorided support and processes for use thereof
EP3274381B1 (en) 2015-04-20 2019-05-15 ExxonMobil Chemical Patents Inc. Catalyst composition comprising fluorided support and processes for use thereof
US9289748B1 (en) 2015-06-11 2016-03-22 Chevron Phillips Chemical Company Lp Treater regeneration
US9861955B2 (en) 2015-06-11 2018-01-09 Chevron Phillips Chemical Company, Lp Treater regeneration
US9540457B1 (en) * 2015-09-24 2017-01-10 Chevron Phillips Chemical Company Lp Ziegler-natta—metallocene dual catalyst systems with activator-supports
KR101711788B1 (ko) 2016-03-09 2017-03-14 한화케미칼 주식회사 혼성 촉매 조성물, 이의 제조방법, 및 이를 이용하여 제조된 폴리올레핀
KR101725004B1 (ko) * 2016-04-27 2017-04-18 한화케미칼 주식회사 혼성 담지 메탈로센 촉매 및 이를 이용한 가공성이 우수한 폴리올레핀 수지
US9803037B1 (en) 2016-05-03 2017-10-31 Exxonmobil Chemical Patents Inc. Tetrahydro-as-indacenyl catalyst composition, catalyst system, and processes for use thereof
WO2017192226A1 (en) 2016-05-03 2017-11-09 Exxonmobil Chemical Patents Inc. Tetrahydroindacenyl catalyst composition, catalyst system, and processes for use thereof
ES2904791T3 (es) * 2016-11-08 2022-04-06 Univation Tech Llc Composición de polietileno
RU2758693C2 (ru) 2016-11-08 2021-11-01 ЮНИВЕЙШН ТЕКНОЛОДЖИЗ, ЭлЭлСи Полиэтиленовая композиция
KR102139364B1 (ko) * 2016-12-20 2020-07-29 주식회사 엘지화학 올레핀 중합체 및 이의 제조 방법
KR102087340B1 (ko) * 2016-12-20 2020-03-10 주식회사 엘지화학 폴리올레핀계 필름
KR102065719B1 (ko) * 2017-01-25 2020-01-13 주식회사 엘지화학 혼성 담지 촉매
WO2018147968A1 (en) * 2017-02-13 2018-08-16 Univation Technologies, Llc Bimodal polyethylene resins
WO2018151903A1 (en) 2017-02-20 2018-08-23 Exxonmobil Chemical Patents Inc. Supported catalyst systems and processes for use thereof
US10723819B2 (en) 2017-02-20 2020-07-28 Exxonmobil Chemical Patents, Inc. Supported catalyst systems and processes for use thereof
EP3618942A1 (en) 2017-05-03 2020-03-11 Chevron Phillips Chemical Company LP Regeneration of a desiccant in an off-line treater of a polyolefin production process
US10030086B1 (en) 2017-07-21 2018-07-24 Chevron Phillips Chemical Company Lp Methods for determining transition metal compound concentrations in multicomponent liquid systems
US10697889B2 (en) 2017-07-21 2020-06-30 Chevron Phillips Chemical Company Lp Methods for determining transition metal compound concentrations in multicomponent liquid systems
CN111051366B (zh) * 2017-08-02 2023-09-29 道达尔研究技术弗吕公司 双功能催化剂组合物
US10844150B2 (en) 2017-08-04 2020-11-24 Exxonmobil Chemical Patents Inc. Mixed catalysts with 2,6-bis(imino)pyridyl iron complexes and bridged hafnocenes
EP3697822A4 (en) 2017-08-04 2020-08-26 ExxonMobil Chemical Patents Inc. MIXED CATALYSTS INCLUDING UNBRIDGED HAFNOCENE WITH -CH2-SIME3 FRACTIONS
US10703838B2 (en) 2017-10-31 2020-07-07 Exxonmobil Chemical Patents Inc. Mixed catalyst systems with four metallocenes on a single support
US10882925B2 (en) 2017-11-29 2021-01-05 Exxonmobil Chemical Patents Inc. Catalysts that produce polyethylene with broad, bimodal molecular weight distribution
US10889663B2 (en) 2017-11-29 2021-01-12 Exxonmobil Chemical Patents Inc. Asymmetric ANSA-metallocene catalyst compounds for producing polyolefins having a broad molecular weight distribution
US10926250B2 (en) 2017-12-01 2021-02-23 Exxonmobil Chemical Patents Inc. Catalyst systems and polymerization processes for using the same
KR102405495B1 (ko) 2017-12-01 2022-06-08 엑손모빌 케미칼 패턴츠 인코포레이티드 촉매계 및 이를 사용하기 위한 중합 방법
KR102248557B1 (ko) * 2017-12-20 2021-05-06 주식회사 엘지화학 촉매 조성물 및 이를 이용한 올레핀 중합체의 제조 방법
EP3670544B1 (en) * 2017-12-20 2022-03-23 Lg Chem, Ltd. Catalyst composition and method for preparing olefin polymer by using same
US10865258B2 (en) 2018-01-31 2020-12-15 Exxonmobil Chemical Patents Inc. Mixed catalyst systems containing bridged metallocenes with a pendant group 13 element, processes for making a polymer product using same, and products made from same
US10851187B2 (en) 2018-01-31 2020-12-01 Exxonmobil Chemical Patents Inc. Bridged metallocene catalysts with a pendant group 13 element, catalyst systems containing same, processes for making a polymer product using same, and products made from same
US11053329B2 (en) 2018-03-19 2021-07-06 Exxonmobil Chemical Patents Inc. Multiple non-coordinating anion activators for propylene-ethylene-diene monomer polymerization reactions
US10679734B2 (en) 2018-03-29 2020-06-09 Chevron Phillips Chemical Company Lp Methods for determining transition metal compound concentrations in multicomponent liquid systems
US10507445B2 (en) 2018-03-29 2019-12-17 Chevron Phillips Chemical Company Lp Methods for determining transition metal compound concentrations in multicomponent liquid systems
WO2019194958A1 (en) 2018-04-06 2019-10-10 Exxonmobil Chemical Patents Inc. Thermoplastic vulcanizates and compositions therefrom
US10792609B2 (en) 2018-05-07 2020-10-06 Chevron Phillips Chemical Company Lp Nitrogen conservation in polymerization processes
KR20210066859A (ko) * 2018-09-28 2021-06-07 유니베이션 테크놀로지즈, 엘엘씨 이중 모드 폴리에틸렌 공중합체 조성물 및 이로 제조된 파이프
CN113646074B (zh) * 2019-04-05 2023-05-09 埃克森美孚化学专利公司 控制聚烯烃产物的分子量分布和化学组成分布
US11014997B2 (en) 2019-05-16 2021-05-25 Chevron Phillips Chemical Company Lp Dual catalyst system for producing high density polyethylenes with long chain branching
WO2021011883A1 (en) 2019-07-17 2021-01-21 Exxonmobil Chemical Patents Inc. Ethylene-based copolymer and propylene-alpha-olefin-diene compositions for use in layered articles
US11667777B2 (en) 2019-10-04 2023-06-06 Chevron Phillips Chemical Company Lp Bimodal polyethylene copolymers
US11472828B2 (en) 2019-10-11 2022-10-18 Exxonmobil Chemical Patents Inc. Indacene based metallocene catalysts useful in the production of propylene polymers
CN112745366B (zh) * 2019-10-30 2024-05-24 中国石油化工股份有限公司 硅基桥联的茂金属化合物及其制备方法、应用
KR102342077B1 (ko) 2019-12-24 2021-12-21 한화토탈 주식회사 에틸렌 중합용 촉매의 제조 방법
US11267919B2 (en) 2020-06-11 2022-03-08 Chevron Phillips Chemical Company Lp Dual catalyst system for producing polyethylene with long chain branching for blow molding applications
US11186662B1 (en) 2020-07-14 2021-11-30 Chevron Phillips Chemical Company Lp Metallocene catalyst systems with chemically-treated solid oxides for producing ethylene-based plastomers and elastomers
CN111974445B (zh) * 2020-08-24 2023-01-17 大连华邦化学有限公司 一种惰性气体纯化催化剂、原料组合物及制备方法
EP4277936A1 (en) 2021-01-12 2023-11-22 ExxonMobil Chemical Patents Inc. Asymmetric constrained geometry catalysts
US11125680B1 (en) 2021-01-14 2021-09-21 Chevron Phillips Chemical Company Lp Methods for determining the activity of an activated chemically-treated solid oxide in olefin polymerizations

Family Cites Families (65)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3248179A (en) 1962-02-26 1966-04-26 Phillips Petroleum Co Method and apparatus for the production of solid polymers of olefins
US3242099A (en) 1964-03-27 1966-03-22 Union Carbide Corp Olefin polymerization catalysts
US4060480A (en) 1971-09-03 1977-11-29 Chevron Research Company Hydrocarbon hydroconversion process employing hydroxy-aluminum stabilized catalysts supports
US4501885A (en) 1981-10-14 1985-02-26 Phillips Petroleum Company Diluent and inert gas recovery from a polymerization process
US4588790A (en) 1982-03-24 1986-05-13 Union Carbide Corporation Method for fluidized bed polymerization
US4452910A (en) 1982-06-15 1984-06-05 Standard Oil Company (Indiana) Chromium expanded smectite clay
US4808561A (en) 1985-06-21 1989-02-28 Exxon Chemical Patents Inc. Supported polymerization catalyst
US4794096A (en) 1987-04-03 1988-12-27 Fina Technology, Inc. Hafnium metallocene catalyst for the polymerization of olefins
US5565175A (en) 1990-10-01 1996-10-15 Phillips Petroleum Company Apparatus and method for producing ethylene polymer
US5575979A (en) 1991-03-04 1996-11-19 Phillips Petroleum Company Process and apparatus for separating diluents from solid polymers utilizing a two-stage flash and a cyclone separator
AU650787B2 (en) 1991-12-09 1994-06-30 Phillips Petroleum Company Process for preparing a pillared chain silicate clay
US5436304A (en) 1992-03-19 1995-07-25 Exxon Chemical Patents Inc. Process for polymerizing monomers in fluidized beds
US5352749A (en) 1992-03-19 1994-10-04 Exxon Chemical Patents, Inc. Process for polymerizing monomers in fluidized beds
US5576259A (en) 1993-10-14 1996-11-19 Tosoh Corporation Process for producing α-olefin polymer
US5455314A (en) 1994-07-27 1995-10-03 Phillips Petroleum Company Method for controlling removal of polymerization reaction effluent
DE69611554T2 (de) 1995-02-20 2001-07-05 Tosoh Corp Katalysator für die Polymerisation von Olefinen und Verfahren zur Herstellung von Olefinpolymerisaten
DE69702506T2 (de) 1996-03-27 2001-03-08 Dow Chemical Co Hochlösliches aktivierungsmittel für olefinpolymerisationskatalysator
US5739220A (en) 1997-02-06 1998-04-14 Fina Technology, Inc. Method of olefin polymerization utilizing hydrogen pulsing, products made therefrom, and method of hydrogenation
US6239235B1 (en) 1997-07-15 2001-05-29 Phillips Petroleum Company High solids slurry polymerization
KR100531628B1 (ko) 1998-03-20 2005-11-29 엑손모빌 케미칼 패턴츠 인코포레이티드 연속적인 슬러리 중합반응의 휘발물질 제거
US6107230A (en) 1998-05-18 2000-08-22 Phillips Petroleum Company Compositions that can produce polymers
US6300271B1 (en) 1998-05-18 2001-10-09 Phillips Petroleum Company Compositions that can produce polymers
US6165929A (en) 1998-05-18 2000-12-26 Phillips Petroleum Company Compositions that can produce polymers
SG85238A1 (en) * 1998-07-02 2001-12-19 Montell Technology Company Bv Compositions containing substantially amorphous alpha-olefin polymers
US6294494B1 (en) 1998-12-18 2001-09-25 Phillips Petroleum Company Olefin polymerization processes and products thereof
US6262191B1 (en) 1999-03-09 2001-07-17 Phillips Petroleum Company Diluent slip stream to give catalyst wetting agent
US6355594B1 (en) 1999-09-27 2002-03-12 Phillips Petroleum Company Organometal catalyst compositions
US6376415B1 (en) 1999-09-28 2002-04-23 Phillips Petroleum Company Organometal catalyst compositions
US6395666B1 (en) 1999-09-29 2002-05-28 Phillips Petroleum Company Organometal catalyst compositions
US6548441B1 (en) 1999-10-27 2003-04-15 Phillips Petroleum Company Organometal catalyst compositions
US6391816B1 (en) 1999-10-27 2002-05-21 Phillips Petroleum Organometal compound catalyst
US6613712B1 (en) 1999-11-24 2003-09-02 Phillips Petroleum Company Organometal catalyst compositions with solid oxide supports treated with fluorine and boron
US6548442B1 (en) 1999-12-03 2003-04-15 Phillips Petroleum Company Organometal compound catalyst
US6750302B1 (en) 1999-12-16 2004-06-15 Phillips Petroleum Company Organometal catalyst compositions
US6524987B1 (en) 1999-12-22 2003-02-25 Phillips Petroleum Company Organometal catalyst compositions
US6667274B1 (en) 1999-12-30 2003-12-23 Phillips Petroleum Company Polymerization catalysts
US7041617B2 (en) * 2004-01-09 2006-05-09 Chevron Phillips Chemical Company, L.P. Catalyst compositions and polyolefins for extrusion coating applications
US6632894B1 (en) 1999-12-30 2003-10-14 Phillips Petroleum Company Organometal catalyst compositions
US6576583B1 (en) 2000-02-11 2003-06-10 Phillips Petroleum Company Organometal catalyst composition
US6388017B1 (en) 2000-05-24 2002-05-14 Phillips Petroleum Company Process for producing a polymer composition
US20040059070A1 (en) 2002-09-19 2004-03-25 Whitte William M. Process and apparatus for controlling molecular weight distribution and short chain branching for olefin polymers
US7119153B2 (en) 2004-01-21 2006-10-10 Jensen Michael D Dual metallocene catalyst for producing film resins with good machine direction (MD) elmendorf tear strength
US7199073B2 (en) 2004-11-10 2007-04-03 Chevron Phillips Chemical Company, Lp Resins that yield low haze films and the process for their production
US7026494B1 (en) 2005-01-10 2006-04-11 Chevron Phillips Chemical Company, Lp Polymerization catalysts for producing high melt index polymers without the use of hydrogen
US7312283B2 (en) 2005-08-22 2007-12-25 Chevron Phillips Chemical Company Lp Polymerization catalysts and process for producing bimodal polymers in a single reactor
US7625982B2 (en) 2005-08-22 2009-12-01 Chevron Phillips Chemical Company Lp Multimodal polyethylene compositions and pipe made from same
US7226886B2 (en) 2005-09-15 2007-06-05 Chevron Phillips Chemical Company, L.P. Polymerization catalysts and process for producing bimodal polymers in a single reactor
US7619047B2 (en) 2006-02-22 2009-11-17 Chevron Phillips Chemical Company, Lp Dual metallocene catalysts for polymerization of bimodal polymers
US8003739B2 (en) 2007-10-17 2011-08-23 Fina Technology, Inc. Multi-component catalyst systems and polymerization processes for forming in-situ heterophasic copolymers and/or varying the xylene solubles content of polyolefins
US20070255022A1 (en) 2006-04-28 2007-11-01 Fina Technology, Inc. Fluorinated transition metal catalysts and formation thereof
US7514510B2 (en) * 2006-07-25 2009-04-07 Fina Technology, Inc. Fluorenyl catalyst compositions and olefin polymerization process
US7847240B2 (en) 2007-06-11 2010-12-07 Dana-Farber Cancer Institute, Inc. Mass spectroscopy system and method including an excitation gate
US8119553B2 (en) 2007-09-28 2012-02-21 Chevron Phillips Chemical Company Lp Polymerization catalysts for producing polymers with low melt elasticity
CA2706822C (en) 2007-11-19 2013-05-28 Mitsui Chemicals, Inc. Bridged metallocene compound, olefin polymerization catalyst containing the same, and ethylene polymer obtained with the catalyst
US7863210B2 (en) 2007-12-28 2011-01-04 Chevron Phillips Chemical Company Lp Nano-linked metallocene catalyst compositions and their polymer products
US8012900B2 (en) 2007-12-28 2011-09-06 Chevron Phillips Chemical Company, L.P. Nano-linked metallocene catalyst compositions and their polymer products
US8080681B2 (en) 2007-12-28 2011-12-20 Chevron Phillips Chemical Company Lp Nano-linked metallocene catalyst compositions and their polymer products
US7884163B2 (en) 2008-03-20 2011-02-08 Chevron Phillips Chemical Company Lp Silica-coated alumina activator-supports for metallocene catalyst compositions
JP5346088B2 (ja) * 2008-09-25 2013-11-20 バーゼル・ポリオレフィン・ゲーエムベーハー 耐衝撃性lldpe組成物及びそれから製造されるフィルム
US7919639B2 (en) 2009-06-23 2011-04-05 Chevron Phillips Chemical Company Lp Nano-linked heteronuclear metallocene catalyst compositions and their polymer products
MX2012000250A (es) 2009-06-29 2012-01-25 Chevron Philips Chemical Company Lp Sistemas catalizadores duales de metaloceno para disminuir el indice de fusion e incrementar las velocidades de produccion de polimero.
US8288487B2 (en) 2010-07-06 2012-10-16 Chevron Phillips Chemical Company Lp Catalysts for producing broad molecular weight distribution polyolefins in the absence of added hydrogen
US8629292B2 (en) 2010-10-07 2014-01-14 Chevron Phillips Chemical Company Lp Stereoselective synthesis of bridged metallocene complexes
US8609793B2 (en) 2010-10-07 2013-12-17 Chevron Phillips Chemical Company Lp Catalyst systems containing a bridged metallocene
US8637616B2 (en) 2010-10-07 2014-01-28 Chevron Philips Chemical Company Lp Bridged metallocene catalyst systems with switchable hydrogen and comonomer effects

Also Published As

Publication number Publication date
CA3035065C (en) 2019-08-06
US8598061B2 (en) 2013-12-03
KR101959694B1 (ko) 2019-03-18
US20140107308A1 (en) 2014-04-17
CA2802498A1 (en) 2012-01-12
US9102821B2 (en) 2015-08-11
KR20180008935A (ko) 2018-01-24
US20120329641A1 (en) 2012-12-27
KR20130113322A (ko) 2013-10-15
WO2012006272A3 (en) 2012-05-18
MX2012015222A (es) 2013-06-28
CN102958948B (zh) 2016-01-13
US8288487B2 (en) 2012-10-16
CA3034897C (en) 2020-12-15
EP2591012B1 (en) 2020-10-28
BR112013000397A2 (pt) 2016-05-17
CA3034897A1 (en) 2012-01-12
BR112013000397B1 (pt) 2020-12-29
EP2591012A2 (en) 2013-05-15
SG186217A1 (en) 2013-01-30
US20120010375A1 (en) 2012-01-12
CN102958948A (zh) 2013-03-06
CA2802498C (en) 2019-05-07
KR101836542B1 (ko) 2018-04-19
WO2012006272A2 (en) 2012-01-12
MX2019011352A (es) 2019-11-05
CA3035065A1 (en) 2012-01-12

Similar Documents

Publication Publication Date Title
MX2019011352A (es) Catalizadores para producir poliolefinas de distribucion de peso molecular ancho en ausencia de hidrogeno adicionado.
MX2011006571A (es) Proceso para producir polimeros de distribucion de peso molecular mas amplia con una distribucion de comonomero inversa y niveles bajos de ramificaciones de cadena larga.
IN2015DN00491A (es)
MY159677A (en) Enhanced procatalyst composition and process
BR112012026842A2 (pt) composições de catalisador para produção de poliolefinas de mz/mw elevados
MY181088A (en) Polyethylene for pipes
WO2012048067A3 (en) Bridged metallocene catalyst systems with switchable hydrogen and comonomer effects
TW200730548A (en) Process for manufacturing ultra high molecular weight polymers using novel bridged metallocene catalysts
MX2015006373A (es) Polimeros de baja densidad a base de etileno con alta resistencia a la fusion.
WO2009064404A3 (en) Polymeriazation catalysts, methods of making; methods of using, and polyolefinproducts made therefrom
WO2010030145A3 (en) Ethylene copolymer and a method of preparing the same
MX344739B (es) Tapas y cierres.
MY154967A (en) A process for the preparation of high performance polypropylene
MX2022001538A (es) Polimeros ramificados de cadena larga y metodos para producir los mismos.
WO2009148889A3 (en) Methods of controlling molecular weight distribution of polymers and compositions thereof
EP3243846A3 (en) Multi-headed chain shuttling agents and their use for the preparation of block copolymers
MY152947A (en) Dual metallocene catalysts for polymerization of bimodal polymers
WO2011129593A3 (ko) 티오펜-축합고리 사이클로펜타디에닐 리간드를 포함하는 전이금속 화합물을 사용한 폴리프로필렌의 제조방법
MY183120A (en) Process for preparing a polyethylene product
WO2012004681A3 (en) Shaped high molecular weight polyethylene articles, their production and use
MX2016002445A (es) Polietilenos con un aumento en la distribucion de peso molecular.
WO2014059019A3 (en) Sponge polymer with controlled long chain branching and broad molecular weight distribution
MY189833A (en) Polyethylene composition and films made therefrom
MX2009007056A (es) Metodo de produccion de poliolefina, poliolefina y 1-hexano para la produccion de un material sin procesar de baja densidad lineal.
WO2012134721A3 (en) Vinyl terminated higher olefin polymers and methods to produce thereof