MX2022010318A - Catalizadores de metaloceno para polietileno. - Google Patents

Catalizadores de metaloceno para polietileno.

Info

Publication number
MX2022010318A
MX2022010318A MX2022010318A MX2022010318A MX2022010318A MX 2022010318 A MX2022010318 A MX 2022010318A MX 2022010318 A MX2022010318 A MX 2022010318A MX 2022010318 A MX2022010318 A MX 2022010318A MX 2022010318 A MX2022010318 A MX 2022010318A
Authority
MX
Mexico
Prior art keywords
sub
metallocene
cyclopentadienyl ligand
ligand
olefin polymers
Prior art date
Application number
MX2022010318A
Other languages
English (en)
Inventor
Jim B Askew
Errun Ding
Qing Yang
Randall S Muninger
Carlton E Ash
Zhou Chen
Original Assignee
Chevron Phillips Chemical Co Lp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Chevron Phillips Chemical Co Lp filed Critical Chevron Phillips Chemical Co Lp
Publication of MX2022010318A publication Critical patent/MX2022010318A/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/14—Monomers containing five or more carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2420/00—Metallocene catalysts
    • C08F2420/07—Heteroatom-substituted Cp, i.e. Cp or analog where at least one of the substituent of the Cp or analog ring is or contains a heteroatom
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/02—Low molecular weight, e.g. <100,000 Da.
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/03—Narrow molecular weight distribution, i.e. Mw/Mn < 3
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

Abstract

Se describen compuestos de metaloceno, composiciones de catalizador que comprenden un compuesto de metaloceno, procesos para polimerizar olefinas, métodos para fabricar composiciones de catalizador, polímeros de olefina y artículos hechos de polímeros de olefina. En un aspecto, los compuestos de metaloceno contienen un ligando fluorenilo y un ligando ciclopentadienilo que están unidos por un grupo de unión, en el que el metaloceno se caracteriza por [1] el ligando ciclopentadienilo sustituido con un grupo heterohidrocarbilo C2-C18 que tiene un átomo de oxígeno situado a 5 átomos de distancia o menos del ligando ciclopentadienilo y [2] el grupo de unión tiene un grupo alquenilo C3-C12 colgante que tiene un doble enlace C=C terminal. Se ha descubierto que una composición de catalizador que comprende un compuesto de metaloceno que tiene estas características puede producir polietileno que tiene un bajo índice de fusión en ausencia de un segundo metaloceno.
MX2022010318A 2020-02-21 2021-02-18 Catalizadores de metaloceno para polietileno. MX2022010318A (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US16/797,875 US11325995B2 (en) 2020-02-21 2020-02-21 Metallocene catalysts for polyethylene
PCT/US2021/018439 WO2021168023A1 (en) 2020-02-21 2021-02-18 Metallocene catalysts for polyethylene

Publications (1)

Publication Number Publication Date
MX2022010318A true MX2022010318A (es) 2022-09-19

Family

ID=74867668

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2022010318A MX2022010318A (es) 2020-02-21 2021-02-18 Catalizadores de metaloceno para polietileno.

Country Status (9)

Country Link
US (1) US11325995B2 (es)
EP (1) EP4107194B1 (es)
KR (1) KR102642111B1 (es)
CN (1) CN115003707B (es)
BR (1) BR112022015058B1 (es)
CA (1) CA3171878C (es)
ES (1) ES2982058T3 (es)
MX (1) MX2022010318A (es)
WO (1) WO2021168023A1 (es)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US11667777B2 (en) 2019-10-04 2023-06-06 Chevron Phillips Chemical Company Lp Bimodal polyethylene copolymers
US12365748B2 (en) * 2020-06-10 2025-07-22 Lg Chem, Ltd. Polyethylene and chlorinated polyethylene thereof
WO2023114773A1 (en) * 2021-12-16 2023-06-22 Chevron Phillips Chemical Company Lp Modifications of sulfated bentonites and uses thereof in metallocene catalyst systems for olefin polymerization
CA3256993A1 (en) * 2022-06-02 2023-12-07 Chevron Phillips Chemical Company Lp HIGH-POROSITY FLUORIDED SILICA-COATED ALUMINUM ACTIVATOR SUPPORTS AND THEIR USES IN METALLOCENE-BASED CATALYST SYSTEMS FOR OLEFIN POLYMERIZATION
US20250340678A1 (en) * 2024-05-01 2025-11-06 Chevron Phillips Chemical Company Lp Heteroatom (o-,s-) tethered metallocenes, catalyst compositions, and processes

Family Cites Families (41)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3242099A (en) 1964-03-27 1966-03-22 Union Carbide Corp Olefin polymerization catalysts
US4808561A (en) 1985-06-21 1989-02-28 Exxon Chemical Patents Inc. Supported polymerization catalyst
US4794096A (en) 1987-04-03 1988-12-27 Fina Technology, Inc. Hafnium metallocene catalyst for the polymerization of olefins
US5576259A (en) 1993-10-14 1996-11-19 Tosoh Corporation Process for producing α-olefin polymer
EP0727443B1 (en) 1995-02-20 2001-01-17 Tosoh Corporation Catalyst for olefin polymerization and process for producing olefin polymers
CA2245839C (en) 1996-03-27 2005-06-14 The Dow Chemical Company Highly soluble olefin polymerization catalyst activator
US5886202A (en) * 1997-01-08 1999-03-23 Jung; Michael Bridged fluorenyl/indenyl metallocenes and the use thereof
US6107230A (en) 1998-05-18 2000-08-22 Phillips Petroleum Company Compositions that can produce polymers
US6300271B1 (en) 1998-05-18 2001-10-09 Phillips Petroleum Company Compositions that can produce polymers
US6165929A (en) 1998-05-18 2000-12-26 Phillips Petroleum Company Compositions that can produce polymers
US6294494B1 (en) 1998-12-18 2001-09-25 Phillips Petroleum Company Olefin polymerization processes and products thereof
US6355594B1 (en) 1999-09-27 2002-03-12 Phillips Petroleum Company Organometal catalyst compositions
US6376415B1 (en) 1999-09-28 2002-04-23 Phillips Petroleum Company Organometal catalyst compositions
US6395666B1 (en) 1999-09-29 2002-05-28 Phillips Petroleum Company Organometal catalyst compositions
US6391816B1 (en) 1999-10-27 2002-05-21 Phillips Petroleum Organometal compound catalyst
US6548441B1 (en) 1999-10-27 2003-04-15 Phillips Petroleum Company Organometal catalyst compositions
US6750302B1 (en) 1999-12-16 2004-06-15 Phillips Petroleum Company Organometal catalyst compositions
US6524987B1 (en) 1999-12-22 2003-02-25 Phillips Petroleum Company Organometal catalyst compositions
US7041617B2 (en) 2004-01-09 2006-05-09 Chevron Phillips Chemical Company, L.P. Catalyst compositions and polyolefins for extrusion coating applications
WO2001053362A1 (en) 2000-01-19 2001-07-26 Borealis Technology Oy Metallocene catalysts comprising monocyclic siloxy substituted cyclopentadienyl group(s) for the polymerisation of olefins
US6528448B1 (en) 2000-04-28 2003-03-04 Phillips Petroleum Company Polymerization catalyst compositions and processes to produce polymers and bimodal polymers
GB0118010D0 (en) * 2001-07-24 2001-09-19 Borealis Tech Oy Catalysts
DE60331613D1 (de) 2003-03-28 2010-04-15 Mitsui Chemicals Inc Propylen-Copolymer, Polypropylen-Zusammensetzung, Verwendung davon, Übergangsmetallverbindungen und Katalysatoren zur Olefin-Polymerisation
US7501372B2 (en) 2003-11-21 2009-03-10 Chevron Phillips Chemical Company Lp Catalyst compositions for producing polyolefins in the absence of cocatalysts
US7148298B2 (en) 2004-06-25 2006-12-12 Chevron Phillips Chemical Company, L.P. Polymerization catalysts for producing polymers with low levels of long chain branching
US7064225B2 (en) 2004-06-25 2006-06-20 Chevron Phillips Chemical Company, L.P. Synthesis of ansa-metallocenes and their parent ligands in high yield
US7294599B2 (en) 2004-06-25 2007-11-13 Chevron Phillips Chemical Co. Acidic activator-supports and catalysts for olefin polymerization
US7199073B2 (en) 2004-11-10 2007-04-03 Chevron Phillips Chemical Company, Lp Resins that yield low haze films and the process for their production
US7026494B1 (en) 2005-01-10 2006-04-11 Chevron Phillips Chemical Company, Lp Polymerization catalysts for producing high melt index polymers without the use of hydrogen
US7226886B2 (en) 2005-09-15 2007-06-05 Chevron Phillips Chemical Company, L.P. Polymerization catalysts and process for producing bimodal polymers in a single reactor
US7312283B2 (en) 2005-08-22 2007-12-25 Chevron Phillips Chemical Company Lp Polymerization catalysts and process for producing bimodal polymers in a single reactor
US7517939B2 (en) 2006-02-02 2009-04-14 Chevron Phillips Chemical Company, Lp Polymerization catalysts for producing high molecular weight polymers with low levels of long chain branching
US7619047B2 (en) * 2006-02-22 2009-11-17 Chevron Phillips Chemical Company, Lp Dual metallocene catalysts for polymerization of bimodal polymers
US7576163B2 (en) 2006-03-31 2009-08-18 Chevron Phillips Chemical Company, Lp Polymerization catalysts for producing polymers with low levels of long chain branching
US8119553B2 (en) * 2007-09-28 2012-02-21 Chevron Phillips Chemical Company Lp Polymerization catalysts for producing polymers with low melt elasticity
US7884163B2 (en) * 2008-03-20 2011-02-08 Chevron Phillips Chemical Company Lp Silica-coated alumina activator-supports for metallocene catalyst compositions
JP5671750B2 (ja) 2010-03-08 2015-02-18 エルジー・ケム・リミテッド 担持メタロセン触媒の製造方法及びそれを用いたポリオレフィンの製造方法
CN110845546A (zh) * 2013-07-17 2020-02-28 埃克森美孚化学专利公司 取代的茂金属催化剂
JP6420911B2 (ja) 2014-09-05 2018-11-07 エルジー・ケム・リミテッド 混成担持触媒およびこれを用いるオレフィン系重合体の製造方法
KR101795748B1 (ko) * 2015-06-15 2017-12-01 주식회사 엘지화학 폴리올레핀의 제조 방법
KR102140260B1 (ko) * 2016-12-22 2020-07-31 주식회사 엘지화학 올레핀 중합체 및 이의 제조 방법

Also Published As

Publication number Publication date
ES2982058T3 (es) 2024-10-14
EP4107194A1 (en) 2022-12-28
CN115003707A (zh) 2022-09-02
CA3171878C (en) 2023-04-11
US20210261697A1 (en) 2021-08-26
BR112022015058B1 (pt) 2024-02-06
BR112022015058A2 (pt) 2022-09-20
KR20220157970A (ko) 2022-11-29
US11325995B2 (en) 2022-05-10
CN115003707B (zh) 2023-07-07
CA3171878A1 (en) 2021-08-26
KR102642111B1 (ko) 2024-02-28
WO2021168023A1 (en) 2021-08-26
EP4107194B1 (en) 2024-04-10

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