MX2021000300A - Proceso de reacción que implica condensación capilar dentro de un catalizador microporoso. - Google Patents

Proceso de reacción que implica condensación capilar dentro de un catalizador microporoso.

Info

Publication number
MX2021000300A
MX2021000300A MX2021000300A MX2021000300A MX2021000300A MX 2021000300 A MX2021000300 A MX 2021000300A MX 2021000300 A MX2021000300 A MX 2021000300A MX 2021000300 A MX2021000300 A MX 2021000300A MX 2021000300 A MX2021000300 A MX 2021000300A
Authority
MX
Mexico
Prior art keywords
catalyst
carboxylate
reaction process
process involving
capillary condensation
Prior art date
Application number
MX2021000300A
Other languages
English (en)
Inventor
Iker Aguirrezabal
Minguez Ignacio Luz
Mustapha Soukri
Marty Lail
Pedro Luis Arias
Original Assignee
Res Triangle Inst
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Res Triangle Inst filed Critical Res Triangle Inst
Publication of MX2021000300A publication Critical patent/MX2021000300A/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08—Catalytic processes
    • C07C2/26—Catalytic processes with hydrides or organic compounds
    • C07C2/32—Catalytic processes with hydrides or organic compounds as complexes, e.g. acetyl-acetonates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/1691—Coordination polymers, e.g. metal-organic frameworks [MOF]
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/03—Catalysts comprising molecular sieves not having base-exchange properties
    • B01J29/035—Microporous crystalline materials not having base exchange properties, such as silica polymorphs, e.g. silicalites
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208—Oxygen, e.g. acetylacetonates
    • B01J31/2226—Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
    • B01J31/223—At least two oxygen atoms present in one at least bidentate or bridging ligand
    • B01J31/2239—Bridging ligands, e.g. OAc in Cr2(OAc)4, Pt4(OAc)8 or dicarboxylate ligands
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/643—Pore diameter less than 2 nm
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/10—Polymerisation reactions involving at least dual use catalysts, e.g. for both oligomerisation and polymerisation
    • B01J2231/12—Olefin polymerisation or copolymerisation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/20—Olefin oligomerisation or telomerisation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/821—Ruthenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/847—Nickel
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
    • C07C2523/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals of the platinum group metals
    • C07C2523/46—Ruthenium, rhodium, osmium or iridium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • C07C2531/22—Organic complexes

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Nanotechnology (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

En la presente se describe un proceso de reacción catalítica que incluye introducir uno o más reactivos de fase gaseosa en un reactor que comprende un catalizador microporoso que tiene un tamaño de poro menor o igual a 2 nm y ajustar la temperatura y/o la presión del reactor de modo que uno o más de los reactivos de fase gaseosa se condensan dentro de los microporos del catalizador, provocando así que la reacción catalítica tenga lugar en una fase líquida. Además, se describe un proceso para modificar defectos en un catalizador de entramado orgánico metálico (MOF) a base de carboxilato. El proceso incluye proporcionar un catalizador MOF a base de carboxilato; y calentar el catalizador MOF a base de carboxilato en una atmósfera de gas inerte a temperaturas entre aproximadamente 150 ºC y aproximadamente 900 ºC.
MX2021000300A 2018-07-26 2019-07-17 Proceso de reacción que implica condensación capilar dentro de un catalizador microporoso. MX2021000300A (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US201862703684P 2018-07-26 2018-07-26
PCT/US2019/042118 WO2020023256A1 (en) 2018-07-26 2019-07-17 Reaction process involving capillary condensation within a microporous catalyst

Publications (1)

Publication Number Publication Date
MX2021000300A true MX2021000300A (es) 2021-04-19

Family

ID=69182368

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2021000300A MX2021000300A (es) 2018-07-26 2019-07-17 Proceso de reacción que implica condensación capilar dentro de un catalizador microporoso.

Country Status (10)

Country Link
US (1) US11795122B2 (es)
EP (1) EP3826761A4 (es)
JP (1) JP2021532090A (es)
KR (1) KR20210046003A (es)
CN (1) CN112839733A (es)
AU (1) AU2019309363A1 (es)
BR (1) BR112021001048A2 (es)
CA (1) CA3106210A1 (es)
MX (1) MX2021000300A (es)
WO (1) WO2020023256A1 (es)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2022081651A1 (en) * 2020-10-13 2022-04-21 Phillips 66 Company Metal organic framework
CN113948718B (zh) * 2021-10-22 2023-08-25 福州大学 一种稀土多酚超分子包覆的共价有机聚合物铈基纳米碳球

Family Cites Families (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NZ221123A (en) * 1986-08-05 1990-06-26 Mobil Oil Corp Conversion of ethene-containing lower olefinic hydrocarbons to liquid hydrocarbons in presence of water using zeolite with nickel component
EP2167511A4 (en) * 2007-07-17 2010-12-22 Univ California PREPARATION OF FUNCTIONALIZED ZEOLITE FRAME
FR2931707B1 (fr) * 2008-05-30 2011-05-20 Inst Francais Du Petrole Systeme catalytique d'oligomerisation d'olefines a base de complexes organometalliques et de solide poreux.
EP2403815A1 (en) * 2009-07-27 2012-01-11 The Regents of The University of California Oxidative homo-coupling reactions of aryl boronic acids using a porous copper metal-organic framework as a highly efficient heterogeneous catalyst
GB201017095D0 (en) * 2010-10-11 2010-11-24 Univ St Andrews Novel large pore MOFs
CN103547347A (zh) * 2011-02-16 2014-01-29 道康宁公司 涂覆多孔基材的方法
FR2973394A1 (fr) * 2011-03-31 2012-10-05 IFP Energies Nouvelles Procede d'oligomerisation d'une charge hydrocarbonee olefinique utilisant un catalyseur comprenant un materiau de la famille des zif de type structural sod
CN105013292A (zh) * 2014-04-28 2015-11-04 中国石油大学(北京) 一种捕集混合气中co2的复合方法
WO2015177511A1 (en) * 2014-05-23 2015-11-26 The Texas A&M University System Method of preparing a metal organic framework
US9943839B2 (en) * 2014-07-15 2018-04-17 Northwestern University Catalyst composition and process for preparing olefin oxides
EP3262029A4 (en) * 2015-02-23 2018-10-17 The Royal Institution for the Advancement of Learning / McGill University Method for the preparation of metal-organic compounds
WO2017210874A1 (en) * 2016-06-08 2017-12-14 Xia, Ling Imperfect mofs (imofs) material, preparation and use in catalysis, sorption and separation
KR102546232B1 (ko) 2016-08-10 2023-06-21 리써치 트라이앵글 인스티튜트 메조다공성 물질들 내에서 금속 유기 골격들의 고체-상태 결정화 방법들 및 그의 하이브리드 물질들
US20180186707A1 (en) * 2016-12-02 2018-07-05 Siluria Technologies, Inc. Ethylene-to-liquids systems and methods
CN106883422B (zh) * 2017-02-22 2020-03-27 山东师范大学 一种基于咪唑磺酸的金属有机框架及制备方法与应用
KR101845661B1 (ko) * 2017-04-13 2018-04-04 국방과학연구소 표면 개질된 금속유기얼개를 이용한 액상 화학작용제의 제독방법
CN107722290B (zh) * 2017-11-02 2021-03-09 中国科学技术大学 一种双有机配体mof及其制备方法、双有机配体荷电型mof及其制备方法

Also Published As

Publication number Publication date
EP3826761A4 (en) 2022-04-20
JP2021532090A (ja) 2021-11-25
KR20210046003A (ko) 2021-04-27
EP3826761A1 (en) 2021-06-02
WO2020023256A1 (en) 2020-01-30
CA3106210A1 (en) 2020-01-30
AU2019309363A1 (en) 2021-01-28
BR112021001048A2 (pt) 2021-04-13
US11795122B2 (en) 2023-10-24
CN112839733A (zh) 2021-05-25
US20210309588A1 (en) 2021-10-07

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