MX2019006918A - Composicion de control de huecos de aire para polimerizacion de monomero que contiene carbonilo. - Google Patents

Composicion de control de huecos de aire para polimerizacion de monomero que contiene carbonilo.

Info

Publication number
MX2019006918A
MX2019006918A MX2019006918A MX2019006918A MX2019006918A MX 2019006918 A MX2019006918 A MX 2019006918A MX 2019006918 A MX2019006918 A MX 2019006918A MX 2019006918 A MX2019006918 A MX 2019006918A MX 2019006918 A MX2019006918 A MX 2019006918A
Authority
MX
Mexico
Prior art keywords
monomer
glycols
carbonyl
short chain
containing monomer
Prior art date
Application number
MX2019006918A
Other languages
English (en)
Inventor
L Swan Dana
Alsbaiee Alaaeddin
Crocker Evan
Original Assignee
Arkema France
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Arkema France filed Critical Arkema France
Publication of MX2019006918A publication Critical patent/MX2019006918A/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/14—Methyl esters, e.g. methyl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/44—Polymerisation in the presence of compounding ingredients, e.g. plasticisers, dyestuffs, fillers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F265/00—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00
    • C08F265/04—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00 on to polymers of esters
    • C08F265/06—Polymerisation of acrylate or methacrylate esters on to polymers thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/05—Alcohols; Metal alcoholates
    • C08K5/053—Polyhydroxylic alcohols
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/16—Nitrogen-containing compounds
    • C08K5/17—Amines; Quaternary ammonium compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K7/00—Use of ingredients characterised by shape
    • C08K7/02—Fibres or whiskers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/04—Homopolymers or copolymers of esters
    • C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
    • C08L33/10—Homopolymers or copolymers of methacrylic acid esters
    • C08L33/12—Homopolymers or copolymers of methyl methacrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L51/003—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
    • C09D4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09D159/00 - C09D187/00
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Polymerisation Methods In General (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Polyethers (AREA)

Abstract

La invención se refiere al uso de bajos niveles de glicoles y dioles de cadena corta para controlar la formación de huecos de aire en cualquier reacción de polimerización que tenga monómeros que contengan carbonilo, y de manera preferente monómeros de éster de ácido carboxílico, en un nivel de al menos 10% de monómero total, donde el monómero tiene una temperatura de reacción exotérmica de polimerización pico de mayor que el punto de ebullición del monómero. Los glicoles y dioles de cadena corta se usan en la mezcla de polimerización en niveles de 0.5 a 10 por ciento en peso, basado en el monómero que contiene éster de ácido carboxílico. Se cree que los glicoles y dioles de cadena corta de hidrógeno se enlazan con el monómero que contiene -(C=O)O- para incrementar el punto de ebullición del monómero, y disminuir o aún eliminar la formación de huecos de aire debido a la ebullición del momento. La invención es especialmente útil en la polimerización de polímeros y copolímero de metacrilato de metilo, ya sea puros, o como un sistema compuesto de polímero.
MX2019006918A 2016-12-14 2017-12-13 Composicion de control de huecos de aire para polimerizacion de monomero que contiene carbonilo. MX2019006918A (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US201662434010P 2016-12-14 2016-12-14
PCT/US2017/066048 WO2018112016A1 (en) 2016-12-14 2017-12-13 Air void control composition for carbonyl-containing monomer polymerization

Publications (1)

Publication Number Publication Date
MX2019006918A true MX2019006918A (es) 2019-08-22

Family

ID=62559740

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2019006918A MX2019006918A (es) 2016-12-14 2017-12-13 Composicion de control de huecos de aire para polimerizacion de monomero que contiene carbonilo.

Country Status (9)

Country Link
US (1) US11578159B2 (es)
EP (1) EP3555156A4 (es)
JP (1) JP7258750B2 (es)
KR (1) KR20190091548A (es)
CN (2) CN110382569B (es)
BR (1) BR112019012076A2 (es)
CA (1) CA3046368A1 (es)
MX (1) MX2019006918A (es)
WO (1) WO2018112016A1 (es)

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1504858A (en) * 1974-07-11 1978-03-22 Ici Ltd Acrylic powder blends
JPS5447791A (en) * 1977-09-21 1979-04-14 Shiyoufuu Toushi Seizou Kk Dental resin polymerization
JPH0625204B2 (ja) * 1985-08-28 1994-04-06 住友化学工業株式会社 ビニル系単量体の重合成形方法
US5061747A (en) * 1988-11-28 1991-10-29 Rohm And Haas Company Methyl methacrylate compositions
JPH02199151A (ja) * 1988-11-28 1990-08-07 Rohm & Haas Co 改良されたメチルメタクリレート組成物
CA2000794A1 (en) * 1988-11-28 1990-05-28 Paul J. Keating Methyl methacrylate compositions
US5466756A (en) * 1988-11-28 1995-11-14 Rohm And Haas Company Methyl methacrylate compositions
JP2567726B2 (ja) * 1990-09-04 1996-12-25 三菱レイヨン株式会社 メタクリル樹脂板の製造方法
US20030195311A1 (en) * 2002-04-16 2003-10-16 Crompton Corporation Multi-component liquid azo-peroxide initiator mixture and method for using same
JP2007277454A (ja) * 2006-04-10 2007-10-25 Mitsubishi Rayon Co Ltd メタクリル系重合硬化物の製造方法及びメタクリル系重合硬化性組成物
CN102219974B (zh) * 2011-04-20 2013-02-27 中国科学院合肥物质科学研究院 具有储热放热性能的有机智能玻璃及其制备方法
JP5829177B2 (ja) * 2011-07-12 2015-12-09 富士フイルム株式会社 インプリント用硬化性組成物、パターン形成方法およびパターン
FR2981652B1 (fr) * 2011-10-21 2015-03-27 Arkema France Composites via la polymerisation in-situ de resines thermoplastiques methacryliques
US9765199B2 (en) * 2012-10-31 2017-09-19 Topasol, LLC Non-yellowing easy-to-clean antimicrobial plastic

Also Published As

Publication number Publication date
EP3555156A4 (en) 2020-06-03
EP3555156A1 (en) 2019-10-23
KR20190091548A (ko) 2019-08-06
WO2018112016A1 (en) 2018-06-21
JP7258750B2 (ja) 2023-04-17
CA3046368A1 (en) 2018-06-21
US11578159B2 (en) 2023-02-14
US20190330446A1 (en) 2019-10-31
BR112019012076A2 (pt) 2019-11-12
CN110382569A (zh) 2019-10-25
CN110382569B (zh) 2023-01-24
JP2020502324A (ja) 2020-01-23
CN116041624A (zh) 2023-05-02

Similar Documents

Publication Publication Date Title
MX355393B (es) Polimerización regulada y continua de polímeros de ácido policarboxílico.
MX2011006571A (es) Proceso para producir polimeros de distribucion de peso molecular mas amplia con una distribucion de comonomero inversa y niveles bajos de ramificaciones de cadena larga.
MY150828A (en) Polycarboxylic acid polymers
MY155971A (en) Methacrylic resin, molded body thereof, and method for producing methacrylic resin
MX2015017872A (es) Composición polimérica de tipo gel obtenida por polimerización de un monómero que contiene grupos ácidos en presencia de un compuesto de poliéter.
MX348804B (es) Polimero de emulsion multietapas y eficiencia mejorada en pigmento.
BRPI0901398B8 (pt) formulações adesivas para a união de materiais compósitos
MX2017005557A (es) Composiciones vulcanizables que contienen copolimeros de etileno acetato de vinilo que contienen grupos epoxi.
MX2013006796A (es) Acidos poliacrilicos estables, su fabricacion y su uso.
MX2018007280A (es) Asfalto modificado usando polimeros que contienen epoxidos.
MX2014004884A (es) Procedimiento para preparar polimerizados que son apropiados para absorber y almacenar liquidos acuosos.
WO2010011924A3 (en) Monomers derived from alpha-or beta-amino-e-caprolactam and polymers made therefrom
MX2013008623A (es) Composicion para el fortalecimiento de agujeros de perforacion.
JP2011524449A5 (es)
MX2018009535A (es) Procesos para producir polimeros del acido acrilico.
FR2995313B1 (fr) Melange primaire d'initiateur et de promoteur de reticulation
MX2019006918A (es) Composicion de control de huecos de aire para polimerizacion de monomero que contiene carbonilo.
TR201909981T4 (tr) Genleşebilir vinil aromatik polimerik bileşimler.
ATE456586T1 (de) Zusammensetzungen, die biscitraconimid, bisitaconimid und/oder citraconimido-itaconimid umfassen
TW201613997A (en) Thermoplastic resin composition, manufacturing method thereof and molded body
IN2015DN03829A (es)
MX2019006923A (es) Composicion de control de huecos de aire para polimerizacion de monomero a granel.
MX2019006922A (es) Composicion de control de huecos de aire para polimerización de monomero que contiene carbonilo.
MX2015008309A (es) Preparacion de polimeros de baja viscocidad.
MX2016006019A (es) Composiciones de catalizador y metodos para prepararlas.