MX2019006923A - Composicion de control de huecos de aire para polimerizacion de monomero a granel. - Google Patents
Composicion de control de huecos de aire para polimerizacion de monomero a granel.Info
- Publication number
- MX2019006923A MX2019006923A MX2019006923A MX2019006923A MX2019006923A MX 2019006923 A MX2019006923 A MX 2019006923A MX 2019006923 A MX2019006923 A MX 2019006923A MX 2019006923 A MX2019006923 A MX 2019006923A MX 2019006923 A MX2019006923 A MX 2019006923A
- Authority
- MX
- Mexico
- Prior art keywords
- polymerization
- air void
- control composition
- monomer polymerization
- monomer
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
- C08F20/02—Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
- C08F20/04—Acids, Metal salts or ammonium salts thereof
- C08F20/06—Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F120/00—Homopolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
- C08F120/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F120/10—Esters
- C08F120/12—Esters of monohydric alcohols or phenols
- C08F120/14—Methyl esters, e.g. methyl (meth)acrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F265/00—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00
- C08F265/04—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00 on to polymers of esters
- C08F265/06—Polymerisation of acrylate or methacrylate esters on to polymers thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/05—Alcohols; Metal alcoholates
- C08K5/053—Polyhydroxylic alcohols
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/17—Amines; Quaternary ammonium compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/04—Homopolymers or copolymers of esters
- C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
- C08L33/10—Homopolymers or copolymers of methacrylic acid esters
- C08L33/12—Homopolymers or copolymers of methyl methacrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/10—Esters; Ether-esters
- C08K5/101—Esters; Ether-esters of monocarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/14—Peroxides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/22—Mixtures comprising a continuous polymer matrix in which are dispersed crosslinked particles of another polymer
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerisation Methods In General (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
La invención se refiere al uso de bajos niveles de ésteres saturados de cadena corta alifáticos para controlar la formación de huecos de aire en cualquier reacción de polimerización exotérmica en la cual la reacción exotérmica excede el punto de ebullición del monómero. Una de tal polimerización es la polimerización a granel de uno o más monómeros que tienen monómeros de éster de ácido carboxílico, en un nivel de al menos 10% de monómero total. Se usan los ésteres saturados de cadena corta alifáticos en la mezcla de polimerización en niveles de 0.5 a 10 por ciento en peso, basado en el monómero que contiene carboxilo. La invención es especialmente útil en la polimerización de polímero y copolímeros de metilmetacrilato, ya sea netos o como un sistema compuesto de polímero.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US201662434002P | 2016-12-14 | 2016-12-14 | |
PCT/US2017/066038 WO2018112009A1 (en) | 2016-12-14 | 2017-12-13 | Air void control composition for bulk monomer polymerization |
Publications (1)
Publication Number | Publication Date |
---|---|
MX2019006923A true MX2019006923A (es) | 2019-09-02 |
Family
ID=62559278
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
MX2019006923A MX2019006923A (es) | 2016-12-14 | 2017-12-13 | Composicion de control de huecos de aire para polimerizacion de monomero a granel. |
Country Status (9)
Country | Link |
---|---|
US (1) | US20200071431A1 (es) |
EP (1) | EP3555157A4 (es) |
JP (1) | JP2020502328A (es) |
KR (1) | KR20190089220A (es) |
CN (1) | CN110382570B (es) |
BR (1) | BR112019012075A2 (es) |
CA (1) | CA3046365A1 (es) |
MX (1) | MX2019006923A (es) |
WO (1) | WO2018112009A1 (es) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN116120600A (zh) * | 2023-01-17 | 2023-05-16 | 哈尔滨工业大学 | 一种纤维增强热塑性复合材料原位浸渍成型方法 |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2524862A (en) * | 1946-07-16 | 1950-10-10 | Ici Ltd | Method and apparatus for producing cast synthetic resin structures by photopolymerization of monomeric material |
JPS5394387A (en) * | 1977-01-24 | 1978-08-18 | Arekusandorobuna Buoronk Irina | Process for producing prepolymer from vinyl monomer |
JP2000313707A (ja) * | 1999-04-28 | 2000-11-14 | Hitachi Chem Co Ltd | 非複屈折性光学用樹脂の製造法及びこの製造法により得られる樹脂を用いた光学用素子 |
FR2981652B1 (fr) * | 2011-10-21 | 2015-03-27 | Arkema France | Composites via la polymerisation in-situ de resines thermoplastiques methacryliques |
JP5959253B2 (ja) * | 2012-03-22 | 2016-08-02 | 住友化学株式会社 | 連続重合装置および重合体組成物の製造方法 |
DE102012022134A1 (de) * | 2012-11-13 | 2014-05-15 | Heraeus Medical Gmbh | Polymethylmethacrylat-Knochenzement |
SG11201601795XA (en) * | 2013-09-11 | 2016-04-28 | Sumitomo Chemical Co | Methacrylic resin composition |
-
2017
- 2017-12-13 BR BR112019012075-0A patent/BR112019012075A2/pt not_active Application Discontinuation
- 2017-12-13 WO PCT/US2017/066038 patent/WO2018112009A1/en unknown
- 2017-12-13 JP JP2019531972A patent/JP2020502328A/ja active Pending
- 2017-12-13 US US16/468,000 patent/US20200071431A1/en not_active Abandoned
- 2017-12-13 KR KR1020197020483A patent/KR20190089220A/ko not_active Application Discontinuation
- 2017-12-13 MX MX2019006923A patent/MX2019006923A/es unknown
- 2017-12-13 CA CA3046365A patent/CA3046365A1/en active Pending
- 2017-12-13 EP EP17881097.4A patent/EP3555157A4/en not_active Withdrawn
- 2017-12-13 CN CN201780077197.0A patent/CN110382570B/zh active Active
Also Published As
Publication number | Publication date |
---|---|
EP3555157A4 (en) | 2020-08-19 |
BR112019012075A2 (pt) | 2019-11-12 |
CN110382570A (zh) | 2019-10-25 |
CA3046365A1 (en) | 2018-06-21 |
JP2020502328A (ja) | 2020-01-23 |
CN110382570B (zh) | 2023-05-30 |
KR20190089220A (ko) | 2019-07-30 |
WO2018112009A1 (en) | 2018-06-21 |
US20200071431A1 (en) | 2020-03-05 |
EP3555157A1 (en) | 2019-10-23 |
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