MX2017001547A - Catalizador ziegler-natta para polimerizacion a alta temperatura. - Google Patents

Catalizador ziegler-natta para polimerizacion a alta temperatura.

Info

Publication number
MX2017001547A
MX2017001547A MX2017001547A MX2017001547A MX2017001547A MX 2017001547 A MX2017001547 A MX 2017001547A MX 2017001547 A MX2017001547 A MX 2017001547A MX 2017001547 A MX2017001547 A MX 2017001547A MX 2017001547 A MX2017001547 A MX 2017001547A
Authority
MX
Mexico
Prior art keywords
ziegler
high temperature
natta catalyst
temperature polymerization
polymerization
Prior art date
Application number
MX2017001547A
Other languages
English (en)
Inventor
Wang Qinyan
Ouskine Helena
Aiffa Mohamed
Baltimore Amy
Severin Holly
Dewit Perry
CLEMENS Steven
Van Asseldonk Lawrence
Jaber Isam
Original Assignee
Nova Chemicals (International) S A
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nova Chemicals (International) S A filed Critical Nova Chemicals (International) S A
Publication of MX2017001547A publication Critical patent/MX2017001547A/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/652—Pretreating with metals or metal-containing compounds
    • C08F4/655—Pretreating with metals or metal-containing compounds with aluminium or compounds thereof
    • C08F4/6555—Pretreating with metals or metal-containing compounds with aluminium or compounds thereof and magnesium or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/001—Multistage polymerisation processes characterised by a change in reactor conditions without deactivating the intermediate polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/642—Component covered by group C08F4/64 with an organo-aluminium compound
    • C08F4/6421—Titanium tetrahalides with organo-aluminium compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/652—Pretreating with metals or metal-containing compounds
    • C08F4/654—Pretreating with metals or metal-containing compounds with magnesium or compounds thereof
    • C08F4/6543—Pretreating with metals or metal-containing compounds with magnesium or compounds thereof halides of magnesium
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/652—Pretreating with metals or metal-containing compounds
    • C08F4/654—Pretreating with metals or metal-containing compounds with magnesium or compounds thereof
    • C08F4/6546—Pretreating with metals or metal-containing compounds with magnesium or compounds thereof organo-magnesium compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/03—Narrow molecular weight distribution, i.e. Mw/Mn < 3
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2323/04—Homopolymers or copolymers of ethene
    • C08J2323/08—Copolymers of ethene

Abstract

La presente invención se refiere en varias modalidades de la invención, a un procatalizador de polimerización de magnesio titanio, métodos para elaborarlos y uso del mismo.
MX2017001547A 2014-08-12 2015-07-15 Catalizador ziegler-natta para polimerizacion a alta temperatura. MX2017001547A (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US14/457,565 US9481748B2 (en) 2014-08-12 2014-08-12 Ziegler-Natta catalyst for high temperature polymerization
PCT/IB2015/055365 WO2016024176A1 (en) 2014-08-12 2015-07-15 Ziegler-natta catalyst for high temperature polymerization

Publications (1)

Publication Number Publication Date
MX2017001547A true MX2017001547A (es) 2017-05-09

Family

ID=53718071

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2017001547A MX2017001547A (es) 2014-08-12 2015-07-15 Catalizador ziegler-natta para polimerizacion a alta temperatura.

Country Status (10)

Country Link
US (4) US9481748B2 (es)
EP (1) EP3180371A1 (es)
JP (1) JP6697444B2 (es)
KR (1) KR102387002B1 (es)
CN (1) CN107155327B (es)
BR (1) BR112017001799B1 (es)
CA (1) CA2896115C (es)
MX (1) MX2017001547A (es)
TW (1) TW201609840A (es)
WO (1) WO2016024176A1 (es)

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9481748B2 (en) * 2014-08-12 2016-11-01 Nova Chemicals (International) S.A. Ziegler-Natta catalyst for high temperature polymerization
TWI627133B (zh) * 2015-12-09 2018-06-21 努發化工（國際）公司 以塞流反應器合成用於ast離線齊格勒－納塔(zn)催化劑之二氯化鎂撐體
BR112019006072B1 (pt) 2016-09-29 2023-02-14 Dow Global Technologies Llc Método de polimerização de uma olefina usando um catalisador ziegler-natta e um catalisador molecular não suportado em um mesmo reator ao mesmo tempo e método de polimerização
US11091572B2 (en) 2016-09-29 2021-08-17 Dow Global Technologies Llc Modified Ziegler-Natta (pro) catalysts and system
KR102449474B1 (ko) * 2016-09-29 2022-10-11 다우 글로벌 테크놀로지스 엘엘씨 마그네슘 할라이드-담지 티탄 (전)촉매
PL3498739T3 (pl) * 2017-12-12 2021-04-06 Henkel Ag & Co. Kgaa Mieszaniny paramagnetycznego tytanu jako katalizatory wulkanizacji
CA3007381A1 (en) 2018-06-06 2019-12-06 Nova Chemicals Corporation Off-line filter free ziegler-natta catalyst preparation
US11214633B2 (en) * 2019-09-10 2022-01-04 Braskem America, Inc. Ziegler-Natta catalyst systems and methods of controlling particle size
CN113397018A (zh) * 2021-06-21 2021-09-17 千禾味业食品股份有限公司 一种提升普通法焦糖色抗氧化性的工艺
KR20230149477A (ko) * 2022-04-20 2023-10-27 에스케이이노베이션 주식회사 저밀도 공중합체 중합용 지글러-나타 촉매의 제조방법
CN114989340A (zh) * 2022-06-28 2022-09-02 杭州双安科技有限公司 一种烯烃聚合方法
CN116023572A (zh) * 2022-11-21 2023-04-28 山东京博石油化工有限公司 一种用于乙烯与α-烯烃共聚的高温溶液聚合工艺

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JPS565806A (en) * 1979-06-29 1981-01-21 Mitsubishi Petrochem Co Ltd Polymerization of olefin
EP0099774B2 (fr) * 1982-06-24 1995-03-22 BP Chimie Société Anonyme Procédé pour la polymérisation et la copolymérisation des alpha-oléfines en lit fluidisé
US4563437A (en) * 1984-08-30 1986-01-07 Toho Titanium Co., Ltd. Process for preparation of catalytic components for polymerization of α-olefins
IT1203330B (it) * 1987-02-06 1989-02-15 Enichem Base Spa Componente di catalizzatore e catalizzatore per la polimerizzazione dell'etilene o la co-polimerizzazione dell-etilene con alfa-olefine
US5589555A (en) 1991-10-03 1996-12-31 Novacor Chemicals (International) S.A. Control of a solution process for polymerization of ethylene
GB9120971D0 (en) * 1991-10-03 1991-11-13 Du Pont Canada Control of a solution process for polymerization of ethylene
GB9121019D0 (en) * 1991-10-03 1991-11-13 Du Pont Canada Activation of catalyst in ethylene polymerization at high temperatures
DE69308153T3 (de) 1992-09-16 2012-04-05 Exxonmobil Chemical Patents, Inc. (N.D.Ges.D. Staates Delaware) Weiche filme mit verbesserten physikalischen eigenschaften
BE1007536A3 (nl) * 1993-09-27 1995-07-25 Dsm Nv Katalysatorsysteem voor de polymerisatie van etheen.
US5661097A (en) * 1994-08-12 1997-08-26 The Dow Chemical Company Supported olefin polymerization catalyst
CA2201224C (en) * 1997-03-27 2004-12-07 Annette Lynn Burke Dual shear mixing element
IT1311978B1 (it) * 1999-03-25 2002-03-22 Polimeri Europa Srl Catalizzatore bimetallico per la (co) polimerizzazione dellealfa-olefine.
US6359072B1 (en) * 2000-02-16 2002-03-19 Univation Technologies, Llc Polyethylene films having improved optical properties
CA2557410C (en) 2006-08-25 2014-01-28 Nova Chemicals Corporation Ziegler-natta catalyst for high temperature polymerization
CA2760264C (en) * 2011-12-05 2018-08-21 Nova Chemicals Corporation Passivated supports for use with olefin polymerization catalysts
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US9481748B2 (en) * 2014-08-12 2016-11-01 Nova Chemicals (International) S.A. Ziegler-Natta catalyst for high temperature polymerization

Also Published As

Publication number Publication date
CN107155327B (zh) 2021-03-30
CN107155327A (zh) 2017-09-12
US20180118863A1 (en) 2018-05-03
EP3180371A1 (en) 2017-06-21
KR20170042302A (ko) 2017-04-18
US10442880B2 (en) 2019-10-15
BR112017001799A2 (pt) 2017-11-21
BR112017001799B1 (pt) 2022-04-19
KR102387002B1 (ko) 2022-04-15
US20170037163A1 (en) 2017-02-09
TW201609840A (zh) 2016-03-16
CA2896115C (en) 2023-01-03
CA2896115A1 (en) 2016-06-08
WO2016024176A1 (en) 2016-02-18
JP2017529421A (ja) 2017-10-05
US20180282453A1 (en) 2018-10-04
US20160046745A1 (en) 2016-02-18
US10590214B2 (en) 2020-03-17
US9481748B2 (en) 2016-11-01
JP6697444B2 (ja) 2020-05-20

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