MX2016007933A - Composicion de revestimiento acuosa y produccion de sistemas de pintura multicapa usando dicha composicion de revestimiento. - Google Patents
Composicion de revestimiento acuosa y produccion de sistemas de pintura multicapa usando dicha composicion de revestimiento.Info
- Publication number
- MX2016007933A MX2016007933A MX2016007933A MX2016007933A MX2016007933A MX 2016007933 A MX2016007933 A MX 2016007933A MX 2016007933 A MX2016007933 A MX 2016007933A MX 2016007933 A MX2016007933 A MX 2016007933A MX 2016007933 A MX2016007933 A MX 2016007933A
- Authority
- MX
- Mexico
- Prior art keywords
- coating agent
- olefinically unsaturated
- unsaturated monomers
- production
- multilayer
- Prior art date
Links
- 239000011248 coating agent Substances 0.000 title abstract 5
- 238000004519 manufacturing process Methods 0.000 title abstract 3
- 239000003973 paint Substances 0.000 title abstract 2
- 239000000178 monomer Substances 0.000 abstract 5
- 125000001931 aliphatic group Chemical group 0.000 abstract 2
- 238000006243 chemical reaction Methods 0.000 abstract 2
- 239000007795 chemical reaction product Substances 0.000 abstract 2
- 239000006185 dispersion Substances 0.000 abstract 2
- 239000000203 mixture Substances 0.000 abstract 2
- 229920002635 polyurethane Polymers 0.000 abstract 2
- 239000004814 polyurethane Substances 0.000 abstract 2
- 239000002253 acid Substances 0.000 abstract 1
- 125000003118 aryl group Chemical group 0.000 abstract 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 1
- 238000000576 coating method Methods 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 125000000524 functional group Chemical group 0.000 abstract 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 abstract 1
- 239000003999 initiator Substances 0.000 abstract 1
- 238000006116 polymerization reaction Methods 0.000 abstract 1
- 230000000379 polymerizing effect Effects 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
- C09D175/14—Polyurethanes having carbon-to-carbon unsaturated bonds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
- B05D7/50—Multilayers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F290/00—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups
- C08F290/08—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups on to polymers modified by introduction of unsaturated side groups
- C08F290/14—Polymers provided for in subclass C08G
- C08F290/147—Polyurethanes; Polyureas
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/0804—Manufacture of polymers containing ionic or ionogenic groups
- C08G18/0819—Manufacture of polymers containing ionic or ionogenic groups containing anionic or anionogenic groups
- C08G18/0823—Manufacture of polymers containing ionic or ionogenic groups containing anionic or anionogenic groups containing carboxylate salt groups or groups forming them
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
- C08G18/4205—Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups
- C08G18/423—Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups containing cycloaliphatic groups
- C08G18/4233—Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups containing cycloaliphatic groups derived from polymerised higher fatty acids or alcohols
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/67—Unsaturated compounds having active hydrogen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/67—Unsaturated compounds having active hydrogen
- C08G18/675—Low-molecular-weight compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
- C08G18/75—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic
- C08G18/751—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring
- C08G18/752—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring containing at least one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group
- C08G18/753—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring containing at least one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group containing one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group having a primary carbon atom next to the isocyanate or isothiocyanate group
- C08G18/755—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring containing at least one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group containing one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group having a primary carbon atom next to the isocyanate or isothiocyanate group and at least one isocyanate or isothiocyanate group linked to a secondary carbon atom of the cycloaliphatic ring, e.g. isophorone diisocyanate
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D151/00—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers
- C09D151/08—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers grafted on to macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
- C09D175/14—Polyurethanes having carbon-to-carbon unsaturated bonds
- C09D175/16—Polyurethanes having carbon-to-carbon unsaturated bonds having terminal carbon-to-carbon unsaturated bonds
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Materials Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Paints Or Removers (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
Abstract
La presente invención se refiere a una composición de revestimiento acuosa que comprende al menos una dispersión acuosa que comprende al menos un copolímero (CP), donde dicho copolímero (CP) es preparable por (i) carga inicial de una dispersión acuosa de al menos un poliuretano y luego (ii) polimerización de una mezcla de monómeros olefínicamente insaturados en presencia del poliuretano de (i), en donde (a) se usa un iniciador soluble en agua, (b) los monómeros olefínicamente insaturados se miden de modo tal que una concentración del 6,0% en peso, en base a la cantidad total de monómeros olefínicamente insaturados usados para polimerización, en la solución de reacción no exceda todo el tiempo de reacción y (c) la mezcla de los monómeros olefínicamente insaturados comprende al menos un monómero poliolefínicamente insaturado y al menos un producto de reacción hidroxi-funcional lineal (R) que tiene un índice de acidez inferior a 20 mg de KOH/g, cuya preparación implica el uso de al menos un compuesto (v) que contiene dos grupos funcionales (v.a) y un radical hidrocarbilo alifático o aralifático (v.b) que se dispone entre los grupos funcionales y tiene 12 a 70 átomos de carbono. La presente invención también se refiere a un método para producir un sistema de pintura multicapa usando la composición de revestimiento y al revestimiento multicapa así producido.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP13197935 | 2013-12-18 | ||
PCT/EP2014/074929 WO2015090807A1 (de) | 2013-12-18 | 2014-11-18 | Wässriges beschichtungsmittel und herstellung von mehrschichtlackierungen unter einsatz des beschichtungsmittels |
Publications (1)
Publication Number | Publication Date |
---|---|
MX2016007933A true MX2016007933A (es) | 2016-09-13 |
Family
ID=49767008
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
MX2016007933A MX2016007933A (es) | 2013-12-18 | 2014-11-18 | Composicion de revestimiento acuosa y produccion de sistemas de pintura multicapa usando dicha composicion de revestimiento. |
Country Status (11)
Country | Link |
---|---|
US (1) | US10344181B2 (es) |
EP (1) | EP3083742B1 (es) |
JP (1) | JP6441365B2 (es) |
KR (1) | KR102298948B1 (es) |
CN (1) | CN105829381B (es) |
BR (1) | BR112016013200B1 (es) |
CA (1) | CA2930775A1 (es) |
ES (1) | ES2880833T3 (es) |
MX (1) | MX2016007933A (es) |
RU (1) | RU2677334C1 (es) |
WO (1) | WO2015090807A1 (es) |
Families Citing this family (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
MX2018005583A (es) | 2015-11-03 | 2018-08-01 | Basf Coatings Gmbh | Materiales acuosos de capa base que comprenden aglutinantes de poliuretano reticulados y una composicion de disolvente especifica. |
CN108368244B (zh) | 2015-12-09 | 2020-12-29 | 巴斯夫涂料有限公司 | 羧基官能的聚醚基反应产物和包含所述反应产物的水性底涂料 |
WO2017102484A1 (de) | 2015-12-16 | 2017-06-22 | Basf Coatings Gmbh | Carboxyfunktionelle polyether-basierte reaktionsprodukte und wässrige basislacke enthaltend die reaktionsprodukte |
EP3430067B1 (de) | 2016-03-14 | 2022-05-11 | BASF Coatings GmbH | Hydroxyfunktionelle polyether-basierte reaktionsprodukte und wässrige basislacke enthaltend die reaktionsprodukte |
WO2018036855A1 (de) * | 2016-08-24 | 2018-03-01 | Basf Coatings Gmbh | Verfahren zur herstellung einer lackierung unter einsatz eines wässrigen basislacks |
US11583487B2 (en) * | 2018-08-09 | 2023-02-21 | Kao Corporation | Method for producing coating |
CN112771018A (zh) * | 2018-08-30 | 2021-05-07 | 罗地亚经营管理公司 | 取代的邻苯二酚单体、共聚物和使用方法 |
CN112752743A (zh) * | 2018-08-30 | 2021-05-04 | 罗地亚经营管理公司 | 涂料中的取代的邻苯二酚添加剂和使用方法 |
KR20220002426A (ko) * | 2019-04-26 | 2022-01-06 | 바스프 코팅스 게엠베하 | 수계 코팅 조성물 및 상기 조성물을 사용하여 다층 코팅 필름을 형성하는 방법 |
BR112021023697A2 (pt) | 2019-07-16 | 2022-01-04 | Basf Coatings Gmbh | Métodos para fabricar uma dispersão de poliuretano de um componente e para revestir um substrato com o material de revestimento, dispersão de poliuretano de um componente, material de revestimento de um componente, substrato revestido, revestimento de multicamadas, e, substrato revestido de multicamadas |
CN114133516B (zh) * | 2021-12-31 | 2023-05-26 | 广东美涂士建材股份有限公司 | 一种自清洁低表面能改性聚氨酯的制备方法 |
Family Cites Families (23)
Publication number | Priority date | Publication date | Assignee | Title |
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NL279307A (es) | 1961-06-06 | |||
DE1768313B2 (de) | 1968-04-27 | 1977-05-18 | Henkel & Cie GmbH, 4000 Düsseldorf | Verfahren zur herstellung hoehermolekularer mehrwertiger alkohole |
BE786548A (fr) | 1971-07-22 | 1973-01-22 | Stamicarbon | Procede pour la preparation de polylactones hydroxyliques en fin de chaine |
DE3545618A1 (de) | 1985-12-21 | 1987-06-25 | Basf Lacke & Farben | Wasserverduennbares ueberzugsmittel zur herstellung der basisschicht eines mehrschichtueberzuges |
EP0353797A1 (en) * | 1988-06-30 | 1990-02-07 | Akzo N.V. | A functionalized polyurethane which can be used to prepare aqueous dispersions of polymer hibrids |
DE3910901A1 (de) * | 1989-04-04 | 1990-10-11 | Ppg Ind Deutschland Gmbh | Verfahren zur herstellung einer waesserigen feinteiligen dispersion eines chlorierten polyolefins und verwendung derselben in waesserigen beschichtungszusammenetzungen |
JPH03261734A (ja) | 1990-03-12 | 1991-11-21 | Henkel Hakusui Kk | 重合アルコールの製法 |
DE4009858C2 (de) | 1990-03-28 | 1998-02-05 | Basf Lacke & Farben | Wäßriger pigmentierter Basislack enthaltend als Bindemittel ein wasserverdünnbares Polyacrylatharz und Verwendung eines solchen Basislacks |
DE4010176A1 (de) * | 1990-03-30 | 1991-10-02 | Basf Lacke & Farben | Verfahren zur herstellung einer mehrschichtigen lackierung und waessriger lack |
DE4107136A1 (de) | 1991-03-06 | 1992-09-10 | Basf Lacke & Farben | Verfahren zur herstellung einer mehrschichtigen, schuetzenden und/oder dekorativen lackierung |
DE4320969A1 (de) * | 1993-06-24 | 1995-01-05 | Basf Lacke & Farben | Verfahren zur Herstellung von Polyurethanharzen und deren Verwendung sowie die Verwendung von Ethoxyethylpropionat zur Herstellung von Polyurethanharzen |
CA2127761C (en) | 1993-07-16 | 2005-10-18 | Armin Gobel | An aqueous dispersion of polyurethane resins, a method of manufacturing them, coating agents containing them and use thereof |
DE4406159A1 (de) * | 1994-02-25 | 1995-08-31 | Bayer Ag | Wäßrige Polyester-Polyurethan-Dispersionen und ihre Verwendung in Beschichtungsmitteln |
DE4437535A1 (de) | 1994-10-20 | 1996-04-25 | Basf Lacke & Farben | Polyurethanmodifziertes Polyacrylat |
DE19930665A1 (de) | 1999-07-02 | 2001-01-11 | Basf Coatings Ag | Basislack und seine Verwendung zur Herstellung von farb- und/oder effektgebenden Basislackierungen und Mehrschichtlackierung |
DE19948004B4 (de) * | 1999-10-06 | 2006-05-11 | Basf Coatings Ag | Polyurethane und Pfropfmischpolymerisate auf Polyurethanbasis sowie ihre Verwendung zur Herstellung von Beschichtungsstoffen, Klebstoffen und Dichtungsmassen |
RU2254351C2 (ru) | 1999-12-23 | 2005-06-20 | Акцо Нобель Н.В. | Водная композиция покрытия, содержащая полимер, полученный ступенчатой полимеризацией, и полиуретан |
DE10043405C1 (de) | 2000-09-04 | 2002-06-27 | Basf Coatings Ag | Verfahren zur Herstellung farb- und/oder effektgebender Lackierungen |
DE10060399A1 (de) * | 2000-12-05 | 2002-06-20 | Basf Coatings Ag | Wäßriger, effektgebender Beschichtungsstoff, Verfahren zu seiner Herstellung und seine Verwendung |
GB0213818D0 (en) * | 2002-06-17 | 2002-07-24 | Ici Plc | Dispersions |
DE10240972A1 (de) | 2002-09-02 | 2004-03-18 | Basf Coatings Ag | Metallpigmente enthaltende, wässrige Pigmentpasten und ihre Verwendung zur Herstellung von effektgebenden wässrigen Beschichtungsstoffen |
KR100969247B1 (ko) * | 2008-08-06 | 2010-07-09 | 애경화학 주식회사 | 내썬크림성 및 내마모성이 우수한 히드록시기 함유 수성폴리우레탄 분산액의 제조방법 및 이를 함유하는 연질 코팅조성물 |
FR2965267B1 (fr) * | 2010-09-27 | 2013-11-15 | Cray Valley Sa | Resines polyesters a base d'acides gras de longueur en huile courte, dispersions aqueuses et revetements lies |
-
2014
- 2014-11-18 MX MX2016007933A patent/MX2016007933A/es unknown
- 2014-11-18 BR BR112016013200-9A patent/BR112016013200B1/pt active IP Right Grant
- 2014-11-18 CN CN201480068993.4A patent/CN105829381B/zh active Active
- 2014-11-18 RU RU2016129054A patent/RU2677334C1/ru active
- 2014-11-18 KR KR1020167015927A patent/KR102298948B1/ko active IP Right Grant
- 2014-11-18 US US15/104,912 patent/US10344181B2/en active Active
- 2014-11-18 JP JP2016541540A patent/JP6441365B2/ja active Active
- 2014-11-18 ES ES14800039T patent/ES2880833T3/es active Active
- 2014-11-18 CA CA2930775A patent/CA2930775A1/en not_active Abandoned
- 2014-11-18 EP EP14800039.1A patent/EP3083742B1/de active Active
- 2014-11-18 WO PCT/EP2014/074929 patent/WO2015090807A1/de active Application Filing
Also Published As
Publication number | Publication date |
---|---|
ES2880833T3 (es) | 2021-11-25 |
EP3083742A1 (de) | 2016-10-26 |
JP6441365B2 (ja) | 2018-12-19 |
KR20160099572A (ko) | 2016-08-22 |
EP3083742B1 (de) | 2021-05-12 |
CN105829381A (zh) | 2016-08-03 |
WO2015090807A1 (de) | 2015-06-25 |
RU2677334C1 (ru) | 2019-01-16 |
RU2016129054A (ru) | 2018-01-23 |
BR112016013200B1 (pt) | 2021-10-05 |
BR112016013200A2 (pt) | 2017-08-08 |
KR102298948B1 (ko) | 2021-09-08 |
CN105829381B (zh) | 2020-01-14 |
US10344181B2 (en) | 2019-07-09 |
CA2930775A1 (en) | 2015-06-25 |
JP2017509725A (ja) | 2017-04-06 |
US20160319155A1 (en) | 2016-11-03 |
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