MX2015012244A - Espuma de poliuretano retardante de la llama y metodo para la produccion de la misma. - Google Patents
Espuma de poliuretano retardante de la llama y metodo para la produccion de la misma.Info
- Publication number
- MX2015012244A MX2015012244A MX2015012244A MX2015012244A MX2015012244A MX 2015012244 A MX2015012244 A MX 2015012244A MX 2015012244 A MX2015012244 A MX 2015012244A MX 2015012244 A MX2015012244 A MX 2015012244A MX 2015012244 A MX2015012244 A MX 2015012244A
- Authority
- MX
- Mexico
- Prior art keywords
- polyurethane foam
- isocyanate
- flame retardant
- producing same
- retardant polyurethane
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/0066—Use of inorganic compounding ingredients
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/14—Manufacture of cellular products
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
- C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
- C08G18/7657—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings
- C08G18/7664—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings containing alkylene polyphenyl groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
- C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
- C08G18/7657—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings
- C08G18/7664—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings containing alkylene polyphenyl groups
- C08G18/7671—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings containing alkylene polyphenyl groups containing only one alkylene bisphenyl group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/77—Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur
- C08G18/78—Nitrogen
- C08G18/79—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates
- C08G18/797—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates containing carbodiimide and/or uretone-imine groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/0014—Use of organic additives
- C08J9/0023—Use of organic additives containing oxygen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/0014—Use of organic additives
- C08J9/0038—Use of organic additives containing phosphorus
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/0095—Mixtures of at least two compounding ingredients belonging to different one-dot groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/04—Carbon
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
- C08K5/52—Phosphorus bound to oxygen only
- C08K5/521—Esters of phosphoric acids, e.g. of H3PO4
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0008—Foam properties flexible
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0025—Foam properties rigid
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0041—Foam properties having specified density
- C08G2110/005—< 50kg/m3
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0041—Foam properties having specified density
- C08G2110/0058—≥50 and <150kg/m3
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0041—Foam properties having specified density
- C08G2110/0066—≥ 150kg/m3
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2201/00—Foams characterised by the foaming process
- C08J2201/02—Foams characterised by the foaming process characterised by mechanical pre- or post-treatments
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2205/00—Foams characterised by their properties
- C08J2205/06—Flexible foams
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2205/00—Foams characterised by their properties
- C08J2205/10—Rigid foams
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2375/00—Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
- C08J2375/04—Polyurethanes
- C08J2375/08—Polyurethanes from polyethers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2375/00—Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
- C08J2375/04—Polyurethanes
- C08J2375/12—Polyurethanes from compounds containing nitrogen and active hydrogen, the nitrogen atom not being part of an isocyanate group
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- Emergency Medicine (AREA)
- Manufacturing & Machinery (AREA)
- Polyurethanes Or Polyureas (AREA)
Abstract
Una espuma de poliuretano que contiene una clasificación de llama vertical UL 94 inicial de V-O y que mantiene la clasificación de llama vertical UL 94 inicial de V-O después de una semana de envejecimiento con calor a 150°C se forma como el producto de reacción de un componente de isocianato y un componente reactivo con isocianato en la presencia de un agente de soplado. El componente de isocianato incluye un compuesto que contiene isocianato y un compuesto de fósforo no reactivo que está presente en una cantidad que va desde 1 a 20 por ciento en peso basado en el peso total de la espuma de poliuretano. El componente reactivo con isocianato incluye un poliol de poliéter y grafito expansible que está presente en una cantidad que va desde 3 a 30% en peso basado en el peso total de la espuma de poliuretano.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US201361787018P | 2013-03-15 | 2013-03-15 | |
PCT/US2014/020506 WO2014149711A1 (en) | 2013-03-15 | 2014-03-05 | Flame retardant polyurethane foam and method for producing same |
Publications (1)
Publication Number | Publication Date |
---|---|
MX2015012244A true MX2015012244A (es) | 2016-02-03 |
Family
ID=50442605
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
MX2015012244A MX2015012244A (es) | 2013-03-15 | 2014-03-05 | Espuma de poliuretano retardante de la llama y metodo para la produccion de la misma. |
Country Status (8)
Country | Link |
---|---|
US (1) | US9908984B2 (es) |
EP (1) | EP2970561B8 (es) |
JP (1) | JP6388905B2 (es) |
KR (1) | KR102195493B1 (es) |
CN (2) | CN111732712A (es) |
BR (1) | BR112015022714B1 (es) |
MX (1) | MX2015012244A (es) |
WO (1) | WO2014149711A1 (es) |
Families Citing this family (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106574037B (zh) * | 2014-06-06 | 2019-09-24 | 陶氏环球技术有限责任公司 | 阻热性和阻燃性聚氨酯泡沫体 |
CN106554612B (zh) * | 2015-09-29 | 2019-08-06 | 万华化学集团股份有限公司 | 无卤阻燃热塑性聚氨酯弹性体组合物及其制品、阻燃剂包 |
CA3017746A1 (en) * | 2016-03-16 | 2017-09-21 | Rco Engineering Inc. | Improved system and process for the manufacture of polymer foam with additives |
US9868835B1 (en) | 2016-08-11 | 2018-01-16 | Ford Global Technologies, Llc | Bio-based polyurethane foam materials including graphite materials |
CN110352222A (zh) * | 2017-03-14 | 2019-10-18 | 陶氏环球技术有限责任公司 | 膨胀型涂料体系 |
CN110857328A (zh) * | 2018-08-23 | 2020-03-03 | 美国圣戈班性能塑料公司 | 聚氨酯泡沫和其形成方法 |
WO2020041397A1 (en) * | 2018-08-23 | 2020-02-27 | Saint-Gobain Performance Plastics Corporation | Polyurethane foam and methods of forming the same |
KR102247683B1 (ko) * | 2018-09-05 | 2021-04-30 | 주식회사 엘지화학 | 난연성 폴리우레탄 폼 조성물 및 이의 경화물을 포함하는 난연성 폴리우레탄 폼 |
KR102255391B1 (ko) * | 2018-09-05 | 2021-05-21 | 주식회사 엘지화학 | 난연성 폴리우레탄 폼 조성물 및 이의 경화물을 포함하는 난연성 폴리우레탄 폼 |
KR102255392B1 (ko) * | 2018-09-05 | 2021-05-21 | 주식회사 엘지화학 | 난연성 폴리우레탄 폼 조성물 및 이의 경화물을 포함하는 난연성 폴리우레탄 폼 |
US20220298292A1 (en) | 2019-08-13 | 2022-09-22 | Dow Global Technologies Llc | Polyurethane foam |
JP2021038317A (ja) * | 2019-09-03 | 2021-03-11 | 三井化学産資株式会社 | 難燃性樹脂組成物 |
CN110615883A (zh) * | 2019-10-18 | 2019-12-27 | 重庆长安汽车股份有限公司 | 一种含有石墨烯的吸隔声材料及其制备方法和应用 |
KR102154867B1 (ko) * | 2020-02-07 | 2020-09-10 | 최규술 | 폴리우레탄 발포폼 및 그 제조방법 |
KR20230111184A (ko) | 2020-09-21 | 2023-07-25 | 생-고뱅 퍼포먼스 플라스틱스 코포레이션 | 폴리우레탄 폼 및 이의 형성 방법 |
WO2023007807A1 (ja) * | 2021-07-26 | 2023-02-02 | 東海化成工業株式会社 | 車両用難燃性防音材 |
CN117885270B (zh) * | 2024-03-14 | 2024-06-11 | 福建大方睡眠科技股份有限公司 | 一种生产生物基聚氨酯的发泡设备及发泡工艺 |
Family Cites Families (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4839393A (en) | 1988-07-08 | 1989-06-13 | Wm. T. Burnett & Co., Inc. | Polyurethane foams containing organofunctional silanes |
DE3909017C1 (es) | 1989-03-18 | 1990-04-12 | Metzeler Schaum Gmbh, 8940 Memmingen, De | |
DE4034046A1 (de) * | 1990-10-26 | 1992-04-30 | Basf Ag | Verfahren zur herstellung von flammwidrigen polyurethan-weichschaumstoffen mit verminderter rauchgasdichte und melamin-blaehgraphit-polyether-polyol-dispersionen hierfuer |
DE4203918A1 (de) * | 1992-02-11 | 1993-08-12 | Basf Ag | Verfahren zur herstellung von fluorchlorkohlenwasserstoff-freien polyurethan-weichschaumstoffen unter verwendung von urethangruppen enthaltenden polyisocyanatmischungen auf diphenylmethan-diisocyanatbasis sowie derartige modifizierte polyisocyanatmischungen |
CZ303184B6 (cs) * | 1999-10-07 | 2012-05-16 | Huntsman International Llc | Zpusob výroby rigidních a flexibilních polyuretanových pen obsahujících látky potlacující horení |
DE10007980B4 (de) * | 2000-02-22 | 2007-07-12 | Hilti Ag | Zweikomponenten-Ortschaumsystem und dessen Verwendung zum Ausschäumen von Öffnungen zum Zwecke des Brandschutzes |
US20050222284A1 (en) * | 2002-05-07 | 2005-10-06 | Williams Barbara A | Synergistic flame retardant blends for polyurethane foams |
JP3987068B2 (ja) * | 2002-05-20 | 2007-10-03 | グレート・レークス・ケミカル・コーポレーション | ポリウレタンフォームのための(アルキル置換)トリアリールホスフェートエステルと燐含有難燃剤とのブレンド |
EP2334735A4 (en) * | 2008-09-15 | 2012-02-29 | Preferred Solutions Inc | POLYURETHANEUM FUEL COMPOSITIONS AND METHOD OF MANUFACTURING THEREOF |
CN101503567A (zh) | 2009-03-05 | 2009-08-12 | 中国科学技术大学 | 一种纳米复合膨胀阻燃聚氨酯泡沫塑料及其制备方法 |
JP5644116B2 (ja) * | 2010-01-21 | 2014-12-24 | 株式会社ブリヂストン | 高難燃性ポリウレタンフォーム |
BR112013012211A2 (pt) * | 2010-11-18 | 2020-10-13 | Dow Global Technologies Inc | formulação reativa para preparar uma espuma de poliuretano flexível à chama, processo para preparar uma espuma de poliuretano flexível resistente a chama e espuma de poliuretano fleíxel resistente à chama |
US9410012B2 (en) * | 2011-06-29 | 2016-08-09 | Dow Global Technologies Llc | Thermally stable flame resistant flexible polyurethane foam |
-
2014
- 2014-03-05 CN CN202010720862.7A patent/CN111732712A/zh active Pending
- 2014-03-05 JP JP2016500629A patent/JP6388905B2/ja active Active
- 2014-03-05 WO PCT/US2014/020506 patent/WO2014149711A1/en active Application Filing
- 2014-03-05 BR BR112015022714-7A patent/BR112015022714B1/pt active IP Right Grant
- 2014-03-05 CN CN201480023502.4A patent/CN105143299A/zh active Pending
- 2014-03-05 US US14/773,926 patent/US9908984B2/en active Active
- 2014-03-05 MX MX2015012244A patent/MX2015012244A/es unknown
- 2014-03-05 KR KR1020157028467A patent/KR102195493B1/ko active IP Right Grant
- 2014-03-05 EP EP14716059.2A patent/EP2970561B8/en active Active
Also Published As
Publication number | Publication date |
---|---|
US20160046779A1 (en) | 2016-02-18 |
BR112015022714A2 (pt) | 2017-07-18 |
EP2970561B1 (en) | 2022-11-02 |
BR112015022714B1 (pt) | 2021-08-17 |
EP2970561A1 (en) | 2016-01-20 |
CN105143299A (zh) | 2015-12-09 |
US9908984B2 (en) | 2018-03-06 |
WO2014149711A1 (en) | 2014-09-25 |
JP2016510837A (ja) | 2016-04-11 |
EP2970561B8 (en) | 2022-12-07 |
CN111732712A (zh) | 2020-10-02 |
KR102195493B1 (ko) | 2020-12-29 |
KR20150132292A (ko) | 2015-11-25 |
JP6388905B2 (ja) | 2018-09-12 |
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