MX2009013236A - Dispositivo y metodo para reacciones cataliticas en fase gaseosa y uso de los mismos. - Google Patents

Dispositivo y metodo para reacciones cataliticas en fase gaseosa y uso de los mismos.

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Publication number
MX2009013236A
MX2009013236A MX2009013236A MX2009013236A MX2009013236A MX 2009013236 A MX2009013236 A MX 2009013236A MX 2009013236 A MX2009013236 A MX 2009013236A MX 2009013236 A MX2009013236 A MX 2009013236A MX 2009013236 A MX2009013236 A MX 2009013236A
Authority
MX
Mexico
Prior art keywords
zone
entry zone
entry
reactors
reaction zone
Prior art date
Application number
MX2009013236A
Other languages
English (en)
Other versions
MX306391B (es
Inventor
Meinhard Schwefer
Rainer Maurer
Rolf Siefert
Michael Groves
Juergen Fuchs
Bernhard Huendgen
Original Assignee
Uhde Gmbh
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Uhde Gmbh filed Critical Uhde Gmbh
Publication of MX2009013236A publication Critical patent/MX2009013236A/es
Publication of MX306391B publication Critical patent/MX306391B/es

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/008Details of the reactor or of the particulate material; Processes to increase or to retard the rate of reaction
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J15/00Chemical processes in general for reacting gaseous media with non-particulate solids, e.g. sheet material; Apparatus specially adapted therefor
    • B01J15/005Chemical processes in general for reacting gaseous media with non-particulate solids, e.g. sheet material; Apparatus specially adapted therefor in the presence of catalytically active bodies, e.g. porous plates
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/0006Controlling or regulating processes
    • B01J19/002Avoiding undesirable reactions or side-effects, e.g. avoiding explosions, or improving the yield by suppressing side-reactions
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/0242Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid flow within the bed being predominantly vertical
    • B01J8/025Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid flow within the bed being predominantly vertical in a cylindrical shaped bed
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/0278Feeding reactive fluids
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/0285Heating or cooling the reactor
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B21/00Nitrogen; Compounds thereof
    • C01B21/20Nitrogen oxides; Oxyacids of nitrogen; Salts thereof
    • C01B21/24Nitric oxide (NO)
    • C01B21/26Preparation by catalytic or non-catalytic oxidation of ammonia
    • C01B21/265Preparation by catalytic or non-catalytic oxidation of ammonia characterised by the catalyst
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B21/00Nitrogen; Compounds thereof
    • C01B21/20Nitrogen oxides; Oxyacids of nitrogen; Salts thereof
    • C01B21/24Nitric oxide (NO)
    • C01B21/26Preparation by catalytic or non-catalytic oxidation of ammonia
    • C01B21/28Apparatus
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008Controlling the process
    • B01J2208/00017Controlling the temperature
    • B01J2208/00106Controlling the temperature by indirect heat exchange
    • B01J2208/00168Controlling the temperature by indirect heat exchange with heat exchange elements outside the bed of solid particles
    • B01J2208/00176Controlling the temperature by indirect heat exchange with heat exchange elements outside the bed of solid particles outside the reactor
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008Controlling the process
    • B01J2208/00017Controlling the temperature
    • B01J2208/00106Controlling the temperature by indirect heat exchange
    • B01J2208/00168Controlling the temperature by indirect heat exchange with heat exchange elements outside the bed of solid particles
    • B01J2208/00203Coils
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008Controlling the process
    • B01J2208/00017Controlling the temperature
    • B01J2208/00106Controlling the temperature by indirect heat exchange
    • B01J2208/00168Controlling the temperature by indirect heat exchange with heat exchange elements outside the bed of solid particles
    • B01J2208/00212Plates; Jackets; Cylinders
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008Controlling the process
    • B01J2208/00017Controlling the temperature
    • B01J2208/00477Controlling the temperature by thermal insulation means
    • B01J2208/00495Controlling the temperature by thermal insulation means using insulating materials or refractories
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008Controlling the process
    • B01J2208/00017Controlling the temperature
    • B01J2208/0053Controlling multiple zones along the direction of flow, e.g. pre-heating and after-cooling
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008Controlling the process
    • B01J2208/00716Means for reactor start-up
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00002Chemical plants
    • B01J2219/00004Scale aspects
    • B01J2219/00006Large-scale industrial plants
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049Controlling or regulating processes
    • B01J2219/00245Avoiding undesirable reactions or side-effects
    • B01J2219/00259Preventing runaway of the chemical reaction
    • B01J2219/00263Preventing explosion of the chemical mixture
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/02Apparatus characterised by their chemically-resistant properties
    • B01J2219/025Apparatus characterised by their chemically-resistant properties characterised by the construction materials of the reactor vessel proper

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Fluid Mechanics (AREA)
  • Physical Or Chemical Processes And Apparatus (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)

Abstract

La invención se refiere a reactores mejorados para reacciones exotérmicas catalíticas en fase gaseosa, que tienen una zona de entrada (1), una zona de reacción (2) que comprende por lo menos un catalizador (4), y una zona de salida (3) para el gas producto, observadas en la dirección del flujo de un gas reactivo; los reactores tienen medios en la zona de entrada (1), o la zona de entrada (1) y la zona de reacción (2), tales como camisas aislantes (6), y/o dispositivos para transportar un enfriador, que reducen el transporte de calor de la zona de reacción (2) a la zona de entrada (1), y de esta manera los riesgos de preignición de la mezcla usada de gas de reactivo o la activación de reacciones secundarias no deseadas en la zona de entrada (1); y/o las paredes internas del reactor en la zona de entrada (1) o en la zona de entrada (1) y la zona de reacción (2), están hechas de un material inerte; los reactores se pueden usar en particular para la oxidación de amoniaco, tal como en sistemas de producción de ácido nítrico, en donde se usan preferiblemente catalizadores de metal de transición en forma de panal que tienen secciones transversales más pequeñas que las mallas de platino usadas típicamente.
MX2009013236A 2007-06-06 2008-05-28 Dispositivo y metodo para reacciones cataliticas en fase gaseosa y uso de los mismos. MX306391B (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE200710026712 DE102007026712A1 (de) 2007-06-06 2007-06-06 Vorrichtung und Verfahren für katalytische Gasphasenreaktionen sowie deren Verwendung
PCT/EP2008/004232 WO2008148487A1 (de) 2007-06-06 2008-05-28 Vorrichtung und verfahren für katalytische gasphasenreaktionen sowie deren verwendung

Publications (2)

Publication Number Publication Date
MX2009013236A true MX2009013236A (es) 2010-01-25
MX306391B MX306391B (es) 2013-01-03

Family

ID=39688796

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2009013236A MX306391B (es) 2007-06-06 2008-05-28 Dispositivo y metodo para reacciones cataliticas en fase gaseosa y uso de los mismos.

Country Status (17)

Country Link
US (1) US9108175B2 (es)
EP (1) EP2160236B1 (es)
JP (1) JP5155390B2 (es)
KR (1) KR101572013B1 (es)
CN (1) CN101678297B (es)
AU (1) AU2008258890B2 (es)
BR (1) BRPI0812424B1 (es)
CA (1) CA2690002C (es)
CL (1) CL2008001646A1 (es)
DE (1) DE102007026712A1 (es)
EG (1) EG25440A (es)
ES (1) ES2530863T3 (es)
MX (1) MX306391B (es)
RU (1) RU2474469C2 (es)
UA (1) UA97397C2 (es)
WO (1) WO2008148487A1 (es)
ZA (1) ZA200908207B (es)

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US20120183467A1 (en) * 2011-01-14 2012-07-19 GM Global Technology Operations LLC Low temperature oxidation of ammonia in nitric acid production
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DE102013004341A1 (de) 2013-03-14 2014-09-18 Thyssenkrupp Uhde Gmbh Verfahren zur Oxidation von Ammoniak und dafür geeignete Anlage
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Also Published As

Publication number Publication date
JP2010528840A (ja) 2010-08-26
AU2008258890A1 (en) 2008-12-11
BRPI0812424B1 (pt) 2017-03-28
WO2008148487A1 (de) 2008-12-11
DE102007026712A1 (de) 2008-12-11
MX306391B (es) 2013-01-03
KR101572013B1 (ko) 2015-11-26
RU2474469C2 (ru) 2013-02-10
KR20100029820A (ko) 2010-03-17
CN101678297A (zh) 2010-03-24
US9108175B2 (en) 2015-08-18
ES2530863T3 (es) 2015-03-06
ZA200908207B (en) 2011-02-23
CL2008001646A1 (es) 2008-09-26
EG25440A (en) 2012-01-08
AU2008258890B2 (en) 2012-03-08
CA2690002A1 (en) 2008-12-11
JP5155390B2 (ja) 2013-03-06
UA97397C2 (ru) 2012-02-10
EP2160236B1 (de) 2014-12-03
BRPI0812424A2 (pt) 2014-12-02
US20100166631A1 (en) 2010-07-01
CN101678297B (zh) 2015-05-13
CA2690002C (en) 2016-02-09
RU2009149317A (ru) 2011-07-20
EP2160236A1 (de) 2010-03-10

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