MX2008010219A - Proceso para la produccion de fracciones altamente enriquecidas de compuestos naturales provenientes de aceite de palma con fluidos supercriticos y casi criticos. - Google Patents
Proceso para la produccion de fracciones altamente enriquecidas de compuestos naturales provenientes de aceite de palma con fluidos supercriticos y casi criticos.Info
- Publication number
- MX2008010219A MX2008010219A MX2008010219A MX2008010219A MX2008010219A MX 2008010219 A MX2008010219 A MX 2008010219A MX 2008010219 A MX2008010219 A MX 2008010219A MX 2008010219 A MX2008010219 A MX 2008010219A MX 2008010219 A MX2008010219 A MX 2008010219A
- Authority
- MX
- Mexico
- Prior art keywords
- enrichment
- separation
- palm oil
- near critical
- supercritical
- Prior art date
Links
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D15/00—Separating processes involving the treatment of liquids with solid sorbents; Apparatus therefor
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D11/00—Solvent extraction
- B01D11/04—Solvent extraction of solutions which are liquid
- B01D11/0403—Solvent extraction of solutions which are liquid with a supercritical fluid
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D11/00—Solvent extraction
- B01D11/04—Solvent extraction of solutions which are liquid
- B01D11/0403—Solvent extraction of solutions which are liquid with a supercritical fluid
- B01D11/0407—Solvent extraction of solutions which are liquid with a supercritical fluid the supercritical fluid acting as solvent for the solute
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D11/00—Solvent extraction
- B01D11/04—Solvent extraction of solutions which are liquid
- B01D11/0426—Counter-current multistage extraction towers in a vertical or sloping position
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D11/00—Solvent extraction
- B01D11/04—Solvent extraction of solutions which are liquid
- B01D11/0492—Applications, solvents used
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
- B01J20/103—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate comprising silica
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
- C11B1/00—Production of fats or fatty oils from raw materials
- C11B1/10—Production of fats or fatty oils from raw materials by extracting
- C11B1/104—Production of fats or fatty oils from raw materials by extracting using super critical gases or vapours
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/54—Improvements relating to the production of bulk chemicals using solvents, e.g. supercritical solvents or ionic liquids
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Analytical Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Inorganic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Fats And Perfumes (AREA)
- Extraction Or Liquid Replacement (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Treatment Of Liquids With Adsorbents In General (AREA)
Abstract
A partir de aceite de palma se pueden derivar compuestos valiosos similares a tococromanoles, carotenoides, fitoesteroles, y otros. El enriquecimiento a fracciones altamente concentradas se obstaculiza por el inmenso número de componentes implicados, la muy baja volatilidad, la muy baja solubilidad de muchos de los compuestos en solventes orgánicos, y la alta viscosidad de las mezclas que serán procesadas. Los materiales de partida para el proceso novedoso son fracciones enriquecidas de tococromanoles (entre aproximadamente 20 hasta aproximadamente 50% en peso) y/o carotenoides (entre aproximadamente 10 hasta 30% en peso) de aceite de palma obtenido mediante procesos convencionales, o mediante procesos de etapas múltiples a contracorriente con dióxido de carbono supercrítico. Estos procesos, no consignados aquí, pueden comprender: la eliminación de ácidos grasos libres, la transesterificación de triglicéridos a ésteres de metilo o etilo, la eliminación de los ésteres, por ejemplo, mediante destilación de trayectoria corta, separación de la fracción de tococromanol a partir de la fracción de carotenoides mediante enfriamiento. En el proceso novedoso, las fracciones derivadas del aceite de palma crudo, ya enriquecido a algún grado en tococromanoles, carotenoides, fitoesteroles, y otros, se tratará mediante tecnología de fluidos supercríticos en una combinación única de separación a contracorriente con adsorción y desorción selectiva utilizando fluidos supercríticos. Un primer enriquecimiento, que comprende uno o más pasos de separación mediante la aplicación de un fluido casi crítico o uno supercrítico en un proceso de separación de etapa individual o múltiple (contracorriente) se combina adecuadamente con un segundo paso de enriquecimiento en donde el producto del primer paso de enriquecimiento se adsorbe directamente en un adsorbente (gel de sílice) al hacer pasar el flujo del producto sobre un lecho fijo de adsorbente sin cambio de presión sustancial, y la posterior desorción con el mismo (u otro) fluido casi crítico o supercrítico a la misma o una presión diferente como en la primera separación, o mediante una secuencia pre-designada de presiones y temperaturas. Para el enriquecimiento con tococromanol, se utiliza dióxido de carbono a condiciones casi críticas superiores a la temperatura crítica del dióxido de carbono. Para el enriquecimiento con carotenoides, se utiliza propano a condiciones casi críticas por debajo de la temperatura crítica del propano.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP06002687A EP1818388B1 (en) | 2006-02-10 | 2006-02-10 | Process for production of highly enriched fractions of natural compounds from Palm Oil with supercritical and near critical fluids |
PCT/EP2007/000802 WO2007090545A1 (en) | 2006-02-10 | 2007-01-31 | Process for production of highly enriched fractions of natural compounds from palm oil with supercritical and near critical fluids |
Publications (1)
Publication Number | Publication Date |
---|---|
MX2008010219A true MX2008010219A (es) | 2008-10-31 |
Family
ID=36694365
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
MX2008010219A MX2008010219A (es) | 2006-02-10 | 2007-01-31 | Proceso para la produccion de fracciones altamente enriquecidas de compuestos naturales provenientes de aceite de palma con fluidos supercriticos y casi criticos. |
Country Status (14)
Country | Link |
---|---|
US (1) | US8048462B2 (es) |
EP (1) | EP1818388B1 (es) |
JP (1) | JP5189991B2 (es) |
CN (1) | CN101379174B (es) |
AT (1) | ATE466065T1 (es) |
BR (1) | BRPI0706288B8 (es) |
DE (1) | DE602006013933D1 (es) |
EC (1) | ECSP088664A (es) |
ES (1) | ES2345396T3 (es) |
HK (1) | HK1130280A1 (es) |
MX (1) | MX2008010219A (es) |
MY (1) | MY144049A (es) |
NI (1) | NI200800212A (es) |
WO (1) | WO2007090545A1 (es) |
Families Citing this family (20)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
MY148321A (en) * | 2007-10-02 | 2013-03-29 | Malaysian Palm Oil Board Mpob | Vitamin e supplementation to tetanus toxoid |
DE102007061436A1 (de) * | 2007-12-20 | 2009-06-25 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. | Verfahren zur Gewinnung von Fettbegleitstoffen aus Kraftstoffen und Verwendung dieses Verfahrens |
US8747673B2 (en) * | 2008-09-25 | 2014-06-10 | Battelle Energy Alliance, Llc | Methods for recovering a solvent from a fluid volume and methods of removing at least one compound from a nonpolar solvent |
ITTO20080797A1 (it) * | 2008-10-29 | 2010-04-30 | Leonardo Boschetti | Applicazione della tecnologia di estrazione in fase supercritica a diverse materie prime al fine di ottenere principi attivi altamente purificati. |
MY188429A (en) | 2009-01-08 | 2021-12-08 | Sime Darby Plantation Berhad | Refining of edible oil |
WO2011014122A1 (en) * | 2009-07-30 | 2011-02-03 | The Thailand Research Fund | System and method for extracting vitamin e from fatty acid distillates |
CN102061130A (zh) * | 2009-11-13 | 2011-05-18 | 天津市食品研究所有限公司 | 一种从辣椒中提取辣椒油树脂的方法 |
FR2989373B1 (fr) * | 2012-04-16 | 2016-05-06 | Roquette Freres | Procede de raffinage du squalene produit par microalgues |
JP6216769B2 (ja) * | 2012-04-16 | 2017-10-18 | ロケット フレールRoquette Freres | 微細藻類により産生されるスクアレンを精製する方法 |
CN102660378B (zh) * | 2012-04-28 | 2013-11-06 | 青岛佰福得科技有限公司 | 一种用棕榈渣提取天然辅酶q10的方法 |
US10123986B2 (en) | 2012-12-24 | 2018-11-13 | Qualitas Health, Ltd. | Eicosapentaenoic acid (EPA) formulations |
US9629820B2 (en) | 2012-12-24 | 2017-04-25 | Qualitas Health, Ltd. | Eicosapentaenoic acid (EPA) formulations |
US10144874B2 (en) * | 2013-03-15 | 2018-12-04 | Terrapower, Llc | Method and system for performing thermochemical conversion of a carbonaceous feedstock to a reaction product |
MY171445A (en) | 2014-02-11 | 2019-10-15 | Evonik Degussa Gmbh | Method for producing vitamine e-enriched, especially tocotrienol-enriched, compositions from natural oils |
EP3002327A1 (en) * | 2014-10-02 | 2016-04-06 | Sensient Flavors Limited | Process for modifying the composition of essential oils |
US11154795B2 (en) | 2016-10-21 | 2021-10-26 | Novasep Equipment Solutions | Use of compressed gas for moving eluent applied to chromatography |
CN110461810B (zh) | 2017-03-24 | 2022-05-13 | 泰拉能源公司 | 用于通过转化成甲酸来再循环热解尾气的方法和系统 |
US10787610B2 (en) | 2017-04-11 | 2020-09-29 | Terrapower, Llc | Flexible pyrolysis system and method |
US10050677B1 (en) * | 2017-05-23 | 2018-08-14 | Nxp B.V. | Antenna coil tuning mechanism for magnetic communication |
CN113509746B (zh) * | 2021-03-29 | 2022-08-09 | 艾斯普瑞(广州)食品有限公司 | 一种类胡萝卜素芝麻油扯动式浸料系统及其浸料方法 |
Family Cites Families (21)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS6048981A (ja) * | 1983-08-29 | 1985-03-16 | Showa Denko Kk | 高純度トコフェロ−ルの製造方法 |
DE3783502T2 (de) | 1986-04-15 | 1993-05-13 | Lion Corp | Verfahren zur reinigung eines caroten enthaltenden konzentrats. |
US5157142A (en) | 1986-06-17 | 1992-10-20 | Hoechst Celanese Corporation | Thiocarbamates and their derivatives |
DE3834988A1 (de) | 1988-10-14 | 1990-04-19 | Sueddeutsche Kalkstickstoff | Verfahren zur entfernung von terpenen aus etherischen oelen |
US5157132A (en) | 1990-05-18 | 1992-10-20 | Carotech Associates | Integrated process for recovery of carotenoids and tocotrienols from oil |
JP2968893B2 (ja) * | 1992-10-26 | 1999-11-02 | 株式会社神戸製鋼所 | 油脂の精製方法 |
DE4241487C2 (de) * | 1992-12-09 | 1996-07-25 | Indena Spa | Neue Extrakte von Cucurbita sp., Verfahren zu deren Herstellung und deren Verwendung in Arzneimitteln und in der Kosmetik |
AU694134B2 (en) | 1994-03-18 | 1998-07-16 | Malaysian Palm Oil Board | Recovery of carotenes |
DE4429506B4 (de) | 1994-08-19 | 2007-09-13 | Degussa Gmbh | Verfahren zur Extraktion natürlicher Carotinoid-Farbstoffe |
DE4447116A1 (de) * | 1994-12-29 | 1996-07-04 | Sueddeutsche Kalkstickstoff | Verfahren zur Fraktionierung bzw. Raffination von lipiden Naturstoffen |
DE19638459A1 (de) | 1996-09-19 | 1998-03-26 | Peter Siegfried | Verfahren zur Reinigung von Fetten und Ölen tierischen oder vegetabilischen Ursprungs |
US6833149B2 (en) * | 1999-01-14 | 2004-12-21 | Cargill, Incorporated | Method and apparatus for processing vegetable oil miscella, method for conditioning a polymeric microfiltration membrane, membrane, and lecithin product |
MY127954A (en) * | 1999-11-04 | 2007-01-31 | Malaysian Palm Oil Board | A method of chromatographic isolation for non-glyceride components |
MY127451A (en) * | 1999-11-04 | 2006-12-29 | Malaysian Palm Oil Board | A method of chromatographic isolation for vitamin e isomers |
US6629256B1 (en) | 2000-04-04 | 2003-09-30 | Texas Instruments Incorporated | Apparatus for and method of generating a clock from an available clock of arbitrary frequency |
FR2830760B1 (fr) * | 2001-10-12 | 2004-06-04 | Pf Medicament | Procede de preparation d'un compose d'interaction de substances actives avec un support poreux par fluide supercritique |
MY136397A (en) | 2002-08-20 | 2008-09-30 | Malaysian Palm Oil Board Mpob | Recovery of palm phytonutrients |
US7455797B2 (en) * | 2003-02-28 | 2008-11-25 | Ferro Corporation | Method and apparatus for producing particles using supercritical fluid |
MY138963A (en) * | 2003-08-27 | 2009-08-28 | Malaysian Palm Oil Board | One-stage and two-stage supercritical fluid extractions of carotenes concentrate, vitamin e concentrate and other minor components concentrates |
ES2238183B1 (es) * | 2004-02-09 | 2006-12-16 | Consejo Sup. Investig. Cientificas | Procedimiento para obtener compuestos de alto valor añadido a partir de hoja de olivo. |
MY146635A (en) * | 2004-09-01 | 2012-09-14 | Malaysian Palm Oil Board | Specialty palm oil products and other specialty vegetable oil products |
-
2006
- 2006-02-10 ES ES06002687T patent/ES2345396T3/es active Active
- 2006-02-10 AT AT06002687T patent/ATE466065T1/de not_active IP Right Cessation
- 2006-02-10 DE DE602006013933T patent/DE602006013933D1/de active Active
- 2006-02-10 EP EP06002687A patent/EP1818388B1/en not_active Not-in-force
-
2007
- 2007-01-31 JP JP2008553653A patent/JP5189991B2/ja not_active Expired - Fee Related
- 2007-01-31 BR BRPI0706288A patent/BRPI0706288B8/pt not_active IP Right Cessation
- 2007-01-31 MX MX2008010219A patent/MX2008010219A/es active IP Right Grant
- 2007-01-31 MY MYPI20082067A patent/MY144049A/en unknown
- 2007-01-31 WO PCT/EP2007/000802 patent/WO2007090545A1/en active Application Filing
- 2007-01-31 CN CN2007800048422A patent/CN101379174B/zh not_active Expired - Fee Related
- 2007-01-31 US US12/278,813 patent/US8048462B2/en not_active Expired - Fee Related
-
2008
- 2008-08-07 EC EC2008008664A patent/ECSP088664A/es unknown
- 2008-08-08 NI NI200800212A patent/NI200800212A/es unknown
-
2009
- 2009-09-04 HK HK09108101.0A patent/HK1130280A1/xx not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
BRPI0706288B8 (pt) | 2017-10-31 |
HK1130280A1 (en) | 2009-12-24 |
ATE466065T1 (de) | 2010-05-15 |
EP1818388B1 (en) | 2010-04-28 |
WO2007090545A1 (en) | 2007-08-16 |
ECSP088664A (es) | 2008-11-27 |
CN101379174A (zh) | 2009-03-04 |
JP2009530426A (ja) | 2009-08-27 |
JP5189991B2 (ja) | 2013-04-24 |
NI200800212A (es) | 2011-12-15 |
ES2345396T3 (es) | 2010-09-22 |
DE602006013933D1 (de) | 2010-06-10 |
CN101379174B (zh) | 2013-01-16 |
EP1818388A1 (en) | 2007-08-15 |
BRPI0706288A2 (pt) | 2011-03-22 |
MY144049A (en) | 2011-07-29 |
US8048462B2 (en) | 2011-11-01 |
US20090155434A1 (en) | 2009-06-18 |
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